Mineralogical Variations Research Articles

Comprehensive Analysis of a Chloride‐Rich Topographic Depression in Terra Sirenum, Mars: A Possible Lost Basin With Astrobiological Significance

AbstractThe hygroscopic nature of chlorides gives them the potential to provide a harbor for microbes to adapt and survive in extreme conditions, which is pertinent to Mars, given its evolution of climatic conditions. Moreover, observations of secondary hydrous minerals in chloride‐rich regions have opened the case for a diverse geological environment on the Martian surface. Therefore, through comprehensive analysis, we aim to reconstruct the geological evolution of a chloride‐rich basin within Terra Sirenum. We conducted morphological, morphometric, and mineralogical analyses of the basin and its surrounding area to determine its geological evolution, longevity, and environmental condi5tions during its activity. Subsequently, we carried out a discharge analysis of the surrounding valley networks and determined the water activity using ionic forms of the associated mineralogy. We observed bright‐toned polygonal cracks within the basin as well as its surrounding terrain, suggesting that the basin extended beyond its present boundary. Mineralogical diversity and age dating of the basin and the surrounding area indicated different geochemical environments and cycles of wetting and drying until the late Hesperian. Whereas, sediment transport modeling suggests that the basin was hydrologically active for more than ten thousand years. Our results show a tell‐tale signature of a large sedimentary basin and a large‐scale geological process within the Terra Sirenum. The water activity modeling show that the geochemical composition of the basin was favorable to support the origin of life forms and/or sustain them and suggest promising aspects of the basin for future landing missions.

A synthesis of the REE-Fe-polymetallic mineral system of the REE-line, Bergslagen, Sweden: New mineralogical and textural-paragenetic constraints

Rare earth elements (REE) have gained increasing significance for numerous technologies, particularly in today’s rapidly expanding “green transition” applications such as wind generators and electric vehicle traction engines. Among the more well-known REE mineralisation types in Sweden, together with alkaline intrusions and apatite-iron oxide ores, is the classic yet enigmatic REE-Fe-polymetallic mineral system of Bastnäs-type. The mineralisation type is regional in context and occurs in a discontinuous SW-NE-striking belt (the REE-line) in the west-central part of the Palaeoproterozoic Bergslagen ore province, Sweden. This contribution is aimed at integrating and synthesising existing geological mineralogical, and textural features with new observations from both well-known and several lesser-known, underexplored or previously unrecognised REE-enriched occurrences within this belt, and to discuss key features within the context of mineral systems modelling. A considerable diversity in both the style and abundance of REE mineralisation as well as in discrete REE mineralogy is evident both regionally across the entire REE-line and locally within different ore districts or mine fields. These variations also extend laterally within or across different stratigraphic levels, and within different host rocks, primarily skarn-altered metacarbonates but also variably altered felsic metavolcanic rocks. Many of the mineralisations share similar textural features, which record a protracted evolution with multiple stages of formation or replacement of REE-minerals. The earliest recognised REE assemblages feature fine-grained cerite-(CeCa) with minor bastnäsite-(Ce) – bastnäsite-(La) or fluorbritholite-(Ce) – fluorbritholite-(Y) or locally britholite-(Ce) – britholite-(Y) minerals. Such assemblages typically display anhedral-granoblastic textures appearing in folded assemblages, all suggesting recrystallisation and ductile deformation during regional metamorphism of REE-minerals that had formed during an early stage of the Svecokarelian orogeny. Overprinting overgrowths and cross-cutting vein-like features of allanite-group minerals likely represent different stage(s) of REE mineralisation and (re)-mobilisation during this orogenic evolution. Several of the REE-enriched occurrences contain variably abundant and diverse polymetallic Cu-Mo-Bi-(Co) sulphide mineralisation that typically occur in late paragenetic positions and show a prevalence to REE-rich assemblages, often dominated by different allanite-group minerals. Sulphide and REE mineralisation are locally strongly associated with metamorphic minerals formed during metamorphism of variably Mg-(Fe)-altered metavolcanic rocks. The diversity in style and intensity of the REE mineralisations, along with variations in textures and specific mineralogy, suggest slight differences in the ore-forming conditions or environment at the time of mineralisation. Additionally, these differences may also reflect variations in the preservation or modification processes that operated later in the evolution of the Svecokarelian orogeny, also featuring remobilisation of REEs and sulphidic minerals. The insights gained from all available evidence synthesised herein, from micro-scale to province-scale, help define key proxies for prospectivity mapping. The combined evidence supports that the primary ore-forming stages in the mineral system coincided with felsic volcanism and associated sub-volcanic to plutonic processes at around 1.9 Ga.

