Chromium speciation and mobility in contaminated coastal urban soils affected by water salinity and redox conditions

Abstract

Chromium (Cr) is a redox-sensitive element in contaminated coastal urban soils. Sea level rise (SLR) with subsequent soil inundation may facilitate Cr transformation and mobilization through alterations in local redox conditions and porewater ion composition. We investigated the impact of water salinity and redox conditions on Cr chemistry in these environments. Synchrotron-based X-ray spectroscopy and wet chemical analyses revealed that the soils contained very high levels of Cr (up to 4320 mg kg-1) and that chromite (∼52%) and Fe-Cr hydroxide coprecipitates (∼44%) were the predominant Cr species. The abundance of these two components resulted in low Cr mobility under non-flooded conditions. Chromium(II) was identified in the soils, potentially derived from the waste parent material. Seawater and anoxic conditions resulted in lower Cr release compared to freshwater and aerobic conditions. Up to three to eight times more Cr was released under aerobic conditions versus anaerobic conditions in the freshwater versus saltwater, respectively, with total dissolved Cr values remaining below 0.02 mg L-1. The decrease in Cr release was likely due to Cr reduction by Fe(II) and sulfide. This work provides important information on how salinity and redox fluctuations impact Cr cycling which is likely to occur during SLR.