Crystalline Minerals Research Articles

Behaviour of nutrients released from crystalline minerals of artificial potassium silicate fertilizer and their supply to the Japanese mustard spinach (Brassica rapavar.perviridis)

AbstractArtificial potassium silicate fertilizer (PSF) is a typical slow‐release potassium fertilizer. However, the exact minerals that are released by PSF and the nutrients that are made available to plants remain unclear. This study quantitatively investigated the behaviour of nutrients released from PSF by the batch‐release test and their supply to plants by the plant growth tests, respectively, to determine the quantitative relationship between nutrients released from PSF and taken up by the plant. X‐ray diffraction (XRD) analysis showed that kalsilite, åkermanite, and potassium–magnesium silicate were the most abundant crystalline minerals in PSF. The XRD peaks of åkermanite and potassium–magnesium silicate were absent after citric acid extraction at a liquid/solid ratio of 20 to 100 (CA20 and CA100). Magnesium‐use efficiencies in PSF (11%) and residue treatments after ammonium acetate extraction (AC, 10%) were higher than those in residue treatments after CA20 (1.8%) and CA100 (6.0%). Potassium (%) released by AC in the batch‐release test (4.5%) was compatible with the difference of potassium‐use efficiencies between the treatments of PSF (21%) and the AC‐residue (16%). Likewise, potassium (%) released by CA20 (8.8%) was lower than the difference of potassium‐use efficiencies between the treatments of PSF (21%) and CA20‐residue (7.9%). This study suggests that potassium is rapidly released from potassium–magnesium silicate in PSF and is readily available to plants.

Zn-containing Adhesives Facilitate Collagen Protection and Remineralization at the Resin-Dentin Interface: A Narrative Review.

This is a narrative review of the literature assessing the potential effectiveness of doping dentin polymeric adhesives with zinc compounds in order to improve bonding efficacy, remineralization and protection against degradation. A literature search was conducted using electronic databases, such as PubMed, MEDLINE, DIMDI and Web of Science. Through our search, we found literature demonstrating that Zn-doped dentin adhesives promote protection and remineralization of the resin-dentin interfaces. The increased bioactivity has also facilitated dentinal tubules’ occlusion by crystals’ precipitation contributing to improved sealing efficacy of restorations. Loading dentin adhesives with zinc gives rise to an increase of both crystallinity of mineral and crosslinking of collagen. The main role of zinc, in dentin adhesives, is to inhibit collagen proteolysis. We concluded that zinc exerts a protective effect through binding at the collagen-sensitive cleavage sites of matrix-metalloproteinases (MMPs), contributing to dentin matrix stabilization. Zinc may not only act as a MMPs inhibitor, but also influence signaling pathways and stimulate metabolic effects in dentin mineralization and remineralization processes. Zn-doped adhesives increase the longevity of dentin bonding through MMPs inhibition. Zn poses a remineralization strategy in demineralized dentin.

Mission to a Metal World: In August, NASA will Launch a Probe to Study a Strange Metallic Asteroid Called Psyche

In August 2022, NASA will launch a probe to study a strange metallic asteroid called Psyche. The Psyche spacecraft will reach its destination in early 2026, where it will commence its two-yearlong scientific survey of the asteroid. What will it find there? Astronomers think we might see enormous surface faults from the contraction of freezing metal, glittering cliffs of green crystalline mantle minerals, frozen flows of sulfur lava, and vast fields of metal shards scattered over the surface from millennia of high-speed impacts. There will no doubt be plenty of surprises, too.

Application of a Fourier Transform Infrared (FTIR) Principal Component Regression (PCR) Chemometric Method for the Quantification of Respirable Crystalline Silica (Quartz), Kaolinite, and Coal in Coal Mine Dusts from Australia, UK, and South Africa.