Whole rock lithogeochemical analysis of the Mount Read Volcanics: a new tool for geochemical exploration

The Mount Read Volcanics (MRV) of western Tasmania is a belt of Middle to Late Cambrian submarine volcanics and volcaniclastics and one of the major base and precious metal provinces within Australia. Exploration success in the MRV has been in decline in recent years due to a variety of challenges including intensely altered rocks with complex stratigraphy and lithofacies variation, and a lack of accessible outcrop. As a result, local and regional mapping of the MRV is often restricted to Group-level stratigraphy, rendering geological mapping ineffective for identifying decametre-scale mine stratigraphy. Surface rock chip and drill hole samples were collected and analysed using commercially available geochemical assays to create a regional geochemical dataset of the MRV, covering the entire province and all major stratigraphic units. From these data, a lithogeochemical methodology was developed, utilizing Ti/Nb and V/Sc systematics that effectively characterizes the samples according to composition and magmatic processes. This method is shown to be robust to biases due to alteration and lithofacies, eliminating the need for highly selective sampling or extensive data filtering. To demonstrate the utility of this method in an exploration context, data from the K-lens of the Rosebery polymetallic volcanic-hosted massive sulfide (VHMS) deposit was used as a case study. Using Ti/Nb–V/Sc systematics, a rock composition classification was developed that allowed for discrimination of the footwall, hanging wall and host stratigraphy of the Rosebery mine sequence. A geochemical fingerprint for the footwall stratigraphy to mineralization was developed, and by correlating this signature to the regional unclassified samples, geochemical analogues for the Rosebery footwall were readily identified. This approach rapidly reduces the exploration search space and provides valuable information for future mineral exploration. The methodology is applicable in other terrains; however, appropriate orientation studies are required to investigate potential biases due to lithofacies, alteration and mineralogical variability.

A long section of serpentinized depleted mantle peridotite.

The upper mantle is critical for our understanding of terrestrial magmatism, crust formation, and element cycling between Earth's solid interior, hydrosphere, atmosphere, and biosphere. Mantle composition and evolution have been primarily inferred by surface sampling and indirect methods. We recovered a long (1268-meter) section of serpentinized abyssal mantle peridotite interleaved with thin gabbroic intrusions. We find depleted compositions with notable variations in mantle mineralogy controlled by melt flow. Dunite zones have predominantly intermediate dips, in contrast to the originally steep mantle fabrics, indicative of oblique melt transport. Extensive hydrothermal fluid-rock interaction is recorded across the full depth of the core and is overprinted by oxidation in the upper 200 meters. Alteration patterns are consistent with vent fluid composition in the nearby Lost City hydrothermal field.

Diagenetic and hydrothermal controls in a modern submarine rear-arc setting: Insights from Izu-Bonin volcanic arc (IODP Site U1437)

International Ocean Discovery Program (IODP) Expedition 350 drilled Site U1437 in a submarine volcano-bounded basin situated in the modern Izu-Bonin rear-arc, NW Pacific Ocean. Subaqueous volcaniclastic sediments and rocks with a maximum deposition age of 15.4 ± 0.8 Ma were recovered from 0 to 1,806.5 m below seafloor (mbsf). In order to document post-depositional processes in such geological setting, we describe variations in bulk and clay mineralogy over the entire volcaniclastic succession. Four alteration stages (1, 2, 3 and 4) were identified through the occurrence and development of diagenetic background mineral assemblages (smectite ± Na-Ca zeolites ± illite) that were further superimposed by hydrothermal alteration. Stages 1 and 2 are characterized by diagenetic reactions linked with low fluid/rock interactions that enabled glass devitrification and subsequent lithification under burial conditions. Stages 3 and 4 are characterized by moderate to pervasive alteration processes that are well developed in coarser-grained rocks, and that may be induced by thermal pulses associated with fluid inputs. Below 1,460 mbsf, infilling and replacement textures overprinted the background alteration and can be directly linked with the development of two hydrothermal mineral assemblages: (i) ordered C/S (chlorite-smectite mixed-layers) ± chlorite ± albite, and (ii) calcite ± chalcedony ± anhydrite ± laumontite. Both assemblages evidence relatively low-temperature (up to 225 °C) hydrothermal activity that affected subaqueous volcaniclastic rocks at Site U1437. These assemblages are comparable with propylitc alteration facies present in ore-bearing hydrothermal systems. The preferential development of alteration mineral assemblages in high-permeability, coarse-grained lithofacies, reflects the significant influence of the physical properties of volcaniclastic rocks with depth on chemical kinetics, in comparison with those imposed by the local geothermal gradient.

Soil organic carbon sequestration potential explained by mineralogical and microbiological activity using spectral transfer functions

The ability of soil to sequester carbon and reduce atmospheric CO2 concentrations is limited and depends on the soil minerals and their interaction with the microbiota. Microbial activities are closely associated with the types and amounts of soil organic matter (SOM) and clay minerals that have functional groups that interact with energy in Vis NIR-SWIR and Mid-IR wavelengths. The main objective of this research was to determine, based on these spectral ranges, the relation between mineralogical and organic compounds, as their sequestration and specialization in soils from Brazil. It was possible to map microbiological activity by spectral transfer functions and digital soil mapping reaching R2 from 0.77 to 0.85. Multiple regression equations were constructed to quantify enzymatic activity, microbial biomass carbon (MBC), particulate organic matter (POM), and resistant forms of carbon, and SOM associated with the mineral fraction (MAOM). All these properties were detected by specific bands obtained with the recursive feature elimination (RFE) algorithm, reaching correlations from 0.64 to 0.98 in specific ranges. The prediction model of the carbon sequestration potential was adjusted with microbiological and mineralogical variables from Vis-NIR-SWIR and the Mid-IR spectral range. A SARAR double autoregressive model was adjusted with r 0.61 and to a spatial error model (SEM) with r 0.7. The explanatory variables were associated with kaolinite, hematite, goethite, gibbsite, and the abundance of fungi, actinomycetes, vesico-arbuscular mycorrhizal fungi, enzymatic activity of beta-glucosidase, urease and phosphatase, and POM. Among the microbiological variables, the general abundance of fungi was the most important, in contrast to enzymatic activity that was the least important. The interaction between the different maps constructed and historical land use allowed the identification of areas that contribute to sequestering new carbon and could be the key to climate change mitigation strategies.

