Mid-infrared Interband Cascade Lasers Research Articles

Photoacoustic trace gas detection of OCS using a 2.45 mL Helmholtz resonator and a 4823.3 nm ICL light source

A miniaturized photoacoustic spectroscopy-based gas sensor is proposed for the purpose of detecting sub-ppm-level carbonyl sulfide (OCS) using a tunable mid-infrared interband cascade laser (ICL) and a Helmholtz photoacoustic cell. The tuning characteristics of the tunable ICL with a center wavelength of 4823.3 nm were investigated to achieve the optimal driving parameters. A Helmholtz photoacoustic cell with a volume of ∼2.45 mL was designed and optimized to miniaturize the measurement system. By optimizing the modulation parameters and signal processing, the system was verified to have a good linear response to OCS concentration. With a lock-in amplifier integration time of 10 s, the 1σ noise standard deviation in differential mode was 0.84 mV and a minimum detection limit (MDL) of 409.2 ppbV was achieved at atmospheric pressure and room temperature.

Nonlinear dynamics of an interband cascade laser with optical injection

This work reports the nonlinear dynamics of a mid-infrared interband cascade laser (ICL) subject to optical injection. It is shown that the stable locking regime is asymmetric and broadens with increasing injection strength. Outside the locking regime, the ICL mostly produces period-one oscillations. However, three categories of periodic pulse oscillations are observed in the vicinity of the Hopf bifurcation and the saddle-node bifurcation. In particular, it is found that the ICL generates broadband chaos at a near-threshold pump current, and the chaos bandwidth is over 300 MHz.

Mid-infrared Ring Interband Cascade Laser: Operation at the Standard Quantum Limit.

Many precision applications in the mid-infrared spectral range have strong constraints based on quantum effects that are expressed in particular noise characteristics. They limit, e.g., sensitivity and resolution of mid-infrared imaging and spectroscopic systems as well as the bit-error rate in optical free-space communication. Interband cascade lasers (ICLs) are a class of mid-infrared lasers exploiting interband transitions in type-II band alignment geometry. They are currently gaining significant importance for mid-infrared applications from < 3 to > 6 μm wavelength, enabled by novel types of high-performance ICLs such as ring-cavity devices. Their noise behavior is an important feature that still needs to be thoroughly analyzed, including its potential reduction with respect to the shot-noise limit. In this work, we provide a comprehensive characterization of λ = 3.8 μm-emitting, continuous-wave ring ICLs operating at room temperature. It is based on an in-depth study of their main physical intensity noise features such as their bias-dependent intensity noise power spectral density and relative intensity noise. We obtained shot-noise-limited statistics for Fourier frequencies above 100 kHz. This is an important result for precision applications, e.g., interferometry or advanced spectroscopy, which benefit from exploiting the advantage of using such a shot-noise-limited source, enhancing the setup sensitivity. Moreover, it is an important feature for novel quantum optics schemes, including testing specific light states below the shot-noise level, such as squeezed states.

Low-frequency regular pulse and intermittent oscillation in a mid-infrared interband cascade laser with optoelectronic feedback.

In this work, we experimentally investigate the nonlinear dynamics of a mid-infrared interband cascade laser (ICL) subject to optoelectronic feedback (OEF) through inspecting the time series and power spectrum of the laser output. The results show that, within the range of feedback strength limited by the experiment condition, the ICL sequentially presents stable state, continuously periodical oscillation (CPO), low-frequency regular pulse (LF-RP) and intermittent oscillation state with the increase of feedback strength. For the LF-RP state, the peak-to-peak value and the oscillation period increase with the increase of feedback strength. For the intermittent oscillation state, the time series is composed of the laminar region and burst region appeared alternately, and the average value and standard deviation for the duration of burst region gradually decrease with the increase of feedback strength.

Quartz tuning fork (QTF) coating enhanced Mid-Infrared laser Induced-Thermoacoustic spectroscopy (LITES) for human exhaled methane detection

Human exhaled methane (CH4) has essential significance in detecting intestinal flora. In this study, a high-precision quartz tuning fork (QTF) based light-induced thermoelastic spectroscopy (LITES) system was developed, a mid-infrared interband cascade laser (ICL) and a QTF detector coated with polydimethylsiloxane (PDMS) and reduced graphene oxide (rGO) were employed for the CH4 detection. Experimental results indicate that the composite coating resulted in a 3-fold increase in 2f signal amplitude and signal-to-noise ratio (SNR), when compared to the bare QTF detector. The system has achieved a minimum detection limit (MDL) of 58.65 ppbv (part per billion volume) and a normalized noise equivalent absorption coefficient (NNEA) of 2.069 × 10−10 cm−1·W·Hz−1/2, Allan deviation analysis indicates that the optimal measurement accuracy is 36.85 ppbv. 24 healthy college students and 10 overweight/obese students were recruited to measure the CH4 concentration in the exhaled breath. The results show that exhaled CH4 concentrations of healthy individuals range from 0.5 to 3 ppmv (part per million volume), with slightly higher levels in males than females, and higher levels in the obese individuals than those in the normal individuals. The mid-infrared LITES CH4 measurement system holds promise as a new non-invasive method for assessing human metabolic states, with potential applications in medical and life sciences.

