Mid-infrared Range Research Articles

Temporal dynamics of surface phonon polaritons in polar dielectric nanoparticles with nonlocality

Surface phonon polaritons (SPhPs) supported by polar dielectrics have been a promising platform for nanophotonics in mid-infrared spectral range. In this work, the temporal dynamic behavior of polar dielectric nanoparticles without (or with) spatial dispersion/nonlocality driven by the ultrashort Gaussian pulses is carried out. We demonstrate that three possible scenarios for the temporal evolutions of the dipole moment including ultrafast oscillations with the decay, exponential decay, and keeping a Gaussian shape exist, when the pulse duration of the incident field is much shorter than, similar to, and much longer than the localized SPhP lifetime. Once the nonlocal effect is considered, the oscillation period becomes large slightly, and the exponential decay turns fast. Furthermore, nonlocality-induced novel temporal behavior is found such as the decay with long-period oscillations when the center frequency of the incident pulse lies at the frequency of adjacent longitudinal resonant modes. The positive and negative time-shifts of the dielectric response reveal that the excitation of the dipole moment will be delayed or advanced. These temporal evolutions can pave the way towards potential applications in the modulation of ultrafast signals for the mid-infrared optoelectronic nanodevices.

Third order nonlinear correlation of the electromagnetic vacuum at near-infrared frequencies

In recent years, electro-optic sampling, which is based on Pockel’s effect between an electromagnetic mode and a copropagating, phase-matched ultrashort probe, has been largely used for the investigation of broadband quantum states of light, especially in the mid-infrared and terahertz frequency range. The use of two mutually delayed femtosecond pulses at near-infrared frequencies allows the measurement of quantum electromagnetic radiation in different space-time points. Their correlation allows therefore direct access to the spectral content of a broadband quantum state at terahertz frequencies after Fourier transformation. In this work, we will prove experimentally and theoretically that when using strongly focused coherent ultrashort probes, the electro-optic sampling technique can be affected by the presence of a third-order nonlinear mixing of the probes’ electric field at near-infrared frequencies. Moreover, we will show that these third-order nonlinear phenomena can also influence correlation measurements of the quantum electromagnetic radiation. We will prove that the four-wave mixing of the coherent probes’ electric field with their own electromagnetic vacuum at near-infrared frequencies results in the generation of a higher-order nonlinear correlation term. The latter will be characterized experimentally, proving its local nature requiring the physical overlap of the two probes. The parameters regime where higher order nonlinear correlation results predominant with respect to electro-optic correlation of terahertz radiation is provided.

Exploring the hardness of the ionising radiation with the infrared softness diagram

Aims. We explored the softness parameter in the infrared, ηIR′, whose main purpose is the characterisation of the hardness of the incident ionising radiation in emission-line nebulae. This parameter is obtained from the combination of mid-infrared wavelength range transitions corresponding to consecutive ionisation stages in star-forming regions. Methods. We compiled observational data from a sample of star-forming galaxies (SFGs), including luminous and ultraluminous infrared galaxies (LIRGs and ULIRGs), to study the ηIR′ and its equivalent expression in two dimensions, the softness diagram. We compared them with predictions from photoionisation models to determine the shape of the ionising continuum energy distribution in each case. We also used the measured emission-line ratios as input for HCMISTRY-TEFF-IR, a code that performs a Bayesian-like comparison with photoionisation model predictions in order to quantify the equivalent effective temperature (T*) and the ionisation parameter. Results. We found similar average values within the errors of ηIR′ in (U)LIRGs (−0.57) in the rest of the SFGs (−0.51), which could be interpreted as indicative of a similar incident radiation field. This result is confirmed from the analysis using HCM-TEFF-IR, which simultaneously points to a slightly lower, although similar within the errors, T* scale for (U)LIRGs, even when a higher dust-to-gas mass ratio is considered in the models for these objects. These derived T* values are compatible with the ionisation from massive stars, without any need of harder ionising sources, both for (U)LIRGs and the rest of the SFGs. However, the derived T* in (U)LIRGs do not show any correlation with metallicity. This could be interpreted as a sign that their similar average T* values are due to the attenuation of the energetic incident flux from massive stars by the heated dust mixed with the gas. This is supported by the known very large amounts of small grains associated with the very high star formation rates measured in galaxies of this type.

