Mixture Of Ethanol Research Articles

XGBoost algorithm assisted multi-component quantitative analysis with Raman spectroscopy

To improve prediction performance and reduce artifacts in Raman spectra, we developed an eXtreme Gradient Boosting (XGBoost) preprocessing method to preprocess the Raman spectra of glucose, glycerol and ethanol mixtures. To ensure the robustness and reliability of the XGBoost preprocessing method, an X-LR model (which combined XGBoost preprocessing and a linear regression (LR) model) and a X-MLP model (which combined XGBoost preprocessing and a multilayer perceptron (MLP) model) were developed. These two models were used to quantitatively analyze the concentrations of glucose, glycerol and ethanol in the Raman spectra of mixed solutions. The proportion map of hyperparameters was firstly used to narrow down the search range of hyperparameters in the X-LR and the X-MLP models. Then the correlation coefficients (R2), root mean square of calibration (RMSEC), and root mean square error of prediction (RMSEP) were used to evaluate the models’ performance. Experimental results indicated that the XGBoost preprocessing method achieved higher accuracy and generalization capability, with better performance than those of other preprocessing methods for both LR and MLP models.

Impacts of hydrogen fraction and equivalence ratio on the explosion characteristics of ethanol/hydrogen mixtures

With the anticipated widespread integration of biofuels and hydrogen fuels within the future energy landscape, the potential explosion hazards after their release within confined spaces under the atmospheric are deserving of heightened attention. The present work takes the mixtures of ethanol and hydrogen as the objects and experimentally studies the impacts of hydrogen fraction and equivalence ratio on the explosion characteristics in a constant-volume explosion vessel at 0.10 MPa and 400 K. The data reveals that an increase in the hydrogen fraction leads to a rise in the maximum explosion pressure during lean explosions but causes a decrease during rich explosions. Nonetheless, the duration of the explosion decreases with the increase of hydrogen fraction in all the explosions. In consideration of explosion pressure, the maximum pressure rise is found to be exponential in relation to the maximum explosion pressure. However, the confidence level diminishes significantly with an increase in the hydrogen fraction. Conversely, the maximum rate of pressure rise during an explosion appears to be a function of the duration of the explosion, suggesting that the reaction rate plays a more pivotal role in determining the hazardous level. Meanwhile, the duration of fast combustion steadily occupies approximately 83 % of the explosion duration. Furthermore, the deflagration index is no more than 30 MPa*m/s, namely, ethanol/hydrogen mixture is a promising fuel with mild hazardous potential.

Synthesis and characterization of hierarchical Sr-doped ZnO hexagonal nanodisks as an efficient photocatalyst for the degradation of methylene blue dye under sunlight irradiation

This study presents the synthesis and comprehensive characterization of hierarchical hexagonal nanodisks of zinc oxide (ZnO) and strontium (Sr) doped ZnO, prepared via a hydrothermal method. The experimental synthesis procedure involved dissolving zinc nitrate in a water–ethanol mixture, followed by the addition of polyethylene glycol (PEG 200), sonication, and subsequent hydrothermal treatment. Different concentrations of Sr were introduced into the ZnO lattice to generate Sr-doped ZnO samples. Analysis of the obtained results revealed successful incorporation of Sr, evidenced by shifts in the X-ray diffraction (XRD) pattern and alterations in lattice parameters. Moreover, the Williamson-Hall plot indicated minimal strain and high structural stability in both pristine ZnO and Sr-doped ZnO. The morphology of the synthesized Sr-doped ZnO was confirmed through field emission scanning electron microscopy (FESEM) and transmission electron microscopy (TEM), revealing a hexagonal nano disk-shaped morphology akin to pristine ZnO. Elemental composition analysis conducted via X-ray photoelectron spectroscopy (XPS) further confirmed the presence of Sr in the doped ZnO samples. Evaluation of photocatalytic activity against methylene blue dye demonstrated superior performance of the 5 % Sr-doped ZnO catalyst, attributed to its increased surface area compared to pristine ZnO. Notably, the highest degradation rate constant (k) of 0.0389 min−1 was observed for the 5 % Sr-doped ZnO catalyst, emphasizing its efficacy in environmental remediation applications. This research underscores the potential of Sr-doped ZnO as a promising photocatalyst, offering stability, reusability, and effective utilization of UV and visible light for catalytic processes.

