mid-IR Range Research Articles

Ultrabroadband Optical Properties of 2D Titanium Carbide MXene.

MXenes have rapidly ascended as a prominent class of two-dimensional (2D) materials, renowned for their distinctive optical and electrical properties. Despite extensive exploration of MXenes' optical properties, existing studies predominantly focus on the near-infrared (NIR) to the ultraviolet spectral range, leaving the mid-infrared (mid-IR) range relatively uncharted. In this study, we conducted a comprehensive characterization of the intrinsic optical properties of Ti3C2Tx MXene across an ultrabroadband spectral range, spanning from mid-IR (28 meV) to vacuum ultraviolet (VUV, 6.4 eV). For this purpose, Ti3C2Tx MXene films of varying thicknesses were coated on quartz substrates, resulting in two distinct categories: thin film samples with thicknesses below 50 nm and bulk-like samples with thicknesses exceeding 500 nm. Using spectroscopic ellipsometry, we analyzed the optical properties of films of various thicknesses and extracted detailed information on their dielectric functions. Our findings reveal resonances in the mid-IR to VUV range. Employing the Lorentz-Drude model to examine these resonances has uncovered the optical resistivity of MXene films and led to the identification of multiple plasmonic modes active in the visible to NIR range, as well as broad band-to-band transition-like resonances in the mid-IR range. This ultrabroadband optical versatility of Ti3C2Tx MXene is anticipated to bring about a wide range of thermal and optical applications.

High responsivity zero-biased Mid-IR graphene photodetector based on chalcogenide glass waveguide

Graphene’s unique properties have made it a promising material for high-performance photodetectors due to its interesting features including broadband absorption, fast speed, and strong photothermoelectric effect. Here, an optimized waveguide photodetector incorporating double graphene layers with two cores is presented to boost the responsivity (∼twice), at Mid-IR range. The proposed structure operates in the zero-bias regime to eliminate the dark current issue associated with the zero bandgap nature of graphene and leads to lower noise equivalent power. The presented photodetector operating based on split gates to electrostatically induce the p-n junction in graphene channels, operates based on the photothermoelectric effect and provides responsivity, NEP, and 3 dB bandwidth of 6.3 V/W, 0.34 nW/Hz1/2, and 1.54 GHz, respectively for the detection at λ = 5.2 μm. The feasibility of the proposed structure is proved according to recent experimentally demonstrated photodetectors. Hence, the obtained results are reliable, in practice. The study has been accomplished by numerical simulation of mode profiles and solving the heat equation to extract the characteristics of the proposed photodetector. The zero-power consumption and tunability of the proposed structure make it a promising candidate for sensing, industrial, defense, and environmental monitoring applications with high accuracy.

The process of evaporation of a colloidal solution of stabilized Boron nitride nanoparticles

Purpose. Characterization of the chemical structure of boron nitride nanoparticles by IR spectroscopy during the evaporation of their colloidal system and their sizes by small-angle X-ray scattering.Methods. The solvent evaporation process from the colloidal system was studied using a Nicolet iS 50 FT-IR spectrometer in the mid-IR range (400 – 4000 cm-1), with an attenuated total reflectance accessory with a diamond crystal (incident angle of 45°) and a liquid cell (200 μL). The sizes of the colloidal particles were determined using an smallangle X-ray scattering diffractometer in linear collimation mode (resolution 0.03 nm-1, copper anode X-ray tube 2.2 kW, λ = 0.154 nm, exposure time 30 s).Results. The IR spectrum of boron nitride nanoparticles powder was measured, containing lines characteristic of cubic (952 cm-1) ) – c-BN and hexagonal crystalline phases (758, 1301, and 1372 cm-1) – h-BN. The average size of boron nitride nanoparticles in the colloidal system, according to small-angle X-ray scattering data, was 46 and 84 nm. The size of stearic acid, which acts as a stabilizing shell, was 0.8, 1.3, and 2.5 nm. Analysis of the IR spectra showed complete evaporation of the solvents (hexane and chloroform) from a drop of colloidal solution 1.2 mm thick within 30 minutes.Conclusion. In this work, the average sizes of boron nitride nanoparticles stabilized with stearic acid in a colloidal system were determined and the process of its evaporation was studied.