This article describes the approach used to assess the performance of a Fourier transform infrared (FTIR) and principal component regression (PCR) chemometric method when measuring respirable quartz, kaolinite, and coal in samples from a variety of mines from different countries; relative to target assigned values determined using X-ray diffraction (XRD). For comparison, FTIR results using the partial least squares regression (PLSR) method are also available. Bulk dusts from 10 Australian mines were scanned using XRD and grouped into three sets based on the levels of quartz, kaolinite, and feldspar within their crystalline mineral composition. Prediction samples were generated from 5 of these Australian mine dusts, Durrans coal dust, 2 mine dusts from the UK, and a single South African mine dust (71 samples in total) by collecting the aerosolized respirable dust onto 25-mm diameter polyvinylchloride filters using the Safety in Mines Personal Dust Sampler (SIMPEDS) operating at 2.2 l min-1. The predicted values from the FTIR chemometric methods were compared with assigned target values determined using a direct on-aerosol filter XRD analysis method described in Method for the Determination of Hazardous Substances (MDHS) 101. Limits of detection (LOD) and uncertainty values for each analyte were calculated from a linear regression between target and predicted values. The uncertainty was determined using the calibration uncertainty equation for an unweighted regression. FTIR results from PCR and PLSR are very similar. For the PCR method, the LOD for quartz, kaolinite, and coal were 5, 25, and 71 µg, respectively. For quartz, an LOD of 5 µg corresponds to an airborne quartz concentration of 10 µg m-3, assuming a 4-h sampling time and collection flow rate of 2.2 l min-1. The FTIR measurement met the expected performance criteria outlined in ISO 20581 when sampling quartz for more than 4 h using a flow rate of 2.2 l min-1 at a concentration of 0.1 mg m-3 (100 µg m-3), the current workplace exposure limit in Great Britain. This method met the same performance criteria when measuring exposures at the Australian Workplace Exposure Standard (WES) concentration of 0.05 mg m-3, although in this case a sampling period greater than 8 h was needed.

Aeolian driven oxidant and hydrogen generation in Martian regolith: The role of mineralogy and abrasion temperature

The surface of Mars is a dynamic, cold environment where aeolian abrasion leads to the fracturing of silicate minerals which can produce oxidants upon exposure to water. Here we report results of a series of laboratory experiments where the abrasion of sand sized (125 – 300 μm) quartz, labradorite, forsterite and opal were conducted under a simulated Martian atmosphere at a range of temperatures common to Mars' surface (193 to 273 K). Our results suggest that abrasion rates are controlled by temperature; an observation that may have potential for providing insight into Martian paleo-temperatures. On the addition of water, detectable H2O2 was generated in all abraded experiments with crystalline quartz, labradorite and forsterite, but not amorphous opal – supporting previous inferences that mineral crystal structure plays a role in oxidant production. Dissolved Fe concentrations also indicated a strong additional control on net H2O2 production by Fenton reactions. Detectable H2 was similarly measured in abraded experiments with crystalline minerals and not for amorphous opal. Labradorite and forsterite generated minimal H2 and only in more abraded samples, likely due to the reaction of Si• with water. In quartz experiments H2 was only present in samples where a black magnetic trace mineral was also present, and where H2O2 concentrations had been reduced to close to detection. In the quartz samples we infer a mechanism of H2 generation via the previously proposed model of spinel-surface-promoted-electron transfer to water. The presence of H2O2 may exert an additional control on net H2 production rates either directly (via reaction of H2 with OH• and H2O2) or indirectly (by the oxidation of H2 generating sites on mineral surfaces). Overall, our data supports previous inferences that aeolian abrasion can produce additional oxidants within the Martian regolith that can increase the degradation of organic molecules. We further suggest that the apparent control of H2O2 concentrations on net H2 generation in our experiments may help explain some previous apparently contradictory evidence for mineral-water H2 generation at low temperatures.

