Μm Thick Electrode Research Articles

A new insight into the oxygen reduction reaction of the Ca3Co4O9+δ/CGO composite air electrode

The calcium cobaltite Ca3Co4O9+δ (CCO) is an emerging electrode for Solid Oxide Fuel Cells or Solid Electrolyser Cells. Thanks to a thermal expansion coefficient which is in the same range of magnitude than the commonly used electrolytes, it should lead to improved durability. However, because the material suffers of a lack of oxide ion conductivity, it has to be used in composite with an ionic conductor. Displaying good compatability with ceria, first studies were carried out on composite with Ce0.9Gd0.1O1.95 (CGO). At 700 °C, an optimal Area Specific Resistance of 0.5 Ω cm2 was obtained for a 50/50 wt.% CCO/ CGO, 21 μm thick electrode, with CCO powder prepared by a solid-state route whose synthesis method led to large grains compared to the CGO powder. Here, to increase the density of triple-phase boundaries between the gas and the two materials, a CCO powder with smaller grain size was prepared using a citrate route. For screen printed 50/50 wt.% CCO (citrate)/CGO composite electrode deposited on symmetrical cell with a CGO electrolyte, an ASR of 0.35 Ω cm2 was achieved at 700 °C, under air. To go further in the understanding of the oxygen reduction reaction, the cell was then carefully studied at variable temperatures and under variable oxygen partial pressures, combining calculation of the distribution function of relaxation times (DFRT) and complex nonlinear least squares fitting (CNLS) of impedance spectra. At 700 °C, under air, it was shown that 55 % of the ASR was due to the oxygen molecule dissociation and diffusion of atomic oxygen species at the surface of the electrode materials. It was only 37 % at 600 °C. Experiment carried out under 21 % of oxygen in helium proved that gas diffusion was a limiting step at temperature higher that 650 °C whereas the redox of CCO was limiting at lower temperature. When deposited on a commercial anode supported 2R-Cell™ half cell, the maximum power density was improved by 284 %, reaching 532 mW/cm2 at 700 °C with a 50/50 wt.% CCO (citrate)/CGO composite air electrode against 187 mW/cm2 for a 50/50 wt.% CCO (solid-state)/CGO composite air electrode at the same temperature.

A Binary Ionogel Electrolyte for the Realization of an All Solid-State Electrical Double-Layer Capacitor Performing at Low Temperature.

Over the last years, solid-state electrolytes made of an ionic liquid (IL) confined in a solid (inorganic or polymer) matrix, also known as ionogels, have been proposed to solve the leakage problems occurring at high temperatures in classical electrical double-layer capacitors (EDLCs) with an organic electrolyte, and thereof improve the safety. However, making ionogel-based EDLCs perform with reasonable power at low temperature is still a major challenge due to the high melting point of the confined IL. To overcome these limitations, the present contribution discloses ionogel films prepared in a totally oxygen/moisture-free atmosphere by encapsulating 70 wt % of an equimolar mixture of 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide and 1-ethyl-3-methylimidazolium tetrafluoroborate - [EMIm][BF4]0.5[FSI]0.5 - into a poly(vinylidene fluoride-co-hexafluoropropylene) (PVdF-HFP) network. The further called "binary ionogel" films demonstrated a high flexibility and a good ionic conductivity of 5.8 mS cm-1 at 20 °C. Contrary to the ionogels prepared from either [EMIm][FSI] or [EMIm][BF4], displaying melting at Tm=-16 °C and -7 °C, respectively, the crystallization of confined [EMIm][BF4]0.5[FSI]0.5 is quenched in the binary ionogel, which shows only a glass transition at -101 °C. This quenching enables an increased ionicity and ionic diffusion at the interface with the PVdF host network, leading the binary ionogel membrane to display higher ionic conductivity below -20 °C than the parent binary [EMIm][BF4]0.5[FSI]0.5 liquid. Laminate EDLCs were built with a 100 μm thick binary ionogel separator and electrodes made from a hierarchical micro-/mesoporous MgO-templated carbon containing a reasonable proportion of mesopores to enhance the mass transport of ions, especially at low temperature where the ionic diffusion noticeably decreases. The EDLCs operated up to 3.0 V with ideal EDL characteristics from -40 °C to room temperature. Their output specific energy under a discharge power of 1 kW kg-1 is ca. 4 times larger than with a cell implementing the same carbon electrodes together with the binary [EMIm][BF4]0.5[FSI]0.5 liquid. Hence, this binary ionogel electrolyte concept paves the road for developing safe and flexible solid-state energy storage devices operating at subambient temperatures in extreme environments.