Multifunctional plasmonic metamaterial absorber in the middle infrared range for polarization detection

It is significant to enhance the absorption rate, extend bandwidth and obtain the polarization information of electromagnetic radiation for detection technology. Here, we design and propose the simulation model of broadband and highly polarization-sensitive mid-IR metamaterial absorber by regulating the light field with the plasmonic response. The absorber is based on a simple subwavelength metal grating construction. Its absorption response can cover the 3–5 μm infrared atmospheric window. Detection technology in the mid-IR range has a strong ability to detect objects at high temperatures. In this waveband, the maximum absorption rate can reach more than 98% for TM polarization radiation. In comparison, it is less than 2% for TE polarization radiation, and the extinction ratio of 50 is concurrently achieved. The absorption spectrum can be broadened to the high and low-frequency direction by reasonably adding nanostrips in the unit cell. We also investigate the relationship between incident angle and spectral absorption and clarify the absorption stability of the absorber under oblique incidence. By integrating with the infrared focal plane detector, the device can make the infrared photodetector integrate and develop from a single sensor to multi-dimensional information and promote the development of polarization detector to miniaturization, high efficiency and high integration.

Optimizing transparent electrodes: Interplay of high purity SWCNTs network and a polymer

The discovery of transparent electrodes led to the development of optoelectronic devices such as touchscreens, infrared (IR) sensors, etc. Carbon nanotubes (CNTs) have been a potential replacement for ITO due to their exceptional properties, especially in the IR region. In this work, we present the development of a CNT-polymer composite thin film that exhibits outstanding transparency across visible and IR spectra prepared by layer-by-layer (LbL) technique. This approach ensures uniform integration and crosslinking of CNTs into lightweight matrices, and also represents a cost-effective method for producing transparent electrodes with remarkable properties. The produced films achieved a transparency above 80 % in the UV/VIS range and approximately 70 % in the mid-IR range. The sheet resistance of the fabricated thin films was measured at about 4 kΩ/sq, showing a tendency to decrease with the number of bilayers. In this work we have investigated electrical properties and transport mechanisms in more detail with computational analysis. Computational analysis was performed to better understand the electrical behavior of nanotube-polymer junctions in the interbundle structure. Based on all results, we propose that the transparent electrodes with 4 and 6 bilayers are the most optimal structures in terms of optical and electrical properties.

Binding Energies and Vibrational Spectral Features of S n Species on Amorphous Water-ice Mantles: A Quantum Mechanical Study

In the denser and colder regions of the interstellar medium (ISM), gas-phase sulfur is depleted by 2 or 3 orders of magnitude with respect to its cosmic abundance. Thus, which species are the main carriers of sulfur is an open question. Recent studies have proposed S n species as potential sulfur reservoirs. Among the various sulfur allotropes, the most stable one is the S8 ring, detected in the asteroid Ryugu and Orgueil meteorite. Shorter species, namely S3 and S4, have been found in the comet 67P/C-G, but their presence in the ISM remains elusive. In this study, we compute the binding energies (BEs) of S n (n = 1–8) species on an amorphous water-ice surface model and analyze their infrared (IR) and Raman spectral features to provide data for their identification in the ISM. Our computations reveal that these species exhibit lower BEs than previously assumed and that their spectral features experience minimal shifts when adsorbed on water ice, because of the weak and nonspecific S n –ice interactions. Furthermore, these species display very low IR band intensities and, therefore, very accurate instruments operating in the mid-IR range are required for detecting the presence of these species in dense interstellar environments.