Fabrication of ceramic monoliths from diatomaceous earth: effects of calcination temperature on silica phase transformation

The raw diatomaceous earth from the vicinity of Bitola (North Macedonia) showed low bulk density (0.61-0.69 g/cm3), high-water absorption (75-81%) and porosity (66- 72%). The chemical composition was determined with ICP-MS, revealing the following results for the diatomaceous earth: SiO2 (63.69 wt%), Al2O3 (11.79 wt%), Fe2O3 (5.95 wt%), MnO (0.15 wt%), TiO2 (0.65 wt%), CaO (1.51 wt%), MgO (2.24 wt%), P2O5 (0.13 wt%), K2O (1.64 wt%), Na2O (0.93 wt%), LOI (11.21 wt%). XRPD data of the examined sample of clayey diatomite mainly depicted crystalline behavior with a small presence of amorphous phase. The crystalline mineral phases mainly comprise: silica (quartz), feldspars (plagioclase), mica (muscovite), chlorites and dolomite. SEM and TEM results show cased presence of micro- and nanostructures with pores ranging from 250 to 600 nm. The clayey diatomite was sintered at three temperatures (900, 1000 and 1100?C) for a period of 1 h. XRPD of the sintered samples at 1100?C showed certain thermal stability and formation of new phases (mullite and tridymite) that makes the analyzed diatomaceous earth suitable for production of various types of ceramic, construction and thermal insulating materials.

Crystal Structure Algorithm (CryStAl) Based Selective Harmonic Elimination Modulation in a Cascaded H-Bridge Multilevel Inverter

This paper introduces an effective Selective Harmonic Elimination (SHE) modulation technique in a five, seven, and nine-level cascaded H-bridge (CHB) multilevel inverter (MLI). Minimization of the harmonics and device counts is the basis for the ongoing research in the area of MLI. Reduced harmonics and hence the lower Total Harmonic Distortion (THD), improve the output power quality. SHE is a low-frequency modulation scheme to achieve this goal. SHE techniques are used to eliminate the distinct lower-order harmonics by determining the optimum switching angles. These angles are evaluated by solving the non-linear transcendental equations using any optimization technique. For this purpose, the Crystal Structure Algorithm (CryStAl) has been used in this paper. It is a metaheuristic, nature-inspired, and highly efficient optimization technique. CryStAl is a simple and parameter-free algorithm that doesn’t require the determination of any internal parameter during the optimization process. It is based on the concept of crystal structure formation by joining the basis and lattice point. This natural occurrence can be realized in crystalline minerals in their symmetrically organized components: ions, atoms, and molecules. The concept has been utilized to solve non-linear transcendental equations. SIMULINK/MATLAB environment has been used for the simulation. The simulation result shows that the crystal structure algorithm is very effective and excels the other metaheuristic algorithm. Hardware results validate the performance.

Characterization of fly ash for potential utilization in green concrete

Coal-based thermal power plants are the residue material of the combustion of FA (Fly Ash). The use of FA has become an attractive alternative to disposals by raising the consciousness of the environment. The present study aims to examine the prospective use of FA in concrete and building applications, the physical, chemical, mineral and thermal properties of FA. FA obtained at the Rajiv Gandhi thermal plant, Hisar, Haryana, India, Electrostatic precipitations for experimental purposes. The FA sample is characterized as being mostly enriched in silicon; alumina and iron oxides fall into the F-type FA group. In the ash sample, Quartz and Mullite are the main mineral crystalline phases. Distinguishing thermal examination of the FA sample reveals degradation from 400 °C to 700 °C in a particular stage. The absorbed humidity and light volatility is removed in the sample during initial area. The findings of the characterization show that FA has the ability to replace the principal components of concrete like sand and to improve strength. The effects on the environment and economics of disposing FA will be reduced by establishing new opportunities for further use.

Radioactivity, Metals Pollution and Mineralogy Assessment of a Beach Stretch from the Ionian Coast of Calabria (Southern Italy).

