Mineral Clasts Research Articles

Thermal analysis of Romanian ancient ceramics

The present work is focused on thermoanalyt- ical investigations as thermogravimetric analysis (TG) and derivative thermal analysis (DTG), applied for the char- acterization of some samples collected from archaeological sites (Brasov and Trofeum Traiani) located in different regions of Romania. New informations derived about ceramic technologies concerning raw materials and binding materials (mineralogical components) have been obtained. All these experimental results have been correlated with related techniques as X-ray diffraction (XRD), energy- dispersive X-ray fluorescence (EDXRF) and inductively coupled plasma—atomic emission spectrometry (ICP- AES). By progressive heating in static air atmosphere and in the temperature range of 20-800 � C, all investigated materials exhibit three main successive processes, associ- ated with the dehydration and thermo-oxidative degrada- tions. The rate of the first thermooxidative process, temperatures corresponding to the maximum rate of the second thermooxidative process and shrinkage temperature were associated with the damage of the investigated materials due to environmental impact. Heating also affects the contact between the fine-sized clay matrix and mineral clast fragments, appearing in reaction rims, sometimes showing newly formed phases. The temperature at which ancient ceramics and pottery were fired varies over a wide range (600-800 � C) depending on the type of clay used, although firing temperatures not above 30-400 � C have also been suggested. Clay minerals, as the main material for production of ceramics and pottery, show some char- acteristic reactions (dehydroxylation, decomposition, transformation) in the course of firing (heating effects) and several thermoanalytical criteria can be used for recon- struction of former production conditions.

地化学・貯留層シミュレーションによる二酸化炭素の地化学トラッピングの検討：東京湾岸モデル

Two dimensional numerical simulation was performed using reactive geochemical transport code TOUGHREACT based on the geology of the Tokyo Bay area to understand long-term geochemical evolution of aqueous and mineral phases after CO2 injection and to elucidate key issues affecting CO2 mineral trapping. The injected CO2 migrates upward in the reservoir (the Umegase Formation) towards the cap rock (the Kokumoto Formation) driven by buoyant force. In the CO2 plume, water pH drops from 7.8 (initial) to 4.9 by dissolution and dissociation of CO2. The acidified water containing CO2 and related species induces mineral dissolution and promotes complexing of dissolved ions, which increase the water density and cause its downward movement to the bottom of the reservoir. This process gives rise to convective mixing which further promotes CO2 solubility trapping. In the peripheral zone of the CO2 plume, the acidified water comes in contact with intact reservoir water, giving rise to the precipitation of calcite (and siderite, in lesser amount). The precipitation of calcite and other carbonates might form a low permeability barrier surrounding the CO2 plume, and is expected to increase the storage security with time. Among newly formed carbonates, calcite becomes the most dominant in a long period after injection cease. Dawsonite, which is occasionally considered to be important in trapping CO2, is found to have limited stability that requires high CO2 partial pressure at the conditions of saline aquifer storage. Our study also finds that the formation of dawsonite is in a close relation to the dissolution of plagioclase, and that its precipitation is strongly suppressed by the formation of kaolinite. After reviewing rates of dissolution of carbonates and feldspars, we conclude that the precipitation of dawsonite is controlled by plagioclase dissolution kinetics which determines the supply of Al as a major constituent of dawsonite. Plagioclase is a dominant clastic mineral in sandstones in geologically young formations of the Japanese Islands. Its dissolution could be a key issue in geochemical modeling of CO2 aquifer storage.

GRS evidence and the possibility of paleooceans on Mars

The Gamma Ray Spectrometer (Mars Odyssey spacecraft) has revealed elemental distributions of potassium (K), thorium (Th), and iron (Fe) on Mars that require fractionation of K (and possibly Th and Fe) consistent with aqueous activity. This includes weathering, evolution of soils, and transport, sorting, and deposition, as well as with the location of first-order geomorphological demarcations identified as possible paleoocean boundaries. The element abundances occur in patterns consistent with weathering in situ and possible presence of relict or exhumed paleosols, deposition of weathered materials (salts and clastic minerals), and weathering/transport under neutral to acidic brines. The abundances are explained by hydrogeology consistent with the possibly overlapping alternatives of paleooceans and/or heterogeneous rock compositions from diverse provenances (e.g., differing igneous compositions).

