Mineral Fibers Research Articles

Development of multifunctional nylon 6,6-based nanocomposites with high electrical and thermal conductivities by scalable melt and dry blending methods for automotive applications

With the advent of intelligent automobile technology, the demand for multifunctional composites with higher electrical and thermal conductivities is increasing. We have herein reported for the first time the effect of polyolester on the dispersion of carbon nanotube (CNT) in the short-carbon fiber (CF)/nylon 6,6 (PA66) composite using a scalable melt-mixing and dry-blending method and its subsequent improvement in electrical and thermal conductivities. Masterbatches were prepared with a higher concentration of CNT (both untreated and polyolester-treated) followed by dry blended with reference composite (30 wt% CF and 10 wt% mineral fiber filled PA66) before making coupons via injection molding. A 500 % and 63 % improvements in electrical (3.14 S cm−1) and thermal conductivities (in-plane) (1.99 W m−1 K−1) conductivities were observed by adding 1.5 wt% treated CNT compared to the reference composite. The improvements were even higher than that of untreated CNT due to better dispersion. Furthermore, the electromagnetic shielding effectiveness reached 61 dB for 1.5 wt% treated CNT-filled composite (39 % enhancement). These results are significant in imparting multiple functionalities to the automotive composite parts.

The in vitro cytotoxic effects of natural (fibrous epsomite crystals) and synthetic (Epsom salt) magnesium sulfate.

Exposure to mineral fibers represents an occupational and environmental hazard since particulate inhalation leads to several health disorders. However, few data are available on the effect of fibers with high solubility like natural epsomite, a water-soluble fiber with an inhalable size that allows it to penetrate biological systems, with regard to the respiratory tract. This study evaluated the natural (fibrous epsomite) and synthetic (Epsom salt) magnesium sulfate pathogenicity. Investigations have been performed through morpho-functional and biochemical analyses, in an in vitro cell model that usually grows as monocytes, but that under appropriate conditions differentiates into macrophages. These latter, known as alveolar macrophages, if referred to lungs, represent the first line of defense against harmful inhaled stimuli. Morphological observations reveal that, if Epsom salt induces osmotic stress on cell culture, natural epsomite fibers lead to cellular alterations including thickening of the nuclear envelope and degenerated mitochondria. Moreover, the insoluble fraction (impurities) internalized by cells induces diffuse damage characterized at the highest dosage and exposure time by secondary necrosis or necrotic cell death features. Biochemical analyses confirm this mineral behavior that involves MAPK pathway activation, resulting in many different cellular responses ranging from proliferation control to cell death. Epsom salt leads to MAPK/ERK activation, a marker predictive of overall survival. Unlike, natural epsomite induces upregulation of MAPK/p38 protein involved in the phosphorylation of downstream targets driving necrotic cell death. These findings demonstrate natural epsomite toxicity on U937 cell culture, making the inhalation of these fibers potentially hazardous for human health. RESEARCH HIGHLIGHTS: Natural epsomite and synthetic Epsom salt effects have been evaluated in U937 cell model. Epsom salt induces an osmotic cellular stress. Natural epsomite fibers lead to cellular damage and can be considered potentially dangerous for human health.

Characterization of calumite-modified melaphyre glass in terms of mineral fibres and glass-ceramic materials production

The possibility of utilizing calumite (BSF) in the glass-ceramic industry was analyzed in this study. The properties of melaphyre glasses modified with 25 % and 50 % of calumite were determined after the post-melting and directional crystallization process. The produced glasses were subjected to microstructural analysis using light LM and scanning electron microscopy SEM. Their chemical composition was determined using XRF spectroscopy. After melting and directional crystallization, the glasses' structural tests were performed using FTIR spectroscopy and XRD phase analysis. The characteristic temperatures and the thermal stability of the glasses were determined with thermal analysis (DTA/TG) and dilatometric tests, which analysis was also valuable to determine the parameters of the directional crystallization process of melaphyre glasses. The results showed that unmodified melaphyre glasses demonstrate a low crystallization ability and do not crystallize even at 900 °C, while incorporating calumite into their composition increases their crystallization ability. The study showed that calumite significantly influences the chemical and structural characteristics of melaphyre glasses, which gives it the chance to be successfully used as a raw material for producing glass crystalline materials or mineral fibres. Notably, the findings underscore the potential utility of calumite as a proficient raw material for fabricating glass crystalline fibrous or insulating materials.