Adhesion and adsorption properties of water, ethanol, rhamnolipid and Triton X-165 mixture in quartz-mixture-air system

Wetting behaviour of the solutions including water, ethanol (ET), rhamnolipid (RL) and Triton X-165 (TX165) with regard to the quartz surface tension was investigated. The investigations were based on the measurements of the contact angle on the quartz surface for the solutions at the constant ET and RL concentrations and variable of TX165. The obtained results were considered with regard to the adhesion work of the solution to the quartz surface, adsorption of particular components of the solution at the quartz-air, quartz-solution and solution-air interfaces as well as to solution interactions across the quartz-solution interface. The considerations of the adhesion work and parameter of solution interactions across the quartz-solution interface as well as the adsorption of ET, RL and TX165 at different interfaces were based on the quartz surface tension and its components determined by different methods. These research results allow to establish the correlations between the adhesion work and the adsorption film pressure at the quartz-air interface and those between the parameter of interactions at the quartz-solution interface and its tension. The mechanism of the adsorption of particular components of the solution at the interfaces and their standard Gibbs free energy of adsorption were also discussed.

The Effect of Avgas and Ethanol Fuel Mixture on Fuel Spray Temperature

This research aims to examine the effect of the avgas-ethanol fuel mixture on the fuel spray temperature. The research was carried out using a pressurized tube which was sprayed into the mock up which was assumed to be an aircraft combustion chamber with a pressure of 2 bar and a distance of 7,73 cm which would later be sprayed using pure avgas, a mixture of avgas and ethanol namely A80E20 and A60E40 then added with a temperature sensor at the end nozzle, center of jet, and impact wall. The spray temperature can result in incomplete combustion and result in higher exhaust emissions and also damage to the engine if it does not match the temperature capacity of the combustion chamber walls. The spray temperature results for the A60E40 fuel mixture are the lowest temperature, namely 25o-18.2oC and knowing that the more fuel is mixed, the lower the temperature of the fuel.

Response Surface Optimization of Brake Thermal Efficiency and Specific Fuel Consumption of Spark-Ignition Engine Fueled with Gasoline–Pyrooil and Gasoline–Pyrooil–Ethanol Blends

<div>The present study explores the performance of high-density polyethylene (HDPE) pyrooil and ethanol blends with gasoline in SI engine using statistical modeling and analysis using response surface methodology (RSM) and the Anderson–Darling (AD) residual test. The pyrooil was extracted from HDPE through pyrolysis at 450°C and then distilled to separate the liquid fraction. Two blends were prepared by combining pyrooil and gasoline, and pyrooil–ethanol mixture (volume ratio of 9:1) and gasoline, both at volumetric concentrations ranging from 2% to 8% to evaluate brake thermal efficiency (BTE) and specific fuel consumption (SFC) in a SI engine. An experimental matrix containing speed, torque, and blend ratio as independent variables for both blends were designed, analyzed, and optimized using the RSM. The results show that a 4% blend of pyrooil with gasoline (P4) and a 6% blend of pyrooil–ethanol mixture with gasoline (P6E) were optimum for an SI engine. Also, the experimental findings show that the P6E blend exhibits 11% higher BTE and 11.82% lower SFC compared to base fuel (pure gasoline), and 7.55% higher BTE and 6% lower SFC than P4. From the AD test, the residuals for BTE and SFC follow a normal distribution. The results conclude that distilled HDPE pyrooil could be used in SI engines at concentrations of P4 and P6E without requiring engine modification.</div>