The Dhala structure, Bundelkhand craton, Central India—Eroded remnant of a large Paleoproterozoic impact structure

Abstract— The newly discovered Dhala structure, Madhya Pradesh State, India, is the eroded remnant of an impact structure with an estimated present‐day apparent diameter of about 11 km. It is located in the northwestern part of the Archean Bundelkhand craton. The pre‐impact country rocks are predominantly granitoids of ˜2.5 Ga age, with minor 2.0–2.15 Ga mafic intrusive rocks, and they are overlain by post‐impact sediments of the presumably >1.7 Ga Vindhyan Supergroup. Thus, the age for this impact event is currently bracketed by these two sequences. The Dhala structure is asymmetrically disposed with respect to a central elevated area (CEA) of Vindhyan sediments. The CEA is surrounded by two prominent morphological rings comprising pre‐Vindhyan arenaceous‐argillaceous and partially rudaceous metasediments and monomict granitoid breccia, respectively. There are also scattered outcrops of impact melt breccia exposed towards the inner edge of the monomict breccia zone, occurring over a nearly 6 km long trend and with a maximum outcrop width of ˜170 m. Many lithic and mineral clasts within the melt breccia exhibit diagnostic shock metamorphic features, including multiple sets of planar deformation features (PDFs) in quartz and feldspar, ballen‐textured quartz, occurrences of coesite, and feldspar with checkerboard texture. In addition, various thermal alteration textures have been found in clasts of initially superheated impact melt. The impact melt breccia also contains numerous fragments composed of partially devitrified impact melt that is mixed with unshocked as well as shock deformed quartz and feldspar clasts. The chemical compositions of the impact melt rock and the regionally occurring granitoids are similar. The Ir contents of various impact melt breccia samples are close to the detection limit (1–1.5 ppb) and do not provide evidence for the presence of a meteoritic component in the melt breccia. The presence of diagnostic shock features in mineral and lithic clasts in impact melt breccia confirm Dhala as an impact structure. At 11 km, Dhala is the largest impact structure currently known in the region between the Mediterranean and southeast Asia.

Geological setting of Earth's oldest fossils in the ca. 3.5 Ga Dresser Formation, Pilbara Craton, Western Australia

Detailed stratigraphic, petrographic, and zircon U–Pb geochronological data are provided for surface outcrops and newly obtained, unweathered drillcore intersections of Earth's oldest fossiliferous sedimentary rocks, the lowermost chert–barite unit of the ca. 3.5 Ga Dresser Formation, Warrawoona Group, Pilbara Craton. Results show that the ∼8 m thick unit at the drilling locality consists of thinly bedded, originally micritic carbonates deposited under quiet water conditions that are interbedded with volcaniclastic conglomerates and coarse polymict conglomerates (diamictites) deposited during periods of tectonic instability. The presence of rapid vertical and lateral facies changes, tilted bedding in some members, and internal erosional unconformities, combined with analysis of fault offsets, indicate that tectonically unstable periods were caused by growth faulting. Intense hydrothermal fluid flow accompanied episodes of growth faulting and resulted in pulsed, repeated precipitation of silica ± barite ± sphalerite that alternated with precipitation of pyrite. Clasts of hydrothermal minerals in sandstone and coarse, polymict conglomerate beds at several levels within the unit highlight the repeated nature of hydrothermal fluid circulation during sediment accumulation. Hydrothermal fluid circulation caused widespread acid–sulfate alteration of the footwall, extensive replacement of the newly deposited carbonate sediments by hydrothermal precipitates, and crystallization of hydrothermal chert–barite–pyrite in veins perpendicular to bedding in the footwall and parallel to bedding in the sedimentary unit. The combined evidence points to deposition of the chert–barite unit within an active volcanic caldera. A 10 cm thick bed of felsic volcaniclastic tuff within finely bedded carbonates near the top of the unit has yielded a maximum age of deposition of 3481.0 ± 3.6 Ma (2 σ uncertainty), confirming earlier Pb–Pb age data for the antiquity of these rocks. Putative signs of life are present as stratiform, columnar, domical, and coniform stromatolitic laminates at various levels throughout the unit. Petrographic observations show that red- and black-weathering stromatolitic laminates on the surface consist of pyrite in unweathered drillcore material. Observation of local relics of carbonate between pyrite crystals in these laminates indicates a carbonate protolith prior to replacement by hydrothermal pyrite, which provides support for a biological origin of stromatolitic laminates. Further support is provided by clasts of laminated carbonaceous material in thinly bedded, primary micritic carbonates. Textural analysis of jaspilitic “cherts” near the top of the unit reveal haematite as tiny crystals within recrystallized siderite/dolomite rhombs in carbonate beds affected by hydrothermal silica alteration. The presence of unaltered diagenetic pyrite crystals in the haematite-altered siderite indicates that alteration did not result from oxidizing fluids. Rather, haematite alteration is interpreted as the result of an increase in pH during diagenetic alteration by mildly reducing, silica-rich fluids associated with eruption of overlying basalts, possibly with the influence of microbial activity. This has important implications for the origin of jaspilitic cherts throughout the early Archean record and for atmospheric conditions of early Earth.

