Mixed Fuels Research Articles

An experimental study on enhancing performance and reducing emissions of CRDI engine operated on Co-pyrolysis oil using particle swarm optimization

This study explores the use of Artificial Neural Network and Particle Swarm Optimization to improve the performance and emissions of a CRDI engine fuelled by a mixture of co-pyrolyzed oil and diesel. Experimental results show that the mixed fuels perform better than pure diesel in various engine conditions, achieving higher brake thermal efficiency and lower smoke emissions. The blend D90P10 has the highest BTE of 37.4% working at FIT 30°bTDC and FIP 500 bar. However, NO and CO2 emissions were increased for the same condition. A multi-parametric ANN model is created to build a predictive model based on this experimental data, relating inputs (fuel injection pressure, fuel injection timing, and blend percentages) to outputs (Brake Specific Fuel Consumption, NO, smoke, CO2 emissions). The ANN model attains high accuracy with R2 values of 0.99, 0.98, 0.99, and 0.99 for BSFC, NO, Smoke, and CO2 emission predictions, respectively. The results indicate that for optimal performance, the best conditions are a FIT of 29.71ºbTDC, a FIP of 500 bar, and a co-pyrolysis oil blend percentage of 19.61%. On the other hand, to minimize engine emissions, the best conditions are FIT of 20.28ºbTDC, FIP of 300 bars, and a blend percentage of 25.6%. A balanced approach results in an optimal condition of FIT at 29.5ºbTDC, FIP of 500 bars, and a blend percentage of 6.11%. Experimental validation of these optimal predictions shows a maximum error of only 3.18%, highlighting the reliability and accuracy of the model.

Prediction of emission characteristics of diesel/n-hexanol/graphene oxide blended fuels based on fast outlier detection-sparrow search algorithm-bidirectional recurrent neural network

This study aims to utilize deep learning (DL) technology to address the issue of carbon soot emission in traditional internal combustion engines. Spraying and combustion experiments were conducted in a constant volume combustion (CVC) chamber using n-hexanol and graphene oxide nanoparticles as partial substitutes for diesel, with the goal of predicting their emission characteristics based on experimental data. Initially, spray and combustion data under different operating conditions were collected using the CVC experimental setup, and outliers were removed using the fast outlier detection (FOD) algorithm. Subsequently, the learning rate and the number of hidden layer neurons in the Bidirectional Recurrent Neural Network (BiRNN) model were optimized using the Sparrow Search Algorithm (SSA) to enhance the model's accuracy and generalization ability. Unlike previous research methods, the novel FOD-coupled SSA optimization method used in this study ensures the optimal parameter configuration of the speed prediction model while accelerating the convergence speed, which ultimately improves the stability of the model. In addition, the optimal output variables were determined based on the Spearman and Pearson correlation coefficient rules. Finally, the effectiveness of the predictive model was validated using evaluation metrics such as root mean square error (RMSE) and R-squared (R2). The results indicate that the KL coefficient for D80H20GO20 fuel in the CVC device is minimal. The FOD-SSA-BiRNN model achieved R2 values of 0.99409, 0.99529, and 0.99692 for D100, D80H20, and D80H20GO20 fuels, respectively. Therefore, this study provides an effective method for the online accurate prediction of carbon soot emissions in mixed fuels.

Experimental investigation on synergistic slow oxidation and rapid combustion of micron-sized iron and aluminum powders for energy storage application