Conformal Electrodeposition of Mesoporous Silica over High Aspect Ratio (AR>100) Nanomesh Electrodes

The high surface area provided by the nanopores of ordered mesoporous silica thin films enables a wide range of electrochemical applications such as sensors, catalysis, energy storage and ion-selective membranes. Further improvements are possible by coating such thin films on large surface area electrodes with high aspect ratios (> 100) to increase the active surface area. Atomic layer deposition (ALD) is often preferred to deposit conformal thin film oxides on high aspect ratio structures. Such vapor-phase depositions are limited by the available surface reactive sites to deposit thin films of thickness ranging from sub-nanometer to few tens of nanometer. However, there is a tradeoff in terms of deposition time/cycles to achieve quality films especially when high aspect ratios (>100) substrates are introduced. Electrochemistry offers an alternative, versatile method to conformally coat layers on 3D electrode surfaces. The electrochemically assisted self-assembly (EASA) of mesoporous silica, utilizes electrochemical reactions to locally increase the pH near the electrode surface, which in turn catalyzes the silica gelation and surfactant self-assembly, thus causing the controlled growth of mesoporous silica thin films [1]. Recently, our group has shown that good quality mesoporous silica films with thickness between 20-2000 nm could be achieved by controlling the hydrodynamic layer in a rotating disc electrode setup [2]. Moreover, EASA of mesoporous silica offers meso-channels that are aligned perpendicular to the underlaying conductive substrate which is optimal for mass-transport.In this follow-up work, we demonstrate a reliable, electrochemically controlled, conformal deposition of mesoporous silica onto large surface area nanomesh electrodes with an aspect ratio close to 100. Nanomesh electrodes developed in our group at imec, is built up of a regularly spaced (50 nm), inter-connected network of vertical and horizontal nanowires of diameter ~40 nm. These electrodes offer an 80x area enhancement (80 cm2 per geometric cm2) while maintaining a porosity close to 75%. We show that, the extent of silica deposition over these nanomesh electrodes can be electrochemically controlled from conformal coatings (~10 nm thick) uniformly coating the whole nanomesh architecture to complete fill and overfill of the nanomesh electrodes (~4 µm thick). Furthermore, excellent mass-transport properties of various silica coated nanomesh electrodes has been demonstrated using a ruthenium hexaammine redox probe. Finally, the area enhancement offered by the silica coated Ni nanomesh is demonstrated using the characteristic accumulation of a positively charged [Ru(NH3)6]3+ probe within the negatively charged silica nanochannels, which shows 55x increase for the amount of charge from the probe stored in the coated nanomesh, compared to a planar silica layer, consistent with the expected surface area enhancement of the 4 µm thick nanomesh electrodes.

Framework for additive manufacturing of porous Inconel 718 for electrochemical applications

Porous electrodes were developed using laser powder bed fusion of Inconel 718 lattice structures and electrodeposition of a porous nickel catalytic layer. Laser energy densities of ∼83–333 J/m were used to fabricate ∼ 500 µm thick electrodes made of body centered cubic unit cells of 200–500 µm and strut thicknesses of 100–200 µm. Unit cells of 500 µm and strut thickness of 200 µm were identified as optimum. Despite small changes in feature sizes by the energy input, the porosity of >50 % and pore size of ∼ 100 µm did not change. In a subsequent step, we used nickel electrodeposition to create smaller scale pores on the electrode. The electrochemical performance of the electrodes for hydrogen/oxygen evolution reaction (HER/OER) was evaluated in a three-electrode setup. For HER, a much larger maximum current density of ∼−372 mA/cm2 at a less negative potential of ∼−0.4 V vs RHE (potential against reversible hydrogen electrode) was obtained in the nickel-coated samples, as compared to −240 mA/cm2 at ∼−0.6 V in the bare ones, indicating superior performance of the coated samples. Conversely, OER exhibited minor performance differences upon application of the coating, indicating insignificant dependence of OER to surface composition and available surface.