Mineralogy, petrology, and shock history of lunar meteorite Sayh al Uhaymir 300: A crystalline impact‐melt breccia

Abstract— Sayh al Uhaymir (SaU) 300 comprises a microcrystalline igneous matrix (grain size <10 μm), dominated by plagioclase, pyroxene, and olivine. Pyroxene geothermometry indicates that the matrix crystallized at ˜1100 °C. The matrix encloses mineral and lithic clasts that record the effects of variable levels of shock. Mineral clasts include plagioclase, low‐ and high‐Ca pyroxene, pigeonite, and olivine. Minor amounts of ilmenite, FeNi metal, chromite, and a silica phase are also present. A variety of lithic clast types are observed, including glassy impact melts, impact‐melt breccias, and metamorphosed impact melts. One clast of granulitic breccia was also noted. A lunar origin for SaU 300 is supported by the composition of the plagioclase (average An95), the high Cr content in olivine, the lack of hydrous phases, and the Fe/Mn ratio of mafic minerals. Both matrix and clasts have been locally overprinted by shock veins and melt pockets. SaU 300 has previously been described as an anorthositic regolith breccia with basaltic components and a granulitic matrix, but we here interpret it to be a polymict crystalline impact‐melt breccia with an olivine‐rich anorthositic norite bulk composition. The varying shock states of the mineral and lithic clasts suggest that they were shocked to between 5–28 GPa (shock stages S1–S2) by impact events in target rocks prior to their inclusion in the matrix. Formation of the igneous matrix requires a minimum shock pressure of 60 GPa (shock stage >S4). The association of maskelynite with melt pockets and shock veins indicates a subsequent, local 28–45 GPa (shock stage S2–S3) excursion, which was probably responsible for lofting the sample from the lunar surface. Subsequent fracturing is attributed to atmospheric entry and probable breakup of the parent meteor.

Drill core LB‐08A, Bosumtwi impact structure, Ghana: Petrographic and shock metamorphic studies of material from the central uplift

