Mineral Water Samples Research Articles

Introducing a High Throughput Nanozymatic Method for Eco-Friendly Nanozyme-Mediated Degradation of Methylene Blue in Real Water Media

A high throughput nanozyme-based catalytic system was developed for eco-friendly nanozyme-mediated biodegradation of organic dye, methylene blue, in real water media. The above-mentioned nanozymes were synthesized and then characterized for their morphology, composition, and size by Transmission Electron Microscopy (TEM), elemental mapping, and Dynamic Light Scattering (DLS) analysis, in order. The nanozymatic properties of the as-prepared nanomaterials were evaluated by standard enzyme activity assay, revealing high peroxidase-like performances for the as-prepared nanozymes. Therefore, for more precise reporting of the peroxidase-like performances of the nanozymes, the kinetics behavior of the as-prepared nanozymes was evaluated by the standard Lineweaver-Burk method, revealing a Vmax as high as 0.263 µM sec-1 and a Km as low as 0.03 mM, revealing high catalytic efficiency and affinity of the as-prepared nanozymes. Hence, the as-prepared nanozymes were utilized for the degradation of organic dye in real water utilizing methylene blue as a model dye. The factors affecting the dye degradation including pH, degradation time, ionic strength, nanozyme amount, etc. were optimized utilizing the one-factor-at-a-time optimization method. At optimal experimental conditions, the as-prepared nanozymes can degrade about 99.0% of the organic dye within a degradation time as low as 7 min. The developed method was finally employed for the nanozyme-mediated degradation of methylene blue from real water media such as pool water, mineral water, river water, and tap water samples. The results of this study revealed an excellent biodegradation yield of over 94.3%-99.0% for the different real samples, proving the suitability of the developed method for dye degradation in real media.

Development of boron nitride incorporated molybdenum disulfide nanocomposite as a simultaneous electrochemical transducer for environmentally hazardous ortho and para-nitroaniline isomers in aquatic environments

Harmful nitroaniline isomers are highly environmentally toxic, their main source being the improper release of industrial waste. These isomers are commonly utilized in various chemical products. The presence of these organic compounds in water and the environment poses a significant carcinogenic risk to humans. Therefore, there is an urgent need to monitor and detect these isomers in aqueous mediums to minimize the potential hazards they pose. To tackle this issue, we have developed an electrocatalyst called boron nitride@molybdenum disulfide nanodisk (BN@MoS2 ND) for the simultaneous detection of o-NA and p-NA in tap, river, and mineral water samples. The synthesized nanodisk was characterized using PXRD, FT-IR, Raman spectra, XPS, and FE-SEM studies. The incorporation of BN with MoS2 as a mediator in the reduction mechanism resulted in excellent electron transfer (Rct = 167.73 Ω) and increased surface area (SBET = 31.606 m2 g−1). The proposed sensor exhibited a good linear range, the limit of detection, and sensitivity toward o-NA and p-NA, under pH-regulated conditions, with values of ca. 0.001–778.88 μM, ca. 0.4 nM, and ca. 20.142 ( ± 0.002) μA μM−1 cm−2 and ca. 0.001–569.96 μM, ca. 0.6 nM, and ca. 14.371 (±0.002) μA μM−1 cm−2, respectively. Furthermore, the BN@MoS2/SPCE demonstrated good recoveries of ∼94–99 % for tap, river, and mineral water samples, thereby confirming its excellent ability to detect harmful nitroaniline isomers in aqueous mediums and the environment.