Microstructural and electrochemical properties of Ni-impregnated GDC10 and 8YSZ freeze tape cast scaffolds as fuel electrodes for solid oxide cells

Ni-impregnated Gd0.1Ce0.9O2 and Y0.08Zr0.92O2 fuel electrodes for solid oxide cells are manufactured by the combination of the freeze tape casting and infiltration techniques. Their morphological properties are investigated by scanning electron microscope and X-Ray microtomography while their electrochemical performance is evaluated in symmetrical Y0.08Zr0.92O2-supported button cells by electrochemical impedance spectroscopy. The microstructural analysis of the manufactured scaffolds highlights the characteristic anisotropy of porosity provided by the freeze tape casting method. The average tortuosity factor across the out of plane direction has been calculated equal to 1.38, being considerably lower than the average values of the other components, (τx = 10.2) and (τy = 6.87). The contribution provided by gas diffusion to the overall polarization resistance of the freeze tape cast electrodes has been estimated around 6·10−4 Ω cm2 in the 600–750 °C temperature range, thus lower than the best reported values for the state-of-the-art electrodes featuring sponge-like porosity. The measured impedance data highlighted the higher electrochemical performance of the Ni-impregnated Gd0.1Ce0.9O2 architecture, holding a polarization resistance of 0.823 Ω cm2 at 750 °C, which is regarded as a very promising result for a ∼600 μm thick electrode. The interpretation of the impedance data was supported by the distribution of relaxation times analysis and the complex non-linear least square fit. In particular, the electrochemical investigation highlighted the presence of two major resistive contributions which have been ascribed to the occurrence of a chemical capacitance within the GDC10 lattice (low frequency contribution) and to the multi-layered architecture of the tested symmetrical cells which increases the contact losses (high frequency contribution).

GEM Parçacık Dedektörlerinde Lignoselülozik Malzeme Kullanım Potansiyeli

This study investigates the potential use of lignocellulosic material for Gas Electron Multiplier (GEM) foils in high-energy physics experiments. A 50 µm thick lignocellulosic film was created using a scattering method, and both surfaces were coated with a 2 µm thick copper electrode layer. Electrical characterization studies were conducted to assess the suitability of lignocellulosic material in GEM detectors. To ensure consistent atmospheric conditions during measurements, a special chamber was designed to monitor temperature and humidity values over time using an SHT3x sensor module and Rense Temperature/Humidity Meter. Electrical measurements were performed using a Keithley 4200 semiconductor characterization system, and I-V curves showing the current-voltage relationship under different atmospheric conditions were plotted. The results demonstrate the potential for developing sustainable and efficient detectors for various high-energy physics experiments using GEM detectors with lignocellulosic foils. This study comprehensively presents the advantages and disadvantages of using lignocellulosic material in GEM foils and contributes to the development of more environmentally friendly alternatives for GEM detector manufacturing.

Multielectrode electrochemical cell for in situ structural characterization of amorphous thin-film catalysts using high-energy X-ray scattering