In the present article, a case study is reported regarding an investigation carried out in order to assess radioactivity concentration, heavy metals pollution and mineralogy of a beach stretch extending from Soverato to Squillace municipalities of the Ionian coast of Calabria, South of Italy, a popular tourist destination, especially in summer. The analysis of radionuclides contents was performed by using a High Purity Germanium (HPGe) gamma-ray detector, in order to quantify the average specific activity of 226Ra, 232Th and 40K natural radionuclides and 137Cs anthropogenic radioisotope. The absorbed dose rate and the annual effective dose equivalent radiological hazard indices were also estimated. Furthermore, X-ray Fluorescence (XRF) spectrometry measurements were carried out for the quantitative elemental analysis of the sand, in order to investigate any possible chemical pollution by heavy metals. For this aim, different indices such as Enrichment Factor (EF), Geoaccumulation Index (Igeo), Contamination Factor (CF) and Pollution Load Index (PLI) were applied to estimate the level of toxicity imposed on the ecosystem by the detected heavy metals. Finally, in order to identify the crystalline mineral components of the investigated sand samples, X-ray Diffraction (XRD) and Micro-Raman Scattering (MRS) measurements were carried out.

The mineral transformation and molten behaviors of biomass waste ashes in gasification-melting process

Understanding the various ash transformation properties is vital for improving gasification behavior and optimizing industrial operation conditions during the gasification-melting process of biomass wastes. In this work, five typical biomass wastes were selected to investigate the slag property. The ash fusion process, mineral transformation and AAEMs solidification behaviors were performed and predicted by mineral transformation analysis and thermochemical calculation. The results indicated that ash fusion process contained sintering, swelling, bubbling and melting stages, which was related to ash chemical compositions. Besides, the ash flow temperature had a linear relationship with the basic-to-acid ratio of biomass waste ashes. High SiO2 content would lead to strong mineral crystallinity at high temperatures. The mineral transformation was also highly related to ash compositions. The complicated reactions of inorganic matters occurred when SiO2 content lied between 50 wt% and 70 wt%. For AAEMs solidification, the alkali was prone to react simultaneously with both SiO2 and Al2O3 to form eutectoid, and the range of 35–65 wt% for SiO2 + Al2O3 contents was beneficial for alkali solidification. All the obtained data was meaningful to provide a modifying reference for the efficient and clean utilization of various biomass wastes during gasification process.

Mineral Scaling on Reverse Osmosis Membranes: Role of Mass, Orientation, and Crystallinity on Permeability.

Prior mineral scaling investigations mainly studied the effects of membrane surface properties rather than on the mineral properties and their impact on membrane permeability. In our study, mass, crystal growth orientation, and crystallinity of mineral precipitates on membranes, as well as their effects on membrane permeability have been investigated. Gypsum scaling tests on bare and bovine serum albumin (BSA)-conditioned membranes were conducted under different saturation indices. Results show that a longer scaling period was required for BSA-conditioned membranes to reach the same membrane permeate flux decline as bare membranes. Though the final reduced permeability was the same for both two membranes, the masses of the mineral precipitates on BSA-conditioned membranes were around two times more than those on bare membranes. Further mineral characterizations confirmed that different permeability decay rates of both types of the membrane were attributed to the differences in growth orientations rather than amounts of gypsum precipitates. Moreover, BSA-conditioned layers with high carboxylic density and specific molecular structure could stabilize bassanite and disrupt the oriented growth to inhibit the formation of needle-like gypsum crystals as observed on bare membranes, thus resulting in lower surface coverage with scales on membranes and alleviating the detrimental scaling effect on membrane permeability.

A three dimensional kinetic Monte Carlo defect-free crystal dissolution model for biological systems, with application to uncertainty analysis and robust optimization

The objective of this study was to construct a novel kinetic Monte Carlo (kMC) model to predict the complete dissolution of nanoscale crystals. The developed framework was designed to predict the dissolution of a wide variety of crystalline minerals, regardless of their composition and crystal structure. The proposed framework was used to explore ways of enhancing crystal dissolution processes by assessing the variability from environmental uncertainties and by performing robust optimization to improve the dissolution performance. The approach was used to simulate calcium carbonate dissolution within the human gastrointestinal system. Polynomial chaos expansions (PCEs) were used to propagate the parametric uncertainty through the kMC model. Robust optimization was subsequently performed to determine the crystal design parameters that achieve target dissolution specifications using low-order PCE coefficient models. The results showcased the applicability of the kMC crystal dissolution model and the need to account for dissolution uncertainty within key biological applications.