A multifunctional quinoxaline-based chemosensor for colorimetric detection of Fe3+ and highly selective fluorescence turn-off response of Cu+2 and their practical application

A new dual responsive colorimetric and fluorescent turn-off sensor for Fe3+ and Cu2+ was designed and synthesized based on quinoxaline derivative by a simple procedure reaction. 2,3-bis(6-bromopyridin-2-yl)-6-methoxyquinoxaline (BMQ) was fabricated and characterized using ATR-IR, 13C and 1H NMR, and Mass spectroscopy. The interaction of BMQ with Fe3+ caused a significant color change from colorless to yellow. The sensing complex BMQ-Fe3+ with high selectivity was described to be 1:1 by the molar ratio plot. In this experiment, iron was detected by naked-eye using a recently synthesized ligand (BMQ). This color change was unexpectedly observed in iron-overloaded plasma, which had previously been admitted by AAS (Atomic Absorption Spectroscopy). Normal plasma, however, did not exhibit this color change. Interestingly, Cu2+ ions cause a quench at the local emission around 565 nm. On the other hand, receptor-binding selectivity for Cu2+ over a wide linear concentration range was observed through changes in the emission spectra. BMQ-Cu2+ was characterized to be 1:1 by the Job's plot. The emission intensity of BMQ–Cu2+ complex was balanced within only 1 min. various mineral water samples were analyzed for detecting Cu2+. The results show the great potential of the developed probe BMQ for the sensing of Cu2+ ions in mineral and drinking water samples.

Chemical Analysis of Essential Trace Elements in Wastewater Samples Collected from Four Different Mines

Mine water contains trace heavy metals which are some essential trace elements in high concentrations causing the pollution of nearby water bodies, related ground waters and soils degradation. The aim of the study is to identify and quantify the essential trace elements present in the different mine water samples and their level of toxicity. Digestion technique was employed to pretreat the mine wastewater before analysis. Physicochemical analysis was conducted for pH, electrical conductivity (EC), total dissolved solids (TDS), and salinity. The samples collected from four different locations are Sample A (Gold mine), Sample B (Copper mine), Sample C (Iron mine), Sample D (Tin mine). The raw or untreated mine water samples were analyzed using inductively coupled plasma optical emission spectroscopy (ICP-OES). The results showed the essential trace elements present in all the mine water samples are Mn, Cu, Fe and Zn. Cu is highly concentrated in copper (73.87 mg/L) and tin (2.09 mg/L) mine water while Fe is dominant in water samples collected from gold (7.19 mg/L) and iron (13.12 mg/L) mine. In conclusion, the essential trace elements Mn, Cu, and Fe present in all the mines are very high and can be harmful to human life in the environment but the concentrations of Zn in the entire mine water samples are within the permissible level of standard drinking water and hence it can pose no threat to human life.

Ultrathin 2D/2D nanohybrid for efficient electrochemical detection of nitrite

An excessive amount of nitrite ions and their long-term accumulation pose a significant threat to both the ecological system and the public health. Thus, it is highly desirable to construct a unique electrode architecture for the precise and efficient quantification of nitrite. This study reports an electrochemical nitrite sensor using an ultrathin 2D/2D hematene/GO nanohybrid with a few nanometers of thickness and face-to-face contact. Due to their high surface-to-volume ratio, which make them extremely susceptible to their interaction with the surrounding environment, and the high density of active surface sites, they exhibit remarkable electrochemical sensing performance towards nitrite. The proposed ultrathin 2D/2D hematene/GO nanohybrid sensor responds linearly with increasing concentrations of nitrite up to 1000 µM and a low detection limit (2 µM). In addition, the sensor's selectivity, stability, and reproducibility qualities are also evaluated. Furthermore, it successfully detected the analyte in tap water, mineral water, and river water samples with relative standard deviations (RSD) less than 5%. Density functional theory (DFT) simulations demonstrate that the hematene/GO nanohybrid efficiently lowers the energy barrier for the electrochemical oxidation of HNO2 to HNO3 and that the synergistic impact of hematene and GO enhances the electrochemical sensing reactivity for the reaction of nitrite detection.