A multielectrode-based electrochemical cell allows the structural characterization of an amorphous thin-film water oxidation catalyst under various electrochemical potentials using high-energy X-ray scattering and atomic pair distribution function (PDF) techniques. A multielectrode with five electrodes provides a sufficiently low background signal to enable high-energy X-ray scattering (HEXS) measurements and amplifies the extremely low HEXS signals from samples for high-resolution PDF analysis of in situ data from thin-film catalysts. Glassy carbon (GC) creates a relatively low intensity HEXS pattern and is used as a working electrode. Instead of a three-dimensional (3D) porous electrode architecture, the flat geometry of the electrode enables various deposition techniques to be used for the preparation of a highly conductive metal oxide layer. PDF analysis demonstrates high spatial resolution for a 230 nm thick amorphous iridium oxide film deposited on two roughened 60 µm thick GC electrodes. The PDF analysis resolves the domain size and distinguishes changes in fine structure which are directly correlated with the structure and function of the catalysts. The results bring the opportunity to analyze the structure of nanometre-scale amorphous thin-film catalysts in an electrolyte-compatible and compact 3D-printed electrochemical cell in a three-electrode configuration.

Thick Electrodes of a Self‐Assembled MXene Hydrogel Composite for High‐Rate Energy Storage

Supercapacitors based on two‐dimensional MXene (Ti3C2Tz) have shown extraordinary performance in ultrathin electrodes with low mass loading, but usually there is a significant reduction in high‐rate performance as the thickness increases, caused by increasing ion diffusion limitation. Further limitations include restacking of the nanosheets, which makes it challenging to realize the full potential of these electrode materials. Herein, we demonstrate the design of a vertically aligned MXene hydrogel composite, achieved by thermal‐assisted self‐assembled gelation, for high‐rate energy storage. The highly interconnected MXene network in the hydrogel architecture provides very good electron transport properties, and its vertical ion channel structure facilitates rapid ion transport. The resulting hydrogel electrode show excellent performance in both aqueous and organic electrolytes with respect to high capacitance, stability, and high‐rate capability for up to 300 μm thick electrodes, which represents a significant step toward practical applications.

Artificial Interphase Design Employing Inorganic–Organic Components for High-Energy Lithium-Metal Batteries

To increase the energy density of today's lithium batteries, it is necessary to develop an anode with higher energy density than graphite or carbon/silicon composites. Hence, research on metallic lithium has gained a steadily increasing momentum. However, the severe safety issues and poor Coulombic efficiency of this highly reactive metal hinder its practical application in lithium-metal batteries (LMBs). Herein, the development of an artificial interphase is reported to enhance the reversibility of the lithium stripping/plating process and suppress the parasitic reactions with the liquid organic carbonate-based electrolyte. This artificial interphase is spontaneously formed by an alloying reaction-based coating, forming a stable inorganic/organic hybrid interphase. The accordingly modified lithium-metal electrodes provide substantially improved cycle life to symmetric Li||Li cells and high-energy Li||LiNi0.8Co0.1Mn0.1O2 cells. For these LMBs, 7 μm thick lithium-metal electrodes have been employed while applying a current density of 1.0 mA cm-2, thus highlighting the great potential of this tailored interphase.

Freestanding carbon nanofoam papers with tunable porosity as lithium-sulfur battery cathodes.

To reach energy density demands greater than 3 mA h cm-2 for practical applications, the electrode structure of lithium-sulfur batteries must undergo an architectural redesign. Freestanding carbon nanofoam papers derived from resorcinol-formaldehyde aerogels provide a three-dimensional conductive mesoporous network while facilitating electrolyte transport. Vapor-phase sulfur infiltration fully penetrates >100 μm thick electrodes and conformally coats the carbon aerogel surface providing areal capacities up to 4.1 mA h cm-2 at sulfur loadings of 6.4 mg cm-2. Electrode performance can be optimized for energy density or power density by tuning sulfur loading, pore size, and electrode thickness.

Ultrafast Sodium Intercalation Pseudocapacitance in MoS2 Facilitated by Phase Transition Suppression

Sodium-ion intercalation pseudocapacitance promises fast energy storage that is cheaper than lithium-ion-based systems. MoS2 is an attractive sodium-ion host due to its large van der Waals gaps, high Na+ mobility, and high electronic conductivity in the 1T phase. In this paper, we have quantified high levels (>90%) of pseudocapacitive charge storage in 30 μm thick MoS2 nanocrystal-based composite electrodes, which can be charged to almost 50% of their 1C capacity in just under 40 s. In addition, very little decay is observed in the delivered capacity (retention of 97%) after 1800 cycles at a rate of 20C. Synchrotron-based operando X-ray diffraction shows that the pseudocapacitive performance is enabled through suppression of the trigonal 1T-MoS2 to triclinic NaxMoS2 phase transition in MoS2 nanocrystals during charge–discharge.

