Mixture Of Diesel Research Articles

Synergistic enhancing low-rank coal flotation mechanisms using nanocarrier collector through pore sealing and surface hydrophobicity

Low-rank coal (LRC) is difficult to float using conventional oily collectors due to the rich oxygen-containing functional groups and abundant pores on its surface. In this study, an effective nanocarrier collector containing both nanoemulsion and nanoparticle with droplet size of 10–70 nm was developed, through diesel-beeswax mixture and AEO-7 using low-energy shearing and rapid cooling emulsification to enhance the LRC flotation. The surface morphology and elemental compositions of LRC were firstly characterized using SEM and EDS, identifying its difficult-to-float mechanisms. Then, the macroscopic appearance and microscopic size distribution of nanocarriers, and flotation tests were conducted to determine the optimum formula of nanocarrier collector for LRC. The results indicated that the recovery rate of combustibles was first increased and then decreased, by increasing the mass ratio of beeswax to diesel. When the mass ratio of diesel, beeswax, and AEO-7 was 2:3:5, the recovery rate of combustibles could be achieved to 92.98 %. Finally, the BET specific surface area, water adsorption, contact angle and wrap angle experiments were conducted to clarifying the synergistic enhancing LRC flotation mechanisms of nanocarriers collector. The nanocarriers could permeate into and seal the LRC surface pores, thereby reducing the both surface pore volumes and specific surface area. In addition, the mixtures of diesel and beeswax synergistically improved the surface hydrophobicity. Consequently, this research provides new insight into the development of effective collectors for LRC flotation.

Ammonia diffusion combustion and emission formation characteristics in a single cylinder two stroke engine

Liquid ammonia diffusion combustion (LADC) is an effective approach to achieving high ammonia energy ratio (AER) and combustion efficiency in engines. However, there is a lack of simulation studies of LADC mode in ammonia/diesel dual direct injection engines. To address this gap, the study develops a numerical model based on an independently modified marine two-stroke engine. This model analyzes the combustion performance of ammonia in LADC mode and the pollutant generation mechanisms in LADC mode across various AER conditions. The findings indicate that in the LADC mode, the liquid phase ammonia spray exhibits a concentrated distribution area, facilitating thorough combustion of ammonia fuel. The diesel mixture and flame are entrained into the liquid phase ammonia spray, facilitating multi point ignition. This process notably enhances combustion speed, thereby reducing overall combustion duration. In comparison to pure diesel combustion, soot emissions are reduced by 99 % under the LADC mode, and CA90 advanced by 11.8 °C A. In addition, when the AER range is from 50 % to 70 %, the engine exhibits favorable combustion and emission characteristics. By appropriately adjusting the liquid ammonia injection quantity, the indicated thermal efficiency improves by 10.7 %, the equivalent indication specific fuel consumption decreases by 13.9 %, and the emission such as NOx and soot can be also reduced effectively.

Analytical Method for Determining the Viscosity Index of Engine Lubricating Oils

This paper proposes a simple analytical method for determining the viscosity index (VI) that effectively aligns with results obtained from the applicable standards. This method simply needs the kinematic viscosity of the tested oil at 40 and 100 °C as input parameters and does not need to use tables that are an integral part of the mentioned standards. This work presents a method and evaluates the accuracy of determining auxiliary parameters in the form of kinematic viscosity values at 40 °C for two hypothetical oils. These oils have a kinematic viscosity at 100 °C equal to that of the oil under testing and have VI = 0 and 100. The relative fitting error percentage and the coefficient of determination are found for the specified auxiliary indicators. The method is validated using data obtained from previous studies in the form of the kinematic viscosity of lubricating oil–diesel mixtures. The mixtures of viscosity grades SAE 30 and SAE 40 lubricating oil with diesel oil at concentrations of 0, 1, 2, 5, 10, 20, and 50% w/w are tested. The viscosity index for each mixture is determined using a standard-based manual calculation using the Anton Paar viscosity index calculator and the proposed method. The results obtained from the proposed analytical method are compared with those from two other methods. The maximum percentage relative fitting error (δmax ≈ 1%) and the coefficient of determination (R2 > 0.999) are determined. The obtained results demonstrate a very good fit and, thus, confirm the usefulness of the proposed approach.