Tunable Near and Mid-Infrared (1.3–5 µm) Picosecond Pulsed Optical Vortex Parametric Oscillator

In this paper, we present a picosecond pulsed, synchronously pumped optical parametric oscillator producing vortex beam output with tunable wavelengths in the near- to mid-infrared range. The system utilizes a Nd:YVO4 picosecond pulsed solid-state laser emitting at a wavelength of 1.064 µm to pump a Z-shaped, singly resonant OPO which contains a MgO:PPLN crystal with a fan-shaped grating. The wavelength tuning characteristics of the OPO output are examined both as a function of the MgO:PPLN grating period and crystal temperature. The orbital angular momentum of the pump field can be selectively transferred to either the signal or idler fields by appropriately adjusting the location of the MgO:PPLN crystal within the OPO cavity. The maximum output power of the signal and idler vortex fields are 5.12 W and 3.46 W, respectively, for an incident pump power of 19 W.

A non-destructive measuring device in the mid-infrared range for measuring the CO2 concentration in the headspace of food packaging

Carbon dioxide (CO2) is the most common gas used in modified atmosphere packaging (MAP) to protect packaged foods from spoilage and pathogenic microorganisms and thus extend the shelf life of food products. Non-destructive measurement of CO2 concentration of the packaging headspace is of great interest as it could be used at various stages of the value chain, from outgoing goods inspection to storage tests and possible monitoring of the modified atmosphere at retail. Therefore, the aim of this work was to develop a measuring device operating non-destructively on closed MAP trays. Absorption measurement in the mid-infrared range at four different wavelengths proved to be a suitable principle for determining the CO2 gas concentration in a closed packaging system: 4.26 μm (2347 cm−1) and 4.27 μm (2342 cm−1) in the range of the antisymmetric stretching vibration, as well as 4.45 μm (2247 cm−1) at the edge of the antisymmetric stretching vibration, and 3.95 μm (2532 cm−1) as a reference measurement outside the absorption band with a thermal infrared source. Measurement principle and setup - the measurement in the absorbing and non-absorbing range and the guiding of the thermal infrared (IR) emitter at a 45° angle through the corner of the tray - allows a measurement largely independent of tray shape, height, and packaged product. The measurement can also be used for pigmented and printed trays - except for carbon black pigments. Optical impairments of the packaging and labeled areas of the lidding film appeared to have the greatest influence on the measurement accuracy. The applicability of the measurement system was evaluated and successfully demonstrated using commercially available food packaging from a local supermarket by comparing the CO2 gas concentrations yielded with those obtained using a destructive measurement device.

Hybridization of graphene-gold plasmons for active control of mid-infrared radiation

Many applications in environmental and biological sensing, standoff detection, and astronomy rely on devices that operate in the mid-infrared range, where active devices can play a critical role in advancing discovery and innovation. Nanostructured graphene has been proposed for active miniaturized mid-infrared devices via excitation of tunable surface plasmons, but typically present low efficiencies due to weak coupling with free-space radiation and plasmon damping. Here we present a strategy to enhance the light-graphene coupling efficiency, in which graphene plasmons couple with gold localized plasmons, creating novel hybridized plasmonic modes. We demonstrate a metasurface in which hybrid plasmons are excited with transmission modulation rates of 17% under moderate doping (0.35 eV) and in ambient conditions. We also evaluate the metasurface as a mid-infrared modulator, measuring switching speeds of up to 16 kHz. Finally, we propose a scheme in which we can excite strongly coupled gold-graphene gap plasmons in the thermal radiation range, with applications to nonlinear optics, slow light, and sensing.

Far- and mid-infrared FT-IR analysis of the single-crystal pentacene using a linearly polarized synchrotron radiation light source

Understanding and control of molecular vibrations are essential aspects for both fundamental and application considerations of organic semiconductor electronics. The reason is that the organic electronic devices are driven by diverse electronic processes in molecular solids, such as charge carrier transport and excitonic progression, that are strongly influenced by coupling with vibrations. In the present study, molecular vibrations of single-crystals of pentacene, a representative organic semiconductor material, were examined in the far- to mid-infrared range by means of Fourier transform infrared (FT-IR) spectroscopy using a linearly polarized synchrotron radiation light source. The IR absorption spectra exhibited significant modulation depending on the crystalline in-plane azimuthasl angle of c*-oriented single-crystal pentacene.