Icing Mitigation by MEMS-Fabricated Surface Dielectric Barrier Discharge

Avoiding ice accumulation on aerodynamic components is of enormous importance to flight safety. Novel approaches utilizing surface dielectric barrier discharges (SDBDs) are expected to be more efficient and effective than conventional solutions for preventing ice accretion on aerodynamic components. In this work, the realization of SDBDs based on thin-film substrates by means of micro-electro-mechanical-systems (MEMS) technology is presented. The anti-icing performance of the MEMS SDBDs is presented and compared to SDBDs manufactured by printed circuit board (PCB) technology. It was observed that the 35 μm thick electrodes of the PCB SDBDs favor surface icing with an initial accumulation of supercooled water droplets at the electrode impact edges. This effect was not observed for 0.3 μm thick MEMS-fabricated electrodes indicating a clear advantage for MEMS-technology SDBDs for anti-icing applications. Titanium was identified as the most suitable material for MEMS electrodes. In addition, an optimization of the MEMS-SDBDs with respect to the dielectric materials as well as SDBD design is discussed.

Proton Radiation Hardness of Perovskite Solar Cells Utilizing a Mesoporous Carbon Electrode

When designing spacefaring vehicles and orbital instrumentation, the onboard systems such as microelectronics and solar cells require shielding to protect them from degradation brought on by collisions with high‐energy particles. Perovskite solar cells (PSCs) have been shown to be much more radiation stable than Si and GaAs devices, while also providing the ability to be fabricated on flexible substrates. However, even PSCs have their limits, with higher fluences being a cause of degradation. Herein, a novel solution utilizing a screen‐printed, mesoporous carbon electrode to act bi‐functionally as an encapsulate and the electrode is presented. It is demonstrated that the carbon electrode PSCs can withstand proton irradiation up to 1 × 1015 protons cm−2 at 150 KeV with negligible losses (<0.07%) in power conversion efficiency. The 12 μm thick electrode acts as efficient shielding for the perovskite embedded in the mesoporous TiO2. Through Raman and photoluminescence spectroscopy, results suggest that the structural properties of the perovskite and carbon remain intact. Simulations of the device structure show that superior radiation protection comes in conjunction with good device performance. This work highlights the potential of using a carbon electrode for future space electronics which is not limited to only solar cells.

Stable Cycling of a 4 V Class Lithium Polymer Battery Enabled by In Situ Cross-Linked Ethylene Oxide/Propylene Oxide Copolymer Electrolytes with Controlled Molecular Structures.

Commercial lithium-ion batteries are vulnerable to fire accidents, mainly due to volatile and flammable liquid electrolytes. Although solid polymer electrolytes (SPEs) are considered promising alternatives with antiflammability and processability for roll-to-roll mass production, several requirements have not yet been fulfilled for a viable lithium polymer battery. Such requirements include ionic conductivity, electrochemical stability, and interfacial resistance. In this work, the ionic conductivity of the SPEs is optimized by controlling the molecular weight and structural morphology of the plasticizers as well as introducing propylene oxide (PO) groups. Electrochemical stability is also enhanced using ethylene oxide (EO)/PO copolymer electrolytes, making the SPEs compatible with high-Ni LiNixCoyMn1-x-yO2 cathodes. The in situ cross-linking method, in which a liquid precursor first wets the electrode and is then solidified by a subsequent thermal treatment, enables the SPEs to soak into the 60 μm thick electrode with a high loading density of more than 8 mg cm-2. Thus, interfacial resistance between the SPE and the electrode is minimized. By using the in situ cross-linked EO/PO copolymer electrolytes, we successfully demonstrate a 4 V class lithium polymer battery, which performs stable cycling with a marginal capacity fading even over 100 cycles.