Thermodynamic investigation and 4Es analysis of a VCR diesel engine using emulsified diesel with catalytic co-pyrolysis fuel derived from waste LDPE and Pongamia pinnata seeds

Global challenges for massive plastic waste disposal and regular decrement of conventional resources, converting plastic and biomass seeds waste into transportation-grade fuels through co-pyrolysis offer a better option for providing a promising solution. This investigation signifies a thermodynamic power cycle model, and 4Es (Energy, Exergy, Environmental, Economic) analysis of a direct injection unmodified diesel engine powered with various blends of test fuels derived from thermo-catalytic co-pyrolysis of low-density polyethylene (LDPE) wastes and Pongamia pinnata seeds at 500 °C with calcium oxide as catalyst, mixed with diesel. The fuel mixtures of pure diesel and pyrolytic test fuels are utilized for diesel engine testing with varying compression ratio. The synergistic effects of major parameters such as full engine load, varying compression ratios (16:1, 17:1, 18:1, and 19:1), and fuel blends (10, 20, 30, and 40 %) are considered for engine run. The Brake thermal energy was found to increase for the 20 % blend at 6.6 % (40 % load) in comparison to pure diesel. Also, the Brake specific fuel consumption was the least for the same blend, 0.31 kg/kWh at 18:1 CR. The smoke was also found to have lowered by 22 % for the 20 % blend in comparison to pure diesel. At a compression ratio of 18:1, the NOx formation also decreased by approximately 1.4 % in comparison to the pure diesel for almost all considered fuel blends. The fuel efficiency was observed to increase for the 20 % blend compared to pure diesel by 20 %. The cost and exergy destruction analysis also confirmed the D80PB20 to have the least and maximum values respectively for both parameters. The energy, exergy, emission, and economic (4Es) analysis confirmed the suitability of blended fuels for achieving improved engine performance and emissions. In addition, the economic and fuel sustainability analysis foster the techno-economic feasibility of the test fuels as compared to conventional diesel fuel.

Butanol Used as a Potential Alternative Fuel Blend with N-Decane and Diesel in CI Engines for Marine Application

For compression ignition engines, butanol is the most promising alternative fuel, in comparison with other alcoholic fuels. Butanol is superior to other alcoholic fuels because it has excellent physical and chemical properties that make it appropriate for diesel fuel blends. When butanol and diesel are blended, butanol is fully miscible in all proportions. Because butanol is hygroscopic, it does not absorb moisture from the environment. Because acetone-butanol-ethanol (ABE) fermentation may create butanol, it is commonly touted as a possible biofuel. This research is a significant step in gaining a thorough understanding of the effects of butanol on the fuel based on hydrocarbon. The fuel's molecular interactions mixes are studied using infrared (IR) spectroscopy. Binary mixes of butanol and n-decane, are investigated initially. After that, the mixture of butanol and diesel is investigated. When butanol is mixed with diesel, it forms strong bonds including the components of biodiesel that contain groups of esters. Furthermore, the possibility of employing Infrared spectroscopy for numerical mix analysis is assessed. The spectra are provided to enable a highly precise determination of the butanol concentration.

The investigation of the performance and exhaust emissions of the compression-ignition engine with a mixture of diesel and aluminum particles

In this study, aluminum particles were added to diesel fuel in amounts of 75 and 150 ppm, with a particle size of 15 micrometers and a purity of 98.95 %. A magnetic stirrer was used to achieve homogeneous mixing of aluminum particles in diesel. In order to prevent aluminum particles from settling, fuel mixtures were stirred for 45 minutes for every 2 kg of fuel mixture. Fuel mixtures prepared to prevent settling were used immediately to avoid affecting the experimental results. The experiments were conducted at torque values of 100, 150, and 200 Nm, with a constant 660 rpm. The experiments initially started with pure diesel. Then, they continued with diesel fuels containing 75 and 150 ppm of aluminum additives, respectively. Positive effects of aluminum addition on engine performance were observed. The highest efficiency was obtained with the fuel containing 75 ppm of aluminum additive. The fuel with 75 ppm of aluminum additive provided efficiency increases of 4.57 %, 2.90 %, and 2.23 % compared to pure diesel at torque values of 100, 150, and 200 Nm, respectively. Although the fuel with 150 ppm of aluminum additive showed less efficiency improvement compared to 75 ppm, it still provided efficiency improvement compared to pure diesel. Improvements in NOx, CO, and HC emissions were observed in experiments conducted with aluminum particle-added fuels. The aim of this study is to increase the efficiency of diesel engines and reduce exhaust emissions by using aluminum particle additives.

