Minor Grains Research Articles

Biotechnological approaches to reduce the phytic acid content in millets to improve nutritional quality.

The review article summarizes the approaches and potential targets to address the challenges of anti-nutrient like phytic acid in millet grains for nutritional improvement. Millets are a diverse group of minor cereal grains that are agriculturally important, nutritionally rich, and the oldest cereals in the human diet. The grains are important for protein, vitamins, macro and micronutrients, fibre, and energy sources. Despite a high amount of nutrients, millet grains also contain anti-nutrients that limit the proper utilization of nutrients and finally affect their dietary quality. Our study aims to outline the genomic information to identify the target areas of research for the exploration of candidate genes for nutritional importance and show the possibilities to address the presence of anti-nutrient (phytic acid) in millets. So, the physicochemical accessibility of micronutrients increases and the agronomic traits can do better. Several strategies have been adopted to minimize the phytic acid, a predominant anti-nutrient in cereal grains. In the present review, we highlight the potential of biotechnological tools and genome editing approaches to address phytic acid in millets. It also highlights the biosynthetic pathway of phytic acid and potential targets for knockout or silencing to achieve low phytic acid content in millets.

A comprehensive analysis on nutritional composition, functional properties, antioxidant and enzyme inhibitory potential of selected minor millet grains

Minor millets regarded as storehouse of proteins, dietary fibres, minerals, vitamins, fatty acids and phytochemicals have nutrigenomic role in human health. Determination of such components is an essential approach to choose highly efficient millet grains. Hence, this study has estimated and compared the mineral composition, proximates, functional properties, phytochemical and in vitro pharmacological properties of the seed grains of Setaria italica (Foxtail millet), Echinochloa frumentacea (Barnyard millet), Paspalum scrobiculatum (Kodo millet), and Panicum sumatrense (Little millet) cultivated in Kolli hills of Tamil Nadu, India. Mineral analysis revealed the presence of calcium, copper, magnesium, manganese, iron, phosphorus, potassium, and zinc. Occurrence of high content of protein, carbohydrate and vitamin E were also ascertained. The proximate composition (moisture, ash, crude lipid, and crude fibre) and functional features (water and oil absorbing capacity, bulk density, foaming and emulsifying property) of these millet flours have demonstrated their potential in food product formulation, particularly weaning foods. Total phenolic content was ranged between 53.28±0.71 and 110.42 ± 1.42 mg GAE g−1 of dried extract; and total flavonoid content was in the range of 23.80±1.09 to 65.1 ± 1.23 mg QE g−1 of dried extract in the studied millets. Significant free radical scavenging and enzyme inhibition activity was observed in P. sumatrense (IC50 of 128.92±1.18 µg mL−1 in DPPH assay), E. frumentacea (IC50 of 120.89±1.46 µg mL−1 in ABTS assay and 126.52±0.78 µg mL−1 in tyrosinase inhibition assay), S. italica (IC50 of 119.94±1.40 µg mL−1 in SO radical scavenging assay) and P. scrobiculatum (IC50 of 101.59±1.27 µg mL−1 in α-amylase enzyme inhibition assay and 94.63±0.78 µg mL−1 in α-glucosidase enzyme inhibition assay). The findings highlight the nutraceutical ability of these minor millets which can be employed as a valuable ingredient in food product preparation.

Compressive creep behavior of selective electron beam melted high Nb containing TiAl alloy

In this study, the compressive creep behavior of Ti–45Al–8Nb alloy fabricated by selective electron beam melting technology at 800 °C and 850 °C was investigated. This alloy is mainly composed of equiaxed γ grains, and minor α2 and B2 grains. Creep results show that compressive creep behavior of this alloy is dependent on temperature, which is manifested in the significant increase of creep strain and creep rate with the increase of temperature. Through a multi-step creep test, the stress exponent n (2.65 at 800 °C and 3.65 at 850 °C) and activation volume V* (36.49 b3 at 800 °C and 53.51 b3 at 850 °C) were measured. Combined with kinetic analysis based on n and V* and TEM observation, compressive creep deformation of this alloy at 800 °C and 850 °C is dominated by dislocation motion, including dislocation slip and climb. Additionally, mechanical twinning also plays an important role in creep deformation. Driven by dislocation pile-ups or mechanical twins, discontinuous dynamic recrystallization (DDRX) occurs during creep. The degree of DDRX at 850 °C is greater. Sufficient DDRX greatly softens the alloy and accelerates creep rate, resulting in no steady-state creep stage at 850 °C.

