Fine solid wastes such as coal fly ash (CFA), diatomite, and red mud have been widely applied as alternative fillers for porous asphalt pavement (PAP), and have varying impacts on the mechanical performance of materials. However, whether they will affect the runoff purification performance of PAP has not been studied yet. Based on the laboratory simulation rainfall test, this study investigated the purification performance of porous asphalt mixture (PA) with three fine solid wastes fillers. Combined with the analysis of multi-scale pore characteristics of PA, the purification mechanism was further discussed. The results show that pollutants are mainly removed within 3 cm on the surface of PA in 20–30min rainfall. Diatomite and red mud fillers can effectively increase the removal rates of some heavy metals and nutrients by 20–40%. On the one hand, diatomite and red mud can leach some ions, which are conducive to physical adsorption and chemical degradation (including chemical precipitation and ion change) of pollutants. On the other hand, they also contain abundant porous structures and large specific surface areas, which significantly improve the micro-surface physical properties of PA and enhance the interaction between PA and pollutants.
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