The increasingly serious urban heat island (UHI) effect is unfavorable to urban development. This study utilized land cover data and land surface temperature (LST) data of China in 2020 by using correlation analysis and spatial regression models to analyze the relationships between LST and two influencing factors (land cover and digital elevation model (DEM)). The results showed the following: (1) The correlation between LST and forest was highest in the Northeast China Plain (NCP), Huang-Huai-Hai Plain (HHP), Qinghai Tibet Plateau (QTP), and Loess Plateau (LP). DEM mean displayed its highest correlation in the Northern arid and semiarid region (NAR), Sichuan Basin and surrounding regions (SCR), Yunnan-Guizhou Plateau (YGP), and Middle-lower Yangtze Plain (MYP). Southern China (SC) had the highest correlation between LST and construction land. (2) There was spatial heterogeneity between land cover and LST. Unused land on LP had larger impact on LST. For every 1% increase in the proportion of unused land area, the LST increased by 0.250 °C. LST in some central and western regions of China (the NAR, the LP, the SCR, and the YGP) was mainly affected by local land cover; LST in eastern coastal regions (the HHP, MYP, NCP, SC) and QTP was not only affected by local land cover, but also by LST or land cover of neighboring regions. The warming effect of construction land on LST was more significant, with LST increasing by 0.079 °C to 0.338 °C for every 1% increase in the proportion of construction land area. Coordination of land use planning and synergistic remediation in different regions and rational planning of construction land are essential to mitigate the UHI effect. (3) Water bodies in the NCP, NAR, and MYP had the greatest cooling impact on LST, with LST decreasing by 0.277 °C, 0.246 °C, and 0.079 °C, respectively, for every 1% increase in the proportion of water bodies area. Forest on the QTP, LP, SC, and YGP had the greatest cooling impact on LST, and for every 1% increase in the proportion of forest area, LST decreased by 0.144 °C, 0.089 °C, 0.086 °C, and 0.038 °C, respectively. Actively planting trees and increasing the area of forests and water bodies are of positive significance in alleviating the UHI effect and improving the ecological environment.
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