Pengaruh Penambahan Butanol Pada Bahan Bakar Solar Terhadap Karakteristik Pembakaran Single Droplet

Dependence on fossil fuels is one of the most serious threats to the global environment. In addition, petroleum reserves are also decreasing. Meanwhile, the level of oil consumption is always increasing to meet the demand for fuel. Economical and sustainable alternative energy solutions are essential to meet the growing global energy demand without compromising environmental sustainability. One type of alternative fuel that shows very promising potential is biofuel, especially biodiesel. Biodiesel has potential as a more environmentally friendly alternative to diesel fuel, but its low combustion rate and higher viscosity compared to conventional diesel fuel present technical challenges that need to be overcome. The different chemical properties of butanol from biodiesel allow it to have a positive impact on combustion characteristics, such as viscosity, flash point, heating value, and combustion rate. The combustion characteristics that will be studied in this research using single droplet combustion testing include droplet visualization to measure the dimensions of the flame, temperature during the combustion process recorded by a thermocouple, data logger, and video recording during the combustion process to obtain information regarding the ignition delay value. The test steps were repeated five times for each fuel variation and then averaged. In this study, the samples tested included pure diesel, diesel blend with 10% butanol, diesel blend with 20% butanol, diesel blend with 30% butanol, diesel blend with 40% butanol and diesel blend with 50% butanol. From this study, the visualization of the flame is obtained, where the combustion of pure diesel oil droplets has a higher and wider flame, while the flame of the butanol diesel mixture produces a flame whose maximum height is lower than pure diesel oil. The ignition delay time of pure diesel oil is greater than the ignition delay time of the diesel butanol blend. In addition, the maximum combustion temperature produced by each blend is different

Implementation of various injection rate shapes in an ammonia/diesel dual-fuel engine with special emphasis on combustion and emissions characteristics

As the problem of global warming continues to intensify, carbon-free fuel ammonia is crucial for internal combustion engines, and a potential ammonia combustion route is dual-fuel mode. The impact of various injection rate shapes (trapezoid, wedge, slope, triangle, and rectangle) on engine combustion and emissions performance with 0 %, 20 %, and 40 % ammonia energy fractions were estimated. Under the identical ratio of the ammonia-doped schemes, the fuel injection gross mass and fuel injection duration are the same. The results indicate that the triangle injection rate shape can make the mixture of diesel and ammonia gas more uniform, leading to combustion in the combustion chamber closer to homogeneous combustion. When the injection shape is the triangle, the indicated mean effective pressure in the cylinder is the highest at 10.29 bar, which is 4.04 % higher than that of the pure diesel original injection shape. The triangle injection shape makes the ammonia-diesel dual fuel burn more concentrated, resulting in lower unburned ammonia loss and higher thermal efficiency. Under the 40 % ammonia energy fraction and triangle injection shape, the highest thermal efficiency reaches 40.57 %, 1.58 % higher than the pure diesel original injection shape. Additionally, it significantly reduces unburned ammonia emissions. The injection rate shapes have a minor impact on CO2 emissions. The rapid increase in-cylinder average temperature can substantially reduce N2O emissions, thereby lowering total greenhouse gas emissions. Among them, the total greenhouse gas emissions of 40 % ammonia energy fraction and triangle injection shape are the lowest, at 81619 ppm, which is 11.3 % lower than that of pure diesel original injection shape. On the contrary, it will increase NOx emissions. Conversely, the slopes exhibit the lowest NOx emissions at 220.8 ppm, representing an 88 % reduction compared to the pure diesel original injection shape.

