Plastic Mixtures Research Articles

High-voltage Electrostatic Separation and Equivalent Reuse of Plastics Used in Passenger Vehicle

The recycling and high-valued added reuse of automotive plastics have elicited global attention as the number of end-of-life vehicles increase. In the paper, the two-stage high-voltage electrostatic separation is used to explore the sorting of passenger vehicle plastic mixtures of PP, ABS and PVC. The purities of PP, ABS and PVC are all higher than 97%, and the recovery rates are 55%, 93%, and 48%, respectively. Taking PP plastic as an example, the mechanical properties of the recycled materials and the different ratios of recycled and new material mixtures are studied. Results show that the passenger car bumpers reproduced with a 7:3 ratio of new and recycled materials can satisfy the performance requirements. The finding provides a reference for the high additional value reuse of other automotive plastics.

Preliminary investigation of microorganisms potentially involved in microplastics degradation using an integrated metagenomic and biochemical approach

Plastic pollution is becoming an emerging environmental issue due to inappropriate disposal at the end of the materials life cycle. When plastics are released, they undergo physical and chemical corrosion, leading to the formation of small particles, commonly referred to as microplastics. In this study, a microbial community derived from the leachate of a bioreactor containing a mixture of soil and plastic collected during a landfill mining process underwent an enrichment protocol in order to select the microbial species specifically involved in plastic degradation. The procedure was set up and tested on polyethylene, polyvinyl chloride, and polyethylene terephthalate, both in anaerobic and aerobic conditions. The evolution of the microbiome has been monitored using a combined approach based on microscopy, marker-gene amplicon sequencing, genome-centric metagenomics, degradation assays, and GC–MS analyses. This procedure permitted us to deeply investigate the metabolic pathways potentially involved in plastic degradation and to depict the route for microplastics metabolization from the enriched microbial community. Six enzymes, among the ones already identified, were found in our samples (alkane 1-monooxygenase, cutinase, feruloyl esterase, triacylglycerol lipase, medium-chain acyl-CoA dehydrogenase, and protocatechuate 4,5-dioxygenase) and new enzymes, addressed as MHETases most probably for the presence of the catalytic triad (His-Asp-Ser), were detected. Among the enzymes involved in plastics degradation, alkane 1-monooxygenase was found in high copy number (between ten and 62 copies) in the metagenomes that resulted most abundant in the microbiome enriched with polyethylene, while protocatechuate 4,5-dioxygenase was found between one and eight copies in the most abundant metagenomes of the microbial culture enriched with polyethylene terephthalate. Degradation assays, performed using both bacterial lysates and supernatants, revealed interesting results on polyethylene terephthalate degradation. Moreover, this study demonstrates to what extent different types of microplastics can affect the microbial community composition. The results obtained significantly increase the knowledge of the plastic degradation process.

Sustainable Valorization of E-Waste Plastic through Catalytic Pyrolysis Using CO2

A massive amount of waste of electrical and electronic equipment (E-waste) is being discarded as a solid waste. A valorization platform for the organic part in E-waste has not been fully matured, while metallic compounds have been properly recycled. In these respects, a reliable disposal platform for complex plastic compounds in E-waste is developed in this study. Using a pyrolysis platform, the complicated plastic mixture in E-waste was valorized into value-added products. To deliberate a more environmentally benign process, CO2 was used as a cofeedstock. As a model E-waste, LCD monitor waste (LMW) was tested. The exact types of plastics in LMW (polyacrylonitrile, polybutadiene, polystyrene, poly(methyl methacrylate), polyethylene terephthalate, and polycarbonate) and their mass fractions were determined. From pyrolysis of LMW, the heterogeneous mixture of liquid (toxic) hydrocarbons was generated. To selectively convert/detoxify hydrocarbon into syngas (H2/CO), catalytic pyrolysis was applied. A Ni catalyst led to chemical bond scissions, improving H2 formation. When CO2 was fed as a cofeedstock, volatile hydrocarbons were further turned into CO through chemical reactions between CO2 and hydrocarbons. This synergistic effect of CO2 and Ni catalyst improved syngas formation more than 15 times. CO2 also greatly extended the stability of a catalyst, effectively preventing coke formation.