DETERMINATION OF POLYPHENOLIC COMPOUNDS IN PHYTOEXTRACTS WITH ANTIBACTERIAL PROPERTIES AND STUDY POTENTIAL EFFECTS

Objectives. The research work is a comparative study of the polyphenolic compounds and flavonoid content of the phytoextracts obtained from the ultrasonic extraction process (Stegler DG-360) with 95% ethanol and ethanol-propyleneglycol mixture (in 95 : 5 ratio) from the Clove buds (Caryophyllos aromaticus L. Myrtaceae), hibiscus flowers (Hibiscus sabdariffa L. (Hs, roselle; Malvaceae)) and common yarrow (Achillea millefolium L. Asteraceae) plants, which are rich in biologically active substances with high therapeutic effect, as well as their devoted to the investigation of antioxydant activity and antimicrobial potential. Material and methods. The research work was carried out in the Central Research and Application Laboratory of Ağrı İbrahim Çeçen University (MERLAB), Republic of Turkey, using a Japanese Shimadzu brand Mistral-AB SCIEX 4000 QTRAP liquid chromatograph-mass spectrometer device. Results.It was found that in both extraction processes, the active substances penetrated sufficiently from the medicinal-plant raw materials into the extractant. 20 names of compounds containing polyphenol, flavonoid and anthocyanin derivatives have been determined. However, the amount of active substances in the phytoextract obtained with the presence of the penetrate (propylene glycol) was higher. In particular, rutin ( 75.74 ± 4.91mg/g), quercetin (110.12 ± 1.30 mg/g), gallic acid (4503.19 ± 46.83mg/g), quinic acid (4041.99 ± 187.3 mg/g), chlorogenic acid (582.30 ± 1.30mg/g), vanilin (155.6g/g1 ± 3.95mg/g) prevailed. Conclusion. The research work proves once again that the studied phytoextracts are rich in polyphenolic compounds and flavonoids. The amount of biologically active substances in the phytoextract obtained with the ethanol-propylene glycol mixture which is the penetrate substance (in the ratio of 95:5) is higher than that of the other sample (with 95% ethanol). The resulting amount of biologically active substances is a clear proof that the phytoextract has sufficient antioxidant and antimicrobial properties.

Greenness assessment and comparison of the developed and validated green HPLC-PDA, HPLC-FLD, and HPLC-ELSD methods for the determination of melatonin in various products using analytical eco-scale, NEMI, GAPI, and AGREE greenness metric tools

Melatonin, recognized as the hormone governing sleep, is an endogenous hormone synthesized by the pineal gland situated in the brain. It orchestrates the sleep-wake cycle and fosters optimal circadian rhythm. Owing to its manifold metabolic advantages, particularly in the realm of circadian rhythm regulation, melatonin finds extensive application in various supplementary formulations. The elimination of hazardous chemical waste in common chromatographic separations has become an essential issue. We present a green, eco-friendly, novel, sensitive, rapid, robust, and three simple methods including the HPLC-PDA, HPLC-FLD, and HPLC-ELSD approach for the simultaneous determination of MEL in various products. The mobile phase of all the HPLC methods consists of only water and an ethanol mixture and is free from any toxic solvents. All the separations were made on a C18 column (5 μm particle size, 250 mm x 4.6 mm id.). LODs were found to be as 1.20 ng mL−1, 0.02 ng mL−1, 1.26 µg mL−1, and LOQs 4.00 ng mL−1, 0.07 ng mL−1, 4.21 µg mL−1 for PDA, FLD and ELSD, respectively. The recovery results were found to be within 98.58–102.35 %. Moreover, the greenness assessment of all the HPLC methods was assessed using the Analytical Eco-scale, NEMI, AGREE, and GAPI. The developed methods have been demonstrated to be applicable in routine analyses for the determination of melatonin in various preparations.

Novel tributyl phosphate-based deep eutectic solvent: Application in microwave assisted extraction of carotenoids