The investigation into the individual application of iron and aluminum as carbon-free fuel sources has been extensively explored and holds significant promise. However, there remains a gap in understanding synergistic effects achievable through the blending of these two fuels, as well as a need for comparative analyses between the slow oxidation and rapid combustion processes of these fuels to complement each other. This research proposes blending micron aluminum and iron powders to analyze their slow oxidation and rapid combustion features under diverse atmospheric conditions and heating rates, using thermogravimetric methods, kinetic calculations, and in-flow experiments. The research blending micron iron and aluminum powders to analyze their slow oxidation and rapid combustion features under diverse atmospheric conditions and heating rates, using thermogravimetric methods, kinetic calculations, and in-flow experiments. The findings reveal that the combination of aluminum and iron powders promotes oxidation, resulting in increased weight gain and heat flux rate compared to individual metals. Moreover, the triggering temperature rises from 545 to 652 °C with an increase in aluminum powder content. As heating rates increase, characteristic parameters T1, T2, and Hpeak2, rise for both fuels. However, aluminum powder tends to decrease Ti, while iron powder slightly increases it due to differences in oxide layers. The slow oxidation of aluminum and iron powders conforms to different models, yielding distinct oxidation patterns. The apparent activation energy of aluminum decreases from 258.4 to 238.7 kJ·mol−1 with rising heating rates, while that of iron exhibits a lower increase and remains lower than aluminum providing insights into combustion initiation conditions. Combustion initiation is contingent upon the concentration of metal powder and oxygen, with both aluminum and iron powders combustion being enhanced and subsequently attenuated with increasing excess air ratio. However, due to differing reactivity and surface passivation layers, the excess air ratio required for aluminum powder combustion (1.2–2.4) exceeds that of iron powder (1.3–1.7). The research elucidates the mechanisms underlying the slow oxidation of iron and aluminum fuels, delineates suitable combustion conditions, and furnishes new empirical and theoretical underpinnings for the oxidation characteristics of mixed iron-aluminum fuels, thereby advancing metal-fueled energy storage technologies.

TECHNOLOGICAL ASPECTS OF THE DEVELOPMENT OF A MIXED FUEL FILTER FOR DIESEL AND BIOFUELS

This article discusses the technological aspects of the development and efficient operation of a fuel filter designed to purify a mixture of diesel and biofuels. The authors analyze the engineering implementation challenges associated with the production and use of this type of filter. The article discusses in detail the technical solutions that determine the efficiency and duration of operation of such a fuel filter in conditions of use of mixed fuel. A separate section is devoted to the study of the impact of mixed fuels on engine operation, with a focus on combustion efficiency and possible cases of malfunction. The article also examines the environmental benefits of using blended fuels, focusing on reduced emissions and positive environmental impacts compared to traditional diesels. Particular attention is paid to innovative materials and technologies used to create fuel filters adapted to mixed fuels. The authors consider the advantages and disadvantages of different materials and their impact on the functionality of the filter. The article concludes with an overview of the standards and regulations that govern the use of blended fuels, with a focus on fuel filter requirements to ensure safety, efficiency, and environmental compliance. Taking into account current trends in the development of fuel systems, the article is aimed at supporting engineers, scientists and specialists from the automotive and energy industries in improving the technologies of blended fuels and their elements.

Revolutionizing Fuel Efficiency with Optimal Octane Mixtures

Increasing the octane value of fuel can significantly improve engine performance and efficiency. This study explores mixing fuels with different octane ratings to achieve a desired balance of high octane and cost-effectiveness. Fuels with octane numbers 82, 86, 92, and 96 were mixed in various ratios (30%, 50%, 70%) of premium, pertalite, pertamax, and pertamax turbo. Results showed that mixtures like premium and pertalite (octane 85) and premium and pertamax turbo (octane 93) effectively increased octane levels. The study concludes that mixing fuels can enhance octane values and optimize fuel composition for better performance and cost efficiency. Future research could further explore various fuel types and ratios. Highlight: Mixing fuels increases octane rating and engine performance. Optimal fuel composition balances high octane and cost-effectiveness. Significant results with premium and pertamax turbo mixture. Keywoard: Octane Rating, Fuel Mixing, Engine Performance, Fuel Efficiency, Cost-Effective Fuel