Plasticizers and Salt Concentrations Effects on Polymer Gel Electrolytes Based on Poly (Methyl Methacrylate) for Electrochemical Applications.

This work describes the electrochemical properties of a type of PMMA-based gel polymer electrolytes (GPEs). The gel polymer electrolyte systems at a concentration of (20:80) % w/w were prepared from poly (methyl methacrylate), lithium perchlorate LiClO4 and single plasticizer propylene carbonate (PMMA-Li-PC) and a mixture of plasticizers made by propylene carbonate and ethylene carbonate in molar ratio 1:1, (PMMA-Li-PC-EC). Different salt concentrations (0.1 M, 0.5 M, 1 M, 2 M) were studied. The effect of different plasticizers (single and mixed) on the properties of gel polymer electrolytes were considered. The variation of conductivity versus salt concentration, thermal properties using DSC and TGA, anodic stability and FTIR spectroscopy were used in this study. The maximum ionic conductivity of σ = 0.031 S/cm were obtained for PMMA-Li-PC-EC with a salt concentration equal to 1 M. Ion-pairing phenomena and all ion associations were observed between lithium cations, plasticizers and host polymers through FTIR spectroscopy. The anodic stability of the PMMA-based gel polymer electrolytes was recorded up to 4 V. The glass temperatures of these electrolytes were estimated. We found they were dependent on the plasticization effect of plasticizers on the polymer chains and the increase of the salt concentration. Unexpectedly, it was determined that an unreacted PMMA monomer was present in the system, which appears to enhance ion conduction. The presence and possibly the addition of a monomer may be a technique for increasing ion conduction in other gel systems that warrants further study.

Stepwise flotation separation of WEEE plastics by polymeric aluminum chloride towards source control of microplastics

The mismanagement of waste electrical and electronic equipment (WEEE) resulted in numerous discarded plastics in the natural environment, and these waste plastics might experience aging, breaking, and migration, which becomes a crucial microplastic source. Sustainable management of WEEE plastics presents a considerable opportunity for resource recovery and microplastic pollution prevention. Flotation separation is a significant process of mechanical recycling, while most flotation methods can only deal with binary plastic mixtures. In this work, an advanced, stepwise, and sustainable flotation method was advocated to separate multi-plastics by polymeric aluminum chloride (PAC) modification. The abundant hydrophilic groups and environmental friendliness of PAC prompted us to further investigate the wetting effect. PAC had varied hydrophilization effects on acrylonitrile butadiene styrene (ABS) and polystyrene (PS) surfaces, but polyethylene terephthalate (PET) retained hydrophobicity. Treatment conditions, including PAC dosage, temperature, time, and pH were optimized. 100% of PET could be purified after primary separation, and the purities of ABS and PS could reach 100% and 97.4% after secondary separation, respectively. The strength of the interaction was determined by the different surface potentials and functional groups. In PAC solution, long-chain molecules or ions might interact with plastic surfaces electrostatically, and Al3+ could bridge long-chain molecules and plastic surfaces, thereby strengthening the polymer hydrophilicity. We further improved the PAC treatment process, and the reuse of PAC reduced modifier usage to 84.4 g/ton waste plastics, which was cost-effective in industrial applications. A preliminary evaluation of the energy consumption and environmental impact indicated that PAC treatment was superior to other modification methods. This work is an initial attempt at the stepwise separation of waste plastic and shows promising prospects for recycling plastic waste.

Plastic Interactions with Pollutants and Consequences to Aquatic Ecosystems: What We Know and What We Do Not Know.