A contribution to the use of deep eutectic solvents (DES) and microwave-assisted extraction (MAE) was made for bioactive compounds recovery, especially those with lipophilic character, from tomato and carrot samples rich in carotenoids. For the first time, a novel deep eutectic solvent was synthesized, comprising tributyl phosphate (TBP) as a hydrogen bond acceptor and acetic acid (AcOH) as a hydrogen bond donor. The total antioxidant capacity (TAC) of tomato and carrot extracts obtained by MAE, in which optimization of operational parameters and modeling were made with the use of Box-Behnken design of the response surface methodology (RSM), was evaluated using the Cupric Reducing Antioxidant Capacity (CUPRAC) method. For the highest TAC, operational parameters that best suit the MAE procedure were set at 80 °C, 35 min, and 25 mL/2.0 g. The TAC values of extracts obtained by MAE using TBP:AcOH, 1:2 (mol/mol) were examined against those of extracts acquired by classical solvent extraction using a mixture of hexane, ethanol and acetone (H:E:A, 2:1:1 (v/v/v)) mixture. TAC of extracts in DES varied between 5.10 and 0.71 lycopene equivalents (mmol LYC kg−1). The highest extraction yield comparable to conventional organic solvents was obtained with TBP:AcOH (1:2). It was observed that, in addition to lipophilic antioxidants, some hydrophilic antioxidant compounds were partially extracted with the proposed DES. Moreover, the extracted antioxidant compounds were identified and quantified by HPLC analysis. The proposed DES and MAE process will find potential application for hydrophobic antioxidant extraction from tomatoes and carrots on an industrial scale after further studies.

Pervaporation Dehydration Mechanism and Performance of High-Aluminum ZSM-5 Zeolite Membranes for Organic Solvents.

Membrane-based pervaporation (PV) for organic solvent dehydration is of great significance in the chemical and petrochemical industries. In this work, high-aluminum ZSM-5 zeolite membranes were synthesized by a fluoride-assisted secondary growth on α-alumina tubular supports using mordenite framework inverted (MFI) nanoseeds (~110 nm) and a template-free synthesis solution with a low Si/Al ratio of 10. Characterization by XRD, EDX, and SEM revealed that the prepared membrane was a pure-phase ZSM-5 zeolite membrane with a Si/Al ratio of 3.8 and a thickness of 2.8 µm. Subsequently, two categories of PV performance parameters (i.e., flux versus separation factor and permeance versus selectivity) were used to systematically examine the effects of operating conditions on the PV dehydration performance of different organic solvents (methanol, ethanol, n-propanol, and isopropanol), and their PV mechanisms were explored. Employing permeance and selectivity effectively disentangles the influence of operating conditions on PV performance, thereby elucidating the inherent contribution of membranes to separation performance. The results show that the mass transfer during PV dehydration of organic solvents was mainly dominated by the adsorption-diffusion mechanism. Furthermore, the diffusion of highly polar water and methanol molecules within membrane pores had a strong mutual slowing-down effect, resulting in significantly lower permeance than other binary systems. However, the mass transfer process for water/low-polar organic solvent (ethanol, n-propanol, and isopropanol) mixtures was mainly controlled by competitive adsorption caused by affinity differences. In addition, the high-aluminum ZSM-5 zeolite membrane exhibited superior PV dehydration performance for water/isopropanol mixtures.

Alternative green extraction techniques to enhance recovery of antioxidant compounds from red peel prickly pear (Opuntia ficus-indica L. Miller)

Prickly pear (Opuntia ficus-indica L. Miller) is a natural source of antioxidant compounds that have gained significant attention due to their potential health benefits. This study aims to investigate the effectiveness of pressurized liquid extraction (PLE) and Ultrasound-Assisted Extraction (UAE), combined with water–ethanol mixtures from 0 to 60%, at moderate temperatures between 50 °C to 70 °C to improve the recovery of antioxidant compounds from red peel prickly pear. The recovery of these compounds was affected by solvent composition and temperature for both extraction techniques. Interestingly, the use of pure water at 70 °C during the PLE process allowed the recovery of high concentrations of antioxidant compounds (12.96 mg GAE/g dw, IC5O: 2.03 mg/mL, ORAC: 625 µmol TE/g dw). On the contrary, when the UAE process was combined with 30% ethanol at 50 °C, the extractability of these compounds (10.52 mg GAE/g dw, IC5O: 3.09 mg/mL, ORAC: 561.26 µmol TE/g dw) was improved. In addition, different solvent compositions were identified to improve the recovery of specific polyphenols. For PLE, pure water at 70 °C was effective in recovering phenolic acids, flavanols, and flavonols, while the highest concentrations of stilbenes were obtained with 60% ethanol at 70 °C. For UAE, the use of 30% ethanol at 50 °C was more effective in extracting phenolic acids and stilbenes, whereas pure water at 50 °C provided high concentrations of flavanols and flavonols. These results contribute to the development of sustainable and efficient extraction strategies for obtaining antioxidant-rich extracts from prickly pear peel with important applications in functional foods, nutraceuticals, and pharmaceutical industries.