A Quantitative and Qualitative Analysis of the Lubricity of Used Lubricating Oil Diluted with Diesel Oil

Experience shows that dilution of lubricating oil with diesel oil is unfavorable to the engine, causing issues including deterioration of engine performance, shortening of oil life, and reduction in engine reliability and safety. This paper presents the verification of the hypothesis that the changes in lubricity, friction coefficient, and decreasing oil film thickness (using a relative approach, given as a percentage) are similar for lubricating oil and diesel mixtures prepared from fresh lubricating oil and used lubricating oil. To validate this hypothesis, an experiment is conducted using a high-frequency reciprocating rig (HFFR), in which the lubricity is determined by the corrected average wear scar WS1.4, the coefficient of friction μ, and the percentage relative decrease in oil film thickness r. A qualitative visual assessment of the wear scars on the test specimens is also performed after the HFFR tests. The testing covers mixtures of SAE 30 grade Marinol CB-30 RG1230 lubricating oil with Orlen Efecta Diesel Biodiesel. The used lubricating oil is extracted from the circulating lubrication system of a supercharged, trunk-piston, four-stroke ZUT Zgoda Sulzer 5 BAH 22 engine installed in the laboratory of ship power plants of the Maritime University of Szczecin. Mixtures for the experiment are prepared for fresh lubricating oil with diesel oil and used lubricating oil with diesel oil. Mixtures of these lubricating oils with diesel oil are examined for diesel oil concentrations in the mixture equal to 1, 2, 5, 10, 15, and 20% m/m. The results of the experiment confirm the hypothesis, proving that, for up to 20% m/m diesel oil concentration in lubricating oil, the changes in the lubricity of used lubricating oil diluted with diesel oil can be evaluated based on reference data prepared for mixtures of diesel oil with fresh lubricating oil. The linear approximation of μ and r trends is made with a certain margin of error we estimated. The experiment also confirms the results of previous studies which state that oil aging products in small quantities contribute to improved lubricity.

An experimental study on enhancing performance and reducing emissions of CRDI engine operated on Co-pyrolysis oil using particle swarm optimization

This study explores the use of Artificial Neural Network and Particle Swarm Optimization to improve the performance and emissions of a CRDI engine fuelled by a mixture of co-pyrolyzed oil and diesel. Experimental results show that the mixed fuels perform better than pure diesel in various engine conditions, achieving higher brake thermal efficiency and lower smoke emissions. The blend D90P10 has the highest BTE of 37.4% working at FIT 30°bTDC and FIP 500 bar. However, NO and CO2 emissions were increased for the same condition. A multi-parametric ANN model is created to build a predictive model based on this experimental data, relating inputs (fuel injection pressure, fuel injection timing, and blend percentages) to outputs (Brake Specific Fuel Consumption, NO, smoke, CO2 emissions). The ANN model attains high accuracy with R2 values of 0.99, 0.98, 0.99, and 0.99 for BSFC, NO, Smoke, and CO2 emission predictions, respectively. The results indicate that for optimal performance, the best conditions are a FIT of 29.71ºbTDC, a FIP of 500 bar, and a co-pyrolysis oil blend percentage of 19.61%. On the other hand, to minimize engine emissions, the best conditions are FIT of 20.28ºbTDC, FIP of 300 bars, and a blend percentage of 25.6%. A balanced approach results in an optimal condition of FIT at 29.5ºbTDC, FIP of 500 bars, and a blend percentage of 6.11%. Experimental validation of these optimal predictions shows a maximum error of only 3.18%, highlighting the reliability and accuracy of the model.