Abstract— During a recent drilling project sponsored by the International Continental Scientific Drilling Progam (ICDP), two boreholes (LB‐07A and LB‐08A) were drilled into the crater fill of the Bosumtwi impact structure and the underlying basement, into the deep crater moat and the outer flank of the central uplift, respectively. The Bosumtwi impact structure in Ghana (West Africa), which is 10.5 km in diameter and 1.07 Myr old, is largely filled by Lake Bosumtwi.Here we present the lithostratigraphy of drill core LB‐08A (recovered between 235.6 and 451.33 m depth below lake level) as well as the first mineralogical and petrographic observations of samples from this core. This drill core consists of approximately 25 m of polymict, clast‐supported lithic breccia intercalated with suevite, which overlies fractured/brecciated metasediment that displays a large variation in lithology and grain size. The lithologies present in the central uplift are metasediments composed dominantly of fine‐grained to gritty meta‐graywacke, phyllite, and slate, as well as suevite and polymict lithic impact breccia. The suevites, principally present between 235.6 and 240.5 m and between 257.6 and 262.2 m, display a fine‐grained fragmental matrix (about 39 to 45 vol%) and a variety of lithic and mineral clasts that include meta‐graywacke, phyllite, slate, quartzite, carbon‐rich organic shale, and calcite, as well as melt particles, fractured quartz, unshocked quartz, unshocked feldspar, quartz with planar deformation features (PDFs), diaplectic quartz glass, mica, epidote, sphene, and opaque minerals). The crater‐fill suevite contains calcite clasts but no granite clasts, in contrast to suevite from outside the northern crater rim.The presence of melt particles in suevite samples from the uppermost 25 meters of the core and in suevite dikelets in the basement is an indicator of shock pressures exceeding 45 GPa. Quartz grains present in suevite and polymict lithic impact breccia abundantly display 1 to (rarely) 4 sets of PDFs per grain. The shock pressures recorded by the PDFs in quartz grains in the polymict impact breccia range from 10 to ∼30 GPa. We also observed a decrease of the abundance of shocked quartz grains in the brecciated basement with increasing depth. Meta‐graywacke samples from the basement are heterogeneously shocked, with shock pressures locally ranging up to 25–30 GPa. Suevites from this borehole show a lower proportion of melt particles and diaplectic quartz glass than suevites from outside the northern crater rim (fallback impact breccia), as well as a lack of ballen quartz, which is present in the external breccias. Similar variations of melt‐particle abundance and shock‐metamorphic grade between impact‐breccia deposits within the crater and fallout impact breccia outside the crater have been observed at the Ries impact structure, Germany.

Heavy clastic minerals from the Far East island-arc complexes

The results of the study of heavy clastic minerals from the Cretaceous-Paleogene terrigenous complexes of Sikhote-Alin and Kamchatka, as well as from the Cenozoic sediments of the deepwater Vanuatu Trench, are summarized. The data obtained have been interpreted on the basis of their comparison with heavy mineral assemblages of recent sediments deposited in known geodynamic settings. It is shown that the heavy clastic minerals of sedimentary rocks, their relative quantities, and chemical compositions may serve as reliable indicators of different island-arc settings and magmatic processes; these indicators may also be used for identification of such settings in paleobasins of orogenic regions.

Electron Spin Resonance (ESR) Dating in Karst Environments

Electron spin resonance (ESR) dating has been developed for many materials, including hydroxyapatite in enamel, bone, and some fish scales, aragonite and calcite in travertine, molluscs, and calcrete, and quartz from ash, which have many potential applications in karst settings. Although the complexity of the signals in some materials has hampered routine application, research is solving these problems to make the method even more widely applicable. When tested against other dating tech­niques, age agreement has usually been excellent. Generally, the most reliable applications seem to be tooth enamel, some mol­lusc species, calcite deposits, and quartz minerals. ESR dating uses signals resulting from trapped charges created by radia­tion in crystalline solids. Ages are calculated by comparing the accumulated dose in the dating sample with the internal and external radiation dose rates produced by natural radiation in and around the sample. For fossils and authigenic minerals, no zeroing is necessary to obtain accurate ages. In sediment which contains reworked mineral clasts, ESR can be used to date the age of the mineral grain itself if it was not zeroed during ero­sion. For dating the sedimentation age, however, ESR signals must have been zeroed in order to give the correct age. High pressure, heating, and in some minerals, light exposure and grinding can zero an ESR signal, but some like hydroxyapatite have very high stability at surface temperatures. For materi­als that absorb uranium (U) during their burial history, such as teeth, bones, or mollusc shells, the age calculation considers their U uptake by cross calibrating with U series or U/Pb dat­ing or by assuming different uptake models. Some difficulties in calculating the external dose rate can be overcome by ap­plying the ESR isochron method, in which the sample acts as its own dosimeter. In open-air karst environments, changes in the external dose rate due to altered sediment cover, and hence, changing cosmic dose rates, need to be modelled. For all karst environments, sedimentary water concentration and mineralogical variations with time also need to be considered. Many ESR applications are currently used in karst settings, but several more are also possible.