Investigations on Pressure Broadening Coefficients of NO Lines in the 1←0 Band for N2, CO2, Ar, H2, O2 and He

A tunable diode laser absorption spectroscopy (TDLAS)-based spectrometer employing a mid-infrared (Mid-IR) interband cascade laser (ICL) was developed and used to determine pressure broadening coefficients of two NO absorption transitions at 1914.98 cm−1 and 1915.76 cm−1 in the fundamental (1←0) band (R11.5 Ω1/2 and Ω3/2) for CO2, N2, Ar, O2, He, and H2. For the first time, a reliable and consistent set of six different pressure-broadening coefficients for the NO line has been measured by a consistent approach covering pressures from 100 to 970 mbar at a temperature of 294 K. Air pressure broadening has been calculated based on N2 and O2 coefficients. The stated pressure-broadening coefficients for N2, CO2, Ar, H2, O2, He, and Air have relative errors in the 0.5–1.5% range. For CO2 and H2, broadening results of NO (1←0) band (R11.5 Ω1/2 and Ω3/2) lines are reported for the first time. The results are also compared to previously available literature data. It was found that the broadening coefficients for O2 and Air are in agreement with literature values, whereas results for Ar and He show larger differences.

Highly sensitive methane detection using a mid-infrared interband cascade laser and an anti-resonant hollow-core fiber.

For over a decade hollow-core fibers have been used in optical gas sensors in the role of gas cells. However, very few examples of actual real-life applications of those sensors have been demonstrated so far. In this paper, we present a highly-sensitive hollow-core fiber based methane sensor. Mid-infrared distributed feedback interband cascade laser operating near 3.27 µm is used to detect gas inside anti-resonant hollow-core fiber. R(3) line near 3057.71 cm-1 located in ν3 band of methane is targeted. Compact, lens-free optical setup with an all-silica negative curvature hollow-core fiber as the gas cell is demonstrated. Using wavelength modulation spectroscopy and 7.5-m-long fiber the detection limit as low as 1.54 ppbv (at 20 s) is obtained. The demonstrated system is applied for a week-long continuous monitoring of ambient methane and water vapor in atmospheric air at ground level. Diurnal cycles in methane concentrations are observed, what proves the sensor's usability in environmental monitoring.

Mid-Infrared Frequency Combs based on Single Section Interband Cascade Lasers

In this work we show Frequency Comb (FC) and short pulsed operation of mid-infrared Interband Cascade Lasers (ICLs) in a single long section. This is through the use of an adapted ultrafast Quantum Well Infrared Photodetectors (QWIPs), and correlating the microwave beatnotes with high resolution spectra of the ICL. In particular, we will show active mode-locking (ML) of single -section ICL that does not require RF optimisation of the ICL device and highlight its temporal characteristics using Shifted Wave Infrared Fourier Transform Spectroscopy (SWIFTS) analysis to reconstruct the intensity in the time domain.

A laser-absorption sensor for in situ detection of biofuel blend vapor in engine intakes

A novel, mid-infrared laser-absorption sensor was developed for measurements of biofuel blend (E85) vapor in the intake runner of a single-cylinder internal combustion engine. The sensor used two mid-infrared interband cascade lasers to target a region of strong E85 absorbance near 3.35 µm. The lasers were co-aligned and fiber-coupled into the engine, and a two-color, online-offline differential absorption strategy was used to provide sensitive measurements of E85 vapor mole fraction and reject interference due to beam-steering and fuel droplet spray. An intensity-modulation spectroscopy (IMS) sensing scheme was employed to reject low-frequency additive noise and allow for frequency-domain multiplexing of the two lasers. High-resolution E85 absorption cross-section measurements were conducted in a static cell at a range of intake-relevant conditions. Validation experiments were performed in a laboratory setting to demonstrate sensor accuracy and noise rejection capability. The sensor was deployed on a single-cylinder development engine during dynamometer testing to provide time-resolved E85 vapor mole fraction measurements at a measurement rate of 40 kS/s, which corresponds to one measurement per crank angle degree at 6700 rpm. Time-resolved and average sensor measurements provide key performance insights for the development of intake systems in high-performance internal combustion engines.

Modeling of Amplitude Squeezing in a Pump-Noise-Suppressed Interband Cascade Laser

A semi-classical rate equation model for the amplitude squeezing of mid-infrared interband cascade lasers is presented based on Green's function method. We analytically investigate the squeezing performance through a small signal analysis, where an additional partition noise in the output power is considered because of the anti-correlation between photons reflected and transmitted at the output laser facet. Thus, the squeezing effect can be achieved in the low frequency region with noise-suppressed pump. Amplitude squeezed states in interband cascade lasers can qualitatively be evaluated depending on the pump noise conditions. Such ultra-low amplitude noise laser sources enable various applications such as high precision measurements, metrology, and spectroscopy range where squeezed states can be used to replace current shot-noise limited laser mid-infrared sources.