Tribological, mechanical, and metallurgical performance of natural fiber-reinforced composites: A comprehensive review

Composite materials have an ever-increasing demand for their application in numerous applications such as aerospace, automobile, petroleum, etc. These materials vary according to their chemical composition, properties, manufacturing techniques, etc. Natural fiber-reinforced composites are the composites where natural fibers such as plant, animal, and mineral fibers are used as reinforcement material. Reinforcement of these fibers yields composite material with extensive properties such as high strength, durability, reliability, etc. These properties lead them to commercial applications in several areas. Therefore, this paper describes various characteristics of the matrix, reinforcement, and resin used for natural fiber composite materials. Also, multiple parameters that affect the growth of these composites are investigated. The tribological behavior of natural fiber composites is focused mainly on friction, wear, and lubrication. Furthermore, the material's mechanical performance and metallurgical behavior are also given significant importance. These materials’ application in various fields is explored separately, and multiple conclusions are drawn.

Binders for Materials Based on Glass and Mineral Fibers (Review)

Binders for Materials Based on Glass and Mineral Fibers (Review)

Experimental Study of Amphibolite-Basalt (SiO2-AlO3-CaO-Fe2O3) Glasses for Glass-Ceramic Materials Production.

The paper presents research on multicomponent glasses obtained from natural and secondary raw materials, i.e., basalt, amphibolite, and cullet. The raw materials were used as potential sets to produce mineral fibres or glass-ceramic materials. FTIR spectroscopy and XRD studies were carried out to identify the composition of the phase type in the glass sets. The results were supported by SEM-EDS microstructural studies of the obtained materials. The ability of the melts to crystallize and their basic properties required in producing mineral fibres, i.e., the hardness and the acidity modulus, were also determined. In the glass samples after the crystallization process, the spectroscopic studies revealed an increase in the half-width of the band at 1200-800 cm-1 and splitting at the values of about 870 cm-1 and 970 cm-1. These changes probably indicate the formation of pyroxene-type crystalline phases. Moreover, based on the XRD results, it was confirmed that the obtained materials were fully amorphous. After annealing at 800 °C for 2 h, the materials show a small proportion of crystalline phases. For the materials annealed at higher temperatures, clear peaks from the crystalline phases were represented mainly by pyroxenes. The proportion of crystalline phases in the samples was also found to rise with increasing temperature, and the hardness values for the basalt glasses and glasses after crystallization rose from 753 to 946 HV0.05. Such an effect positively affects the properties of the obtained glass-ceramic materials based on the proposed sets. However, in the case of mineral fibres, crystallization at early 2 h at 800 °C can be a disadvantageous feature from the point of view of their application because crystalline phases can lead to fibre damage after a short period of operation; this will be confirmed in this study.

Mineralogical, Petrological and Geochemical Characterisation of Chrysotile, Amosite and Crocidolite Asbestos Mine Waste from Southern Africa in Context of Risk Assessment and Rehabilitation

Derelict asbestos mine sites in South Africa pose a considerable risk to human, environmental and socio-economic health. Comprehensive mineralogical and geochemical datasets for the existing hazardous geological materials still exposed in Southern African derelict asbestos mines remain largely non-existent, as very little published and up-to-date literature is available. In this study, three representative types of asbestos mineral fibres from derelict asbestos mines in Southern Africa, namely chrysotile from Havelock mine, amosite from Penge mine and crocidolite from Prieska mine, are characterized mineralogically and geochemically to critically evaluate actual hazards in rural and asbestos-fibre-contaminated regions. The samples were examined using polarising light microscopy, X-ray fluorescence (major and trace elemental analysis), X-ray diffraction (including Rietveld refinement), specific surface area analysis and bio-durability testing. Data are discussed in view of their potential toxicities on both human health and the environment in the context of developing countries. Finally, information on the mineralogical and geochemical status of asbestos mine waste and its importance as baseline data for rehabilitation considerations is also evaluated.