Heavy clastic minerals as a criterion for the identification of island-arc environments in paleobasins of orogenic zones in the Russian Far East

Heavy clastic minerals as a criterion for the identification of island-arc environments in paleobasins of orogenic zones in the Russian Far East

Clastic heavy mineral assemblages in Permian-Mesozoic accretionary cherty and siliceous-clayey complexes of Sikhote Alin

The paper presents results of the study of assemblages of clastic heavy minerals and geochemical features of some assemblages in several Permian-Mesozoic cherty and siliceous-clayey sequences of Sikhote Alin. They are composed of pelagic and hemipelagic sediments of the Panthalassa (Paleopacific) Ocean. Four typical mineral assemblages and their environments are established. In one of the ocean segments, where sedimentary cover formed during the Late Paleozoic-Early Cretaceous, the Permian pelagic domain was characterized by the amphibole-pyroxene assemblage with heavy minerals derived from ophiolites. The Triassic-Jurassic stage was marked by development of the clinopyroxene assemblage with heavy minerals derived from intraplate alkaline volcanic complexes. Middle-Late Jurassic hemipelagic sediments host the zircon-clinopyroxene assemblage with a greater role of continental environments and the presence of volcanic products of the convergence zone. Another segment of the ocean accumulated red cherts and siliceous-clayey sediments during the Jurassic-Early Cretaceous under the influence of island-arc volcanism.

Characteristics of claystones across the terrestrial Permian-Triassic boundary: Evidence from the Chahe section, western Guizhou, South China

X-ray diffraction (XRD), scanning electronic microscopy (SEM) and X-ray fluorescence spectroscopy (XFS) studies were undertaken for claystones and/or mudstones from the Chahe section—a terrestrial Permian-Triassic boundary (TPTB) section. Our results indicate that the compositions of claystones in the Permian-Triassic boundary (PTB) interval (Beds 66f–68) outlined by biostratigraphy are different from claystones and/or mudstones found either below or above the interval of the same section. The clay minerals in the claystones of the PTB interval are mainly composed of illite–montmorillonite interlayers, with a few montmorillonites and chlorites. The other claystones and/or mudstones underlying and overlying the PTB consist of chlorites and/or kaolinites. Some authigenic clastic minerals, such as hexagonal dipyramid quartz and zircons, are only found in claystones in the PTB interval from the Chahe section and some marine PTB sections in western Guizhou and eastern Yunnan, southwestern China. In addition, some elements are present in abnormal concentrations in the claystones of the PTB interval as well. Most important is that we found no spherules in all the claystones studied, indicating no evidence of an extraterrestrial impact during the Permian-Triassic transition. The particular characteristics of the TPTB claystones at the Chahe section indicate their volcanic origin and thus provide a reliable auxiliary event marker for high-resolution demarcation of the TPTB in South China. They are also indicative in the marine PTB claystones in South China. Thus, the PTB claystones can be used as auxiliary markers for high-resolution correlation of the PTB from marine facies to land in South China when direct fossil evidence in the PTB sequence is lacking.

Speciation of some heavy metals in bottom sediments of the Ob and Yenisei estuarine zones

The speciation of Fe, Mn, Zn, Cu, Co, Ni, Cr, Pb, and Cd was studied in 52 samples of bottom sediments collected during Cruise 49 of the R/V Dmitrii Mendeleev in estuaries of the Ob and Yenisei rivers in the southwestern Kara Sea. Immediately after sampling, the samples were subjected to on-board consecutive extraction to separate metal species according to their modes of occurrence in the sediments: (1) adsorbed, (2) amorphous Fe-Mn hydroxides and related metals, (3) organic + sulfide, and (4) residual, or lithogenic. The atomic absorption spectroscopy of the extracts was carried out at a stationary laboratory. The distribution of Fe, Zn, Cu, Co, Ni, Cr, Pb, and Cd species is characterized by the predominance of lithogenic or geochemically inert modes (70–95% of the bulk content), in which the metals are bound in terrigenous and clastic mineral particles and organic detritus. About half of the total Mn amount and 15–30% Zn and Cu is contained in geochemically mobile modes. The spatiotemporal variations in the proportions of metal species in the surface layer of sediments along the nearly meridional sections and through the vertical sections of bottom sediments cores testify that Mn and, to a lesser extent, Cu are the most sensitive to changes in the sedimentation environment. The role of their geochemically mobile species notably increases under reducing conditions.