Arima Forecasting In Soymeal And Beyond: An Empirical Study Bridging The Path To Millet-Based Forecasting

Soymeal, a rich source of protein and fiber, held paramount importance in livestock and poultry sectors. Derived post oil extraction from soybean seeds, its production and price dynamics hinged on multiple factors including seed supply-demand, crushing costs, transportation expenses, and competition from alternative feed constituents. The study aimed to employ the Autoregressive Integrated Moving Average (ARIMA) model to forecast soymeal production, import, export, and price trends globally for year 2023 by using data from 2016 to 2022. By combining historical insights with predictive analytics, the paper endeavored to illuminate the prospective trajectory of soymeal dynamics on a global scale, offering valuable insights for stakeholders. Moreover, it is noteworthy that the applicability of the ARIMA forecasting model extends beyond soymeal, encompassing other agricultural commodities such as millets and other minor grains. Millets, celebrated for their nutritional value and resilience, hold immense potential in addressing global food security challenges. The ARIMA model's capability to unravel temporal intricacies and patterns could likewise provide insights into millet production, pricing, and trade, contributing to the sustainable development of diverse agricultural sectors. This research not only enriches our understanding of soymeal dynamics but also underscores the versatility of the ARIMA model for forecasting a spectrum of agricultural commodities, promoting informed decision-making and strategic planning.

Anomalous Enrichment of As and Hg in Underground Coal Dust: A Case from Xishan Coalfield, Shanxi Province, North China.

Coal dust is an important source of coal workers' pneumoconiosis, which is harmful to the health of underground workers. The coal dust samples were directly collected using a coal dust sampler from four major production positions in the underground coal mine. The particle size distribution, mineralogy, and occurrence of As and Hg in the coal dust samples were investigated. The results indicated that the contents of As and Hg were depleted or normal in the parent coal samples compared with the average values of C-P coal in North China and Chinese coal, but they were anomalously enriched in coal dusts. The concentrations of As and Hg in the coal dust samples studied are greater than the values of the elements in the parent coal. The As content in the coal dust samples studied is about one to three orders of magnitude above the parent coal value and the Hg content in the studied coal is 1.28 to 20.28 times higher than the parent coal value. The modes of occurrences of As and Hg were studied by sequential chemical extraction in combination with field emission scanning electron microscopy-energy dispersive spectroscopy (FESEM-EDS) and high-resolution transmission electron microscopy-EDS (HRTEM-EDS). The occurrence of As is dominated mainly by pyrite and secondarily by carbonate and silicate in the coal dust samples. Pyritic Hg and organic Hg may be the dominant forms in mining face and heading face samples, and carbonate and pyritic Hg are the main forms in rocks roadway and return airway samples. It is considered that the mechanochemical effect resulted in the formation of surface active sites and modification of the morphology. Harmful trace elements, such as As, Cd, Hg, Se, Pb, Co, Sb, and Tl, and minor grains associated with nanominerals that bear much hazardous elements, could easily be originally fractionated or adsorbed by airborne particulates. This research aims to provide a theoretical basis for the prevention of occupational disease and underground environmental evaluation.