Lightweight composite gypsum boards with clay mineral and glass fibre for enhanced fire-resistance

The current strategy for developing fire-resistant gypsum boards is mainly based on adding porous materials. However, these additives are generally weaker in strength due to higher porosity and are usually produced via energy-intensive processes with relatively higher costs. This paper presents a novel strategy to fabricate lightweight fire-resistant composite gypsum boards through the synergistic coupling of naturally abundant clay mineral - palygorskite (0–30 wt%) and cost-effective glass fibre (0.5 wt%). The bulk density of the obtained boards decreases from 1059 (0 wt% palygorskite addition) to 795 kg/m3 (30 wt% palygorskite). Attributed to the higher initial porosity, reduced shrinkage above 650 °C, and the decomposition of CaSO4 above 925 °C to absorb heat, the ambient side temperature of a composite gypsum board after a 90-min standard fire test is reduced significantly by 150 °C. The new board shows a commendable post-fire strength of 0.15 MPa and fewer cracks than commercial products, which are caused by increased porosity and the bridging effect of glass fibre and sintered palygorskite particles. Through the effective integration of in-situ high-temperature X-ray diffraction, thermal mass loss/heat exchange, and thermal dilatometry, the real-time thermal behaviours of composite gypsum boards are characterised, and the microstructure, physical and mechanical properties and fire resistance are investigated.

Evaluation of porous asphalt mixtures stabilized by human scalp hair

Porous asphalt (PA) is an open-graded hot mixed asphalt that presents improved surface drainage during rainfall, improving road safety in wet weather and preventing rainfall water from receding in closed areas. The main challenge facing PA paving is binder draindown during mix transportation and placement due to the confluence of low fillers cases, open-graded aggregate gradation, and high asphalt contents. Mineral fibers such as slag wool (SW), despite their negative effects on human health and the environment, have been used as stabilizers in PA mixtures to increase binder retention and avoid stability reduction. This study evaluates using human scalp hair (HSH) as an alternative stabilizing fiber to SW in PA mixtures. Using HSH in PA mixtures is a sustainable waste recycling method and an economical solution to enhance the binder retention and stability of PA mixtures. The performance of the PA mixtures that stabilized with SW (control) and HSH was compared with National Asphalt Pavement Association (NAPA) requirements. The fiber length of 1–5 mm was maintained for SW and HSH. The PA standard gradation suggested by NAPA was used to form the stone matrix of the investigated PA mixtures. The Marshall design method was used to obtain the optimum asphalt and stabilizer contents. The performance evaluation tests were performed on SW and HSH mixtures, including loss of stability, moisture sensitivity, draindown, cantabro abrasion and rutting depth. Based on the results of the performance evaluation tests, the PA mixtures stabilized by HSH show a convergent performance compared with those stabilized by SW. The findings indicated that HSH can be considered an adequate stabilizer for PA mixtures instead of SW fibers.

Evaluation of the Effect of SBS on Performance Behavior of Stone Matrix Asphalt Mixture Containing Mineral Fiber

Evaluation of the Effect of SBS on Performance Behavior of Stone Matrix Asphalt Mixture Containing Mineral Fiber

Basalt of Kanzafarova Open Pit Mine: Raw Material for Production of Mineral Fiber

Basalt of Kanzafarova Open Pit Mine: Raw Material for Production of Mineral Fiber

Investigation on Mechanical Properties of Hybrid Natural Fiber Reinforced Polymer Composite