Combustion and emission of diesel/PODE/gasoline blended fuel in a diesel engine that meet the China VI emission standards

The present study examined the impact of blending polyoxymethylene dimethyl ethers (PODE) and gasoline with diesel on combustion and emission characteristics in an engine compliant with China VI emission standards. The effects on cylinder pressure, combustion duration, and emissions (CO, THC, PN, and NOx) by blending 20 % PODE into diesel and adjusting the gasoline content (0 %, 5 %, and 10 %) were analyzed. The results showed that the cylinder pressures and the combustion duration were reduced with the addition of PODE, compared to the cases of the pure diesel. Moreover, it was found that PODE contributed to reducing the emissions of CO, THC, and PN, and but increasing NOx emissions. Compared to the cases of PODE and diesel blended fuel, the effect of the addition of gasoline on the cylinder pressures and combustion duration presented a minor increasing tendency, and the lower proportion of gasoline blending was found to effectively curb NOx formation. Specifically, blending 5 % gasoline with a 20 % PODE and diesel mixtures resulted in a 4.01 % reduction in NOx emissions. Based on the results of the present study, it can be concluded that 5 % gasoline and 20 % PODE blend in diesel can enhance combustion efficiency and heat release rate and also can achieve a balanced reduction in NOx emissions. The present study provides valuable insights for the development of energy-saving and emission reduction technologies for diesel engines, highlighting the potential of optimized fuel blends to improve combustion and emissions control.

Investigation of nanoparticle (Fe3O4) addition to 3rd generation biodiesel (spirulina microalgae)/diesel mixture as an innovative fuel according to different engine variables: An RSM optimization

In order to reduce dangerous air pollution and lessen the hazards associated with climate change, biofuels made from vegetable biomass can be utilized as fuel in diesel engines. However, feedstocks and the crop space needed for their cultivation are unavoidable barriers that hinder its adoption and result in a shortage of farmland for increasing food profits. Nevertheless, microalgae are the most reliable and competent biodiesel supply because they are not edible and do not require cropland. Additionally, the addition of nanoparticles has become popular to improve the negative aspects of biodiesel. Based on these, in this study, multi-purpose optimization research was conducted on the addition of iron oxide (Fe3O4) nanoparticles in three different amounts (25, 50, and 75 ppm) to 20 % synthesized spirulina microalgae biodiesel (SSMB)/80 % diesel mixtures. Tests were conducted at three different compression ratios (14.5:1, 15.5:1, and 16.5:1) (CoR) and four different engine loads (25 %, 50 %, 75 %, and 100 %). The response surface methodology (RSM) optimization process was performed with the test results. According to RSM, a desirability coefficient of 0.8299, 15.80:1 CoR, 68 ppm AoN, and 45 % LoE were the ideal conditions. The optimum responses under these circumstances were 421.9653 g/kWh, 19.4014 %, 0.0939 %, 4.0785 %, 73.1716 ppm and 253.0620 ppm for brake-specific fuel consumption (BSFC), brake-thermal efficiency (BTHE), carbon monoxide (CO), carbon dioxide (CO2), hydrocarbon (HC), and nitrogen oxide (NOx), respectively. RSM could be used successfully because the error rates (maximum 6.5 %) when comparing the test results with the RSM optimization outcomes were within reasonable bounds.

TECHNOLOGICAL ASPECTS OF THE DEVELOPMENT OF A MIXED FUEL FILTER FOR DIESEL AND BIOFUELS

This article discusses the technological aspects of the development and efficient operation of a fuel filter designed to purify a mixture of diesel and biofuels. The authors analyze the engineering implementation challenges associated with the production and use of this type of filter. The article discusses in detail the technical solutions that determine the efficiency and duration of operation of such a fuel filter in conditions of use of mixed fuel. A separate section is devoted to the study of the impact of mixed fuels on engine operation, with a focus on combustion efficiency and possible cases of malfunction. The article also examines the environmental benefits of using blended fuels, focusing on reduced emissions and positive environmental impacts compared to traditional diesels. Particular attention is paid to innovative materials and technologies used to create fuel filters adapted to mixed fuels. The authors consider the advantages and disadvantages of different materials and their impact on the functionality of the filter. The article concludes with an overview of the standards and regulations that govern the use of blended fuels, with a focus on fuel filter requirements to ensure safety, efficiency, and environmental compliance. Taking into account current trends in the development of fuel systems, the article is aimed at supporting engineers, scientists and specialists from the automotive and energy industries in improving the technologies of blended fuels and their elements.