Pyritic stromatolites from the Paleoarchean Dresser Formation, Pilbara Craton: Resolving biogenicity and hydrothermally influenced ecosystem dynamics.

This study investigates the paleobiological significance of pyritic stromatolites from the 3.48 billion-year-old Dresser Formation, Pilbara Craton. By combining paleoenvironmental analyses with observations from well-preserved stromatolites in newly obtained drill cores, the research reveals stratiform and columnar to domal pyritic structures with wavy to wrinkly laminations and crest thickening, hosted within facies variably influenced by syn-depositional hydrothermal activity. The columnar and domal stromatolites occur in strata with clearly distinguishable primary depositional textures. Mineralogical variability and fine-scale interference textures between the microbialites and the enclosing sediment highlight interplays between microbial and depositional processes. The stromatolites consist of organomineralization - nanoporous pyrite and microspherulitic barite - hosting significant thermally mature organic matter (OM). This includes filamentous organic microstructures encased within nanoporous pyrite, resembling the extracellular polymeric substance (EPS) of microbes. These findings imply biogenicity and support the activity of microbial life in a volcano-sedimentary environment with hydrothermal activity and evaporative cycles. Coupled changes in stromatolite morphology and host facies suggest growth in diverse niches, from dynamic, hydrothermally influenced shallow-water environments to restricted brine pools strongly enriched in from seawater and hydrothermal activity. These observations, along with S stable isotope data indicating influence by S metabolisms, and accumulations of biologically significant metals and metalloids (Ni and As) within the microbialites, help constrain microbial processes. Columnar to domal stromatolites in dynamic, hydrothermally influenced shallow water deposits likely formed by microbial communities dominated by phototrophs. Stratiform pyritic structures within barite-rich strata may reflect the prevalence of chemotrophs near hydrothermal venting, where hydrothermal activity and microbial processes influenced barite precipitation. Rapid pyrite precipitation, a putative taphonomic process for preserving microbial remnants, is attributed to microbial sulfate reduction and reduced S sourced from hydrothermal activity. In conclusion, this research underscores the biogenicity of the Dresser stromatolites and advances our understanding of microbial ecosystems in Earth's early history.

Effect of Freeze-Thaw on CBR in Soils with Different Gradation and Mineralogy

Freeze-thaw cycles are prevalent climatic phenomena with substantial effects on soils, leading to alterations in soil strength, stiffness, and hydraulic properties due to disruptions in the soil structure. With the ongoing climate change, weather patterns have grown progressively erratic, resulting in more frequent occurrences of extreme weather events, including heavy snowfall, intense rainfall, and windstorms, even in regions characterized typically with mild climates across the globe. The climate change can potentially threat man-made infrastructure constructed within or upon local soils, regardless of their susceptibility to freezing in temperate climates. The principal objective of this study is to assess the influence of freeze-thaw cycles on the California Bearing Ratio (CBR %) across 12 distinct soils with variations in granulometry and mineralogy. The freeze-thaw cycles resulted in a notable decrease in CBR (%) within the range of 40% to 70%. A strong inverse correlation with D50 was observed regarding the decrease in CBR (%). Nevertheless, it was discerned that the decrease in CBR (%) subsequent to freeze-thaw cycles varied among soil samples sharing identical D50 and liquid limit characteristics. The aim of this study is to enhance our comprehension of how freeze-thaw cycles can impact the bearing capacity of these soils, thereby providing essential insights for predicting their behavior and potential influence on infrastructure in the context of climate change.

Variable Iron Mineralogy and Redox Conditions Recorded in Ancient Rocks Measured by In Situ Visible/Near‐Infrared Spectroscopy at Jezero Crater, Mars

AbstractUsing relative reflectance measurements from the Mastcam‐Z and SuperCam instruments on the Mars 2020 Perseverance rover, we assess the variability of Fe mineralogy in Noachian/Hesperian‐aged rocks at Jezero crater. The results reveal diverse Fe3+ and Fe2+ minerals. The igneous crater floor, where small amounts of Fe3+‐phyllosilicates and poorly crystalline Fe3+‐oxyhydroxides have been reported, is spectrally similar to most oxidized basalts observed at Gusev crater. At the base of the western Jezero sedimentary fan, new spectral type points to an Fe‐bearing mineral assemblage likely dominated by Fe2+. By contrast, most strata exposed at the fan front show signatures of Fe3+‐oxides (mostly fine‐grained crystalline hematite), Fe3+‐sulfates (potentially copiapites), strong signatures of hydration, and among the strongest signatures of red hematite observed in situ, consistent with materials having experienced vigorous water‐rock interactions and/or higher degrees of diagenesis under oxidizing conditions. The fan top strata show hydration but little to no signs of Fe oxidation likely implying that some periods of fan construction occurred either during a reduced atmosphere era or during short‐lived aqueous activity of liquid water in contact with an oxidized atmosphere. We also report the discovery of alternating cm‐scale bands of red and gray layers correlated with hydration and oxide variability, which has not yet been observed elsewhere on Mars. This could result from syn‐depositional fluid chemistry variations, possibly as seasonal processes, or diagenetic overprint of oxidized fluids percolating through strata having variable permeability.

