When empirical wavelet transform (EWT) is used to identify the modal parameters of civil engineering structures, the frequency band division is generally not accurate due to the noise effect on the Fourier spectrum. This phenomenon will lead to modal mixing and false modes in the analysis results. Therefore, this article establishes a signal frequency band division method by taking advantages of maximal spectrum technique and spectral skewness index. Combining the random decrement technique (RDT) and the least square method of single component modal parameter identification, an adaptive approach based on the improved EWT for operational modal parameter identification of civil engineering structures under stationary environmental excitations is proposed. The traditional frequency band division method based on EWT can not completely and effectively divide the meaningful frequency bands. While the proposed frequency band division technology based on the spectral skewness index can prevent the phenomenon of insufficient division and excessive division and realize adaptive frequency band division. The effectiveness of the proposed approach is validated by a numerical three-story frame and a field three-span concrete box girder bridge under ambient vibrations. The modal identification results from both numerical and experimental validations demonstrate that the proposed approach can effectively and accurately decompose the vibration responses and identify the structural modal parameters under operational conditions.