Erroneous coal maturity assessment caused by low temperature oxidation: Copard, Y. et al. International Journal of Coal Geology, 2004, 58, (3), 171–180

Benched channel samples and continuous block samples of the Hub and Harbour seams from the Sydney Basin, Nova Scotia were studied to define the variations in petrography, geochemistry and palynology of the seams and to interpret the depositional environments of the precursor mires.Petrographic compositions of the seams are very similar with high vitrinite content, low inertinite, moderate liptinite and negligible clastic mineral content. Pyrite content is moderate. There is little variation in petrographic composition between benches in either seam. There are marked variations in petrographic compositions at the lithotype scale. Petrographic facies parameters indicate deposition of the bulk of both seams under fairly uniform conditions in relatively wet mires. Unusually wet or dry periods were rare.The palynological assemblages of both seams indicate a middle to late Westphalian D age. The common to abundant palynomorphs are derived from “arborescent” and “herbaceous” lycopsids, tree ferns and other ferns(?), and sphenopsids. The palynological assemblages support the petrographic interpretation of relatively wet mires. Cordaites pollen (Florinites) is rare, suggesting that there was little contribution from plants growing in dry or upland areas. The absence of the Densospore miospore phase, and the petrographic data, indicate there were no periods in which domed mires occurred.The distinctive dull bands occurring in the Hub and Harbour seams are characterised by low vitrinite contents, high inertinite content, high liptinite and common detrital minerals. Sporinite, showing varying degrees of degradation, is commonly highly concentrated in thin bands. The geochemistry is marked by much higher hi values than normally reported for coals but other indices are typical for coals of this rank. The palynological assemblages of the dull bands are dominated by tree fern spores and other ferns(?) with only a minor contribution by sphenopsid spores. The dull bands were deposited during periods of inundation of mires. Relatively low mineral content indicates that the distributary channels which flooded the mires were quite distant from the depositional sites of the samples.

Fission Track Dating of Authigenic Quartz in Red Weathering Crusts of Carbonate Rocks in Guizhou Province

Abstract The Cenozoic evolution history of Guizhou Province, which is located on the southeastern flank of the Qinghai‐Tibet Plateau, is unclear because of the lack of sedimentation records. The red weathering crusts widespread on the Yunnan‐Guizhou Plateau may bear critical information about their evolution history. This work firstly determined the ages of four red weathering crusts in eastern, central and northern Guizhou. The material used in fission track dating is well‐crystallized quartz occurring in many in‐situ weathering crusts of carbonate rocks. The results showed that the fission track ages of quartz vary over a wide range from 1 to 25 Ma in the four profiles, significantly younger than the ages of the Triassic and Cambrian parent rocks. In combination with the evolution history of the regional geology during the period from 25 to 1 Ma, the ages of quartz can exclude the possibility that the origin of quartz has nothing to do with primary clastic minerals in parent rocks, authigenesis during diagenesis and hydrothermal precipitation or replacement by volcanic activities. It is deduced that the well‐crystallized quartz was precipitated from Si‐rich weathering fluids during the weathering process of carbonate rocks. The recorded ages of quartz from the four profiles are consistent with the episodes of the planauon surfaces on the Qinghai‐Tibet Plateau, the forming stages of red soil in the tropics of South China, the tectonically stable periods in Guizhou, and the ages of weathering in other parts of the world during the Cenozoic era. That is to say, the ages of authigenic quartz dated by the fission track method are well feasible and credible.