Large Fe-Mn oncoids from Early Jurassic Ammonitico Rosso Facies (eastern Sakarya Zone, NE Turkey): new insight into palaeogeographic conditions of Tethys Ocean

ABSTRACT Oncoids, significant sedimentary structures within the Jurassic strata of the Mediterranean Region, serve as valuable indicators of paleoenvironmental conditions during their formation. One of the important examples of oncoids has been discovered in the Pliensbachian (Early Jurassic) Ammonitico Rosso Facies (ARF) of the eastern Sakarya Zone (Eastern Pontides, NE Turkey). This study presents the first comprehensive sedimentological and petrographic (textural and compositional characteristics) examination, as well as geochemical analyses (trace and rare earth elements) of these Fe-Mn oncoids. The oncoids consist of nuclei coated with irregular laminae and exhibit a range of sizes, from 10 to over 45 mm, displaying various colours such as brown, reddish, and metallic-looking. They mostly have a discoidal shape, although some are spherical. The nuclei consist of bioclastic wackestones, containing remnants of ammonoid shells. Some oncoids, especially the discoidal forms, have multiple nuclei. The cortex of the oncoid predominantly consists of wrinkled bands displaying micritic laminae, with an abundance of filamentous bodies and the local presence of encrusting microfossils. In the cortex of the oncoids, iron predominates over manganese, and there are compositional variations within the cortex, especially enriched in Si, Fe, and Ca. They predominantly fall within the region associated with hydrothermal Fe and Mn sediments, as indicated by discrimination diagrams involving Ni, Co, Zn, and plots of Ce/Ce* vs Y/HoN and Nd contents, suggesting a hydrothermal origin. Furthermore, their rare earth elements (REE) chemistry displays distinct Y/Ho, Sm/Yb, Ce/Ce, and Nd values, indicating the presence of seawater mixing with hydrothermal fluids. However, they show relatively low Sm/Yb, Y/Ho, Eu/Sm, Nd/YbN, and La/Yb values, suggesting a limited contribution from hydrothermal sources to the surrounding seawater. Nevertheless, the cortex of the oncoids exhibits a complex and variable mineralogy that changes over short distances, implying the dynamic nature of the depositional environment, characterized by fluctuating hydrological regimes, varying oxygen levels, elemental supply, and the saturation of specific elements in seawater. The increased presence of specific trace elements, including Fe, and REE during this period, is likely linked to hydrothermal fluid input into marine environments, coinciding with intensified syn-sedimentary tectonic activity, where ongoing extensional tectonic movements occasionally influenced paleoenvironmental conditions. In these conditions, the formation of oncoids is influenced by various sedimentary factors, including the availability of metal sources, specific paleoenvironmental conditions, and the presence of microbial organisms, thereby enriching our understanding of palaeogeography during the Early Jurassic period. Additionally, the studied oncoids, with their comparable stratigraphic position and petrographic characteristics to those in both the eastern and western parts of the Tethyan basin, underscore their significance in palaeogeography and stratigraphy.

Skeletal mineralogy of marine calcifying organisms shaped by seawater temperature and evolutionary history—A case study of cheilostome bryozoans

AbstractAimQuantify the contribution of environmental factors (water temperature, salinity and depth) and evolutionary history to varied skeletal mineralogy in calcifying marine organisms.LocationGlobal Ocean.Time periodPresent.Major taxa studiedOrder: Cheilostomatida; Phylum: Bryozoa.MethodsWe employed X‐ray diffraction (XRD) to analyse the skeletal mineral composition of 872 individual colonies, representing 437 bryozoan species, in terms of calcite/aragonite ratios. We integrated these data with equivalent published data, thus reaching 981 species, and applied linear models (LMs), generalized linear models (GLMs) and phylogenetic generalized least squares models (PGLSs) to investigate the influences of temperature, salinity, depth and phylogenetic history on the mineralogy of nearly 1000 cheilostome bryozoan species.ResultsCheilostome bryozoans vary considerably in their skeletal mineral composition: in our dataset 65% of the species possess purely calcite skeletons, 15% exclusively employ aragonite and 20% exhibit mixed (i.e. calcite and aragonite) mineralogies. Temperature is the predominant measured environmental factor influencing bryozoan skeletal mineralogy, accounting for 20% of its variability across species, when phylogenetic relatedness is unaccounted for. Bryozoans in lower latitudes, characterized by higher seawater temperatures, have higher aragonite concentrations. By accounting for phylogenetic structure using a subset of 87 species for which we have topological information, 40% of the observed mineralogical variability could be attributed to present‐day temperature. In contrast, depth and salinity played minor roles, explaining less than 1% of the mineralogical variation each.Main conclusionsThis study emphasizes the influence of evolutionary history on the mineralogical variability of calcifying organisms, even when it can be shown that a single environmental factor (temperature) explains a substantial amount of this variability. When confronted with changing temperature, calcifiers such as bryozoans are likely to respond in diverse ways, depending on the species, given their phylogenetic relatedness and the external conditions they meet.