Evidence for abundant organic matter in a Neoarchean banded iron formation

Abstract Microbial Fe(II) oxidation has been proposed as a major source of Fe minerals during deposition of banded iron formations (BIFs) in the Archean and Proterozoic Eons. The conspicuous absence of organic matter or graphitic carbon from BIFs, however, has given rise to divergent views on the importance of such a biologically mediated iron cycle. Here, we present mineral associations, major element concentrations, total carbon contents and carbon isotope compositions for a set of lower amphibolite-facies BIF samples from the Neoarchean Zhalanzhangzi BIF in the Qinglonghe supracrustal sequence, Eastern Hebei, China. Graphite grains with crystallization temperatures (~470 °C) that are comparable to that predicted for the regional metamorphic grade are widely distributed, despite highly variable iron (12.9 to 54.0 wt%) and total organic carbon (0.19 to 1.10 wt%) contents. The crystalline graphite is interpreted to represent the metamorphosed product of syngenetic bio-mass, based on its co-occurrence with apatite rosettes and negative bulk rock δ13Corganic values (–23.8 to –15.4‰). Moreover, the crystalline graphite is unevenly distributed between iron- and silica-rich bands. In the iron-rich bands, abundant graphite relicts are closely associated with magnetite and/or are preserved within carbonate minerals (i.e., siderite, ankerite, and calcite) with highly negative bulk rock δ13Ccarb values (–16.73 to –6.33‰), indicating incomplete reduction of primary ferric (oxyhydr) oxides by organic matter. By comparison, only minor graphite grains are observed in the silica-rich bands. Normally, these grains are preserved within quartz or silicate minerals and thus did not undergo oxidation by Fe(III). In addition, the close association of graphite with iron-bearing phases indicates that ferric (oxyhydr)oxides may have exerted a first order control on the abundance of organic matter. Combined, the biological oxidation of Fe(II) in the oceanic photic zone and subsequent burial of ferric (oxyhydr)oxides and biomass in sediments to form BIFs, suggests that a BIF-dependent carbon cycle was important in the Archean Eon. Although significant re-adsorption of phosphorus to ferric (oxyhydr)oxides and the formation of authigenic phosphate minerals at the sediment-water interface would be expected, oxidation of biomass in BIFs may have recycled at least a portion of the P (and other nutrients) released from reactions between organic matter and ferric (oxyhydr)oxides to the overlying water column, potentially promoting further primary productivity.

Minor millets: a review on nutritional composition, starch extraction/modification, product formulation, and health benefits.

Minor millet grains are the abode of healthy constituents of human concern that contribute to healthy longevity. Additionally, they are excellent in nutritional value including macronutrients namely, protein (7-13%), carbohydrates (60-70%), fat (1.5-5%), fiber (2-7%) and for micronutrients as well namely; iron, calcium, phosphorus, and magnesium, etc. All these beneficial traits along with the availability of bioactive constituents (polyphenols and antioxidants) prove them to be therapeutic in action and also uplift the immunity among users. Employed isolation tactics for starch also govern yield characteristics and is usually preferred by way of wet method. Minor millets are abundant in starch (50-70%) thus application broadness is another attribute which could be addressed in vivid food segments. In case, native starches somehow possess least application credentials in food and non-food sectors thus modification is the only alternative to eliminate shortcomings. As in trend, modification using physical, chemical, and enzymatic ways have a wide impact on the properties of millet starch. The present review summarizes the nutritional, bioactive and therapeutic potential of minor millets, along with ways of starch modification and product development through millet involvement. © 2023 Society of Chemical Industry.

New geochronological and provenance constraints on the Late Mesozoic sedimentary formations in the western Shandong Province and Tanlu fault zone, China

We present new LA-ICP-MS detrital zircon U-Pb age and trace element data of the Late Mesozoic sedimentary sequences from the western Shandong and Tanlu fault zone, with the aim to constrain the depositional ages and sedimentary sources. The samples from the western Shandong have similar U-Pb age spectra, which can be divided into three major age groups, peaking age at circa 2,475–2,540 Ma, 1820–1870 Ma and 257–285 Ma, with minor Mesoproterozoic, Neoproterozoic and Paleozoic detrital zircon grains. The sample JN recovered from the Tanlu fault zone has an overwhelming majority of the Early Cretaceous detrital zircons with the age peak at circa 125 Ma, whereas the Archean and Paleoproterozoic detrital zircons are subordinate. The weighted average age of the youngest zircons show that the Santai Formation probably had begun deposition at circa 158 Ma and terminated deposition at circa 150 Ma, and the Tianjialou Formation of the Dasheng Group had begun deposition at circa 122 Ma. Our study indicates that the activity of the dinosaurs might occur during the Late Jurassic rather than the Cretaceous in the Shandong province. In addition, most detrital zircons of the studied samples are characterized by the high Th/U ratios and left-inclined REE patterns, revealing a magmatic origin. Morphologically, most detrital zircon grains characterized by angular to sub-rounded shapes indicate a middle-short distance transport from the source regions, whereas minor detrital zircon grains show rounded shapes, indicating a long-distance transport or multiphase recycling. According to detrital age populations in this study, combined with previously published data, we conclude that depositional provenances of the Santai Formation were mainly derived from the western Shandong and Jiao-Liao Belt, and minor detritus were derived from the northern part of the North China Craton and Xing-Meng orogenic belt. The sediments deposited in the Tanlu fault zone were mainly derived from the volcanic and subvolcanic rocks of the Qingshan period in the eastern Shandong, and subordinate depositional sources were from the Jiao-Liao and the basement uplift of the western Shandong, with minor supplier being derived from the Yinshan-Yanshan orogenic belt. The detrital provenance of the Santai Formation indicates that extension of the eastern NCC occurred during the Late Jurassic. The Neoproterozoic detrital zircons play a minor role in the studied strata, indicating that the large sinistral movement of the Tanlu fault zone might have occurred at the Early-Middle Jurassic and formed a paleogeographic separation of the western Shandong and eastern Shandong (Sulu orogenic belt).