Augmentation of hot cell facility for pyro-process of irradiated metal fuels

Hot cells with an inert atmosphere are used for handling air-sensitive, hygroscopic, and radioactive materials like mixed carbide fuels and for pyro-processing metallic fuels. Pyro-processing of spent metal fuels was based on the electrochemical recovery of actinides in high-temperature molten salts (LiCl-KCl eutectic with 58.5 mol.% LiCl). To demonstrate the remote operation feasibility of the electro-refining process of irradiated U-6 wt% Zr inside hot cells and also to study the process parameters, a pilot scale (∼100 g) pyro-process facility was set up in one of our hot cells. For this purpose, the existing hot cell facility was augmented with necessary modifications and customized to the experimental needs. This paper discusses in detail the augmentation works carried out on the existing facility to facilitate the remote operation of electro-refining of irradiated metallic fuels.

Efficiency Evaluation of Using Water-Fuel Emulsion as Fuel for Automobiles

Road transport is the main consumer of petroleum fuel as well as a source of toxic substances. Therefore, reducing fuel consumption and emissions of harmful substances in road transport is one of the most important problems facing modern engine construction. One of the ways to solve this problem is through the use of mixed fuels, including water-fuel emulsions. Water-fuel emulsion is a promising alternative fuel that could fulfill such requests in that it can improve the combustion efficiency of internal combustion engines and reduce harmful exhaust emissions, especially nitrogen oxide (NOx) and particulate matter (PM). Up to now, there have been many studies on water-fuel emulsions, especially on performance, emissions and micro-explosion phenomena. Using water-fuel emulsion as fuel for ships worldwide was studied and applied to the 80-ies of the last century, but using it for automobiles is still limited by the emulsion stability and economic difficulties to calibrate engine parameters for a new fuel. This article provides an overview of the mechanism and performance operating cycle of internal combustion engines using water-fuel emulsions and the efficiency, economy, and environmental friendliness of this fuel type for automobiles. Hence, conclusions are drawn about the possibility and effectiveness of using emulsions as fuel for automobiles, especially under conditions in Vietnam.

Effect of preparation method of pyrolysis liquid mixed with coal on its ignition and combustion characteristics

Relevance. The need to develop technological solutions to increase the competitiveness of pyrolysis processing of various wastes. Combustion of pyrolysis liquid in a mixture with coal is one of these solutions, which makes it possible to stabilize the properties of the obtained fuel and use in standard energy equipment. Aim. To determine the influence of the method of preparing a mixture of pyrolysis liquid and low-grade coal on its ignition and combustion characteristics, as well as on composition of the released gas-phase products, depending on the temperature of heating medium and concentration of the additive. Methods. Pyrolysis and oxidation characteristics were studied using thermogravimetric analysis, and formal kinetic constants were calculated using the Coates–Radfern method. Samples of mixed fuels were prepared by the methods of homogeneous mixing and surface wetting of pyrolysis liquid of rubber processing and low-grade coal. Ignition and combustion characteristics were determined using an experimental stand, and composition of gas-phase combustion products was determined using once-through gas analyzer. Results. The authors have determined the features of pyrolysis and oxidation of the pyrolysis liquid as well as the values of formal kinetics constants, indicating the physical nature of the factors that defining the rate of these processes. It was found that at 600 °C the ignition of the studied mixtures weakly depended on concentration of the additive, while at 700 and 800 °C the dependence was linear, and the differences between the samples prepared using different methods were insignificant. For samples obtained by the method of surface wetting, combustion of the additive occurred in the gas phase near the surface of the sample. For the samples obtained by the method of uniform mixing, it occurred predominantly in the bulk of the backfill. This led to more intense and complete coal combustion in these compositions due to more uniform releasing of heat and initiation of coal particles. The concentration curves of the NO, CO and CO2 release demonstrated, that behavior of the fuel mixture components was additive in terms of released gas-phase combustion products, as well as the absence of significant nonlinear effects over the entire studied range of temperatures and additive concentrations.