Plastics are a group of synthetic materials made of organic polymers and some additives with special characteristics. Plastics have become part of our daily life due to their many applications and uses. However, inappropriately managed plastic waste has raised concern regarding their ecotoxicological and human health risks in the long term. Due to the non-biodegradable nature of plastics, their waste may take several thousands of years to partially degrade in natural environments. Plastic fragments/particles can be very minute in size and are mistaken easily for prey or food by aquatic organisms (e.g., invertebrates, fishes). The surface properties of plastic particles, including large surface area, functional groups, surface topography, point zero charge, influence the sorption of various contaminants, including heavy metals, oil spills, PAHs, PCBs and DDT. Despite the fact that the number of studies on the biological effects of plastic particles on biota and humans has been increasing in recent years, studies on mixtures of plastics and other chemical contaminants in the aquatic environment are still limited. This review aims to gather information about the main characteristics of plastic particles that allow different types of contaminants to adsorb on their surfaces, the consequences of this adsorption, and the interactions of plastic particles with aquatic biota. Additionally, some missing links and potential solutions are presented to boost more research on this topic and achieve a holistic view on the effects of micro- and nanoplastics to biological systems in aquatic environments. It is urgent to implement measures to deal with plastic pollution that include improving waste management, monitoring key plastic particles, their hotspots, and developing their assessment techniques, using alternative products, determining concentrations of micro- and nanoplastics and the contaminants in freshwater and marine food-species consumed by humans, applying clean-up and remediation strategies, and biodegradation strategies.

Unifying Step-Growth Polymerization and On-Demand Cascade Ring-Closure Depolymerization via Polymer Skeletal Editing

The inherent skeletal and thermal features to forge polymers by step-growth polymerization are conflicting with any depolymerization strategies via cascade back-biting reactions that necessitate adequate ceiling temperature, spacers, and functionalities to create cyclic compounds. Here, we report the edition of step-growth poly(carbonate-urea)s and poly(carbonate-amide)s that are depolymerized on demand into their native precursor or added-value offspring oxazolidinones, together with a hemiacetal cyclic carbonate. The unprotected in-chain secondary amide or urea functionalities of the polymers trigger their degradation via cascade ring-closing events upon a thermal switch (from 25 to 80 °C) in the presence of an organic base as a catalyst. Although most studies are realized in solution for understanding the deconstruction process, the polymers are also fully degraded in 2 h in neat conditions without any catalyst at 150 °C. At 80 °C, the organic base is required to accelerate the process. On the road to sustainability and circularity, we validate the concept by exploiting monomers designed from waste CO2 and upcycled commodity plastics. Ultimately, these polymers are selectively depolymerized from plastic mixtures composed of commodity poly(ethylene terephthalate) and polycaprolactone, offering new options for recycling plastic waste mixtures while delivering high-value-added chemicals.

Impact of Environmental Pollution on Female Reproduction

The increased pollution in the world atmosphere is a global concern. Water, air, and soil are polluted by various sources, such as farm fertilizer, sewage industrial waste products, fumes, and plastics, which in turn impact human health. Plastics and other mixtures of waste affect live in the water. Moreover, the ecosystem is disrupted by the use of heavy metal-containing chemicals in agriculture, and those are eventually consumed by humans. The consequences are a significant negative impact on health including reproductive health, which impairs fertility in the human population. Reproductive functions are severely affected by different chemicals which may interfere with hormonal functions. Greater consequences are faced by the women as the number of germ cells present in the ovary is fixed during fetal life, and which are nonrenewable. From the production of ovum to fertilization, to implantation, and finally continuation of pregnancy, all are affected by the heavy metals and endocrine disruptors. Lifestyle modifications such as consumption of organic foods, plastic product avoidance, separation of residential areas from industrial/agricultural areas, proper waste disposal, and so on, may help to improve the situation.