Ultraviolet photon upconversion in Er–SiAlON under 1550 nm excitation

SiAlON ceramics are well known for their exceptional mechanical, thermal, and chemical stability, making them ideal for demanding industrial applications such as cutting tools, equipment for molten metal handling, extrusion molds, gas turbine engines, etc. Despite these applications, the potential for photonic applications such as photon upconversion (UC) in SiAlON ceramics remains less explored. This report demonstrates broad spectral photon UC properties in Er-doped SiAlON (Er–SiAlON) ceramics, covering the ultraviolet (UV) to near-infrared (NIR) range upon 1550 nm excitation. The Er–SiAlON ceramic was synthesized by hot press sintering. X-ray diffraction (XRD), transmission electron microscopy (TEM) and elemental mapping results confirmed the stabilization of the α-SiAlON phase by Er3+ ions. Optical spectra showed distinct transitions of Er³⁺ ions and high transparency of over 70 % in the mid-IR range for the sample thickness of 0.49 mm. Under 1550 nm excitation, UC emission spectra revealed UV, violet, blue, green, red, and NIR emissions. The Er³⁺ ions exhibited self-sensitization, acting both as sensitizers and activators for the UC luminescence. Decay curve analysis showed long excited state lifetimes, with ground state absorption (GSA), excited state absorption (ESA), and energy transfer UC (ETU) processes facilitating multi-photon absorption and diverse spectral emissions. Given the inherent mechanical properties of SiAlON ceramics, these findings highlight the potential of Er–SiAlON ceramics for advanced UC photonic devices operating in high-temperature and harsh environments.

Generation and registration of high harmonics at surface plasma in coherent wake emission and relativistic oscillating mirror modes by high-power laser pulses

A universal technique is developed for the detection of high harmonics generated by relativistic and subrelativistic laser pulses irradiating a solid target. The characteristic features typical of two different generation methods are analyzed: parametric generation in the mid-IR range and amplification of chirped pulses in the near-IR range. Experimental spectra of harmonics in the range up to 35 nm were recorded. They can be used as a source of coherent radiation in the extreme UV region.

A proposal for a fast infrared bursts detector

The gravitational wave GW170817 from a binary neutron star merger and the simultaneous electromagnetic detection of the GRB170717A by Fermi Gamma-Ray Space Telescope, opened a new era in the multi-messenger astronomy. Furthermore, the GRBs (Gamma-Ray Bursts) and the mysterious FRBs (Fast Radio Bursts) have sparked interest in the development of new detectors and telescopes dedicated to the time-domain astronomy across the electromagnetic spectrum. Time-domain astronomy aims to acquire fast astronomical bursts in temporal range between a few seconds down to 1 ns. Fast InfraRed Bursts (FIRB's) have been relatively understudied, often due to the lack of appropriate tools for observation and analysis. In this scientific scenario, the present contribution proposes a new detection system for ground-based reflecting telescopes working in the mid-infrared (mid-IR) range to search for astronomical FIRB's. Experience developed in the diagnostics for lepton circular accelerators can be used to design temporal devices for astronomy. Longitudinal diagnostic instruments acquire bunch-by-bunch particle shifts in the direction of flight, that is equivalent to temporal. Transverse device integrates the beam signal in the horizontal and vertical coordinates, as standard telescopes. The proposed instrument aims to work in temporal mode. Feasibility study tests have been carried out at SINBAD, the infrared beam line of DAFNE, the e+e- collider of INFN. SINBAD releases pulsed infrared synchrotron light with 2.7 ns separation. The front-end detector system has been evaluated to detect temporal fast infrared signals with 2–12 μm wavelengths and 1 ns rise times. The present contribute aims to be a step toward a feasibility study report.

Frequency Conversion of Femtosecond Ti:Sapphire Laser Pulse to the Long-Wave Mid-IR Range with BaGa2GeSe6 Crystal

Generation of ultrashort mid-IR pulses spanning from 8.5 to 10.5 μm with high energy (up to 4.5 μJ) was experimentally demonstrated through difference frequency generation in BaGa2GeSe6 crystal pumped by 100-fs 0.95-μm Ti:sapphire laser pulses. Optical damage threshold and two-photon absorption coefficient were determined for this pump pulses. Frequency conversion efficiency reached 0.24% at 1.85 mJ pump pulse energy and was decreased at higher one. Estimations indicate that application of 15 mm in diameter wide-aperture BaGa2GeSe6 sample will allow one to increase pump pulse energy up to ~10 mJ, and to increase the mid-IR pulse energy up to 24 μJ at the same efficiency.