Numerical Simulation of a Gas Burner Using Mixed Propane/Ammonia Fuel

In recent years, ammonia has received more and more interest to be used as carbon-free energy. In the present study, a computational model of a burner for the domestic hot water boiler in the building has been developed. The combustion characteristics of propane/ammonia-mixed fuel in the burner were investigated by numerical simulation under different ammonia blending ratios and equivalence ratios. Based on the flue gas concentration distribution of the numerical simulation results, the baseline carbon emission of hot water supply in a community was calculated. The results show that as the ammonia blending ratio increases, the overall combustion temperature decreases. At the outlet of the burner, when the ammonia blending ratio is 0.5, the emission concentration of carbon dioxide can be reduced by 31.4% compared to pure propane combustion. When the ammonia blending ratio increases from 0 to 50%, the carbon baseline emission decreases from 9.89 kg/GJ to 6.87 kg/GJ, and the carbon emission under the baseline decreases from 17.20 T to 11.94 T. The emission of NO pollutants remains basically unchanged due to the decrease of combustion temperature. It indicates that the mixed fuels can effectively reduce carbon emissions in domestic water heaters and have good potential for future application.

Effect of lignin on coal slime combustion characteristics and carbon dioxide emission

The escalating total amount of industrial solid waste is increasingly taxing the ecological environment. Co-combustion technology is seen as a potential solution to this problem. This study investigated the interaction mechanism and carbon dioxide emissions during the co-combustion process of coal slime and biomass (lignin) using a programmed heating method. The experimental results reveal that the two sub-reaction models effectively depict the combustion process of coal slime. In the co-combustion process, the comprehensive combustion and ignition performance of the mixed fuels surpasses that of coal slime, but the stability of the combustion flame is reduced. The combustion performance of the mixed fuel is primarily influenced by two common factors. The interaction between lignin and coal slime significantly changes with the variation of mixing ratio and heating rate. The main product in the combustion process of mixed fuels is carbon dioxide. Due to the competition for oxygen among volatile matter, the emission of carbon dioxide is lower than the theoretical value. When the mass percentage of lignin is 70 %, the impact on carbon dioxide is most pronounced. The experimental results of this study provide a foundation for understanding the interaction mechanism of coal slime and biomass co-combustion. The research findings also provide theoretical guidance for the safe operation of coal slime and biomass co-combustion equipment.

Dry and Hydrothermal Co-Carbonization of Mixed Refuse-Derived Fuel (RDF) for Solid Fuel Production

The present study aims to test several conditions of the thermochemical pretreatment of torrefaction and carbonization to improve the physical and combustible properties of the Portuguese RDF. Therefore, two different types of RDF were submitted alone or mixed in 25%, 50%, and 75% proportions to dry carbonization processes in a range of temperatures between 250 to 350 °C and residence time between 15 and 60 min. Hydrothermal carbonization was also carried out with RDF samples and their 50% mixture at temperatures of 250 and 300 °C for 30 min. The properties of the 51 chars and hydrochars produced were analyzed. Mass yield, apparent density, proximate and elemental analysis, ash mineral composition, and higher heating value (HHV), among others, were determined to evaluate the combustion behavior improvement of the chars. The results show that after carbonization, the homogeneity and apparent density of the chars were increased compared to the raw RDF wastes. The chars and hydrochars produced present higher HHV and lower moisture and chlorine content. In the case of chars, a washing step seems to be essential to reduce the chlorine content to allow them to be used as an alternative fuel. In conclusion, both dry and wet carbonization demonstrated to be important pretreatments of the RDF to produce chars with improved physical and combustion properties.