The use of natural fibers in composite is increasing day by due to eco-friendly nature of the fibres and reuse of waste. Natural fibers can be classified according to their source of origin such as plant fiber, mineral fiber, and animal fiber. In the present article, epoxy was taken as the matrix and wool fiber for reinforcement with flax flax fiber for fabricating the composite using the hand layup technique. The impact of the hybridization of flax and wool fibers on the mechanical properties of natural fiber reinforced polymer composite was investigated. These fibers were blended in varying percentages with fixed fiber content of 5% [(100% flax fiber), (40% wool/60% flax fiber), (50% flax/50% wool fiber), (60% wool fiber/40% flax), (100% wool fiber)] with epoxy resin and sampled as F5, WF23, WF2.5, WF32, and W5 respectively. Tensile strength, flexural strength, and impact strength were investigated through experimentation. All hybrid composites outperformed non-hybrid wool fiber composites in terms of mechanical properties. The wool fiber is poor in mechanical strength which was compensated by high strength of flax fiber.

Plasma Electrolytic Oxidation on Magnesium AZ31 with Sepiolite as Inhibitor Carrier for Improved Corrosion Protection

Plasma electrolytic oxidation (PEO) in an alkaline silicate electrolyte containing nanosized sepiolite fibers was carried out on magnesium alloy AZ31. The mineral fibers were loaded with different corrosion inhibitors and incorporated in situ during the PEO treatment. The composition and microstructure of the PEO coatings were investigated by SEM. It was shown that the fibers are located on the surface as well as inside the “weak spots” of the coating, i.e., pores and discharge channels. The fixation of the particles is caused by sintering due to the heat developed during the PEO treatment. Investigations using electrochemical impedance spectroscopy and linear sweep voltammetry in 0.01 M NaCl solution confirmed an improvement of the corrosion protection. The use of the inhibitors shifts the critical pitting potential in the anodic direction. Regarding efficiency, cerium-loaded sepiolite showed the best behavior by shifting the pitting potential by +0.9 V.

Application of Natural (Plant) Fibers Particularly Hemp Fiber as Reinforcement in Hybrid Polymer Composites - Part I. Origin of Hemp and Its Coming into Prominence, Cultivation Statistics, and Legal Regulations

ABSTRACT This paper presents a multi-aspect analysis of whether it is feasible and practical to process natural (plant) fibers into fabrics and mats as homogeneous or hybrid reinforcement in polymer composites for use in various industrial sectors. The current, stringent environmental rules of safe recycling and/or disposal of worn or damaged products at the end of their lifetime require new reinforcing materials to be used in polymer composites that need to meet the criteria of energy and material recycling. The paper comparatively analyzed chemical compositions of some selected (plant) natural fibers and compared their physical and chemical properties relative to commonly used synthetic (mineral and carbon) fibers. The world production of respective species of natural fibers has been presented. Industrial hemp was singled out as the possible quality reinforcement to be used in polymer composites in Poland and in Europe. The paper also provided a broader historical perspective of hemp’s importance for mankind over the past 28 thousand years. Hemp’s history and its impact on human development have been discussed. Finally, the paper compiled knowledge on industrial hemp use, agriculture, and processing as well as its current legal status in Poland and abroad.

The biointegration profile of fiber-reinforced plates following tibial implantation in sheep.