Rock weathering controls the potential for soil carbon storage at a continental scale

As rock-derived primary minerals weather to form soil, they create reactive, poorly crystalline minerals that bind and store organic carbon. By implication, the abundance of primary minerals in soil might influence the abundance of poorly crystalline minerals, and hence soil organic carbon storage. However, the link between primary mineral weathering, poorly crystalline minerals, and soil carbon has not been fully tested, particularly at large spatial scales. To close this knowledge gap, we designed a model that links primary mineral weathering rates to the geographic distribution of poorly crystalline minerals across the USA, and then used this model to evaluate the effect of rock weathering on soil organic carbon. We found that poorly crystalline minerals are most abundant and most strongly correlated with organic carbon in geographically limited zones that sustain enhanced weathering rates, where humid climate and abundant primary minerals co-occur. This finding confirms that rock weathering alters soil mineralogy to enhance soil organic carbon storage at continental scales, but also indicates that the influence of active weathering on soil carbon storage is limited by low weathering rates across vast areas.

Micro CT and Experimental Study of Carbonate Precipitation from CO2 and Produced Water Co-Injection into Sandstone

Carbon dioxide geological storage involves injecting captured CO2 streams into a suitable reservoir. Subsequent mineral trapping of the CO2 as carbonate minerals is one of the most secure forms of trapping. Injection of CO2 dissolved in water or co-injection of CO2 with water may enhance trapping mechanisms. Produced waters are already re-injected into reservoirs worldwide, and their co-injection with CO2 could enhance mineral trapping in low reactivity rock by providing a source of cations. Sandstone drill core from a reservoir proposed for CO2 storage was experimentally reacted with supercritical CO2 and a synthetic produced water. Micro computed tomography (CT), QEMSCAN, and SEM were performed before and after the reaction. The sandstone sample was predominantly quartz with minor illite/muscovite and kaolinite. The sandstone sub-plug micro-CT porosity was 11.1% and 11.4% after the reaction. Dissolved Ca, Mg, and Sr decreased during the reaction. After the reaction with CO2 and synthetic produced water, precipitation of crystalline carbonate minerals calcite and dolomite was observed in the pore space and on the rock surface. In addition, the movement of pore filling and bridging clays, as well as grains was observed. Co-injection of CO2 with produced waters into suitable reservoirs has the potential to encourage CO2 mineral trapping.

Experimental Study for Sand Filter Backwash Water Management: Low-Cost Treatment for Recycling and Residual Sludge Utilization for Radium Removal

Management of backwash water (BW) generated from sand filtration of groundwater naturally contaminated with iron (Fe), manganese (Mn), and radium (Ra) remains a challenge worldwide. The present study investigated the effectiveness of a low-cost clay ceramic filter for BW recycling along with residual sludge utilization for Ra removal from BW. A 15 day continuous ceramic filtration process operated at a constant flux of 2000 L/m2/d (83 LMH) showed 99% removal of Fe, Mn, and turbidity. The treated BW was found suitable for recycling back to the sand filters. Subsequently, the residual sand filter backwash sludge (BS) was collected, characterized by scanning electron microscopy (SEM) and X-ray diffraction, and examined as a potential adsorbent to the Ra. Results showed that the sludge constituted heterogeneous basic elements, with higher percentages of iron and manganese oxides. The sludge can be classified as typical mesoporous and poorly crystalline minerals consisting primarily of quartz and Mn2O3. Over 60% of Ra from the initial 2.1 bq/L could be removed by sludge in 30 min at neutral pH. The adsorption kinetics of sludge described well by the pseudo-second order model and Ra adsorption on the sludge were mainly controlled by chemisorption rate-controlling steps, intraparticle diffusion, and external mass transfer processes. Treatment of BW by low-cost clay ceramic filters and the utilization the BS for Ra removal would be a sustainable sand filter BW management practice.