Analysis of mineral water quality based on SNI 3553:2015 and its consequences from legal perspectives

This study aims to analyze the quality of mineral water based on physical, chemical, and microbial parameters and its legal consequences. The assessment standard used is SNI 3553:2015, and the test was conducted using five samples of mineral water produced and marketed in Bantaeng Regency, Indonesia. Physical testing parameters consist of odor, taste, turbidity, and Total Dissolved Solid (TDS). Chemical testing parameter consist of pH. While microbial parameter is Total Plate Count (TPC). At the same time, the statute approach is used to see the legal consequences. The results obtained indicate that all test parameters namely odor, taste, turbidity, TDS, pH and TPC meet the mineral water quality requirements according to SNI 3553:2015. Then, the regulation of mineral water standards is an obligation based on the Regulation of the Minister of Industry of the Republic of Indonesia. The legal consequences if the fulfillment of mineral water quality is not required can befall business actors, ranging from sanctions for revocation of business licenses to criminal sanctions. Therefore, mineral water as a basic modern human need must meet the quality requirements according to SNI 3553:2015 which is accompanied by severe legal consequences.

Selectivity Quantification with the Fluorescent Quantitative Model-Assisted Semi-Selective Probe (Carbon Dots): Accurate Determination of Chlortetracycline in Aqueous Environments with Interference.

Probes such as carbon dots (C-dots) have extensive and important applications in the quantitative analysis of complex biological and environmental systems. However, the development of probes is often hindered by incomplete selectivity, i.e., a probe that responds to one substance is also prone to respond to coexisting structurally similar substances. Therefore, the above dilemma often leads to be developed as semi-selective probes, so that the development of probes is abandoned halfway. This work shows how a semi-selective probe can enhance selectivity by combining a proper multivariate calibration model. Primarily, we developed a semi-selective fluorescent probe that responded to tetracyclines (TCs) with discarded tobacco leaves. Then, we introduced the multivariate quantitative fluorescence model (QFM) to enhance its selectivity and solve the problem of fluorescence spectral shift. For the determination of chlortetracycline (CTC) with this semi-selective C-dots probe in mineral and lake water samples and compared to the traditional quantitative model, the introduced QFM resulted in an average relative predictive error (ARPE) in mineral water spiked samples decreased from 57.1 to 5.6%, which reduced the ARPE in the lake water spiked samples from 18.1 to 4.7%. The above results show that the QFM-assisted semi-selective probe C-dots strategy (QFMC-dots) can enhance selectivity, and QFMC-dots achieved high-selective and accurate determination of CTC in interfering mineral and lake water samples, with the limit of detection and limit of quantitation of 0.55 and 1.66 μM, respectively. The proposed strategy of enhancing selectivity by introducing a proper multivariate calibration model can reduce the difficulty and increase success rate of developing probes, which can be expected to provide an interesting alternative for the development of probes, especially when encountering semi-selective problems.

Dispersion liquid microextraction of fluoroquinolones

The dispersive liquid-liquid microextraction method of norfloxacin, ciprofloxacin and enrofloxacin with chromatographic detection was developed. The optimization of dispersive microextraction was carried out, and the optimal parameters were determined as follows: 5 ml of aqueous solution; 70 l of chloroform; 500 l of isopropanol; extraction time of 5 min; centrifugation time of 5 min; and pH 7.0–9.0. The concentration range was 4.0–100 g/ml, and the limit of detection was not exceeded 1.5 g/ml. The microextraction method was tested on mineral water samples by the standard addition method. The obtained results indicate sufficient accuracy and reproducibility of the developed method. The relative standard deviation does not exceed 2%.

Gross alpha and gross beta radioactivity levels in bottled mineral water samples in Morocco determined by liquid scintillation counting method

Gross alpha and gross beta radioactivity levels in bottled mineral water samples in Morocco determined by liquid scintillation counting method

Folic Acid Adjustive Polydopamine Organic Nanoparticles Based Fluorescent Probe for the Selective Detection of Mercury Ions.