Additive manufacturing enabled, microarchitected, hierarchically porous polylactic-acid/lithium iron phosphate/carbon nanotube nanocomposite electrodes for high performance Li-Ion batteries

The growing need for higher capacity, faster charging-rate, longer cycle-life, and less expensive Li-ion batteries (LIBs) requires architectured cathodes and novel manufacturing strategies. Herein, we report the charge/discharge performance of microarchitected, hierarchically porous nanocomposite cathodes, composed of biodegradable polylactic-acid (PLA)/LiFePO4 (LFP)/carbon nanotube (CNT) enabled by 3D printing. We realize LFP/PLA/CNT cathodes with different CNT loadings (3, 5, 7, and 10 wt%), interconnected porosities (10%, 30%, 50%, and 70%) and thicknesses (100, 200 and 300 μm) by utilizing in-house nanoengineered filaments. The nanocomposite cathodes exhibit a specific capacity of 155 and 127 mAh g−1 and an areal capacity of 1.7 and 4.4 mAh cm−2 for 100 and 300 μm thick electrodes, respectively, at 0.39 mA cm−2. Moreover, we observe that the specific capacity of the thicker electrode (300 μm) enhances from 125 to 151 mAh g−1 without any loss in areal capacity with increase in porosity. The results demonstrate that the effect of thickness on the specific capacity can be negated by engineering desired porosity, and thereby specific and areal capacities can simultaneously be enhanced. The convergence of emerging nanoscale additive manufacturing and the ability to design ever-more-tightly controlled nano- and micro-architected hierarchical structures will enable the creation of high-performance LIBs.

Impact of Total Ionic- and Individual Li+-Conduction in Dual-Cation Electrolytes on Power Performances for Thick Electrode Li4Ti5O12//AC Hybrid Capacitors

The utilization of dual-cation electrolytes constructed with a Li-based electrolyte (LiBF4) and an additional supporting electrolyte (quaternary ammonium salts or ionic liquids) is a promising strategy toward simultaneously achieving thick-electrode (∼100 μm) Li-based energy storage devices with high power and high energy densities. We observed that 1-ethyl-3-methylimidazolium tetrafluoroborate was suitable for the dual-cation electrolyte in a Li4Ti5O12 (LTO)//activated carbon (AC) (LTO//AC) hybrid capacitor, showing 64% capacity retention at a high current density of 200 mA cm–2. The EMI-based dual-cation system exhibited the highest total ionic conductivity and output characteristics compared to other dual-cation systems even with lowered Li+ transport in the bulk electrolyte. The simulation of the charge-transfer resistance (Rct) based on the transmission line model shows that the dual-cation electrolyte with high ionic conduction mitigates the Rct distribution within the macropores of a 200 μm thick LTO electrode, resulting in a decrease of the mean value of Rct. A combination of spectroscopic analysis and electrochemical characterization at different electrolyte compositions revealed that a good balance between the total ionic and individual Li+-conductivities should be found by controlling the concentration ratio between Li-based and supporting electrolytic salts in order to extract the maximum performance of the thick-electrode LTO//AC systems.

A wideband picosecond pulsed electric fields (psPEF) exposure system for the nanoporation of biological cells

The effects and mechanisms of ultrashort and intense pulsed electric fields on biological cells remain some unknown. Especially for picosecond pulsed electric fields (psPEF) with a high pulse repetition rate, electroporation or nanoporation effects could be induced on cell membranes and intracellular organelle membranes. In this work, the design, implementation, and experimental validation of a wideband psPEF exposure system (WPES) is reported, comprising picosecond pulser and wideband biochip, for the in vitro exposure of suspended cells to high-intensity psPEF. Excited by repetitive picosecond pulses (the duration of 200 ps and the amplitude of a few kilovolts), the proposed biochip adopts grounded coplanar waveguide (GCPW) for a wide working bandwidth, which was fabricated with 160 μm thick electrodes for uniform distribution of psPEF in the cross-section. To ensure that only psPEF is generated in the biological medium containing cells except for ionic current, this work proposes to install capillary tubes in the electrode gaps for electrical insulation and cells delivery. By electrical measurements in the time domain and frequency domain, the exposure system is adapted for local generation of extremely high-intensity psPEF with the 3 dB bandwidth up to 4.2 GHz. Furthermore, biological experiments conducted on the developed exposure system verified its capability to permeabilize biological cells under the exposure of high-intensity psPEF.