Some Mineralogical Characteristics of the Egyptian Black Sand Beach Ilmenite Part I: Homogeneous Ilmenite and Titanhematite-Ferriilmenite Grains

The high-grade Egyptian beach ilmenite concentrate contains various mineral textures in addition to the main homogeneous ilmenite grains (63%), which may contain solid solutions of geikielite (MgTiO3) and pyrophanite (MnTiO3) mineral components. Few homogeneous ferrilmenite grains (2%) associated with the concentrated ilmenite grains are detected. The contents of Fe2O3, MgO, Al2O3, and Cr2O3 in the ferrilmenite grains range between 7.3% and 22.8%, 3.4% and 6.6%, 0.2% and 0.7%, and 0% and 1.2% respectively. The detected hematite-ilmenite exsolved intergrowths (21.4%) have titanhematite exsolutions of different shapes, sizes, and orientations. They occupy 5%-40% of the whole intergrowth and may show one or two distinct generations. In some ferrilmenite components, MnO ranges between 1.5% and 8.6%. The Cr2O3 and Al2O3 contents range between 0% and 1.2% and 0% and 3.2% respectively. They are mostly between 0% and 0.1% for either of the ferrilmenite components, while relatively greater content is present in the titanhematite components. In some grains, the titanhematite exsolution bodies are replaced by goethite or hydrated iron oxides. In others, the ferrilmenite intergrowth may be partially or completely altered into leucoxene. Some minor composite grains are detected in the concentrate, where each grain consists of two parts, one part is titanhematite-ferrimenite and the other is ferrilmenite-titanhematite. The titanhematite exsolved components have relatively lower TiO2 content (5.8%-23.8%). Both MgO and MnO are positively correlated with FeO rather than Fe2O3. The presence of sphenes in the obtained ilmenite concentrate may be responsible for the recorded amounts of SiO2 (30.1%-30.8%) and CaO (28.1% and 28.8%). The Cr2O3 content is relatively much higher in sphene spots than in ilmenite spots, ensuring that Cr2O3 neither follows TiO2 nor FeO. The nature of the problem of the relatively lower Ti content and the relatively higher Fe and Cr contents of the obtained ilmenite concentrates is the target of the article. The problem is related to the mineralogy of ilmenite or to the used physical concentration flowsheet of the separated concentrate and the ability to improve the ilmenite concentrate’s specifications. It is concluded that although the homogeneous ilmenite is characterized by low Cr2O3 content, some of the other exsolved texture components, e.g. titanhematite and sphenes, have relatively higher Cr2O3, in addition to Fe2O3, SiO2, or CaO. They can negatively affect the marketable specifications of the separated Egyptian black sand ilmenite concentrate.

Fermented Minor Grain Foods: Classification, Functional Components, and Probiotic Potential.

Fermented minor grain (MG) foods often have unique nutritional value and functional characteristics, which are important for developing dietary culture worldwide. As a kind of special raw material in fermented food, minor grains have special functional components, such as trace elements, dietary fiber, and polyphenols. Fermented MG foods have excellent nutrients, phytochemicals, and bioactive compounds and are consumed as a rich source of probiotic microbes. Thus, the purpose of this review is to introduce the latest progress in research related to the fermentation products of MGs. Specific discussion is focused on the classification of fermented MG foods and their nutritional and health implications, including studies of microbial diversity, functional components, and probiotic potential. Furthermore, this review discusses how mixed fermentation of grain mixtures is a better method for developing new functional foods to increase the nutritional value of meals based on cereals and legumes in terms of dietary protein and micronutrients.