Analisis Pengaruh Rasio Kompresi Dan Persentase Etanol Pada Bahan Bakar Terhadap Kinerja Mesin Otto 4 Langkah

The public demand for better vehicle performance is increasing. Increasing the compression ratio and fuel octane is one solution to improve vehicle performance. This study aims to determine the effect of increasing the compression ratio and ethanol mixture in fuel on the power and torque of the 125 cc Otto engine. The method used is an experiment using a dynotest. The compression ratio was varied to 8.9, 9.2, and 9.6, with ethanol mixtures of 5%, 10%, and 15%. The test data were analyzed using the two-way ANOVA method. The results showed that increasing the compression ratio and ethanol mixture can increase engine power and torque. The highest peak power and torque occurred at a compression ratio of 9.6 with 15% ethanol, which was 6.11 kW and 10.23 N.m. A compression ratio of 9.2 produces 6.07 kW of power and 10.07 N.m of torque at 15% ethanol. A compression ratio of 8.9 produces 5.62 kW of power at 15% ethanol and 9.73 N.m of torque at 10% ethanol.

An activity coefficient model for mixed-solvent electrolyte mixtures based on Gibbs–Duhem’s equation: A case study of mixtures of water, KCl and ethanol

Thermodynamic properties of mixtures with several fluid components and electrolytes are challenging to model. Models are needed to develop and improve a wide range of electrochemical systems such as fuel cells, lithium-ion batteries, and processes with ion-exchange membranes. In the literature, activity coefficients are extracted using fundamentally different experimental methods that rely on electrochemical cells, vapour pressure measurements, solubility measurements, etc. The reference states of the activity coefficients obtained from these methods are likely to differ. This makes it difficult to combine or compare activity coefficient models from different sources. In this work, we present a method using Gibbs–Duhem’s equation for the development of activity coefficient models of mixtures that are based on experimental data from different methods. We use the ternary mixture of KCl, H2O and ethanol as example. First, empirical expressions are developed for the logarithm of the activity coefficients of KCl and ethanol. The expression for the activity coefficient of H2O is next derived using Gibbs–Duhem’s equation. The resulting three activity coefficient models are fitted to available experimentally data from several sources, generating linear and relatively low-complexity activity coefficient models. The empirical activity coefficient models are next compared to the electrolyte cubic plus association (e-CPA) equation of state. The models give saturation pressures in ternary mixtures that have average absolute relative deviations for water/ethanol of 8.3/3.4% for the empirical model and 11.8/3.3% for e-CPA. Experimental data reduction procedures for concentration cells, formation cells, and vapour pressure measurements are discussed, and the freedom to choose the reference state and the consequences are highlighted.

Photo-responsive anticounterfeiting inks switching between colorless and cyan/magenta/yellow for flexible, full-color, and large-area printing

Inkjet printing of photo-responsive patterns capable of switching between colorless and full-color is regarded as an innovative anticounterfeiting technique with a higher security level. Therefore, colorless inks which can be changed to cyan (C), magenta (M), and yellow (Y) upon photochromism are highly required. Herein, three photochromic (PC) inks C, M, and Y switching between colorless and cyan/magenta/yellow, respectively, have been successfully prepared by dissolving viologen derivatives AV, AEV, and NOV in solvent mixtures of water, ethanol, and ethylene glycol, with sodium dodecyl sulfate (SDS) as surfactant. With a mass fraction of 0.5 wt% for SDS, an optimal rheological property with a viscosity of 3.48 mPa·s, a contact angle of 29.4° on poly (ethylene terephthalate) (PET) substrate, a surface tension of 23.16 mN m−1, and a Z value of 3.85, is realized for ink C. Under the same conditions, inks M and Y are prepared and display suitable rheological properties for inkjet printing. The films are invisible initially and become colorful upon UV irradiation with no significant decay after 20 repetitive PC switching. Subsequently, various colorful patterns with high resolutions were printed on conventional A4 paper and become visible only after irradiation by a UV lamp. Therefore, these photo-responsive tricolor inks can be used in anticounterfeiting field and two practical examples of a stamp and a personal check with cryptical texts and color information have been demonstrated. Overall, the developed photo-responsive C/M/Y inks can be utilized in flexible, full-color, and large-area printing, providing a novel approach towards innovative anticounterfeiting technology.

