The AA6061 aluminium alloy surface characteristics presented in this study were obtained after it was machined using die sinking electro discharge machining (EDM) with a composite electrode developed through powder metallurgy. Machining was performed using negative polarity. In order to obtain optimum material removal rate (MRR) and surface roughness (SR), the research has been carried out, and EDM parameters like voltage, current and pulse on time were optimized using the response surface methodology that integrates the central composite design. The parameter interaction effects on EDM machined surface characteristics were studied with the aid of ANOVA. It was determined from model that the regression for MRR and SR were 98.6% and 98.3% respectively, means empirical model is considered sufficient. It was observed that increased MRR and SR were observed in the condition of increased current, but MRR and SR decreased at increased voltage and pulse on time. This could be due to strengthened ionization temperature that increased MRR with acceptable SR. The microstructure of the machine was assessed using microscopic evaluation. The increased current contributed to the formation of a recast layer and debris which hinders the machining process and reduces MRR. The experimental results show that the maximum MRR of 0.087 mg/min and minimum SR of 1.893 µm were achieved. Additionally, the use of WC–Cu composite electrodes led to an increase in hardness from 65 HV to 78 HV in the machined region. It is concluded that WC–Cu composite electrodes typically result in higher hardness, improved MRR and better SR for the AA6061 alloy compared to conventional Cu electrodes.