Effects of sodium and potassium on fusion characteristics of petroleum coke ash with high vanadium and nickel

Ash fusion temperatures (AFTs) are widely employed to evaluate petroleum coke ash fusibility, which has significant effects on its high-value and clean utilization. Sodium (Na) and potassium (K) both are considered to be the effective components to improve the ash fusion characteristics for slag tapping of entrained flow gasifiers. Herein, the effects of (Na2O + K2O) and Na2O/K2O mass ratio on the fusion behaviors of petroleum coke ash with high vanadium (V) and nickel (Ni) were investigated by AFTs tests in conjunction with X-ray diffraction and thermodynamic equilibrium calculations. The results demonstrated that AFTs followed a significant decline with the increase in (Na2O + K2O) content. Vanadium trioxide (V2O3), coulsonite (FeV2O4), nickel (Ni) and nepheline ((Na,K)AlSiO4) were the dominant crystalline minerals formed in high-temperature ash. The formation of low-melting (Na,K)AlSiO4 was responsible for the variation in AFTs because of the low ionic potential of Na+ and K+. AFTs dropped slightly as the Na2O/K2O mass ratio decreased from 10/0 to 4/6, and then exhibited a sharp rise. The mixed alkaline effect between Na and K effectively influenced the AFTs variations. When the Na2O/K2O mass ratio was higher than 8/2, Na existed in eutectics or amorphous matters rather than Na-bearing crystalline species at high temperatures. As the Na2O/K2O mass ratio further decreased, the crystalline phase (Na,K)AlSiO4 was converted into high-melting leucite (KAlSi2O6), which resulted in the sharp increase in AFTs.

Dose-dependent effects of pharmaceutical treatments on bone matrix properties in ovariectomized rats

As both anabolic and anti-catabolic osteoporosis drugs affect bone formation and resorption processes, they may contribute to bone's overall mechanical behavior by altering the quality of the bone matrix. We used an ovariectomized rat model and a novel fracture mechanics approach to investigate whether treatment with an anabolic (parathyroid hormone) or anti-catabolic (alendronate) osteoporosis drugs will alter the organic and mineral matrix components and consequently cortical bone fracture toughness. Ovariectomized (at 5 months age) rats were treated with either parathyroid hormone or alendronate at low and high doses for 6 months (age 6–12 months). Specifically, treatment groups included untreated ovariectomized controls (n = 9), high-dose alendronate (n = 10), low-dose alendronate (n = 9), high-dose parathyroid hormone (n = 10), and low-dose parathyroid hormone (n = 9). After euthanasia, cortical microbeams from the lateral quadrant were extracted, notched, and tested in 3-point bending to measure fracture toughness. Portions of the bone were used to measure changes in the 1) organic matrix through quantification of advanced glycation end-products (AGEs) and non-collagenous proteins, and 2) mineral matrix through assessment of mineral crystallinity. Compared to the ovariectomized group, rats treated with high doses of parathyroid hormone and alendronate had significantly increased cortical bone fracture toughness, which corresponded primarily to increased non-collagenous proteins while there was no change in AGEs. Additionally, low-dose PTH treatment increased matrix crystallinity and decreased AGE levels. In summary, ovariectomized rats treated with pharmaceutical drugs had increased non-collagenous matrix proteins and improved fracture toughness compared to controls. Further investigation is required for different doses and longer treatment periods.

Melatonin-doped polymeric nanoparticles induce high crystalline apatite formation in root dentin