The construction of structural defects in MoAlB thin films by leveraging the enhanced Kirkendall effect for improved infrared stealth performance

MoAlB, known for its exceptional oxidation resistance and anti-ablation properties, holds significant promise as a protective thin film for high-temperature components in military equipment. However, the high thermal conductivity of MoAlB poses a challenge to its compatibility with infrared stealth performance. In this study, structural defects were intentionally implanted into the MoAlB thin film by leveraging the amplified Kirkendall effect to hinder heat propagation. The results revealed that the MoAlB MAB phase thin film with a notable amount of edge dislocations was achieved by subjecting the post-annealed (Mo–B)/Al nanostructured multilayers (NMs) to an elevated temperature of 700 °C. The room-temperature resistivity of the thin film was 1.43 μΩ m. Furthermore, the infrared emissivity of the thin film was assessed within the mid-infrared wavelength range, ranging from 0.11 to 0.25. Simultaneously, the resulting thin film was found to possess a low thermal conductivity of 11.44 W m−1 K−1, consequently achieving excellent infrared stealth capability.

Investigation of hybrid chalcogenide photonic crystal fiber for MIR supercontinuum generation and optical communication

Abstract This study describes a wideband supercontinuum generation (SCG) in the mid-infrared range using a chalcogenide multi-material microstructured fiber design with significant non-linearity under optical communication. The fiber has a single core of As2Se3 and three rings of As2S5 rods arranged in hexagonal pattern in the AsSe2 cladding region. The reported PCF design has effective area and nonlinear coefficients as 59.4174 μm2 and 219.36 W−1 km−1 respectively at 5.3 μm pump wavelength. Additionally, it has a chromatic dispersion profile that is nearly zero and flattened over a large wavelength range of 5–15 µm, which is advantageous for broadband supercontinuum spectrum in the mid-infrared region. Specifically, with pulse width and pulse peak power of 200 fs and 10 kW, respectively, for a 100 mm fibre length, this research work illustrates the SCG that expands from 1000 nm to over 15,000 nm. These extremely nonlinear PCFs are robust contenders for applications that are nonlinear in nature, such as the generation of slow-light and supercontinuum.

Implementation of Unilateral thermal nonreciprocity and front and rear electromagnetic nonreciprocity based on Weyl semimetal

The Weyl semimetal-dielectric multi-layer structure (WDMS) is proposed in this work to achieve nonreciprocal thermal absorption and emission in the mid-infrared wavelength range from both structural orientations. Employing the transfer matrix method (TMM), we effectively calculate emissivity and absorptivity. From both directions of the WDMS, it is observed that non-reciprocity originates at an incident angle of around 30°, with a larger incident angle consistently enhancing this characteristic. Upon increasing the incident angle to 45°, thermal absorption peaks at λ = 3.08 μm from the forward direction, showcasing a stronger non-reciprocity phenomenon as the angle increases. Similarly, from the backward direction, the absorption peak is situated at λ = 3.02 μm. Concurrently, we engage in a thorough discussion of pertinent factors, including the thickness of the unit structure. Furthermore, we delve into the specifics of the Weyl semimetal thickness and the number of periods in the dielectric unit layer. Utilizing simulation software, we observe their collective impacts on non-reciprocity, inducing variations in absorption and emission bands across diverse wavelengths (λ) and angular perspectives (θ). Our research underscores the influence of these factors on non-reciprocity and its impact on absorption and emission bands across varying wavelengths and angles. This work not only contributes to a deeper understanding of nonreciprocal thermal behavior but also offers valuable insights for the innovative design and manufacturing of thermal conversion devices and thermal radiation emitters.

Broadband transmissive polarization rotator by gradiently twisted α -MoO3

Polarization engineering has been proven to enhance the capabilities of light manipulation and thus facilitate the development of integrated photonic devices. In this study, we introduce a polarization rotator based on a gradiently twisted α-MoO3 thin film, which works in the mid-infrared range and functions in a transmission mode. To be specific, the proposed device is constructed by gradiently twisted α-MoO3 multilayers with a subwavelength thickness of only 5 μm, namely, one-third of the working wavelength. Our analytical calculation demonstrates the efficacy of this subwavelength thin film rotator in converting a linearly polarized wave into its orthogonal counterpart, thanks to its chiral nature. The twisted α-MoO3 multilayers exhibit the capability to significantly manipulate dispersion characteristics while maintaining low optical losses, thereby enabling a wide bandwidth exceeding 2.5 THz with a polarization ratio surpassing 17 dB. Moreover, the operational frequency can be adjusted across a 3.4 THz range by altering the incident angle of the incident waves. This adaptable design, characterized by its polarization versatility, can be customized to suit practical applications within wireless communication, radar systems, optical switching, and imaging technologies.

Quantum entanglement and interference at 3 μm.