Biointegrative, mineral fiber-reinforced bone fixation implants recently introduced in orthopedic surgery have expanded available treatment options for fractures and bone deformities. This new technology aims to address the disadvantages of permanent metallic implants while overcoming inherent concerns of adverse inflammatory reactions when using polymer-based orthopedic implants. The purpose of this double-arm preclinical study was to evaluate the safety, biocompatibility, and biointegration of fiber-reinforced plates, following implantation on the tibias of eight sheep. Left tibias underwent periosteal elevation, allowing for implant attachment directly onto the cortical surface; right tibia plates were implanted over intact periosteum. Microcomputed tomography and histopathology were performed at 13, 26, 52, 78, 104, and 134 weeks postimplantation. All animals were evaluated clinically at each time point, with no evidence of local adverse reactions. Histopathology demonstrated anti-inflammatory M2-like macrophages and multinucleated giant cells corresponding to implant bioabsorption, similar for both groups at each time point, and indicating expected implant biocompatibility. Inflammatory cells (i.e., eosinophils, lymphophyctes, plasma cells, and M1-like macrophages) were absent throughout the study. The bioabsorption process had started at 13 W, with the highest rate at 52-78 W. At 104 W, only residual polymer material was left (∼5% of implant area). Low amounts of mineral fibers were evident at 78 W and were absent (fully remodeled) by 104 W. At 134 W, implants at both sites were fully bioabsorbed. In conclusion, these new fiber-reinforced implants demonstrated bone remodeling and complete biointegration, with no adverse tissue response. Clinical significance: In this double-arm, 2.5-year study, a biointegrative, fiber-reinforced plate implanted on the tibias of sheep was fully absorbed within 134 weeks, with no adverse tissue reaction. Bioabsorption was similar, with or without periosteal elevation, mimicking conditions like those observed in traumatic injuries disrupting the periosteum, open reduction and internal fixation, or minimally invasive surgeries. These results demonstrate the feasibility, versatility, and safety of this new class of biointegrative bone implants. This newly developed technology avoids the complications of the removal of metal implants.

A Review of the Mineralogy, Petrography, and Geochemistry of Serpentinite from Calabria Regions (Southern Italy): Problem or Georesource?

Serpentinite rocks testify to the ocean-floor metamorphism that took place and transformed the original mineralogy and fabric of previous ultramafic rocks. Due to their tectonic and petrological importance, in recent decades, there has been increasing interest in serpentinites. From the economic point of view, it is worth noting that, due to their beauty and attractiveness, serpentinite rocks have been exploited and traded as building and ornamental stones since prehistorical times worldwide. In this work, we provide a comprehensive report of the petrographic, mineralogical, petrophysical, and geochemical features of the serpentinites cropping out in the northern sector of the Calabria–Peloritani Orogen (Italy), where the historical quarries are located. Since these serpentinite rocks have been traded for a long time and employed as an excellent building material, their detailed knowledge may provide a useful tool to understand their behavior when they are employed as building materials, to predict their performances upon emplacement in monuments, and to plan correct restoration by considering the provenance of the lithotypes employed. Moreover, comprehensive characterization is also particularly important because it has been reported that serpentinites from Calabria may contain asbestiform and other fibrous minerals, as testified by the occurrence of chrysotile, tremolite, and actinolite asbestos located within the veins, which could lead to health problems due to asbestos fiber exposure. Finally, serpentinite may be considered as an important potential CO2 sequestration sink.

Exposure to insulating materials and risk of coronary artery diseases: a cross-sectional study.

Although previous reports link exposure to insulating materials with an increased risk of mesothelioma and chronic respiratory diseases, studies evaluating their associations with the risk of coronary artery diseases (CAD) are lacking. We aimed at evaluating the associations between exposure to insulating materials and the 10-year risk of CAD among insulators. In this cross-sectional study, we recruited 643 adults (≥18 years), full-time insulators from the Local 110 Heat and Frost Insulators and Allied Workers Union in Edmonton, Alberta. We obtained demographic information, personal and family history, and job-exposure history, including experience (years) and types of exposure to insulating materials. Clinical profiling including Framingham risk scores (FRS) was assessed. Of all insulators, 89% were men (mean ± SD age: 47 ± 12 years), 27% had a parental history of cardiac diseases, and 22% had a comorbid chronic respiratory disease. In total, 53% reported exposure to asbestos, while 61, 82, and 94% reported exposure to ceramic fibers, fiberglass, and mineral fibers, respectively. In single-exposure multivariable regression models adjusted for experience, marital status, and body mass index (BMI), asbestos was found to be associated with higher FRS (β: 1.004; 95%CI: 0.003-2.00). The association remained consistent in multi-exposure models and a higher association was found between asbestos exposure and FRS among insulators with comorbid chronic respiratory disease. Our study demonstrates that apart from cancer and chronic respiratory diseases, asbestos exposure may also have a cardiac effect, thus warranting the need for systematic surveillance to protect workers from the adverse effects of these materials.