Thermo-catalytic conversion of waste plastics into surrogate fuels over spherical activated carbon of long-life durability

Recovery of value-added fuels or chemicals from waste plastics by pyrolysis is a promising way to eliminate the waste plastics accumulation and alleviate the energy crisis, while developing efficient catalysts of high durability remains a challenge. Herein, activated carbon spheres of various surface chemistry were fabricated and subsequently used in ex-situ catalytic pyrolysis of low-density polyethylene to produce jet fuel and gasoline-ranged hydrocarbons. Experiment results indicate that with the increase of activation time and temperature, the acidity of activated carbon increased slightly owning to the oxygen-containing functional groups increased, and the specific surface area reached the maximum value (707 m2/g) at the activation condition of 800℃ for 60 min. The enlarged specific surface area promotes the C-C bond cleavage that releases more small gases at the expense of liquid yield, and the increase in density of oxygen-containing functional groups and acidity boosts the formation of aromatic hydrocarbons in liquid. When the activated carbon spheres were activated at 800℃ for 80 min, 100% of the hydrocarbons in the liquid belonged to jet fuel and gasoline, and their selectivity was 81.70 area.% and 96.25 area.%, respectively. More importantly, the catalyst exhibits excellent catalytic activity after four reactivation cycles, where the quality of the liquid product is similar to or even better than that achieved by the fresh catalyst. Furthermore, the catalyst still showed excellent performance in the catalytic pyrolysis of waste plastic mixture.

Production and Analysis of the Physicochemical Properties of the Pyrolytic Oil Obtained from Pyrolysis of Different Thermoplastics and Plastic Mixtures.

The constant search for the proper management of non-degradable waste in conjunction with the circular economy makes the thermal pyrolysis of plastics an important technique for obtaining products with industrial interest. The present study aims to produce pyrolytic oil from thermoplastics and their different mixtures in order to determine the best performance between these and different mixtures, as well as to characterize the liquid fraction obtained to analyze its use based on said properties. This was carried out in a batch type reactor at a temperature of 400 °C for both individual plastics and their mixtures, from which the yields of the different fractions are obtained. The liquid fraction of interest is characterized by gas chromatography and its properties are characterized by ASTM standards. The product of the pyrolysis of mixtures of 75% polystyrene and 25% polypropylene presents a yield of 82%, being the highest, with a viscosity of 1.12 cSt and a calorific power of 42.5 MJ/kg, which has a composition of compounds of carbon chains ranging between C6 and C20, for which it is proposed as a good additive agent to conventional fuels for industrial use.

Pyrolysis of mixed plastic waste (DKR-350): Effect of washing pre-treatment and fate of chlorine

Pyrolysis of a post-consumer plastic waste stream (DKR-350) has been performed at a laboratory scale in a fixed-bed reactor at 500 °C. DKR-350 is a complex mixture of post-consumer plastics comprising polyethylene, polypropylene, polystyrene, polyethylene terephthalate, clogged materials, multilayer flexibles, together with considerable amounts of biogenic and inorganic residues and halogens. The influence of different washing procedures on feedstock composition and pyrolysis product yields was investigated. Washing effectively lowers the biogenic, inorganic and halogen contents in DKR-350, though does not affect the yield of the desired oil/wax (66 to 69 wt%). 27% of the oil/wax lies in the boiling point range of naphtha and gasoline (< 200 °C). During pyrolysis, the oxygen content of the oil/wax is reduced to 8–14 wt%, compared to 10–16 wt% in the feed. Chlorine analysis revealed that most of the chlorine present in the feed is removed by washing. Nevertheless, the concentration of chlorine in the oil/wax is still high (>150 ppm), showing the presence of recalcitrant organochlorides in the feed. Thus, post-treatment is still required to upgrade it to feedstock for the production of fuels and/or chemicals.