Given the important advantages of the mid-infrared optical range (2.5 to 25 μm) for biomedical sensing, optical communications, and molecular spectroscopy, extending quantum information technology to this region is highly attractive. However, the development of mid-infrared quantum information technology is still in its infancy. Here, we report on the generation of a time-energy entangled photon pair in the mid-infrared wavelength band. By using frequency upconversion detection technology, we observe the two-photon Hong-Ou-Mandel interference and demonstrate the time-energy entanglement between twin photons at 3082 nm via the Franson-type interferometer, verifying the indistinguishability and nonlocality of the photons. This work is very promising for future applications of optical quantum technology in the mid-infrared band, which will bring more opportunities in the fields of quantum communication, precision sensing, and imaging.

Leveraging Intermolecular Charge Transfer for High-Speed Optical Wireless Communication.

Intermolecular charge transfer (CT) complexes have emerged as versatile platforms with customizable optical properties that play a pivotal role in achieving tunable photoresponsive materials. In this study, we introduce an innovative approach for enhancing the modulation bandwidth and net data rates in optical wireless communications (OWCs) by manipulating combinations of monomeric molecules within intermolecular CT complexes. Concurrently, we extensively investigate the intermolecular charge transfer mechanism through diverse steady-state and ultrafast time-resolved spectral techniques in the mid-infrared range complemented by theoretical calculations using density functional theory. These intermolecular CT complexes empower precise control over the -3 dB bandwidth and net data rates in OWC applications. The resulting color converters exhibit promising performance, achieving a net data rate of ∼100 Mb/s, outperforming conventional materials commonly used in the manufacture of OWC devices. This research underscores the substantial potential of engineering intermolecular charge transfer complexes as an ongoing progression and commercialization within the OWC. This carries profound implications for future initiatives in high-speed and secure data transmission, paving the way for promising endeavors in this area.

Towards Mid-Infrared Gas-Discharge Fiber Lasers

A 2.03 μm gas-discharge fiber laser based on atomic xenon is investigated. Various gas mixtures, such as He–Xe, Ar–Xe, He–Ar–Xe, and He–Ne, are studied by optical emission spectroscopy. The possibility of extending laser generation further into the mid-infrared range is analyzed.

Mid-infrared seven-core chalcogenide fiber with ultra-large mode field area and high beam quality

A seven-core chalcogenide fiber with an ultra-large mode field for mid-infrared range of 2.5–11 μm is designed and fabricated. Through manipulation of the core radius and pitch in the seven-core configuration, we are engaged in a comprehensive exploration of crosstalk characteristics and the mode field area (MFA). In addition, the relationship between the parameters of seven-core fiber for infrared and the beam quality of the output laser is analyzed for the first time. A theoretical MFA of 8914 μm2 can be calculated with a core radius of 24 μm and the pitch of 50 μm. This impressive MFA is realized through the deployment of an improved drilling technique in the fabrication of a Ge–As–Se seven-core fiber. The fiber has a relatively low loss at the wavelength range of 2.5–11 μm, and the minimum loss is 1.4 dB m−1 at 8.5 μm. The measured MFA of the fiber at 10.6 μm is 7364 μm2, which is 6.2 times higher than that of traditional stepped single-core fiber, but slightly lower than the theoretical value. The power delivery capability of the fiber has been significantly improved about two times compared with that of single-core fiber. The output beam quality factor M 2 is calculated as 1.13. In all, the seven-core fiber exhibits substantial potential for high-power laser propagation with high quality and flexibility.

High-entropy strategy for high-temperature broadband infrared radiation and low thermal conductivity

Developing high-performance infrared radiation ceramic materials with desired broadband emissivity while reducing thermal conductivity to prevent heat transfer is highly desirable for emerging industrial and aerospace applications. Nevertheless, it remains a grand challenge to simultaneously meet these requirements in existing infrared radiation ceramic materials. Herein, a high-entropy strategy is employed to enhance the high-temperature infrared radiation property with a high emissivity above 0.9 at room temperature and 0.68 at 1200 °C across the entire range of wavelength (1–14 μm), and integrate a low thermal conductivity (<0.88 W m−1 K−1 at 1000 °C) and remarkable mechanical properties. High-entropy rare earth (RE) disilicates ((Y0.4Yb0.4Tm0.1Lu0.05Ho0.05)2Si2O7) ceramic coating with high lattice entropy has a more complex electronic structure, inducing lattice distortion and extra multi-mode vibrations, which boosts the emissivity in mid-infrared range (3–14 μm). Meanwhile, the high-entropy strategy prompts the formation of impurity energy levels as gap states, achieving optical absorption at low photon energies, and thus enhancing the emissivity in near-infrared range (1–3 μm). Simultaneously, (Y0.4Yb0.4Tm0.1Lu0.05Ho0.05)2Si2O7) ceramic coating owns diffusion-mediated thermal transport properties with strong phonon scattering, assisted further by the lamellar porous structure, thereby enabling a low thermal conductivity. The excellent mechanical properties ensure the reliability of the coating in extreme environments. All these merits render the high-entropy ceramic coating competitive for the development of high-temperature broadband high-emissivity thermal radiation materials.