Geoenvironmental characteristics of ferroniobium slag from the saint Lawrence columbium mine, Oka, Québec, Canada

Niobium (Nb) is a critical metal usually hosted in pyrochlore and mined from carbonatite deposits. The aluminothermic reduction of pyrochlore concentrate yields ferroniobium (FeNb) alloy and a slag waste. This study presents results from mineralogical, geochemical, and radiochemical investigations of FeNb slag found at the former Saint Lawrence Columbium mine in Oka, Québec, Canada. Slag casts exhibit a vertical zonation resulting from fractional crystallization and differentiation in the melt. Sampling of the slag was designed to characterize resulting chemical and mineralogical variations within casts. The median bulk composition of samples (n = 14) is dominated by Al2O3 (47%) and CaO (16%) from process reagents. The slag also contains significant TiO2 (4%) and trace elements including Zr (6763 ppm), U (601 ppm), and Th (1371 ppm) from pyrochlore that partition preferentially from concentrate to the slag. Based on radiochemical analyses of daughter products and assuming secular equilibrium, median (n = 3) activity concentrations for U and Th decay series are 213 and 111 Bq/g, respectively. A field spectral radiometric survey of the slag disposal area found median (n = 37) equivalent U and Th concentrations of 1069 and 2101 ppm, respectively. The primary mineralogy of the top and middle of slag casts is dominated by hibonite, grossite, and perovskite. Most of the U and Th is hosted by perovskite. The bottom of slag casts is an assemblage of mainly gehlenite, ferri-gehlenite, hercynite, grossite, and anorthite. The casts also contain a (Na,F,Ce) calcium-aluminate glass decreasing in abundance from top to bottom, and a (Na,F,Ce,Ti,Zr) calcium-aluminosilicate glass in the cast bottoms. The (Na,F,Ce) calcium-aluminate glass, grossite, and hibonite are the phases most susceptible to weathering. Perovskite, gehlenite, and hercynite show little or no signs of alteration. A leach test was performed on three columns filled with material from the top, middle, and bottom of casts. In the field, a parallel leach experiment was conducted with three barrels filled with undifferentiated slag material and open to atmospheric conditions. Column leachate was found to be highly alkaline, with pH in the top column reaching 13.2. Median pH values in column and barrel leachate were 10.4 and 9.2, respectively. The maximum U concentration in column leachate was 13 μg/L whereas in barrel leachate it was 65 μg/L. Maximum Th concentrations in column and barrel leachates were 7.65 and 0.2 μg/L, respectively. Median Al concentrations in column and barrel leachates were 74.9 and 3.9 mg/L, respectively. Slag from the production of FeNb is readily weathered and represents a technologically enhanced naturally occurring radioactive material (TENORM) requiring environmental management because of its radioactivity and the alkaline nature of its leachate.

Imaging porosity evolution of tight sandstone during spontaneous water imbibition by X-ray Micro-CT

Water imbibition is an important process in reservoir rocks during hydraulic fracturing and water-based enhanced oil recovery operations. However, the water imbibition behavior in tight sandstones has not been fully understood due to their complex pore structure, including the presence of nano and micron-sized pores and throats, surface properties, and wide variation in mineralogy. The present study focuses on the effect of spontaneous water imbibition on the porosity evolution of a tight sandstone. Within this context, a core of Torrey Buff sandstone was characterized by using a combination of multiscale imaging methods (X-ray Computed Tomography, Scanning Electron Microscopy), laboratory experiments (porosity-permeability measurements), and analytical techniques (X-ray Diffraction, Fourier Transform Infrared Spectroscopy, Scanning Electron Microscopy-Energy Dispersive Spectroscopy, and Thermogravimetry). The studied tight sandstone core has a porosity of 12.3 % and permeability of 2.05mD with minerals of quartz (58 %), clays (kaolinite and illite, 23 %), K-feldspar (7 %), dolomite (7 %) and calcite (5 %). Primary and secondary pores, ranging in size from 60 to 140 μm and 30–50 μm, respectively, are mostly filled with highly-soluble carbonate minerals and hydrophilic illite, which influence the spontaneous water imbibition capacity of the tight sandstone. The multiscale imaging technique indicates that after a 10-h long water imbibition experiment, the average pore size of the tight sandstone increased by 1.28 %, reaching 2.35 % at the rock-water contact and 0.13 % at the top of the core. In other words, throughout the core, the porosity changes upon water imbibition are not uniform but show an almost linear trend. This observation could be explained by the significant contribution of highly-soluble carbonates and hydrophilic illite on the microstructure of the tight sandstone. This study implies that multiscale imaging techniques, crucial in examining spontaneous water imbibition, hold promise for further research in enhanced oil recovery or hydraulic fracking in tight sandstones.