A petrologic and microstructural study of a compact type A calcium‐aluminum‐rich inclusion from the Northwest Africa 5028 CR2 chondrite: Implications for nebular and parent‐body processes

AbstractCompact type A calcium‐aluminum‐rich inclusions (CTA CAIs) are believed to have experienced partial melting that erased all information on their original nebular condensation. To investigate this question, we report new microstructural data on a CTA CAI, composed primarily of melilite, spinel, and perovskite, in the Northwest Africa 5028 CR2 chondrite. The melilite grains contain low (5–10 mole%) åkermanite contents and are not compositionally zoned. Spinel and perovskite each occur as near endmember compositions MgAl2O4 and CaTiO3 and contain minor V and Al, respectively. A continuous rim composed of melilite, spinel, and perovskite, with minor hibonite grains occur around the CAI. We extracted two regions of interest from the interior CAI and two from the rim using focused ion beam techniques for detailed analysis using transmission electron microscopy. Evidence for thermal processing occurs as a perovskite–spinel–spinel triple junction in an interior section and a spinel inclusion within perovskite in a rim section. Evidence for parent‐body alteration occurs in the form of Fe‐rich sheet silicates in the rim, and localized amstallite in the interior of the CAI. While previous work suggested that many CTA CAIs experienced thermal processing in the solar nebula, including partial melting, our data show that signatures of primary condensation can be preserved in the form of more refractory phases contained within less refractory minerals, namely melilite and perovskite grains within spinel, and hibonite grains within perovskite, respectively. The inclusion we report on here has a complex history involving gas‐phase condensation, nebular thermal processing, and parent‐body alteration.

Geochronology, ore-forming processes and fluid sources of the Qinglonggou gold deposit, North Qaidam (NW China): Constraints from in-situ U-Pb dating of monazite and geochemistry of pyrite

The Tanjianshan goldfield is the most important gold producer in the North Qaidam, NW China. Genesis of gold deposits in Tanjianshan is enigmatic, primarily because of uncertainties as to timing, mineralization processes and fluid sources. We investigate these uncertainties through a comprehensive study of the texture and geochemistry (LA-MC-ICPMS trace elements and sulfur isotopes) of pyrite and in-situ U-Pb dating of monazite from the Qinglonggou gold deposit. Six types of pyrite with distinct textures, trace element contents and sulfur isotopes have been identified, and provide constraints on two overprinting gold-related hydrothermal events. Stage I consists of Py1, occurring as veinlets parallel to S1 deformation in a schist, is characterized by extremely low Co/Ni ratios with high contents of Ni, and high δ34S values (+14.9 ‰ to +16.1 ‰), and were likely derived from metamorphism of the sedimentary strata in the Tanjianshan and Wandonggou Group. In stage II, Py2 occurs in the pyrite-quartz veins that cut Py1 veinlets. They have similar δ34S (+13.1 ‰ to +17.8 ‰) to Py1, indicating that sulfur was likely derived from the dissolution of Py1. The stage I and II veins formed during an early gold pre-concentration event, which is constrained at 429.1 ± 5.9 Ma by in-situ U-Pb dating of monazite that coexists with Py1. Stage III includes Py3 and Py4 which occur in the altered carbonaceous schist and accompanying quartz veins. Trace metals are highest in Py3 (Ag, Au, Sb, and Bi) which represent the most economic ore stage in the deposit, whereas the following Py4 shows low concentrations of most trace elements due to abundant Py3 precipitation. In contrast, trace elements contents increase in Py5 to similar levels as those seen in Py3, suggesting a new pulse of fluid in stage IV. Minor Py6 grains precipitated in the youngest quartz-calcite veins associated with stage V, and contain low concentrations of trace elements. The δ34S values of Py3 (+5.2 ‰ to +6.0 ‰) and Py4 (+4.2 ‰ to +6.1 ‰) are within the range of magmatic sulfur, suggesting a dominantly magmatic source. The δ34S values increase from Py3-4 to Py5 (+6.3 ‰ to +7.4 ‰), and to Py6 (+8.7 ‰ to +9.6 ‰), probably due to increasing contribution from the host rocks, as well as decreasing fO2, through incremental fluid-rock interaction. Stages III and IV represent a late gold-mineralizing event during Late Paleozoic to Early Mesozoic, while stage V is post-mineralization. The overprinting gold pre-concentration and mineralization events in the Tanjianshan goldfield correspond to orogenic evolution of the Proto-Tethys Ocean and Paleo-Tethys Ocean, respectively.

Steryl ferulates composition in twenty-two millet samples: Do “microwave popping” and fermentation affect their content?