Studi eksperimental kinerja mesin TV-1 (engine research test) berbahan bakar campuran diesel-biodiesel

This research is a laboratory experimental research that uses research testing machines. Using biodiesel fuel, a mixture of oil and diesel fuel. The composition of the biodiesel mixture used in this research was B35, B40, and B50 into diesel fuel in millilitres (ml). Tests were carried out by varying the load and compression ratio (CR), namely loads of 3 kg, 5 kg, 8 kg, and compression ratios of 14, 16, and 18. Data collection used observation techniques using tables to record the study results obtained. By using descriptive analysis techniques in the form of graphs and tables to make it easier to find out the study results. The results of the study from the engine performance research tests obtained were that performance increased with increasing loading at low compression ratios with the addition of biodiesel to diesel fuel, while at high compression ratios, the greatest power was obtained from B35 mixed fuel. However, the lowest fuel consumption in the mixture composition is the B35 mixture. Meanwhile, the lowest emission density opacity obtained was in the mixture of B35 and B40 biodiesel.

Enhancing the Viability of a Promising E-Fuel: Oxymethylene Ether–Decanol Mixtures

Achieving sustainable mobility is a crucial factor in maintaining long-term economic growth without adverse effects on human health and the environment. E-fuels, such as the promising oxymethylene ether (OME), can contribute to sustainable road transport. However, this compound does not meet the requirements of EN590; thus, it is unsuitable for unmodified diesel engines. This work aims to improve the applicability of OME by blending it with n-decanol, which can also be produced sustainably. Combustion and emissions were investigated in a medium-duty commercial diesel engine with different binary and ternary mixtures of oxymethylene ether, n-decanol, and B7 diesel. Laboratory analysis of six key mixture parameters revealed that the formulated blends met the EN590 requirements, with the exception of that of density. The results demonstrated that the created mixtures, including one without any diesel fuel, can be efficiently utilized in unmodified diesel engines. OME’s beneficial effects on combustion and emission were preserved while its viability was improved; a maximum increase of 7.6% in brake thermal efficiency was observed, alongside a potential decrease of nearly 70% in PM emissions at unaltered NOx levels.

An Experimental Study Using Canola Oil Biodiesel to Examine the Properties of a Diesel Engine with Decanol as an Additive

A naturally beneficial use of diesel is primarily threatened by the depletion of natural resources and the alarming rise in pollution levels. The majority of research conducted to date has been on the use of lower alcohols; information regarding a higher alcohol mix in canola oil biodiesel is less abundant. This study investigates the effects of adding a ternary mixture of diesel, biodiesel, and decanol as an additive to a CI engine. Diesel and biodiesel were combined with decanol to conduct tests. While the diesel concentration was maintained at 50% throughout, the decanol mixing concentrations were 10%, 20%, and 30% by volume. According to the study, as decanol concentration rises, brake specific fuel consumption falls and brake thermal efficiency rises. At full load, BTE values of 32.24% and 31.68% for pure diesel and D50COME20DEC30, respectively, were noted. The ternary blend D50COME20DEC30 BSFC was 12.89% and 20.63% lower than those of COME100 and D50COME50. Although the total heat release rate is seen to be reduced during the end phase of ignition, heat release rate is observed to increase with the expansion of decanol content in the ternary mix. NOx emissions for D50COME50 and for 10%, 20%, and 30% of decanol in the ternary blend were 1869 PPM, 1838 PPM, 1819 PPM, and 1810 PPM. Therefore, in order to increase engine performance and emissions without altering the CI engine, the present examination recommends a 30% blend of decanol, 20% biodiesel, and 50% diesel. Key Words: COME (Canola oil methyl ester), Decanol, Diesel, Performance, Combustion, Emission, CI Engine.