Substitution Garden and Polyethylene Terephthalate (PET) Plastic Waste as Refused Derived Fuel (RDF)

The generation of polyethylene terephthalate (PET) plastic and garden waste must be recycled to support the circular economy. An alternative way to reduce the plastics waste is to reduce this waste by converting it into energy such as Refused Derived Fuel (RDF) as an alternative for processing waste. Substitution of plastic and garden waste is an opportunity to be analyzed. Hence, This study aimed to investigate the potential for converting material substitution from PET and garden waste into RDF. The RDF characterized test method was carried out by proximate, water content, ash content, and analysis. At the same time, the calorific value. was tested by bomb calorimetry. Substitution of the mixture of plastic and garden waste affects each parameter of RDF pellet quality including water, ash, and caloric value (sig.&lt; 0.05). The increase of plastic waste in pellets consistently increases the calorific value of RDF from 18.94 until 25.04 MJ/kg. The RDF pellet water and ash content also invariably affect the rate of increase in the calorific value of RDF in the multilinearity model (sig.&lt;0.05; R2 is 0.935). The thermal stability of the pellets occurred at a temperature of 5000C decomposition of hemicellulose, cellulose, and lignin in mixed garden waste with plastic in RDF pellets. The decrease in the decomposition of PET into terephthalic acid monomer from the thermal stability of raw materials and waste PET plastic pellets occurs at a temperature of 4500˚C. This potential finding can be used as a basis for consideration in regions or countries that have the generation of garden waste and plastic, especially the type of PET to be used as an environmentally friendly fuel.

Evaluation of lab performance of stamp sand and acrylonitrile styrene acrylate waste composites without asphalt as road surface materials

Acrylonitrile styrene acrylate (ASA) plastic and stamp sand are both waste materials that impose a significant burden on the environment. This study investigates the potential of using stamp sand and ASA plastic composite as the pavement structure. It should be noted that this new material does not use the asphalt binder. A series of lab tests usually used for asphalt pavement materials were employed for the stamp sand and ASA plastic composite material. The high-temperature properties were analyzed by the Hamburg wheel tracking device (HWTD), while the low-temperature performance was measured by the disc-shaped compact tension (DCT) test. The tensile strength ratio (TSR) was used to determine the moisture susceptibility and the dynamic modulus was used to assess the deformation characterize under various loads and frequencies, the coefficient of permeability was estimated by the water permeability test, and the mass loss of aggregate was estimated by the Cantabro loss test. The dynamic modulus results showed that the ASA mixtures have improved high-temperature deformation resistance as compared to the asphalt mixtures. The ASA mixture with 40% sand showed higher stiffness than the ASA mixture with 30% sand. The ASA mixtures have excellent rutting resistance and moisture damage resistance. The fracture energy of the asphalt mixture is 42–77% higher than the ASA mixture. The tensile strength ratio of the ASA and asphalt mixture are all larger than 0.8 and therefore satisfy the Superpave specification. The average coefficient of permeability of the ASA mixture is 6–10 times higher than the asphalt mixture in the same air void level. The average aggregate loss percent of the ASA mixtures is 9.2–10.8 times higher than asphalt mixtures. In summary, the implementation of stamp sand and ASA plastic mixtures may be a successful solution to mitigate the environmentally harmful effects of waste plastic and stamp sand, as well as assist in offsetting the cost and negative effects of the asphalt mixtures typically used for road surfaces.

Effect of Temperature, Concentration, and Type of Plasticizer on Edible Pectin Film Characteristics of Mango Peel (Mangifera indica L.)

Plastic is a polymer product that is widely used by the community and is generally non-degradable. Its high usage makes plastic a source of waste that is difficult to decompose. It is important to transform the use of degradable materials as packaging by the community in an effort to overcome plastic waste. The edible film is an environmentally friendly packaging medium, which is generally synthesized from a mixture of pectin, plasticizer, and tapioca starch by heating and stirring. This study aims to study the effect of mixing temperature, pectin concentration, and type of plasticizer on the characteristics of the edible film. The temperature was varied at 70 o C, 80 o C, and 90 o C, with variations in pectin concentrations of 1%, 2%, and 3%. The types of plasticizers used were glycerol, sorbitol, and polyethylene glycol (PEG 400). The characteristics of the edible film were tested from thickness, tensile strength, elongation, and solubility. In the range of variables studied, the optimum conditions for producing the best edible film characteristics were 70 o C, 3% pectin, and the plasticizer of glycerol, giving solubility of 0.670 g water/g edible film, the thickness of 0.392 mm, the tensile strength of 3.200 MPa, and elongation of 0.134.