Retention of 226Ra in the sandy Opalinus Clay facies from the Mont Terri rock laboratory, Switzerland

The safety assessment of deep geological disposal of nuclear waste requires a sound understanding of radionuclide retention in the repository host rocks. Here, we investigate the retention behaviour of the safety relevant radionuclide 226Ra in the heterogeneous sandy facies of the Opalinus Clay (OPA-SF) at the Mont Terri underground rock laboratory. Various rock samples were selected from a drill core (BAD-1) located in the lower sandy facies, which were representative for its textural and mineralogical heterogeneity. The samples were carefully characterized with respect to mineralogy and chemistry using X-Ray diffraction and electron microscopy. The amounts of quartz, carbonates and clay minerals in the samples ranged between 58 wt.% – 65 wt.%, 13 wt.% – 35 wt.% and 5 wt.% – 25 wt.%, respectively, underpinning the mineralogical heterogeneity. Rare (Ba,Sr)-sulphate precipitates were identified in the clay matrix by electron microscopy. The uptake behaviour of Ra was evaluated using batch sorption experiments. Corresponding to the mineralogical variability of the rock samples, the measured distribution ratios Rd for the 226Ra retention varied between 20 L kg−1 and 260 L kg−1 after 120 days. The experimental results and thermodynamic modelling approaches suggest that various processes contribute to the uptake of 226Ra on different time scales: fast cation exchange and surface complexation reactions by clay minerals and the (slower) formation of solid solutions during recrystallisation of (Ba,Sr)-sulphates as well as retention by carbonate minerals; the latter mechanism still requiring further investigation.

Origin and modern microbial ecology of secondary mineral deposits in Lehman Caves, Great Basin National Park, NV, USA.

Lehman Caves is an extensively decorated high desert cave that represents one of the main tourist attractions in Great Basin National Park, Nevada. Although traditionally considered a water table cave, recent studies identified abundant speleogenetic features consistent with a hypogenic and, potentially, sulfuric acid origin. Here, we characterized white mineral deposits in the Gypsum Annex (GA) passage to determine whether these secondary deposits represent biogenic minerals formed during sulfuric acid corrosion and explored microbial communities associated with these and other mineral deposits throughout the cave. Powder X-ray diffraction (pXRD), scanning electron microscopy with electron dispersive spectroscopy (SEM-EDS), and electron microprobe analyses (EPMA) showed that, while most white mineral deposits from the GA contain gypsum, they also contain abundant calcite, silica, and other phases. Gypsum and carbonate-associated sulfate isotopic values of these deposits are variable, with δ34SV-CDT between +9.7‰ and +26.1‰, and do not reflect depleted values typically associated with replacement gypsum formed during sulfuric acid speleogenesis. Petrographic observations show that the sulfates likely co-precipitated with carbonate and SiO2 phases. Taken together, these data suggest that the deposits resulted from later-stage meteoric events and not during an initial episode of sulfuric acid speleogenesis. Most sedimentary and mineral deposits in Lehman Caves have very low microbial biomass, with the exception of select areas along the main tour route that have been impacted by tourist traffic. High-throughput 16S rRNA gene amplicon sequencing showed that microbial communities in GA sediments are distinct from those in other parts of the cave. The microbial communities that inhabit these oligotrophic secondary mineral deposits include OTUs related to known ammonia-oxidizing Nitrosococcales and Thaumarchaeota, as well as common soil taxa such as Acidobacteriota and Proteobacteria. This study reveals microbial and mineralogical diversity in a previously understudied cave and expands our understanding of the geomicrobiology of desert hypogene cave systems.

Hydropedological Characterization of a Coal Mining Waste Deposition Area Affected by Self-Burning

Coal mining often produces severe environmental effects, including impacts on the soil system and, specifically, on hydropedological conditions that control the leaching of significant ions and Potentially Toxic Elements (PTEs). The research objective is to assess changes in the hydropedological conditions in an area with a coal mining waste pile that underwent self-burning. An integrative approach was implemented, starting with the definition of hydropedological zoning based on field observations of soil formation factors (namely, parent material, relief, biological activity, anthropic influence, and time). The soil profile in each hydropedological zone was characterized regarding morphological features. The upper mineral horizons were sampled and characterized in terms of mineralogy and PTE geochemistry. Field measurements of unsaturated hydraulic conductivity, soil water content, and hydrophobicity were performed. Afterwards, the hydrogeochemistry of leachates was determined, and the soil leaching potential was evaluated. The research outcomes express substantial differences regarding the hydropedological zones: development of different soil profiles, diverse mineralogy and PTE geochemistry, higher unsaturated hydraulic conductivity and leaching of major ions, and PTEs in soils affected by coal mining activities. Finally, a Principal Component Analysis confirmed the existence of significant contrasts according to hydropedological zoning.