Active Galactic Nucleus Properties of ∼1 Million Member Galaxies of Galaxy Groups and Clusters at z < 1.4 Based on the Subaru Hyper Suprime-Cam Survey

Herein, we present the statistical properties of active galactic nuclei (AGNs) for approximately 1 million member galaxies of galaxy groups and clusters with 0.1 < cluster redshift (z cl) < 1.4 selected using the Subaru Hyper Suprime-Cam, the so-called CAMIRA clusters. In this research, we focused on the AGN power fraction (f AGN), which is defined as the proportion of the contribution of AGNs to the total infrared (IR) luminosity, L IR (AGN)/L IR, and examined how f AGN depends on (i) z cl and (ii) the distance from the cluster center. We compiled multiwavelength data using the ultraviolet–mid-IR range. Moreover, we performed spectral energy distribution fits to determine f AGN using the CIGALE code with the SKIRTOR AGN model. We found that (i) the value of f AGN in the CAMIRA clusters is positively correlated with z cl, with the correlation slope being steeper than that for field galaxies, and (ii) f AGN exhibits a high value at the cluster outskirts. These results indicate that the emergence of the AGN population depends on the redshift and environment and that galaxy groups and clusters at high redshifts are important in AGN evolution. Additionally, we demonstrated that cluster–cluster mergers may enhance AGN activity at the outskirts of particularly massive galaxy clusters. Our findings are consistent with a related study on the CAMIRA clusters that was based on the AGN number fraction.

Advances in the development of few-cycle gigawatt-peak-power mid-IR optical parametric amplifiers pumped by Cr:Forsterite laser using non-oxide nonlinear crystals

We demonstrate an experimental and theoretical comparison of non-oxide LiGaS2, HgGa2S4, and AgGaS2 crystals performance for wavelength conversion into the near and mid-IR range 1.5–8 μm in optical parametric amplifier pumped by Cr:Forsterite laser, delivering 100 fs pulses at 1.24 μm. It is shown that exceptionally high total energy conversion efficiency into the idler (4–5 μm) and signal (1.65–1.8 μm) waves up to 18% can be achieved using the HGS crystal, providing high nonlinearity, while the LGS crystal is more preferable for generating few-cycle mid-IR pulses due its unique dispersive properties. Our source features high peak power in gigawatt regime (0.4–2.4 GW) with pulse duration below 80 fs and optical synchronization with high harmonic generation (HHG) and THz beamlines, which is ideal for pump-probe experiments of nonlinear and strong-field physics.

AFM-IR nanospectroscopy of nanoglobule-like particles in Ryugu samples returned by the Hayabusa2 mission

Context. The JAXA Hayabusa2 mission returned well-preserved samples collected from the carbonaceous asteroid Ryugu, providing unique non-terrestrially weathered samples from a known parent body. Aims. This work aims to provide a better understanding of the formation and evolution of primitive asteroidal matter by studying the fine scale association of organic matter and minerals in Ryugu samples. We characterized the samples by IR nanospectroscopy using infrared photothermal nanospectroscopy (AFM-IR) technique. This technique overcomes the diffraction limit (of several microns) of conventional infrared microspectroscopy (µ-FTIR). The samples were mapped in the mid-IR range at a lateral spatial resolution about a hundred times better than with µ-FTIR. This provided us with unique in situ access to the distribution of the different infrared signatures of organic components at the sub-micron scale present in the Ryugu whole-rock samples as well as to the characterization of the compositional variability of Ryugu in the insoluble organic matter (IOM) chemically extracted from the Ryugu samples. Methods. The AFM-IR maps of whole-rock particles and IOM residues from Ryugu samples were recorded with a lateral resolution of tens of nanometers. Spectra were recorded in the 1900–900 cm−1 spectral range by AFM-IR (Icon-IR) for all samples, and additional spectra were recorded from 2700 to 4000 cm−1 for one IOM sample by an optical photothermal IR (O-PTIR) technique using a mIRage® IR microscope. Results. Organic matter is present in two forms in the whole-rock samples: as a diffuse phase intermixed with the phyllosilicate matrix and as individual organic nanoparticles. We identify the Ryugu organic nanoparticles as nanoglobule-like inclusions texturally resembling nanoglobules present in primitive meteorites. Using AFM-IR, we record for the first time the infrared spectra of Ryugu organic nanoparticles that clearly show enhanced carbonyl (C=O) and CH contributions with respect to the diffuse organic matter in Ryugu whole-rock and IOM residue.