Polydopamine fluorescent organic nanomaterials present unique physicochemical and biological properties, which have great potential application in bio-imaging and chemical sensors. Here, folic acid (FA) adjustive polydopamine (PDA) fluorescent organic nanoparticles (FA-PDA FONs) were prepared by a facile one-pot self-polymerization strategy using dopamine (DA) and FA as precursors under mild conditions. The as-prepared FA-PDA FONs had an average size of 1.9 ± 0.3 nm in diameter with great aqueous dispersibility, and the FA-PDA FONs solution exhibit intense blue fluorescence under 365 nm UV lamp, and the quantum yield is ~8.27%. The FA-PDA FONs could be stable in a relatively wide pH range and high ionic strength salt solution, and the fluorescence intensities are constant. More importantly, here we developed a method for rapidly selective and sensitive detection of mercury ions (Hg2+) within 10 s using FA-PDA FONs based probe, the fluorescence intensities of FA-PDA FONs presented a great linear relationship to Hg2+ concentration, the linear range and limit of detection (LOD) were 0-18 µM and 0.18 µM, respectively. Furthermore, the feasibility of the developed Hg2+ sensor was verified by determination of Hg2+ in mineral water and tap water samples with satisfactory results.

Hydrochemical Characteristics of Mine Water and Their Significance for the Site Selection of an Underground Reservoir in the Shendong Coal Mining Area

Underground reservoir technology can mitigate water shortage and pollution problems in water shortage coal mining areas and has a good application prospect. While still a new technology, the theory and method of underground reservoirs need to be improved. This research focused on the hydrochemical characteristics of mine water and their significance for the site selection of underground reservoirs. With the Shendong coal mining area as a case study, the hydrochemical major ions, toxicological indexes, and stable isotopes of hydrogen and oxygen were tested for the mine water samples, and the water quality was quantitatively evaluated and the origins of over-limit variables were investigated by hydrogeochemical numerical simulation and ionic ratio analysis. The influencing factors of water quality were analyzed and the significance of mine water quality for the site selection of underground reservoirs was discussed. The results show that the main over-standard variables are Na+, F−, SO42−, TDS, and sodium ion adsorption ratio (SAR), and a strong positive correlation exists between F− and SAR and a negative correlation exists between F− and Ca+. Na+ in mine water originates from the dissolution of halite and silicate rocks, as well as reverse cation exchange. F− originates from reverse cation exchange and the displacement between OH− in alkaline water and F− adsorbed on the surface of minerals. On the whole, the mine water quality is better on the east than on the west of the WL River. The water–rock interactions in goaf increase the concentrations of F− and Ca2+ and SAR. The areas where the mine water samples have low concentrations of Na+, F−, and low SAR values, such as the shallow coal seams at the SGT, DLT, and WL mines, are favorable sites for the underground reservoir. The outcomes may benefit the reasonable site selection of underground reservoirs in similar coal mining areas with water shortage.

Improved 31P NMR analysis of phosphorus in highly mineralized lake water using a modified pretreatment procedure with H resin

31P Nuclear Magnetic Resonance (31P NMR) is an important analytical tool for identifying and quantifying phosphorus-based compounds in aquatic environments. However, the precipitation method typically used for analyzing phosphorus species via 31P NMR has limited application. To expand the scope of the method and apply it to highly mineralized rivers and lakes worldwide, we present an optimization technique that employs H resin to assist phosphorus (P) enrichment in highly mineralized lake water. To explore how to reduce analysis interference from salt in highly mineralized water and improve the accuracy of P analysis using 31P NMR, we conducted case studies on Lake Hulun and Qing River. This study aimed to increase the efficiency of phosphorus extraction in highly mineralized water samples by using H resin and optimizing key parameters. The optimization procedure included determining the enriched water volume, H resin treatment time, AlCl3 addition amount, and precipitation time. The final recommended optimization enrichment procedure involves treating 10 L of filtered water sample with 150 g of Milli-Q water-washed H resin for 30 s, adjusting the pH of the treated sample to 6–7, adding 1.6 g of AlCl3, stirring the mixture, and allowing the solution to settle for 9 h to collect the flocculated precipitate. The precipitate was then extracted with 30 mL of 1 M NaOH +0.05 M DETA extraction solution at 25 °C for 16 h, and the supernatant was separated and lyophilized. The lyophilized sample was redissolved in 1 mL of 1 M NaOH +0.05 M EDTA. This optimized analytical method using 31P NMR effectively identified phosphorus species in highly mineralized natural waters and can be applied to other highly mineralized lake waters globally.