Proximal sensors for modeling clay mineralogy and characterization of soil textural fractions developed from contrasting parent materials

Proximal sensors combined with X-ray diffraction (XRD) have optimized soil characterization, but scarce studies have focused on predicting the contents of minerals under this scope. The objectives herein were to: a) use the portable X-ray fluorescence (pXRF) spectrometry, diffuse reflectance spectroscopy in the range of visible and near-infrared (Vis-NIR), magnetic susceptibility (χ) and XRD to characterize the mineralogy of soils derived from representative Brazilian soil parent materials, and b) create models to quantify the minerals obtained via XRD. Twenty-two soil profiles developed from gabbro, gneiss, quartzite, mineral and organic sediments were described with 53 soil horizons sampled. Each sample had the sand, silt and clay fractions separated and analyzed with XRD, pXRF, χ, and Vis-NIR. Models were created using the Random Forest algorithm permuting the following predictor variables (separately and combined): pXRF, parent material (PM), χ, soil texture (sand, silt, and clay content), and Vis-NIR. Models’ accuracy was calculated using the leave-one-out cross-validation method. Si, Al, Fe, Ca, K, and Ti contents obtained by pXRF and the χ discriminated the soil particle size fractions according to the parent material. XRD analysis allowed the evaluation of the pedogenetic development of soils and their relation to the respective parent material. The best models for mineral contents were found for hematite (Hm) (104)+(Gt) (130) (R2 = 0.85), Hm (110) + Mh (131) (R2 = 0.76), kaolinite (Kt) (001) (R2 = 0.73), Kt (002) (R2 = 0.80), mica (Mc) (001) (R2 = 0.77), and Mc (020) + Kt (020) (R2 = 0.81). Clay mineralogy content was accurately modeled using only pXRF and parent material data. This approach can facilitate and speed up detailed soil mineralogy characterization. Further studies are encouraged to model the content of minerals found in the sand and silt fractions of soils with diverse mineralogy via proximal sensors and using larger data sets.

Flowsheet development for and commissioning of the Kamoa-Kakula project

The Kamoa-Kakula copper resource, located west of Kolwezi in the Democratic Republic of the Congo, was discovered and explored by Ivanhoe from 2008/9 on. As a greenfield project with prospects of high grade ore and a long life-of-mine, the need for best practice flowsheet development was recognised, so as to ensure sustainability of metallurgical performance at the at the maximum economic level from the orebody during metallurgical operations. Process Mineralogy, a hybrid discipline, has been developed in the mining industry over the last forty years, and its proper use has seen very successful outcomes in flowsheet development (Bradshaw, 2014; Lotter, 2011; Lotter et al., 2003; McKay et al., 2007; Pease et al., 2005). Drill core was sampled at site across six phases of flowsheet development that worked with the developing mine plan. The two main geomet units were hypogene and supergene, with the hypogene being unusually rich in bornite. The main variability is between supergene and hypogene, and between Kamoa and Kakula, but with less spatial variability within them. The first viable flowsheet was developed and demonstrated in nine months of test work, followed by various revisions and iterations as required by the discovery of variable mineralogy. The first flowsheet, called “Milestone”, was then challenged with an opportunity for a simpler but better-performing flowsheet, which became known as IFS4A. The simultaneous discovery of the Kakula resource refocussed the project due to its shallower depth and higher grade. Laboratory scale flotation testing using IFS4A in Phase 6 of Kamoa and two drill-holes of Kakula quickly confirmed that the Kakula ore outperformed the Kamoa supergene ore using this flowsheet. A mini-pilot plant campaign was run in 2019 with this flowsheet plus modifications, using 985 kg of metallurgical drill cores material to demonstrate the full flowsheet mass and value balance on a continuous operating campaign. This mass and value balance produced an estimated 85.6 % Cu recovery with a saleable concentrate grading 57.3 % Cu. Whereas this paper concentrates on the mineralogy and its contribution to process implications such as grinding requirements and flotation strategy, it is recognized that first-class design, engineering and construction contributed in no small measure to the successful start-up. This mass and value balance was used in the design of the grinding and flotation circuits, and contributed to the successful commissioning of the new concentrator in 2021, which averaged a recovery of 84.7 % at a grade of 50.5 % Cu, in good agreement with the testwork. A McNulty model for the commissioning data shows a better than Type 1A start-up. The flowsheet development part of the project is discussed in this paper as a case study.

Variations in weathering conditions related to sea level changes during the Albian-Santonian interval in the Western Australian margin as evidenced by clay minerals and Nd/Sr isotopes