GaAs Mid-IR Electrically Tunable Metasurfaces.

In this work, we explore III-V based metal-semiconductor-metal structures for tunable metasurfaces. We use an epitaxial transfer technique to transfer a III-V thin film directly on metallic surfaces, realizing III-V metal-semiconductor-metal (MSM) structures without heavily doped semiconductors as substitutes for metal layers. The device platform consists of gold metal layers with a p-i-n GaAs junction. The target resonance wavelength can be tuned by modifying the geometry of the top metal grating on the GaAs, while systematic resonance tunability has been shown through the modulation of various carrier concentration injections in the mid-IR range. Electrically tunable metasurfaces with multilevel biasing can serve as a fundamental building block for electrically tunable metasurfaces. We believe that our demonstration can contribute to understanding the optical tuning of III-V under various biased conditions, inducing changes in metasurfaces.

Mid-infrared spectroscopic thermotransmittance measurements in dielectric materials for thermal imaging

Thermal considerations affect the performance of most microsystems. Although surface techniques can give information on the thermal properties within the material or about buried heat sources and defects, mapping temperature and thermal properties in three dimension (3D) is critical and has not been addressed yet. Infrared thermography, commonly used for opaque materials, is not adapted to semi-transparent samples such as microfluidic chips or semiconductor materials in the infrared range. This work aims at answering these needs by using the variations of transmittance with temperature to obtain information on the temperature within the thickness of the sample. We use a tunable mid-infrared light source combined with an infrared camera to measure these variations of transmittance in a glass wafer. We couple this technique with a thermal model to extract the thermotransmittance coefficient—the coefficient of temperature variation of the transmittance. We then introduce a semiempirical model based on Lorentz oscillators to estimate the temperature-dependent optical properties of our sample in the mid-IR spectral range. Combined with the measurement, this paper reports the spectroscopic behavior of the thermotransmittance coefficient in the mid-IR range and a way to predict it.

A new instrumentation for simultaneous terahertz and mid-infrared spectroscopy in corrosive gaseous mixtures.

The correct interpretation of infrared (IR) observations of planetary atmospheres requires an accurate knowledge of temperature and partial and global pressures. Precise laboratory measurements of absorption intensities and line profiles, in the 200-350K temperature range, are, therefore, critical. However, for gases only existing in complex chemical equilibria, such as nitrous or hypobromous acids, it is not possible to rely on absolute pressure measurements to measure absolute integrated optical absorption cross sections or IR line intensities. To overcome this difficulty, a novel dual-beam terahertz (THz)/mid-IR experimental setup has been developed, relying on the simultaneous use of two instruments. The setup involves a newly constructed temperature-controlled (200-350K) cross-shaped absorption cell made of inert materials. The cell is traversed by the mid-IR beam from a high-resolution Fourier transform spectrometer using along a White-cell optical configuration providing absorption path lengths from 2.8 to 42m and by a THz radiation beam (82.5GHz to 1.1THz), probing simultaneously the same gaseous sample. The THz channel records pure rotational lines of molecules for which the dipole moment was previously measured with high precision using Stark spectroscopy. This allows for a determination of the partial pressure in the gaseous mixture and enables absolute line intensities to be retrieved for the mid-IR range. This new instrument opens a new possibility for the retrieval of spectroscopic parameters for unstable molecules of atmospheric interest. The design and performance of the equipment are presented and illustrated by an example of simultaneous THz and mid-IR measurement on nitrous acid (HONO) equilibrium.