Isolation and Identification of Bacterial Communities in Neutral Mine Drainage in Central Slovakian Neovolcanites (Slovakia)

There are several sources of mine drainage left over from past mining sites in the Central Slovakian neovolcanites. The neutral pH and high concentrations of sulphates and multiple potentially hazardous elements, such as zinc or manganese, are typical in this region. However, this environment could be home to specific microbiota. The aim of the study was to characterize bacterial populations in mine drainage in the Central Slovakian neovolcanites. Direct microscopic observations, cultivation methods, MALDI TOF mass spectrometry, and 16S rRNA gene sequencing of isolates were used for identification. Gram-positive and Gram-negative bacteria were almost equally represented in the mine water samples. The most abundant bacterium was the genus Bacillus spp. (43.48%). Another large group of bacteria consisted of Proteobacteria (34.78%), represented by Pseudomonas spp. (17.39%), Serratia spp. (13.04%), and Providencia spp. (4.35%). Our data confirm the presence of Bacillus spp. and Pseudomonas spp. as bacterial species occurring in an environment polluted by potentially hazardous elements, which may indicate their bioremediation potential.

Hydrochemical formation mechanism of mineral springs in Changbai Mountain (China)

Changbai Mountain area is an important mineral water storage and development area in China. The hydrochemical composition of mineral water is the decisive factor for mineral–water quality. Based on the hydrochemical data of 74 mineral water samples collected from 2018 to 2020, the characteristics and formation mechanism of the hydrochemical components of the mineral water were analyzed. The results show that the formation of single-type mineral springs (metasilicate mineral water) is controlled by rock weathering; compound mineral springs (metasilicate mineral water with high CO2 content) are the product of CO2-rich, weakly acidic, confined hot groundwater with high salinity, which are mixed with shallow groundwater as rising along the fracture. The volcanic geological process greatly influences the formation of the hydrochemical components of mineral springs on the North slope of Changbai Mountain. The mineral springs on the Longgang Mountain are greatly affected by human activities. The results of cluster analysis only consider that hydrochemical components are consistent with the classification of the areas which concentrated distributions of mineral as determined by hydrogeological and geomorphological studies. The results of this study are useful for understanding the distribution, hydrochemical characteristics, and formation mechanism of mineral springs in the Changbai Mountain area of China and provide the theoretical basis for the protection and development of mineral spring.

ANALISIS PENURUNAN KADAR LOGAM BESI (Fe) & MANGAN (Mn) DENGAN PENGGUNAAN KOAGULAN TERHADAP AIR TAMBANG BATUBARA PT. ADARO INDONESIA