Study on Oxidation Activity of Hydrogenated Biodiesel–Ethanol–Diesel Blends

In the pursuit of understanding the oxidation mechanisms of hydrogenated biodiesel fuels and elucidating the combustion behavior of biomass fuels when blended with diesel, this study presents a comprehensive investigation into the reaction mechanism of hydrogenated biodiesel–ethanol–diesel mixtures. We develop a comprehensive reaction mechanism encompassing 187 components and 735 reactions for hydrogenated biodiesel–ethanol–diesel mixtures. Through kinetics analysis under varied conditions, including 1.0 MPa pressure, an equivalence ratio of 1.0, and temperatures of 900 K and 1400 K, we explore the impact of cross-reactions and changing fuel blend ratios on low- and high-temperature oxidation. Our findings indicate that oleic and stearic acid methyl esters serve as better substitutes for representing hydrogenated biodiesel kinetics than methyl decanoate. At lower temperatures, increased hydrogenated biodiesel and ethanol content leads to reduced OH generation, impacting reactivity. Conversely, higher temperatures result in enhanced OH production with increased hydrogenated biodiesel and ethanol concentrations, promoting reactivity. A cross-reaction analysis reveals CH2O as a prominent product, with the CH2O→HCO→CO pathway playing a pivotal role. In summary, our research unveils the intricate oxidation mechanisms of hydrogenated biodiesel–ethanol–diesel mixtures, providing insights into their combustion characteristics and offering implications for optimizing fuel blends for cleaner and more efficient energy solutions.

Detection of gaseous pollutants emitted from engine powered by biodiesel and diesel mixtures

Nowadays air pollution has been regarded as a serious environmental problem. One of the main generators of air pollution is the transportation, since the gas combustion from various chemical species is emitted mainly in urban transportation, using mainly diesel fuel. The use of renewable fuels is an attractive alternative choice to reduce environmental impacts. Brazil stands out in the current world scene as a major of alternative energy producer. Brazilian government introduced a program that includes blends of biodiesel to diesel in order to reduce the environmental impact caused by air pollution. Therefore, this study aims to evaluate the emission of gaseous pollutants using a diesel engine bench with mixtures of B5, B10, B15, B20, B25 and B50 of biodiesel in diesel. For this type of analysis, the Infrared Analyser was used to detect CO2 in the range of 1.88 to 2.76 %, electrochemical sensors were used to detect CO in the range of 1161 to 1485 ppmv and NOx in the range of 213 to 351 ppmv.

Enzymatic In Situ Interesterification of Rapeseed Oil with Methyl Formate in Diesel Fuel Medium

The purpose of this research was to evaluate the process of enzymatic biodiesel synthesis by directly using rapeseed as a raw material, extracting the oil contained within and interesterifying with a mixture of methyl formate and mineral diesel, choosing the amount of mineral diesel so that the ratio between it and the rapeseed oil in the seeds was 9:1. As the final product of the interesterification process, a mixture of mineral diesel and biodiesel was obtained directly, which is conventionally produced by mixing the mineral diesel and biodiesel. The tests were performed using enzymatic catalysis using the lipase Lipozyme TL TIM. Process optimization was performed using the response surface methodology. A model describing the interaction of three independent variables and their influence on the yield of rapeseed oil methyl esters was developed. The physical and chemical indicators of the product obtained under optimal interesterification conditions were evaluated.

Study of the influence of adding Al2O3 nanoparticles to biodiesel on the performance and emissions characteristics of a diesel engine

The use of biodiesel in compression ignition (CI) engines has great potential to reduce emissions and the dependence on fossil fuels. However, the complete adoption of biodiesel in CI engines is limited by several drawbacks. A promising solution to these problems is the addition of nanoparticles to biodiesel or diesel-biodiesel blends. Hence, this paper studies the impact of adding aluminum oxide (Al2O3) nanoparticles on the performance and emission characteristics of a diesel engine running on biodiesel and a mixture of diesel and biodiesel. Al2O3 nanoparticles were added at concentrations of 50, 100 and 150 ppm to biodiesel (B100) and a mixture of 50 % biodiesel and 50 % commercial diesel (B50). The results indicated an increase in fuel conversion efficiency and a reduction in specific fuel consumption. The highest fuel conversion efficiency was 26.5 % for B50 with 100 ppm of Al2O3, indicating an improvement of around 28.6 % compared to diesel fuel (B0). In general, CO emissions were reduced with the addition of nanoparticles, with a maximum reduction of 42.8 % for B100 with 50 ppm Al2O3 compared to B0. The highest reduction in NOX emissions was 30.3 % for B50 with 100 ppm Al2O3 compared to pure diesel B0.