Thermal and Catalytic Pyrolysis of Urban Plastic Waste: Modified Mordenite and ZSM-5 Zeolites

Zeolites have been successfully applied as catalysts in the pyrolysis of plastics to obtain valuable lower molecular weight hydrocarbon compounds. In the present work, mordenite was directly synthesized and chemically modified from commercial mordenite to increase pore volume. For the first time, the performance of these mordenites was compared with that of an alkali-treated ZSM-5 as catalysts for assisting the pyrolysis of simulated urban plastic waste. The investigated zeolites were: (i) as-supplied synthetic ZSM-5 (ZSM-5/AS); (ii) 0.2 M NaOH treated ZSM-5 (ZSM-5/02); (iii) as-supplied mordenite (MOR/AS); (iv) 0.2 M NaOH treated mordenite (MOR/02); and (v) synthetic lab-developed mordenite (MOR/SD). The modified and synthesized zeolites were individually applied as catalysts in the 700 °C pyrolyzes of combined polyethylene, polypropylene, and polystyrene wastes in a mixture simulating most plastics found in Rio de Janeiro (Brazil) city garbage composition. X-ray diffraction revealed crystallite sizes of all zeolites in a nanometric range from 17 to 43 nm. Textural analysis disclosed the alkali-treated ZSM-5/02 with a superior external surface area, 153 m²/g, and mesopore volume equal to 0.253 cm3/g. Lower values were obtained by MOR/02 (39 m²/g and 0.072 cm3/g). The pyrolysis of the plastic mixture with ZSM-5/02 presented a lower initial degradation temperature, 387 °C, followed by MOR/02, with 417 °C. The ZSM-5/02 catalyst obtained the highest conversion in the pyrolysis of the plastic mixture, totaling 49.2%. However, pyrolysis assisted by the MOR/02 catalyst showed the largest fraction (81.5%) of light hydrocarbons.

Can COVID-19 pandemic change plastic contamination? The Case study of seven watercourses in the metropolitan city of Milan (N. Italy)

The more or less extensive lockdowns, quarantines, smart working and the closure of numerous recreational or personal care activities due to the COVID-19 pandemic have not only heavily changed the habits and behaviors of all of us, but have also had consequences on the release of some types of pollutants. The aim of this study was to evaluate the possible changes due to the indirect effects of the pandemic in the contamination of plastic mixtures sampled in 9 sites of the main watercourses of the metropolitan city of Milan (N. Italy), which is one of the major industrialized and urbanized areas in Italy. To achieve this goal, we carried out two sampling campaigns, the first one carried out in November 2019, before the arrival of the SARS-CoV-2 virus in Italy, the second in November 2020, during a severe regional lockdown that coincided with other restrictions imposed at the national level.The main results showed a difference in contamination of plastics between the two samplings, not so much due to a quantitative variation, but certainly qualitative. We obtained non-homogeneous data with respect to changes in the number of plastics sampled in the different waterbodies, while it was evident that the plastics' contamination has shifted from a primary and industrial origin to one due to a secondary origin of the sampled plastics, linked especially to the fragmentation of common use objects, or deriving from synthetic garments.