The Albian-Santonian interval (∼113–83 Ma) is a key interval for Cretaceous climatic and environmental changes. This interval is associated to a rise in sea level until the Late Cenomanian (∼ 94 Ma) and to a progressive increase in oceanic temperatures, leading to consider the Late Cenomanian-Santonian interval (∼ 94–83 Ma) as the warmest period of the last 200 Myr. While the Albian-Santonian interval has been well studied in the Northern Hemisphere, the climatic and environmental variations and their consequences on weathering conditions are less documented of the Southern Hemisphere, especially in mid and high latitudes. To better understanding the evolution of weathering conditions, associated to continental climate and sea level changes during this key period, an integrated study, based on a coupled mineralogical and geochemical approach, was carried out on the clay-sized (< 2 μm) fraction from sediments of International Ocean Discovery Program Site U1513 (Mentelle Basin, South-western Australia) and Oceanic Drilling Program Site 763 (Carnarvon Basin, North-western Australia). To determinate variations in weathering conditions, the mineral assemblages of the clay fraction was determined by X-ray diffraction and observed for selected samples by electron microscopy. To identify sources of clay minerals, the concentrations of major and selected trace elements, including rare earth elements, together with strontium and neodymium isotopic measurements were performed on the clay-sized fraction. The X-ray diffraction analyses reveal that clay fraction is dominated by R0-type illite/smectite mixed-layers (smectites), followed by variable proportions of illites, kaolinites for both sites and only on Site 763 of palygorskites. These clay minerals are associated with opal and clinoptilolites. Electron microscopy observations have highlighted the dominance of detrital fleecy smectites but also the occurrence of recrystallized lathed smectites and volcanogenic folded smectites for Site U1513, and authigenesis of clay minerals, associated to palygorskites especially on Turonian to Santonian deposits for Site 763. This authigenesis, confirmed by negative cerium anomaly, is also carried by other minerals in the clay-sized fraction (e.g., clinoptilolites, barite). These different authigenic minerals record a seawater-derived isotopic signature. Therefore, isotopic compositions of the clay-sized fraction reflect a mix between a continental contribution, carried by detrital clay minerals and marine one, supported by authigenic minerals, which complicates the identification of sediment sources. However, despite this, our study demonstrates the major influence of sea level variations on mineralogical variations from Albian to Cenomanian in Western margin of Australia. The decrease in kaolinite proportions at Site U1513 from the Albian to the end of the Cenomanian, is probably related to the increase of sea level, which cause a decrease in detrital inputs in the Mentelle Basin associated with a decrease of weathering and drainage conditions. The progressive sea level rise has also enhanced the effect of the differential settling process of clay minerals by the deposition of coarse clays (e.g., kaolinites and illites) on the continental shelf. Kaolinite-bearing clay deposits, derived from the weathering of the Western Australian Craton during the Albian-Cenomanian times, have been progressively substituted from the Turonian by a carbonate sedimentation, for which the terrigenous component consists only of rare detrital and volcanogenic smectites. In Site 763, the occurrence in kaolinite content during the Coniacian would indicate a decrease of differential settling process related to the weathering of the north part of the Western Australia Craton.

Petrological and geochemical characteristics of the Low- and High-Hf Nam Meng dioritoid, northwest Vietnam: Implication for the mantle partial melting, mixing, and magmatic differentiation

This paper investigated the petrological, elemental, and isotope geochemical characteristics of the Nam Meng dioritoid to clarify the magma source and process. The Nam Meng massif comprises large amounts of dioritoids (gabbro-diorite and quartz diorite) and lesser amounts of granitoids (granodiorite and granite). The Nam Meng gabbro-diorite is a porphyritic texture with fine-grained plagioclase, amphibole, K-feldspar, and phenocryst biotite. The Nam Meng quartz diorite comprises coarse-grained plagioclase, amphibole, biotite, quartz, and K-feldspar. The Nam Meng gabbro-diorite contains higher plagioclase and lower biotite and quartz than the Nam Meng quartz diorite. The variation in petrography and mineralogy with the negative correlation between SiO2 contents with Al2O3, MgO, Al2O3 + MgO, T-Fe2O3, and CaO contents suggest a magmatic differentiation process. All the Nam Meng dioritoids have low ACNK (mostly less than 1.0), total alkaline (Na2O + K2O ≤ 6 wt.%) with Na2O/K2O ≥ 1, and negative anomalies of Ta, Nb, and Ti. Combined with the U-Pb zircon age of 290 Ma (Hieu et al. (2017), the Nam Meng dioritoid is thought to be an I-type granitic rock formed in the subduction stage of the Indosinian amalgamation event. The low La/Yb ratios (1.14-3.21) suggest that the mantle wedge that was melted to form the Nam Meng magma had a spinel peridotite composition. The εNd (290 Ma) of the Nam Meng dioritoid is close to bulk earth silicate at 290 Ma (-4.43 to 2.34). The 87Sr/86Sr (290 Ma) of the Nam Meng dioritoid varies in a wide range from low to intermediate (0.6987 to 0.7088), and the calculated Nd model age of the Nam Meng dioritoid is 1,258 ± 47 Ma. The Sr and Nd isotope data suggest that the Nam Meng spinel peridotite was a result of mixing between an ancient ocean crust, EM1, and EM2 that occurred in a paleo-subduction zone at Meso-Neoproterozoic Rodinia supercycle. The Hf contents of the low-Hf and high-Hf Nam Meng dioritoid series are 0.38-1.02 and 2.60-8.08, respectively. The LILE/Hf and HSFE/Hf ratios in the low-Hf Nam Meng dioritoids are high and have a strongly negative correlation with Hf. On the other hand, those ratios in the high-Hf Nam Meng dioritoids are low and have a weakly negative correlation with Hf. The Hf contents positively correlate with the degree of partial melting of the mantle wedge in the subduction zone. Therefore, the low Hf, high LILE/Hf, and HSFE/Hf ratios of the Nam Meng dioritoids could be derived from a low degree of partial melting of the mantle wedge. In contrast, the high Hf, low LILE/Hf, and HSFE/Hf ratios of the Nam Meng dioritoids could be produced by a high degree of partial melting of the mantle wedge.