Formation and practical implementation of a helical radiation wavefront in the mid-infrared range

Formation and practical implementation of a helical radiation wavefront in the mid-infrared range

Search and study for meteorites analogous to Didymos

ABSTRACT The Hera mission will arrive at the Didymos system to study the efficiency of momentum transfer and to further investigate the binary system in great detail after the Double Asteroid Redirection Test (DART) mission impact. We took advantage of two online data bases of meteorites spectra and of recent Didymos spectra taken before and after the DART impact. We performed the first selection based on the comparison of the band centre values of the silicate absorption bands (localized at 1 and 2 μm) between Didymos and the meteorites. The second selection was made defining a four-dimensional space parameter whose dimensions were the band depth and the slope of the two bands, normalized to Didymos values. We introduced a distance measure to find the closest meteorites to Didymos in this space. Finally, we made the last selection based on other criteria, such as the presence of different spectra of the same meteorite, the presence of different spectra from different data bases, and the comparison with the literature. The result of this work is a list of six meteorites that are the most analogous to Didymos system. We also found out that Didymos is most probably mainly composed of L/LL ordinary chondrites, with a preference for the LL sub-type. From our list of meteorites, we were able to estimate the normalized abundance of olivine and pyroxene of Didymos. Finally, a match between Didymos and OC meteorites was also found in the Mid-InfraRed (MIR) range.

A high figure of merit of phonon-polariton waveguide modes with hbn/SiO2/graphene /hBN ribs waveguide in mid-infrared range

Natural hyperbolic materials can confine electromagnetic waves at the nanoscale. In this study, we propose a waveguide design that combines a high quality factor (FOM) with low loss, utilizing hexagonal boron nitride and graphene and gold substrate. The waveguide consists of a dielectric rib with a graphene layer sandwiched between two hBN ribs. Numerical simulations demonstrate the existence of two guided modes in the proposed waveguide within the second reststrahlen band (1360.0 cm−1<ω < 1609.8 cm−1) of hBN. These modes are formed by coupling the hyperbolic phonon polariton (HPhP) of two hBN rib in the middle dielectric rib and are subsequently modulated by a graphene layer. Interestingly, we observe variations in four transmission parameters, namely effective length, figure of merit, device length, and propagation loss of the guided modes, with respect to the operation frequency and gate voltage. By optimizing the waveguide's geometry parameters and dielectric permittivity, the modal properties were analyzed. Simulation results indicate that optimizing the waveguide size parameters enables us to achieve a high FOM of 4.0 × 107. The proposed waveguide design offers a promising approach for designing tunable mid infrared range waveguides on photonic chips, and this concept can be extended to other 2D materials and hyperbolic materials.

Short review and prospective: chalcogenide glass mid-infrared fibre lasers

Rare-earth ion doped, silica glass, optical fibre amplifiers have transformed the world by enabling high speed communications and the Internet. Fibre lasers, based on rare-earth ion doped silica glass optical fibres, achieve high optical powers and are exploited in machining, sensing and medical surgery. However, the chemical structure of silica glass fibres limits the wavelength of laser operation to < 2.5 µm, which excludes the mid-infrared longer wavelength range of 3–50 µm. Rare-earth ion doping of fluoride glasses enables manufacture of fibre lasers up to a limiting 3.92 µm wavelength, but the fluoride glass chemical structure again prevents operation at longer wavelengths. Optical fibre lasers that are constructed from different rare-earth ion doped chalcogenide glass fibres will potentially operate across the 4–10 µm wavelength range, where suitable high-power lasers currently do not exist. We present a short review here of our recent work in achieving first time, continuous wave, mid-infrared fibre lasing beyond 5 μm wavelength in Ce3+-doped selenide chalcogenide fibre. We place this disruptive breakthrough into the wider fibre laser context, and also present the unprecedented advances in new cross-sector applications that will be enabled by mid-infrared fibre lasers in the 4–10 µm wavelength range. To surpass the few mW power output of the Ce3+-doped chalcogenide glass fibre lasing achieved to date, the glass quality of the doped chalcogenide fibres must now be improved, similar to the challenges originally facing the first glass fibre lasers based on silica.