ReaxFF molecular dynamics simulation on the combustion mechanism of toluene/ethanol/n-heptane mixed fuel

The addition of ethanol and toluene to diesel fuel serves as an effective approach to mitigate engine knock. In this work, we employed ReaxFF molecular dynamics simulations to investigate the oxidation of toluene, ethanol, and n-heptane mixed fuels. Results show that toluene, ethanol, and 60.12 % of n-heptane molecules initiate dehydrogenation via active species such as O2, OH, HO2, etc. The initial decomposition mechanisms of the remaining n-heptane molecules involve the fission of CC bonds and direct dehydrogenation reactions. The formation of intermediate C2H4 primarily occurs via β-cleavage of saturated alkyl radicals with higher carbon atom numbers. The products CO and CO2 molecules strongly depend on the concentrations of C2H4 and CH3. Notably, the incorporation of ethanol/toluene in the system diminishes the presence of OH, thereby decreasing the consumption of C2H4 by OH. The activation energy values (43.36 ∼ 45.19 kcal mol−1) align well with experimental data.

Novel Method for Desulfurization of Mixed Fuel via Microbubble Oxidation Followed by Microtube Extraction

Novel Method for Desulfurization of Mixed Fuel via Microbubble Oxidation Followed by Microtube Extraction

Breathing Planet Earth: Analysis of Keeling’s Data on CO2 and O2 with Respiratory Quotient (RQ), Part I: Global Respiratory Quotient (RQGlob) of Earth

In biology, respiratory quotient (RQ) is defined as the ratio of CO2 moles produced per mole of oxygen consumed. Recently, Annamalai et al. applied the RQ concept to engineering literature to show that CO2 emission in Giga Tons per Exa J of energy = 0.1 ∗ RQ. Hence, the RQ is a measure of CO2 released per unit of energy released during combustion. Power plants on earth use a mix of fossil fuels (FF), and the RQ of the mix is estimated as 0.75. Keeling’s data on CO2 and O2 concentrations in the atmosphere (abbreviated as atm., 1991–2018) are used to determine the average RQGlob of earth as 0.47, indicating that 0.47 “net” moles of CO2 are added to which means that there is a net loss of 5.6 kg C(s) from earth per mole of O2 depleted in the absence of sequestration, or the mass loss rate of earth is estimated at 4.3 GT per year. Based on recent literature on the earth’s tilt and the amount of water pumped, it is speculated that there could be an additional tilt of 2.7 cm over the next 17 years. While RQ of FF, or biomass, is a property, RQGlob is not. It is shown that the lower the RQGlob, the higher the acidity of oceans, the lesser the CO2 addition to atm, and the lower the earth’s mass loss. Keeling’s saw-tooth pattern of O2 is predicted from known CO2 data and RQGlob. In Part II, the RQ concept is expanded to define energy-based RQGlob,En, and adopt the CO2 and O2 balance equations, which are then used in developing the explicit relations for CO2 distribution amongst atm., land, and ocean, and the RQ-based results are validated with results from more detailed literature models for the period 1991–2018.

The role of bioenergy in Brazil's low-carbon future

The urgency of climate change requires a clear understanding of how global technological trends can alter a country's least-cost, low-carbon strategy (net-zero), considering its own advantages in terms of resources, existing knowledge, and energy facilities and converters. This study compares Brazil's least-cost strategies to reach net zero CO2 emissions by 2050 with strategies based on the technological development patterns suggested by the most recent International Energy Agency's (IEA) net zero report, which are assumed to represent global trends in technology deployment for climate mitigation. Our study is based on the use of an Integrated Assessment Model (IAM) for Brazil. Four different mitigation scenarios are explored. Results show that the IEA technological profile deeply differs from a non-constrained technological deployment for Brazil, particularly in terms of the liquid fuels mix and the time of implementation of electric-driven mobility. In Brazil, biofuels use stand out as the least-cost solution to reach net zero emissions by 2050, mostly due to the use of bioenergy with carbon capture and storage (BECCS), which can slow down fossil fuel phase out in the country. Nevertheless, a hybrid strategy can include the use of ethanol or even hydrogen fuel cells in electric powertrains, though this would require further research and development.