Development and Investigation of Zein and Cellulose Acetate Polymer Blends Incorporated with Garlic Essential Oil and β-Cyclodextrin for Potential Food Packaging Application

The obtainment of new materials with distinct properties by mixing two or more polymers is a potential strategy in sustainable packaging research. In the present work, a blend of cellulose acetate (CA) and zein (60:40 wt/wt CA:zein) was manufactured by adding glycerol or tributyrin as plasticizers (30% wt/wt), and garlic essential oil (GEO), complexed (IC) or not with β-cyclodextrin (βCD), to produce active packaging. Blends plasticized with tributyrin exhibited a more homogeneous surface than those containing glycerol, which showed major defects. The blends underperformed compared with the CA films regarding mechanical properties and water vapor permeability. The presence of IC also impaired the films’ performance. However, the blends were more flexible than zein brittle films. The films added with GEO presented in vitro activity against Listeria innocua and Staphylococcus aureus. The IC addition into films, however, did not ensure antibacterial action, albeit that IC, when tested alone, showed activity against both bacteria. These findings suggest that the mixture of CA and plasticizers could increase the range of application of zein as a sustainable packaging component, while essential oils act as a natural bioactive to produce active packaging.

Dechlorination during pyrolysis of plastics: The potential of stepwise pyrolysis in combination with metal sorbents

Pyrolysis liquid is a valuable product that could be re-introduced into the refinery or petrochemical industry following circular economy principles. However, halogens in the liquid product hinder this approach by causing corrosion of subsequent technologies. Dehalogenation is, therefore, a necessary step that aims to reduce halogen content below the set limit of 10 ppm. Research on this topic often includes contradictory results, and dehalogenation is still not widely used in large-scale operations. The present study explores the possibility of chlorine removal from a model plastic mixture, including 10% PVC utilizing various pyrolysis conditions, stepwise pyrolysis, and sorbents based on Ca(OH)2, Fe3O4, and Fe. Results suggest that it is not suitable to use sorbents in-situ as the captured Cl in the form of chlorides was released at higher temperatures increasing the chlorine content in the liquid products. The limit of 10 ppm for refinery introduction was reached by combining stepwise pyrolysis and sorbents ex-situ. Fe3O4 displayed the best efficiency, while its reduced form was the most efficient considering its low surface area. The obtained results are a necessary preliminary step for the development of a reliable dehalogenation procedure for municipal plastic waste being underway.

Selective flotation separation of polycarbonate from plastic mixtures based on Fenton treatment combined with ultrasonic

Selective flotation separation of polycarbonate from plastic mixtures based on Fenton treatment combined with ultrasonic

Analysis of the Addition of CMC to Biodegradable Plastics from Banana Hump

The use of banana hump flour as a raw material for making biodegradable plastic is an alternative to using banana starch plastic in an effort to reduce plastic waste. Bananas contain 66% carbohydrates, protein, water and essential minerals . To get biodegradable plastic, starch is added along with CMC (carboxy methylcellulose), glycerol and citronella oil as anti-bacterial and antioxidant. In this research, a research was conducted on the manufacture of biodegradable plastic mixture of starch, carboxy methyl cellulose (CMC), glycerol as a plasticizer and citronella oil by modifying CMC, glycerol and citronella oil. This study includes two variables, namely fixed variables and variable variables. Fixed variables include starch concentration with water 1:5, stirring speed 100 rpm and starch gelatinization temperature 70oC, while variables including CMC concentration include levels (5.5; 6.5 ; and 7.5) % (w/w), Citronella oil concentrations included (15; 20; and 25) % (w/v), and glycerol concentrations included (25; 35; and 45)% (w/v). This study aims to determine the effect of adding CMC citronella oil and glycerol as a plasticizer to the mechanical properties, morphology, and biodegradability tests , as well as the antioxidant activity of the resulting plastic . The results of this study indicate that biodegradable plastic has a tensile strength value of 0.210.38 kgf/mm2; elongation value between 16.3-54.20%; Morphological examination showed that the surface of the plastic was smooth and the plastic completely decomposed in the soil within 27 days. Keywords: Biodegradable plastic, CMC, banana starch.