Molecular interactions and thermodynamic modelling of N,N-dimethyl benzyl amine-alkoxy ethanol mixtures: an FT-IR spectroscopy and Jouyban–Acree model approach

ABSTRACT This study examines intermolecular interactions in binary mixtures of N,N-dimethyl benzyl amine (DMBA) with short-chain alkoxy ethanols (2-methoxy ethanol (ME), 2-ethoxy ethanol (EE) and 2-butoxy ethanol (BE)). Densities (ρ), speeds of sound (u) and viscosities (η) were measured from 303.15 K to 313.15 K at atmospheric pressure for all compositions. These data were used to determine excess thermodynamic and transport properties: excess molar volume (V E ), excess isentropic compressibility (κs E ), viscosity deviation (Δη) and excess Gibbs free energy of activation (ΔG *E ). Partial and infinite dilution molar partial properties were also calculated. Results focus on complex formation driven by chemical forces. The Jouyban–Acree model predicted these properties, with accuracy assessed using mean relative deviations (MRDs) and individual relative deviations (IRDs). FTIR spectroscopy provided additional insights into intermolecular interactions.

Compact 3D-Printed Unit for Separation of Simple Gas Mixtures Combined with Chemiresistive Sensors.

Inexpensive chemiresistive sensors are often insufficiently selective as they are sensitive to multiple components of the gas mixture at the same time. One solution would be to insert a device in front of the sensor that separates the measured gas mixture and possibly isolates the unwanted components. This study focused on the fabrication and characterization of a compact unit, which was fabricated by 3D printing, for the separation and detection of simple gas mixtures. The capillary, the basic part of the compact unit, was 4.689 m long and had a diameter of 0.7 mm. The compact unit also contained a mixing chamber on the inlet side and a measuring chamber with a MiCS-6814 sensor on the outlet side. Mixtures of ethanol and water at different concentrations were chosen for characterization. The measured calibration curve was found to have a reliability of R2 = 0.9941. The study further addressed the elements of environmental friendliness of the materials used and their sustainability.

Study of celecoxib dissolution process in the mixtures of ethanol and propylene glycol at different temperatures

ABSTRACT Categorised as a nonsteroidal anti-inflammatory drug targeting the COX-2 enzyme over COX-1, celecoxib (CXB) demonstrates high membrane permeability and low aqueous solubility, placing it in class II of the biopharmaceutical classification system. Therefore, comprehension of its solubility behaviour under different configurations is desirable. The current study explores CXB solubility in propylene glycol and ethanol binary mixtures by varying temperature and cosolvent concentration, using the shake-flask method followed by spectroscopy analysis. The results show increased solubility of CXB in this mixture as ethanol mass fraction and temperature increase. Several cosolvency models were used to correlate data, including van't Hoff, Jouyban-Acree, Jouyban-Acree-van't Hoff, and mixture response surface/modified Wilson models. The mathematical models’ accuracy was investigated through mean relative deviation. The Gibbs and van't Hoff equations were employed to establish the thermodynamic features of CXB dissolution.