40Ar– 39Ar dating of pseudotachylytes: the effect of clast-hosted extraneous argon in Cenozoic fault-generated friction melts from the West Antarctic Rift System

Fault-generated pseudotachylytes are the product of frictional melting during high-velocity slip associated with coseismic faulting. 40Ar– 39Ar dating of pseudotachylytes represents a powerful tool to directly determine the age of brittle faulting which is otherwise dated only indirectly. However, the pronounced spatial heterogeneity of most endogenically generated pseudotachylytes, due to the intimate coexistence of unmelted mineral clasts from the source rock, frictional glass and neogenic igneous minerals, often precludes a straightforward interpretation of argon data. This requires careful evaluation of the role of clasts in plaguing the age record of the pseudotachylyte matrix. This study exploits the full potential of the 40Ar– 39Ar method, using laser step-heating and laser in situ techniques in conjunction with textural and chemical characterisation at the microscale to disentangle the complexity of the first record of pseudotachylytes generated in the right-lateral fault systems which dissect the western shoulder of the West Antarctic Rift System. Pseudotachylytes occur as fault and injection veins. They exhibit glassy matrices with a potassium feldspar-like composition, and invariably contain, at a millimeter to microscopic scale, unmelted quartz and subordinate feldspars from the source rock. Injection veins characteristically contain much fewer mineral clasts. In situ ultraviolet (UV) laser analyses indicate that quartz from the host rock and from clasts within the fault veins contains significant amounts (∼10–50 ppb) of parentless 40Ar, most probably hosted in microscopic to submicroscopic fluid inclusions, associated with high Cl/K ratios. Infrared laser step-heating experiments on fault vein pseudotachylyte matrices yield strongly discordant age spectra with an overall saddle shape characterised by a minimum at ∼34 Ma, unrealistically old ages at high temperatures associated with high Cl/K ratios and total gas ages of 41.5–44.3 Ma. Petrographic data and the pronounced compositional similarity between in situ UV laser data on quartz and the high-temperature end member of step-heating analyses suggest that quartz is the main contaminant of the pseudotachylyte age record. In situ laserprobe analyses on pseudotachylyte matrices give concordant ages at ∼34 Ma for an injection vein and systematically older ages, clustering at ∼40–48 Ma, for fault veins. Although the age cluster fits into the Cenozoic tectonic framework of the region, it is an artefact due to the low spatial resolution of the argon laserprobe compared to the size and spatial distribution of quartz clasts within the pseudotachylyte. The isochron age of 34.11±0.96 Ma, derived from in situ data from the injection vein, overlaps with the emplacement age of syn-tectonic dykes from nearby areas and is interpreted to date a single episode of coseismic faulting. Regionally, the age of the studied pseudotachylytes represents the first direct onshore evidence of right-lateral strike–slip fault system activity in Victoria Land during the Cenozoic.

Dating the earliest lowland glaciation of eastern England: a pre-MIS 12 early Middle Pleistocene Happisburgh glaciation

This paper outlines the evidence for the Happisburgh Glaciation—the first Middle Pleistocene glaciation of lowland eastern England and the adjacent margins of the North Sea Basin. We propose that this glaciation occurred during a pre-Elsterian/Anglian (MIS 12) cold stage based on evidence of clasts of till, erratics and heavy minerals from the third youngest terrace of the ‘pre-glacial’ Bytham River in southern Norfolk. The heavy minerals show a progressive increase in glacially sourced materials from the bottom to the top of the Bytham River third terrace sediments. The till clasts are correlated with the extensive deposits of the Happisburgh Formation on the basis of their colour, heavy minerals and particle size properties. Thus, the Happisburgh Glaciation occurred during the accumulation of the Bytham River terrace deposits and prior to MIS 12, when the Bytham River system was destroyed by the Anglian glaciation. In the absence of any geochronology or robust biostratigraphy, the age of the Happisburgh Glaciation is estimated by the synchronisation of the pattern of large-scale river activity with patterns of Milankovitch-forced global climate change. On this basis, and assuming the British Ice Sheet acted in phase with global patterns of ice volume, the Happisburgh Glaciation is considered to have occurred during MIS 16 and be equivalent of the Don Glaciation of eastern Europe.