Fast Charging of Li-Ion Cells: Part V. Design and Demonstration of Protocols to Avoid Li-Plating

Fast charging of Li-ion batteries would make “fueling” of electric vehicles comparable in time to fueling of gasoline-powered cars, increasing consumer appeal of the new technology. Taking the US Department of Energy goal of safe 6 C charging to 80% capacity as a guide, we describe approaches that can mitigate Li plating on the graphite anode. To make this possible, a variable-rate anode potential charging protocol has been implemented by using a microprobe reference electrode to continuously monitor and adjust the current, in this way avoiding low anode potentials that favor Li deposition. Various implementations of the anode potential control are considered using electrochemical modeling and compared with the experimental data. For charge to 80% capacity at 30 °C, an average C-rate of 4.97 C was obtained for an NCM523/graphite cell with 70 μm thick graphite electrode and 7.40 C for a cell with 47 μm thick graphite electrode. Our electrochemical model accounts for these observations and provides a means to extrapolate the approach to other cell designs and operation regimes, drawing the maximum average fast charging rates that can still avoid Li plating.

Effects of Thinner Compliant Electrodes on Self-Clearability of Dielectric Elastomer Actuators

A metalized plastic capacitor stands a higher chance to clear faults when embodied with thinner electrodes. However, it is not clear whether the same thickness effect applies to carbon-based compliant electrodes in clearing the defects in dielectric elastomer actuators (DEA). This experimental study showed that charcoal-powder compliant electrodes act like fuses and current limiters to successfully clear the defects of an acrylic dielectric elastomer actuator, provided a very thin electrode coating. For example, DEAs with 3 μm thick (average) charcoal-powder electrodes fast cleared faults and sustained high breakdown strength (300 to 400 MV/m), but the ones with thicker charcoal-powder electrodes (30 μm thick on average) succumbed to persisting breakdowns in a weaker electric field (200 to 300 MV/m). Thermo-gravitational analysis and differential scanning calorimetry showed that dielectric elastomer (3M VHB F9473PC) started to ignite at 350 ∘C, and charcoal powders (Mungyo charcoal pastel MP-12CP) started burning above 450 ∘C. This confirmed that flash ignition and its damping of charcoal powder is possible only with a very thin electrode coating relative to acrylic elastomer substrate thickness. Too thick of a charcoal-powder coating could lead to the spread of burning beyond the initial flash point, and incomplete burning that punctures the dielectric layer but shorts across opposite electrodes. With this insight, one can design self-clearable electrodes to improve the dielectric strength of dielectric elastomer actuators.

High energy and high power density supercapacitor with 3D Al foam-based thick graphene electrode: Fabrication and simulation

Thick electrode was promising to increase the energy density in device (battery or supercapacitor) scale, but always suffered the ion polarization upon high rate discharge. We reported the use of 3D Al foam (current collector) to host graphene (with high surface area but very low packing density) to fabricate 450 ​μm thick electrode with mass loading of 10–15 ​mg ​cm−2. The space confinement effect of Al wires on graphene at any regions offered sufficient ordered diffusion channel of liquids, alleviating the ion polarization significantly, compared to the same thick graphene sheet pasted on 2D Al foil by simulation with COMSOL software. The 100 ​F pouch supercapacitor with ionic liquids at 4 ​V exhibited low contact resistance, high specific capacitance in a wide range of current densities, and simultaneously the volumetric energy density of 18 ​Wh L−1 and the power density of 5 ​kW ​kg−1, far better than those of current commercial device.