The performance of reaction mechanism in prediction of the characteristics of the diffusive-thermal oscillatory instability of methane–hydrogen–air burner-stabilized flames

In this work the performance of various detailed reaction mechanisms of combustion of methane–hydrogen fuel mixtures is studied. The investigation is focused on the burner stabilized flame configuration and is undertaken for the normal pressure conditions, which is a starting point for the analysis of the combustion chemistry at elevated pressures met in rocket engine chambers. The study presents the experimental setup, computational approach and results of comparison, which allow us to access the properties of complex combustion systems in variety of dynamical regimes. The comparison of the predicted and measured characteristics of these regimes is used to test the performance of the reaction models. In particular, the critical behavior, e.g. for blow-up, onset of pulsations and quasi-steady flame front propagation and bifurcation between these regimes may be used to characterize and to study properties of combustion systems with mixed fuels. A neutral stability boundary for onset of pulsations is suggested to be used in this study. A method for automatic identification of the boundary is proposed and implemented with several detailed mechanisms. Although for pure methane the results look acceptable, they show gradual divergence with the increase of percentage of hydrogen addition. Significant quantitative differences between experiments and modeling with respects to frequencies of oscillations are reported even for 2:1 ratio of hydrogen to methane in the unburned mixture. The results of the work indicate that current reaction mechanisms need to be improved in order to gain the quantitative predictability of methane–hydrogen–air combustion at normal pressure before proceeding to the conditions fuel-oxygen high pressure combustion more relevant for rocket chamber.

Optimization effect of propylene oxide (PO) on evaporation, combustion, and pollutant emissions of high-energy–density JP-10 fuel

JP-10 is a high-energy–density fuel that is widely used in aerospace propulsion systems due to its wide range of synthetic raw materials and low production costs. However, it faces challenges related to difficult ignition, low combustion efficiency and high pollutant emissions. To address this, blending JP-10 with propylene oxide (PO), a highly volatile substance, provides a practical solution. This study investigates the propagation and evolution characteristics of JP-10/PO binary fuel in large horizontal pipelines. The results demonstrate a synergistic enhancement effect achieved by the JP-10/PO hybrid fuel. PO, with its lower boiling point, quickly evaporates from the mixed droplets, creating a continuous primary flame. As the droplet temperature increases, JP-10, known for its high combustion heat, starts to evaporate, actively participating in the explosion process and forming a secondary flame that spreads in two directions. The combustion of the JP-10/PO mixed droplets involves both physical and chemical processes, including droplet evaporation and gaseous combustion. A binary droplet evaporation model is developed to quantitatively assess the impact of PO fuel ratio on spray evaporation. Additionally, the study examines steam explosion parameters and reaction product characteristics under different PO fuel ratios. It is observed that the evaporation of JP-10/PO mixed droplets occurs in three stages: transient heating, binary equilibrium evaporation, and single component equilibrium evaporation. Increasing the PO fuel ratio leads to a higher temperature rise rate of the droplets and an increased evaporation reaction rate constant. Moreover, the ignition delay time of JP-10/PO gas-phase mixture fuel decreases, while the adiabatic flame temperature gradually reduces. Furthermore, higher PO fuel ratios help reduce the emissions of unstable products in both mixed fuels due to the inherent oxygen content of PO molecules. The current research results can provide scientific references for the improvement of high-energy density fuels and the development of new propellants.

Confined deflagration of propanal/air in the presence of intrinsic instability at elevated pressures