Climate change has led to rediscovery of minor drought tolerant grains such as millet. Among its bioactive molecules, steryl ferulates have been poorly explored. Steryl ferulates composition of was investigated by high performance liquid chromatography-diode array detector-tandem mass spectrometry and high resolution tandem mass spectrometry in twenty-two millet samples and also in some fermented and microwave heated samples. Six compounds were found in Panicum, Pennisetum, Eleusine and Setaria genera, with a prevalence of campestanyl and sitostanyl ferulate. The lowest steryl ferulates content was found in Panicum, with values ranging from 2.98 ± 0.04 µg/g to 8.72 ± 0.41 µg/g. Foxtail millet and finger millet showed the highest amount with 46.07 ± 5.20 µg/g and 85.29 ± 4.30 µg/g, respectively. As for pearl millet, microwave heating and fermentation increased steryl ferulates by two (33.77 ± 0.88 µg/g) and five (75.83 ± 1.25 µg/g) times, with respect to the untreated sample. Microwave heating and fermentation could be used to increase steryl ferulates in millet.

Archean to Paleoproterozoic crustal evolution of the southern Yangtze Block (South China): U–Pb age and Hf-isotope of zircon xenocrysts from the Paleozoic diamondiferous kimberlites

Crustal zircon xenocrysts from mantle-derived magmatic rocks have the potential to probe the deep crust. Here we present integrated U–Pb dating and Hf-isotope analyses of zircons from a Paleozoic diamondiferous kimberlite dike in the Maping area of Zhenyuan County (southeastern Guizhou Province), with implications for the tectonothermal evolution of unexposed continental crust beneath the southern Yangtze Block, South China. All zircons (n = 236) show a wide range of U–Pb ages between Mesoarchean and middle Carboniferous. Among them, 96 zircons with 90–110% concordance yield concordant ages from 2942 ± 8 Ma to 342 ± 2 Ma, and form major age peaks at ∼2.9 Ga, ∼2.6 Ga and ∼2.0 Ga. The overwhelming majority of zircons are dominated by Mesoarchean–Paleoproterozoic U–Pb ages regardless of their concordance degrees. The zircon populations mainly consist of magmatic zircons, with minor metamorphic grains (Th/U < 0.10). The youngest magmatic zircon (Th/U = 0.43) with a well concordant 206Pb/238U age of 342 ± 2 Ma (M1-16) is interpreted as the maximum emplacement age of the Maping diamondiferous kimberlites. Most zircons with pre-eruption ages are considered to be xenocrysts, and they may be derived from the deep-seated continental crust through which kimberlite host magmas have passed. Their U–Pb ages and Hf isotopic compositions suggest the possible existence of a highly evolved Archean basement beneath the southern Yangtze Block, South China, which is much older than its known surface rocks. A lot of magmatic zircon xenocrysts reveal complex Precambrian crustal evolution in the southern Yangtze Block. These processes involved the important growth of continental crust at 2.6–2.5 Ga, and in the meantime, crustal reworking could be intermittently proceeding at 3.0–2.6 Ga. In addition, a group of xenocrystic zircons are identified to be of metamorphic origin, indicating that the proposed Archean basement beneath the southern Yangtze Block likely experienced a metamorphic event around 2.0 Ga. This geologically significant episode is consistent with the well-developed coeval metamorphism in other places of the Yangtze Block (e.g., Kongling Terrane), which has been considered to link to the assembly of the Paleoproterozoic Nuna/Columbia supercontinent. Our zircon data implies that the unexposed Archean basement beneath the southern Yangtze Block was affected by multiple thermal activities.

Chemical composition and in vitro fermentation characteristics of ancient grains using canine fecal inoculum.