DETERMINATION OF THE CHEMICAL AND MINERALOGICAL COMPOSITION OF TRACHIBASALTIC PORPHIRITE FROM THE GAVASAY FOR OBTAINING MINERAL FIBER

The results of studies of the chemical and mineralogical compositions and the main characteristics for determining the suitability of trachybasaltic porphyrite from the Gavasay deposit of Uzbekistan for obtaining heat-insulating material, in particular mineral fiber, are presented. It has been established that this new deposit of igneous rock can be used as the main raw material component for the production of basalt fiber products, a widely demanded and modern material in the construction industry.

Structural and functional heterogeneity of mineralized fibrocartilage at the Achilles tendon-bone insertion.

A demanding task of the musculoskeletal system is the attachment of tendon to bone at entheses. This region often presents a thin layer of fibrocartilage (FC), mineralized close to the bone and unmineralized close to the tendon. Mineralized FC deserves increased attention, owing to its crucial anchoring task and involvement in enthesis pathologies. Here, we analyzed mineralized FC and subchondral bone at the Achilles tendon-bone insertion of rats. This location features enthesis FC anchoring tendon to bone and sustaining tensile loads, and periosteal FC facilitating bone-tendon sliding with accompanying compressive and shear forces. Using a correlative multimodal investigation, we evaluated potential specificities in mineral content, fiber organization and mechanical properties of enthesis and periosteal FC. Both tissues had a lower degree of mineralization than subchondral bone, yet used the available mineral very efficiently: for the same local mineral content, they had higher stiffness and hardness than bone. We found that enthesis FC was characterized by highly aligned mineralized collagen fibers even far away from the attachment region, whereas periosteal FC had a rich variety of fiber arrangements. Except for an initial steep spatial gradient between unmineralized and mineralized FC, local mechanical properties were surprisingly uniform inside enthesis FC while a modulation in stiffness, independent from mineral content, was observed in periosteal FC. We interpreted these different structure-property relationships as a demonstration of the high versatility of FC, providing high strength at the insertion (to resist tensile loading) and a gradual compliance at the periosteal surface (to resist contact stresses). STATEMENT OF SIGNIFICANCE: Mineralized fibrocartilage (FC) at entheses facilitates the integration of tendon in bone, two strongly dissimilar tissues. We focus on the structure-function relationships of two types of mineralized FC, enthesis and periosteal, which have clearly distinct mechanical demands. By investigating them with multiple high-resolution methods in a correlative manner, we demonstrate differences in fiber architecture and mechanical properties between the two tissues, indicative of their mechanical roles. Our results are relevant both from a medical viewpoint, targeting a clinically relevant location, as well as from a material science perspective, identifying FC as high-performance versatile composite.

The Fire Resistance of Transformable Barriers: Influence of the Large-Scale Factor

The paper presents the results of the development of a multi-layer protective product, which is a transformable fire barrier, installed in buildings and structures to limit the spread of flame, heat flow and smoke. Based on the results of the simulation of eight samples of fire curtains, three promising samples of different compositions were selected, demonstrating a fire resistance limit on the loss of thermal insulating capacity (I) of 30 min. During the small-scale tests, it was found that the multilayer fabric of the following composition was promising: heat-treated silica fabric, aluminum foil, mineral fiber heat insulation material, stitched by needle-punching with silica thread, fabric reinforced with fiberglass mesh and stitched through with basalt thread, with seams treated with a fire-resistant elastic sealant. According to the results of a standard large-scale experimental study, a fire curtain with a loss of integrity not less than 60 min, and a loss of thermal insulating ability not less than 15 min were obtained. The results of the study assess the impact of the scale factor on the fire resistance limit of fire curtains in a fire.