Cascade picosecond optical parametric amplification for generating radiation in the 2.1 [formula omitted

The paper demonstrates the experimental implementation of a broadband picosecond radiation source with a wavelength of 2.0−2.2μm based on a cascade parametric amplifier. To do this, in the first cascade, as a result of parametric luminescence in the MgO:PPLN fan-out crystal, pumped by Nd:YAG laser pulses (90 ps, 10 Hz), radiation with a wavelength of 2.1μm and a pulse energy of ∼185 μJ at a pump energy of 6.5 mJ was generated. To increase the output radiation energy to a level of ∼840 μJ, a second parametric amplification cascade based on two KTiOPO4 crystals with a walk-off angle compensation was used. The results of numerical simulation of the spatial and energy characteristics of the radiation being generated are in good agreement with the experimental results. The developed picosecond 2.1μm radiation source is designed to be used for mid-IR range supercontinuum generation in non-oxide crystals.

Refining the Performance of mid-IR CPA Laser Systems Based on Fe-Doped Chalcogenides for Nonlinear Photonics

The chirped pulse amplification (CPA) systems based on transition-metal-ion-doped chalcogenide crystals are promising powerful ultrafast laser sources providing access to sub-TW laser pulses in the mid-IR region, which are highly relevant for essential scientific and technological tasks, including high-field physics and attosecond science. The only way to obtain high-peak power few-cycle pulses is through efficient laser amplification, maintaining the gain bandwidth ultrabroad. In this paper, we report on the approaches for mid-IR broadband laser pulse energy scaling and the broadening of the gain bandwidth of iron-doped chalcogenide crystals. The multi-pass chirped pulse amplification in the Fe:ZnSe crystal with 100 mJ level nanosecond optical pumping provided more than 10 mJ of output energy at 4.6 μm. The broadband amplification in the Fe:ZnS crystal in the vicinity of 3.7 μm supports a gain band of more than 300 nm (FWHM). Spectral synthesis combining Fe:ZnSe and Fe:CdSe gain media allows the increase in the gain band (~500 nm (FWHM)) compared to using a single active element, thus opening the route to direct few-cycle laser pulse generation in the prospective mid-IR spectral range. The features of the nonlinear response of carbon nanotubes in the mid-IR range are investigated, including photoinduced absorption under 4.6 μm excitation. The study intends to expand the capabilities and improve the output characteristics of high-power mid-IR laser systems.

Experimental demonstration of high-Q MRR based on a germanium-on-insulator platform with an yttria insulator in the mid-IR range

We experimentally demonstrate an all-pass microring resonator (MRR) based on a Y2O3 BOX germanium-on-insulator (GeOI) platform operating in the mid-IR region. The ring resonator was numerically designed to have a high quality (Q) factor in the 4.18 μm to 4.22 μm wavelength range in the fundamental TE mode. According to our design, the GeOI ring resonator was fabricated by the direct wafer-bonding technology with an yttria (Y2O3) buried oxide layer, which is transparent at the mid-IR region, for the bonding interface and the electron beam lithography. The experimental resonant characteristic was obtained using our fiber-based mid-IR measurement setup. The GeOI single MRR exhibited an extinction ratio (ER) of 15.28 dB and an insertion loss (IL) of 1.204 dB, and the racetrack showed an ER of 22.77 dB and an IL of 0.627 dB. Furthermore, the free spectral range of the device was 5.29 nm, and the loaded Q factor of 94,528 (176,158 of intrinsic Q factor) was extracted by the nonlinear least squares method. We believe this demonstration of our GeOI MRR offers a valuable opportunity to implement multipurpose devices such as optical sensors, switches, and filters in the mid-IR range.

Ho3+-doped Y3NbO7 transparent ceramic elaborated by air pre-sintering and post-HIP treatment as potential LASER gain material at 2 μm

In the framework of the development of new laser materials at the lowest limit of the mid-IR range, the cubic Y3NbO7 matrix has been doped by trivalent holmium. Fine powders were prepared through a liquid phase synthesis and highly densified using a two-stage sintering process: i) natural sintering was performed in air to reach relative density higher than 95%; ii) Hot Isostatic Pressure was applied to obtain fully dense and, consequently, transparent ceramics. The resulting microstructures were examined and then related to sintering parameters such as temperature and pressure. Refractive index, transmission and luminescence properties were measured and presented for the first time on a bulk material. These encouraging results showed that the Ho3+-doped Y3NbO7 compound is a promising potential candidate as a new laser material.