Nature and origin of arsenic carriers in shallow aquifer sediments of Bengal Delta, India

Sediments from shallow aquifers in Bengal Delta, India have been found to contain arsenic. Rivers of Ganga-Brahmaputra system, responsible for depositing these sediments in the delta, have created a store of arsenic. Geomorphological domains with different depositional styles regulate the pattern of distribution of zones with widely different content of groundwater arsenic. The high arsenic zones occur as narrow sinuous strips confined to channel deposits. A few iron-bearing clastic minerals and two post-depositional secondary products are arsenic carriers. Secondary siderite concretions have grown on the surface of the clastic carriers in variable intensity. The quantity of arsenic in all clastic carriers is in excess of what is generally expected. Excess arsenic is contributed by the element adsorbed on the concretion grown on the surface of the carriers, which adds up to the arsenic in the structure of the minerals. Variable abundance of concretions is responsible for the variable quantity of arsenic in the carriers and the sediment samples. Fe2+ for the growth of siderite concretions is obtained from the iron-bearing clastic carriers. The reaction involves reduction of trivalent iron to bivalent and the required electron is obtained by transformation of As3+ to As5+. It is suggested that oxidation of As3+ to As5+ is microbially mediated. In the Safe zone arsenic is retained in the carriers and groundwater arsenic is maintained below 0.05 mg/l. In the Unsafe zone sorbed arsenic is released from the carriers in the water through desorption and dissolution of concretion, thereby elevating the groundwater arsenic level to above 0.05 mg/l.

Origin of the Red Dog Zn-Pb-Ag Deposits, Brooks Range, Alaska: Evidence from Regional Pb and Sr Isotope Sources

Origin of the Red Dog Zn-Pb-Ag Deposits, Brooks Range, Alaska: Evidence from Regional Pb and Sr Isotope Sources

Petrogenesis of lunar meteorite EET 96008

Lunar meteorite EET 96008 is a fragmental breccia that predominantly consists of basaltic mineral clasts (0.5–2 mm), along with minor lithic fragments and breccia clasts. The matrix consists mainly of smaller mineral fragments (<0.5 mm), bound by glassy cement, the majority of which are pyroxene and plagioclase. The pyroxene possesses extensive exsolution lamellae. These lamellae, up to 1 μm in width, are atypical for mare-basalts. One of the distinguishing textures of EET 96008 is the presence of small pockets (∼400 × 500 μm) of mesostasis areas consisting of coarse (∼20 μm) intergrowths of ferroaugite, fayalite and Si-rich glass. Laths of ilmenite, armalcolite, apatite and whitlockite are also distributed in these areas. Ilmenite grains are abundant and dispersed throughout the thin sections. Chromite and ulvöspinel are present but in minor abundance. Troilite, generally rare in this rock, occurs as several grains in one pyroxene crystal. FeNi metal is conspicuously absent from this meteorite. The molar Fe/Mn ratio in olivines and pyroxenes and the age of the meteorite are evidence for a lunar origin. The mineralogy of EET 96008 shows close affinity to a mare-basalt source, albeit with possible minor highland/non-mare components. The bulk-rock, major-, trace- and rare-earth-element (REE) contents are similar to that of very low-titanium (VLT) basalts, which have experienced extreme fractional crystallization to the point of silicate liquid immiscibility. Mineralogical and textural features of this sample suggest that at least some of the breccia components were derived from a slow-cooled magma. The mineralogy and petrology of EET 96008 is strikingly similar to the lunar meteorite EET 87521, and we support the conclusion that EET 96008 and EET 87521 should be paired. Isochron ages of 3530 ± 270 Ma for apatite and 3519 ± 100 Ma for whitlockite of this rock are consistent with derivation from a mare-basalt precursor. These ages are within error of the low-Ti basalts, dated from the Apollo 12 and 15 sites. The whole-rock, platinum-group-element (PGE) contents of EET 96008 overlap with pristine low-Ti mare basalts, suggesting the presence of only a minimal extraterrestrial component.