The partial oxidation process is a chemical technique with a high risk of deflagration, which involves directly mixing of fuels with oxidizers at elevated conditions. Under non-standard conditions, the deflagration behaviors of fuels are often unavailable to the general public, which hampers progress in further basic research. In this study, the deflagration behaviors of propanal-air mixtures at 75 °C and 0.1–1.0 MPa were investigated, and the effect of initial pressure (P0) and equivalence ratio (φ) on the deflagration characteristics of propanal was discussed. To explain the similarities and differences in the deflagration characteristics under various conditions, the buoyancy instability, hydrodynamic instability and thermal-diffusion instability suffered by the flames were also analyzed. Results show that the pressure generated by the burned mixture is a cubic function of time, and the state of flame propagation can be determined by the monotonicity of the second-order derivative of pressure. Moreover, the peak deflagration pressure (Pm) is more sensitive to changes in φ on the fuel-lean side, but Pm/P0 at the fuel-rich condition is markedly higher than Pm/P0 at the fuel-lean condition. At all φ, an increase in P0 effectively shortens the ignition time and reduces the minimum ignition energy. Nevertheless, there are discernible differences in the variation patterns of the deflagration time (θm) with P0 at various φ. Specifically, θm gradually prolongs with increasing P0 at fuel-lean conditions, whereas it tends to be the same at different P0 and φ = 1. Furthermore, under fuel-rich conditions, θm progressively shortens as P0 increases. The decrease in θm is attributed to the increasing flame speeds in the presence of intrinsic instability, and the self-accelerating flame yields pressure waves, which travel faster than the flame. Then a series of reflected pressure waves are formed after the pressure waves strike the vessel wall, interacting with the flame front and resulting in the pressure oscillation. Moreover, increasing P0 advances the pressure oscillation and augments the intensity of pressure oscillation.

Synthesis of hydroxyapatite via sol–gel combustion route: A comparative analysis of single and mixed fuels

Hydroxyapatite (HAp) is a highly biocompatible mineral source for bone and soft tissue repair, owing to its similarities to native bone. Researchers have adopted combustion synthesis by using various fuels for the synthesis of hydroxyapatite. This study sheds new light on the effects of glycine and succinic acid as single fuels as well as a mixed fuels for hydroxyapatite synthesis. A marked observation from the comparative analysis was that mixed fuels with an optimum ratio resulted in the formation of hydroxyapatite in a single phase with an average crystallite size of 21–23 nm. However, single fuels, such as glycine and succinic acid, produce hydroxyapatite with larger crystallite sizes of 25–28 nm and 38–41 nm. Additionally, the use of mixed fuels facilitated the product formation at a lower temperature of 500 °C, whereas single fuels produced hydroxyapatite at an elevated temperature of 900 °C.

Emission reduction and cost-benefit analysis of the use of ammonia and green hydrogen as fuel for marine applications

Increasingly stringent emission standards have led shippers and port operators to consider alternative energy sources which can reduce emissions while minimizing capital investment. It is essential to understand whether there is a certain economic investment gap for alternative energy. The present work mainly focuses on the simulation study of ships using ammonia and hydrogen fuels arriving at Guangzhou Port to investigate the emission advantages and cost-benefit analysis of ammonia and hydrogen as alternative fuels. By collecting actual data and fuel consumption emissions of ships arriving at Guangzhou Port, the present study calculated the pollutant emissions and cost of ammonia and hydrogen fuels substitution. As expected, it is shown that with the increase of NH3 in fuel, mixed fuels will effectively reduce CO and CO2 emissions. Compared to conventional fuel, the injection of NH3 increases the NOx emission. However, the cost savings of ammonia fuel for CO2, SOx and PM10 reduction are higher than that for NOx. In terms of pollutants, ammonia is less expensive than conventional fuels when applied to the Guangzhou Port. However, the cost of fuel supply is still higher than conventional energy as ammonia has not yet formed a complete fuel supply and storage system for ships. On the other hand, hydrogen is quite expensive to store and transport, resulting in higher overall costs than ammonia and conventional fuels, even if no pollutants are produced. At present, conventional fuels still have advantage in terms of cost. With the promotion of ammonia fuel technology and application, the cost of supply will be reduced. It is predicted that by 2035 ammonia will not only have emission reduction benefits, but also will have a lower overall economic cost than conventional fuels. Hydrogen energy will need longer development and technological breakthroughs due to the limitation of storage conditions.