Human interest in ancient grains replacing traditional carbohydrate sources has reached the pet food market; however, chemical composition of these grains and their digestive properties in the canine model, specifically the fermentative characteristics, have not been established. Five ancient grain varieties were analyzed: amaranth (AM), white proso millet (WPM), oat groats (OG), quinoa (QU), and red millet (RM). Cellulose (CEL) was used as a negative control, and beet pulp (BP) was used as a positive control. Substrates were analyzed for macronutrient composition as well as free and hydrolyzed sugar profiles in addition to their in vitro fermentative characteristics. Substrates were allocated into 2 sets to allow for quantification of pH, short-chain fatty acids, and branched-chain fatty acids, as well as gas volume and composition. Samples were digested for 6 and 18 h with pepsin and pancreatin, respectively, prior to inoculation with fecal bacteria for 0, 3, 6, 9, or 12 h. Detectable levels of cereal β-glucans were observed solely in OG (3.5%), with all other substrate containing <0.35% cereal β-glucans. All test substrates had fairly similar macronutrient and starch profiles with the exception of RM that contained the highest resistant starch content (2.4%), with all other test substrates containing <0.5% resistant starch. However, the analyzed pseudocereals, AM and QU, had the highest concentrations of free glucose while the minor cereal grains, WPM, OG, and RM, contained the highest concentrations of hydrolyzed glucose. All test substrates had propionate production values similar or greater than BP after 3, 6, 9, and 12 h of fermentation, and similar or greater butyrate production values than BP after 6, 9, and 12 h. All substrates had greater (P < 0.05) changes in pH than CEL after 6, 9, and 12 h, with AM, WPM, OG, and RM having greater (P < 0.05) changes in pH than BP after 9 and 12 h. These data suggest select ancient grains have similar fermentation characteristics as BP, a moderately fermentable fiber considered the gold standard in terms of fiber sources in the pet food market today, and that OG and AM may be more fermentable during longer fermentation periods.

Proximate Composition of Minor Millets from Cold Semi-Arid Regions

The nutritional importance of minor millets growing in geographically and environmentally isolated semi-arid regions remains largely unexplored, which has led to it being underutilized for diet diversification. In this study, the proximate composition of three species of minor millets, namely, Barnyard millet (Echinochloa frumentacea),Finger millet (Eleusine coracana) and Foxtail millet(Setaria italica), grown in traditional millet cultivating regions (cold semi-arid) of the Himalayan range, have been analyzed. Two high altitude locations of contrasting cold temperatures in this region were selected for analysis. Dehradun which exhibits a temperature of 25-27℃, is located at 640 masl. (Meters Above Sea Level) in Uttarakhand West (UW), whereas, the second location, Pithoragarh which exhibits a temperature of 15-17℃ is located at 1514 masl. in Uttarakhand East (UE). The results of this study record a 30.75 percent increase in average protein content of Barnyard millet grains when the same seed stock was grown at the second region of lower temperature, i.e. Pithoragarh (15-17℃), as compared to Dehradun (15-17℃). A 42.66 percent increase in average fat content was also recorded for Barnyard millet grains when grown at Pithoragarh (15-17℃). The two other millet species, Finger millet and Foxtail millet, did not record significant differences in protein and fat contents, however, Foxtail millet displayed marginally increased levels of sodium and potassium. In contrast to the other components analyzed, Total Dietary Fiber (TDF) was found to decrease with growth at the comparatively colder location of Pithoragarh. A 36.71 percent decrease in TDF content was recorded for Barnyard millet, whereas, a 19.25 percent decrease was recorded for Finger millet. Foxtail millet displayed a marginal decrease of only 5.3 percent in TDF content with growth at Pithoragarh. Starch concentration and moisture content for all three species was also studied, but did not record any notable differences due to growth at the colder location of Pithoragarh. The results here indicate an important role of cold temperature and high altitude in regulating the proximate composition of minor millet grains. Studies which explore the proximate composition of millet cultivars in such geographically and environmentally distinct millet growing regions, may reveal new information regarding the nutritional importance of minor millets, and the ideal conditions of growth for maximum nutritional benefit.

The sulfurization recorded in tridymite in the monomict eucrite Northwest Africa 11591

AbstractSome of the tridymite in the monomict Northwest Africa (NWA) 11591 eucrite are found to have sulfide‐rich replacement textures (SRTs) to varying degrees. The SRTs of tridymite in NWA 11591 are characterized by the distribution of loose porous regions with aggregates of quartz and minor troilite grains along the rims and fractures of the tridymite, and we propose a new mechanism for the origin of this texture. According to the volume and density conversion relationship, the quartz in the SRT of tridymite with a hackle fracture pattern was transformed from tridymite. We suggest that the primary tridymite grains are affected by the S‐rich vapors along the rims and fractures, leading to the transformation of tridymite into quartz. In addition, the S‐rich vapors reacted with Fe2+, which was transported from the relict tridymite and/or the adjacent Fe‐rich minerals, and/or the S‐rich vapors react with the exotic metallic Fe to form troilite grains. The sulfurization in NWA 11591 most likely occurred during the prolonged subsolidus thermal metamorphism in the shallow crust of Vesta and might be an open, relatively high temperature (&gt;800 °C) process. Sulfur would be an important component of the metasomatic fluid on Vesta.