The purpose of writing this study is to analyze the influence of coagulants to reduce the levels of dissolved metals Iron (Fe) & Manganese (Mn) from coal mine water The place of the study is in the operational area of the PT. Adaro Indonesia in Tabalong and Balangan Regencies, the object of the study of mine water samples was taken at the Settling pond (SP) X inlet located in the Wara mine area. This research was conducted with an experimental method, namely the Jar Test test with an experimental design compiled in a Non-Factorial Group Randomized Design (RAK) consisting of 6 (six) treatments with 3 repetitions. The analysis method carried out to determine the influence of coagulants on the decrease in Fe and Mn metal levels is to use the Anova and Tukey (BNJ) analysis method. The results of this study from all the treatments that have been carried out on coagulants in the study, the coagulants that have the greatest influence in reducing Fe metal levels are the use of coagulant Y with a combination of treatments with an increase in water pH (caustic soda Y) combined with fast and slow stirring (D1) of: 0,002 mg/L, treatment with an increase in water pH (caustic soda Y) combined with rapid stirring (D2) by: The 0,002 mg/L data analysis with the anova and tukey BNJ tests differed from other treatments. The coagulant that has the greatest influence in reducing Mn metal levels is the use of coagulant Y with a combination of treatment with an increase in water pH (caustic soda Y) + auxiliary coagulant Y combined with rapid mixing (F2) of: 2,509 mg/L, treatment with an increase in water pH (caustic soda Y) + auxiliary coagulant Y combined with slow mixing (F3) of: 2,518 mg/L.

Sources and succession of microorganisms in industrial coal flotation system

The water system in a coal preparation plant harbors a variety of microorganisms, which may pose a great effect on coal recovery, however, usually be neglected. In this study, high-throughput sequencing and the growth of indigenous microorganisms in coal slurry containing organic reagents were conducted to trace the sources and succession of the microorganisms in a running plant, and the reason for microbial community succession was deeply explained. The microbiological analysis results found that the microorganisms in the coal slurry are assigned to 34 phyla and 98 genera, all source from the coal seam. Proteobacteria, Acidobacteria, Actinobacteria, and Crenachaeota are the dominant microorganisms at the phylum level, and the abundance of Proteobacteria, Bacteroidetes, and Nitrospirae in the flotation feeding decrease, and the abundance of GAL15 increase compared to the raw coal and mine water samples. Environmental factors are important reasons for microbial community succession. Organic reagents such as collectors and frothers commonly used in coal flotation processes can change the growth environment of microorganisms. The strain QX4, isolated from raw coal and identified as Bacillus sp. can accelerate growth in coal slurry containing organic reagents. Compared with raw coal, the content of chemical oxygen demand (COD) and dissolved oxygen (DO) in the flotation feeding increase by 340 mg/l and 5 mg/l respectively, which inhibit the metabolism of Nitrospirae, Bacteroides, Proteobacteria, and Actinobacteria, while improving the metabolism of GAL15, and change the microbial community and promote the microbial succession in the coal flotation system. Therefore, indigenous microorganisms from coal seam can grow and succeed in the coal flotation system, which has a potential effect on coal flotation efficiency.

Polyamide-coated paper-based sorptive phase applied in high-throughput thin film microextraction designed by 3D printing

A new method was developed for the determination of endocrine disrupting compounds (phthalates, alkylphenols and bisphenols) in water samples by using thin film microextraction technique (TFME) with high-performance liquid chromatography and diode-array detection (HPLC-DAD). This paper reports for the first time the use of a paper-based sorptive phase (PSP) in a high-throughput semi-automated system. This system designed by 3D printing technology allowed us to integrate the PSP with a multi-well plate format. Multivariate design of experiments and one-factor-at-a-time approaches were employed for optimization. The optimized PSP preparation required two dips of the filter paper into the nylon 66 solution followed by the evaporation of the solvent. The best conditions for the extraction step were NaCl 30 % (w/v) added to the sample at pH 2 for 180 min. The desorption showed best results with acetonitrile for 20 min. The calibration curves exhibited coefficients of determination higher than 0.9837. The limits of detection varied from 1.5 to 7.6 μg L-1. Six of ten analytes showed promising results with accuracy ranging from 82 to 117 % and precision (RSD) equal or inferior to 24 % for mineral water sample. We also evaluated a coconut water sample that obtained higher deviations than mineral water sample. The time consumed for each sample was about 8.3 min.