Altering the percolation threshold of PA66‐copper hybrid in an electroless copper deposition process by surface activation of the polymer

AbstractIn this study, the impact of three different principles of surface activation techniques for polyamide fibers on the formation of conductive percolation during the subsequent electroless copper deposition process was investigated. The techniques used are (1) polyamide complexation using a solution mixture of calcium chloride, ethanol and water, (2) atmospheric plasma surface treatment and (3) grafting of 2‐hydroxyethylmethacrylate by radical induced polymerization. As a result, the percolation threshold was shifted to lower copper contents. The copper content required to form conductive structures was reduced ranged between 59% and 89%, depending on the activation techniques. Furthermore, the deposition time was reduced by 37%–57%, resulting in a faster build‐up of the percolation on the fabric. Changes in wetting behavior and substrate surface topography were identified to be the main reasons for these observations. While all applied surface activation techniques led to higher copper contents compared to unmodified reference, the atmospheric plasma modification led to the highest copper contents during the deposition process and a more uniform appearance of the metallised layer.Highlights Three different fiber surface activation methods are evaluated. Fiber surface activation increases wetting and polymer‐metal adhesion. Activated polymer surface leads to faster copper deposition and percolation. Atmospheric plasma modification is the most efficient technique.

Initial Outcomes of Embolization for Type II Endoleak: Comparison of n-Butyl Cyanoacrylate–Ethiodized Oil Mixture with n-Butyl Cyanoacrylate–Ethiodized Oil–Ethanol Mixture

PurposeTo compare the safety and effectiveness of n-butyl cyanoacrylate (nBCA)–ethiodized oil (NE) mixture and nBCA–ethiodized oil–ethanol (NEE) mixture embolization for Type II endoleak (T2EL) after endovascular aortic repair. Materials and MethodsThis study included 32 patients with 49 procedures who underwent T2EL embolization between January 2008 and June 2022. Cases with no follow-up after embolization, technical failure, treatment with coil only, Type I endoleak at the embolization, and re-embolization were excluded. The resultant final cohort included 24 patients (14 men and 10 women; mean age, 83.3 years [interquartile range, 77–89 years]) who underwent initial T2EL embolization, with 15 patients in the NE group and 9 patients in the NEE group. The 2 groups were compared in terms of adverse events (AEs), freedom from sac enlargement, and freedom from reintervention. ResultsThe follow-up period after embolization for T2EL was 960 days (SD ± 1,007) in the NE group and 484 days (SD ± 192) in the NEE group, without significant differences. No AEs above moderate were observed in either group. The rate of freedom from sac enlargement at 1 year was 65.0% in the NE group and 87.5% in the NEE group (P = .03). The rate of freedom from reintervention at 1 year was 69.2% in the NE group and 100.0% in the NEE group (P = .02). ConclusionsThe NEE group had significantly higher rates of freedom from sac enlargement and reintervention at 1 year compared with the NE group. These results suggest that T2EL embolization with NEE may be more effective than that with NE.

Solvent-Mediated Synthesis and Characterization of Li3InCl6 Electrolytes for All-Solid-State Li-Ion Battery Applications.

Superionic halides have attracted widespread attention as solid electrolytes due to their excellent ionic conductivity, soft texture, and stability toward high-voltage electrode materials. Among them, Li3InCl6 has aroused interest since it can be easily synthesized in water or ethanol. However, investigations into the influence of solvents on both the crystal structure and properties remain unexplored. In this work, Li3InCl6 is synthesized by three different solvents: water, ethanol, and water-ethanol mixture, and the difference in properties has been studied. The results show that the product obtained by the ethanol solvent demonstrates the largest unit cell parameters with more vacancies, which tend to crystallize on the (131) plane and provide the 3D isotropic network migration for lithium-ions. Thus, it exhibits the highest ionic conductivity (1.06 mS cm-1) at room temperature and the lowest binding energy (0.272 eV). The assembled all-solid-state lithium metal batteries (ASSLMBs) employing Li3InCl6 electrolytes demonstrate a high initial discharge capacity of 153.9 mA h g-1 at 0.1 C (1 C = 170 mA h g-1) and the reversible capacity retention rate can reach 82.83% after 50 cycles. This work studies the difference in ionic conductivity between Li3InCl6 electrolytes synthesized by different solvents, which can provide a reference for the future synthesis of halide electrolytes and enable their practical application in halide-based ASSLMBs with a high energy density.