Geochemistry of two types of Palaeoproterozoic granites, and zircon U–Pb dating, and Lu–Hf isotopic characteristics in the Kuandian area within the Jiao‐Liao‐Ji Belt: Implications for regional tectonic setting

Palaeoproterozoic granites accompanied with granulite‐facies gneisses can be recognized in the Kuandian area, northern Jiao‐Liao‐Ji Belt (JLJB). This study highlights two episodes of Palaeoproterozoic magmatism, identified by granites and biotite monzogranitic gneisses herein. Zircon grains from biotite monzogranitic gneiss with homogeneous oscillatory zoning yielded a U–Pb age of 2,153 ± 16 Ma, in accordance with the age of zircon cores from the monzogranitic gneiss. Zircon grains from the two granites yielded upper intercept ages of 1,892 ± 38 Ma and 1,859 ± 36 Ma respectively. Monzogranitic gneiss samples are enriched in Th, Rb, Pb, U, and REE, but depleted in Sr and P. They have high 1,000 × Ga/Al ratios versus Zr, Ce, Nb, Y contents, which are usually interpreted as the features of classical A‐type granite that originated in a lithospheric extension setting. The ~1.89–1.86 Ga granite samples have relatively high Al, Rb, Th, U and low Sr, Zr, and Hf contents. These features, combined with the observation of minor apatite grains under the microscope are similar with the I‐type granites. In situ zircon Lu–Hf isotopic analyses revealed that ~1.89–1.86 Ga granite had a similar range and TDM2 ages with the monzogranitic gneiss, but with much lower εHf(t) values. The monzogranitic gneiss may have originated from an Archean crust, while the later granite may be derived from melting of the partial melting of the monzogranitic gneiss or the Archean crust that generated the monzogranitic gneiss. The ~1.89–1.86 Ga granites, together with the coeval S‐type granites in the JLJB, represent an orogeny process that may involve a Palaeoproterozoic subduction.

Formulation and quality evaluation of complementary mixes from foxtail millet, amaranth, spinach, banana, and papaya

Background: Proper nutrition during infancy has a significant effect on a child's future health, immunity and success. Weaning is a transition time for the child during which the consistency and source of its diet shifts. Objective: This study was carried out to formulate foxtail millet-based composite mixes and to assess the feeding practices among the infants under the age group of 0–12 months. Materials and Methods: Foxtail millet and other major ingredients such as Bengal gram dhal, green gram dhal, groundnut, and amaranthus, as well as spinach, were procured from local market in Salem, Tamil Nadu. Fruits such as banana and papaya were also procured from the local market in Salem, Tamil Nadu. Four kinds of complementary feeding mixes were formulated at different combinations. The formulated four composite mixes have undergone an assessment of nutritive value, microbial examination, sensory analysis, and shelf-life studies. Results: The findings showed that the formulated composite mixes compared to Prescribed Dietary Allowances (Recommended Dietary Allowances) were expected to show a significant difference in nutrients such as energy, protein, thiamine, and riboflavin at 0.05% level. Regarding sensory analysis, there was a significant difference between standard and overall acceptability of the formulated mixes at 0.05% level. The shelf-life at the end of 30 days showed no noticeable difference in appearance, consistency, odor, taste and overall acceptability. Conclusion: From this study, it was concluded that minor millet and multi-nutrient grains, green leafy vegetables, and basic low-cost fruits were good sources of energy, protein, iron, and micronutrients to the targeted infants as a supplementing weaning food. It can be recommended based on the infant's length and weight with the supervision. To improve the infant and young child feeding, access to adequate complementary food is necessary. complementary food is necessary.

Palynological, physico-chemical and bioactivity parameters determination, of a less common Greek honeydew honey: “dryomelo”

A less common honeydew honey, “dryomelo”, from different regions in Greece was characterized based on palynological, physico-chemical and bioactivity parameter analyses. Results showed that dryomelo had diverse proportions (%) of Castanea sativa, Polygonum aviculare, Quercus ilex, minor pollen grains and few to medium honeydew elements. Analysis of variance showed significant differences (p < 0.05) in hydroxymethylfurfural, diastase, colour parameters, and % in vitro antioxidant activity values according to region. Application of factor analysis to predominant pollen and the significant parameters, in combination with the Kaiser-Meyer-Olkin test, strengthened the effect of geographical origin and their potential use for quality control analysis of dryomelo.