Study of some physical and chemical properties of drinking water in Samarra city and comparing with mineral water

This study was conducted in the city of Samarra on different samples of Samarra liquefaction and liquefaction of (S.D.I) and some mineral water samples of the most popular markets in the city, such as (nada water and alain water).
 During the study, some physical and chemical properties examination of the samples studied, such as turbidity and conductivity and the amount of soluble salts have also been some chemical properties such as the concentration of chlorine and oxygen concentration and pH measurement function.
 The study shown in the sample liquefaction of (S.D.I) is worst properties like turbidity standards and the concentration of oxygen and chlorine but they were complying in each of the pH and conductivity and the concentration of soluble salts function associated with raw water source, a river water (the Tigris River).
 It came in second place of the poor quality of water Specifications liquefaction Samarra while bottled water showed good readings of the properties studied.

Trace nickel analysis in water samples via paper-based devices coupled with co-precipitation

A simple, fast, low-cost and sensitive microfluidic paper-based analytical device (u-PADs) integrated with the co-precipitation enrichment procedure was developed to analyse Ni(II) in tap and mineral water samples. The impacting factors, including pH, centrifugation (5 min at 4000 rpm), and amounts of reagents were optimized. The limit of detection of 0.009 mg L-1 and linear range of 0.03-2.00 mg L-1 were achieved with good intra- and inter-day precision (4.7 and 5.6% RSD, respectively). The recovery tests were conducted by spiking tap and mineral water samples and analyzed using the u-PADs after co-precipitation enrichment. The results obtained by the proposed method were validated by inductively coupled plasma-optical emission spectrometry (ICP-OES). The recoveries of the present method and ICP-OES were ranged from 92.4-106.8% and 92.9-97.2%, respectively. The two sets of (u-PADs and ICP-OES) results were in good agreement, as a paired t-test indicated no significant differences. The proposed method could be utilized for analyzing trace levels of Ni(II) in water samples in developing countries where the availability of conventional analytical instruments are significant problems.

Preparation of Magnetic Dummy Molecularly Imprinted Meso-Porous Silica Nanoparticles Using a Semi-Covalent Imprinting Approach for the Rapid and Selective Removal of Bisphenols from Environmental Water Samples

Bisphenol compounds (BPs) are a severe threat to humans and creatures; hence it is critical to develop a quick and simple approach for removing trace BPs from water. This research synthesized a novel template–monomer complex, phenolphthalein-(3-isocyanatopropyl)triethoxysilane (PP-ICPTES), as a dummy template, and a molecularly imprinted polymer for bisphenol was made via a semi-covalent approach. By successfully coating the imprinted layer on the Fe3O4@SiO2@mSiO2 structure, a magnetic dummy molecularly imprinted mesoporous silica nanoparticles (m-DMI-MSNPs) with a core-shell structure and superefficient aqueous phase selectivity for bisphenols was synthesized. The morphology and structure of the m-DMI-MSNPs were characterized using transmission electron microscopy (TEM), nitrogen adsorption-desorption analysis, Fourier transform infrared spectroscopy (FT-IR), and vibrating sample magnetometry (VSM). The prepared m-DMI-MSNPs presented excellent water compatibility and magnetic separation abilities. The m-DMI-MSNPs showed excellent recognition selectivity towards BPs with imprinting factors of 7.6, 8.2, and 7.5 for bisphenol F (BPF), bisphenol E (BPE), and bisphenol A (BPA), respectively. Fast binding kinetics (equilibrium time < 1 min) and a high rebinding capacity (maximum adsorption capacity, 38.75 mg g–1) were observed in the adsorption experiments. More importantly, the m-DMI-MSNPs, which combine good water compatibility, class selectivity, and magnetic separation performance, exhibited excellent performance for the removal of BPF, BPE, and BPA from tap water, mineral water, and sewage water samples, with removal efficiencies in the ranges of 96.6–97.8, 95.6–97.1, and 93.1–95.3%, respectively.