ObjectiveTo investigate the effect of novel polymeric nanoparticles (NPs) doped with melatonin (ML) on nano-hardness, crystallinity and ultrastructure of the formed hydroxyapatite after endodontic treatment. MethodsUndoped-NPs and ML-doped NPs (ML-NPs) were tested at radicular dentin, after 24 h and 6 m. A control group without NPs was included. Radicular cervical and apical dentin surfaces were studied by nano-hardness measurements, X-ray diffraction and transmission electron microscopy. Mean and standard deviation were analyzed by ANOVA and Student-Newman-Keuls multiple comparisons (p < 0.05). ResultsCervical dentin treated with undoped NPs maintained its nano-hardness values after 6 m of storage being [24 h: 0.29 (0.01); 6 m: 0.30 (0.02) GPa], but it decreased at apical dentin [24 h: 0.36 (0.01); 6 m: 0.28 (0.02) GPa]. When ML-NPs were used, nano-hardness was similar over time [24h: 0.31 (0.02); 6 m: 0.28 (0.03) GPa], at apical dentin. Root dentin treated with ML-NPs produced, in general, high crystallinity of new minerals and thicker crystals than those produced in the rest of the groups. After 6 m, crystals became organized in randomly oriented polyhedral, square polygonal block-like apatite or drop-like apatite polycrystalline lattices when ML-NPs were used. Undoped NPs generated poor crystallinity, with preferred orientation of small crystallite and increased microstrain. SignificanceNew polycrystalline formations encountered in dentin treated with ML-NPs may produce structural dentin stability and high mechanical performance at the root. The decrease of mechanical properties over time in dentin treated without NPs indicates scarce remineralization potential, dentin demineralization and further potential degradation. The amorphous stage may provide high hydroxyapatite solubility and remineralizing activity.

Recovery of struvite from wastewaters as an eco-friendly fertilizer: Review of the art and perspective for a sustainable agriculture practice in India

The limited rock phosphate deposits present in the earth’s crust are being used at a fast rate and therefore phosphate fertilizers use will be restricted in the future. Hence, there is an urgent need of conserving the use of phosphorous (P) and recover/reuse of P from wastewaters to the maximum extent. Struvite (MgNH4PO4) is a crystalline mineral composed of magnesium, ammonium, and phosphate, and is considered as an adequate source of nutrients especially P. Struvite can be used as raw material for fertilizer production or as slow-release fertilizer. Recently, there were a lot of researches carried out to explore the possibility of recovering the struvite from wastewater streams. This paper reviews the potential sources of P in wastewater streams and the techniques of struvite recovery available in the literature for practical applications. Anaerobic digester supernatant, urine from livestock and humans are identified as potential wastewater sources of P in India. Continuous stirred tank reactor technique can be easily adopted to recover P, which is known to recover 80–90% P in wastewater. Currently, India is the second largest consumer of P due to the low P in soil and depends on imported sources for meeting her demand on fertilizers. Therefore, the work presented in this review would help India to formulate suitable policy guidelines to meet a part of the P demand by recovering struvite from wastewater streams and apply in agricultural field as an eco-friendly fertilizer. Such an effort significantly contributes to promote circular economy and sustainable agriculture.

Hydrothermal conversion of Cd/Zn hyperaccumulator (Sedum alfredii) for heavy metal separation and hydrochar production

The harmless treatment of heavy metal-enriched hyperaccumulator biomass is the main barrier to the industrialization of phytoremediation. Hydrothermal conversion of Sedum alfredii using different solvents (i.e ·H2O and HCl) at 210–300 ℃ was performed to investigate the behaviors of Cd and Zn, and the characteristics and potential application of the derived hydrochars were determined. Low temperature and HCl addition favored the removal of Cd/Zn from the solid phase. The highest removal efficiencies of Cd (95.0%) and Zn (89.3%) were achieved at 210 ℃ with the presence of HCl. The yield, pH, ash content, element concentration, functional groups, and crystalline minerals of the derived hydrochar were influenced by the reaction temperature and addition of HCl. The leaching risk of Cd and Zn was significantly reduced by hydrothermal conversion. The addition of HCl facilitated the immobilization of Zn, while it enhanced the mobility of Cd. Moreover, the hydrochar derived at 210 ℃ showed increased sorption capacity towards Cu, and the addition of HCl greatly improved the energy density of hydrochar. These results suggest that HCl-mediated hydrothermal conversion could be a promising technique to achieve the separation of Cd and Zn from hyperaccumulator biomass as well as the production of value-added hydrochar.