Low threshold InAs-based interband cascade lasers grown by MBE

Mid-infrared interband cascade laser (ICL) structures aimed for emission at room temperature in the 4–5 μm wavelength region are grown by molecular beam epitaxy (MBE) on InAs substrates. High crystalline quality of the epitaxial structures has been confirmed by X-ray diffraction with thickness deviations less than 1% from the designs. Also, the average surface defect density is in the low ten to the fourth level. The broad-area (BA) devices made from the MBE-grown ICL wafers can lase in continuous wave (CW) mode in a wavelength range from 3.5 to 4.8 μm at temperatures up to 257 K, which is the highest reported for BA InAs-based ICLs at similar wavelengths. Their threshold current densities are low (e.g. 2.7 A/cm2 at 80 K), indicating excellent material quality with a very low Shockley-Reed-Hall recombination. In pulsed mode, the lowest threshold current density is 252 A/cm2 at 300 K, and the maximum operating temperature has reached 379 K. By comparisons in device performance among multiple MBE-grown ICL wafers, the importance of beam equivalent pressure stability and accurate control of layer thicknesses is demonstrated for the desirable performance.

Toward robust and practical interband cascade laser frequency combs: A perspective

Multimode emission from a semiconductor laser can sometimes take the form of a low-noise frequency comb with equidistant separation between the modes. Two general types of “passive” comb operation have been explored experimentally: (1) the periodic short-pulse mode achieved by intracavity mode locking, usually obtained by incorporating a saturable absorber section into the cavity, and (2) the so-called frequency-modulated (FM) mode in which the output intensity can vary within wide bounds but does not completely turn off between pulses, and the instantaneous frequency is linearly chirped over a round trip. The FM mode sometimes manifests as a “sparse” harmonic state, with individual modes spaced by multiples of the cavity free spectral range. This Perspective reviews the current understanding of these modes, along with the conditions under which they may arise in practical devices. We then consider in detail the case of type-II mid-infrared interband cascade laser (ICL) frequency combs. Our simulations clarify the roles of carrier dynamics and group velocity dispersion and identify design modifications that may substantially improve the device performance. We find no fundamental roadblocks to the development of practical mode-locked ICL frequency combs that emit short pulses with broad spectral bandwidth for dual comb spectroscopy and other applications, alongside the FM combs that have already been demonstrated experimentally.

A sensitive methane sensor of a ppt detection level using a mid-infrared interband cascade laser and a long-path multipass cell

An ultra-high sensitivity sensor combining a mid-IR (MIR) interband cascade laser (ICL) at center wavelength of 3.37 μm and a multi-pass cell (MPC) with a path-length of 580 m was designed and implemented for methane detection. The ultra-high sensitivity is achieved due to the higher absorbance in the MIR than in the near infrared (NIR), a long interaction path length, and the implementation of a wavelet denoising processing algorithm. The performance of the sensor was evaluated with direct absorption spectroscopy (DAS) and wavelength modulation spectroscopy (WMS) in a series of measurements. For the sensor working in the DAS measurement mode, the optimal set of sub-wavelet functions was chosen and utilized for denoising. A calibration gas with methane concentration of 2.0 ppm was measured with a relative error of ± 1%. The minimum of the Allan deviation of the sensor of 3 ppb was achieved with an averaging time of 200 s. For the WMS technique with the Allan deviation analysis the sensor detection limit for methane of 560 ppt with 290 s averaging time was determined, which is a significant improvement compared to our DAS results and previous reports. The developed sensor has broad applicability in the high-sensitivity measurements of methane and other trace gases.

Mid-infrared absorption by soft tissue sarcoma and cell ablation utilizing a mid-infrared interband cascade laser.

.Significance: Mid-infrared (MIR) light refers to wavelengths ranging from 3 to and is the most attractive spectral region for ablation of soft and hard tissues. This is because building blocks of biological tissue, such as water, proteins, and lipids, exhibit molecular vibrational modes in the MIR wavelengths that result in strong MIR light absorption. To date, researchers investigating MIR lasers for surgical applications have used bulky light sources, such as free electron lasers, nonlinear light generators, and carbon dioxide lasers. We demonstrate the use of a tiny (a few microns wide, a few millimeters long) MIR interband cascade laser (ICL) for surgical thermal ablation applications.Aim: Our goal is to demonstrate the use of an ICL for surgical thermal ablation and demonstrate its efficacy in ablating normal fibroblasts and primary undifferentiated pleomorphic sarcoma tumor cells (C1619).Approach: We conducted Fourier transform infrared spectroscopy analysis of healthy and cancerous tissue samples, which indicated that the absorption of tumor tissue is higher than healthy tissue around wavelength. These results enabled us to select an ICL emission wavelength, , of to probe normal fibroblast and primary undifferentiated pleomorphic sarcoma cell survival after ICL exposure.Results: We show that the absorption of tumorous tissue is higher than that of healthy tissues around the MIR wavelength. We demonstrate that the ICL is able to ablate cancer cells at very low-power levels that can be clinically implemented but that this effect does not appear to be specific to C1619 when compared to normal fibroblasts.Conclusions: Our study demonstrates that ICLs may represent an exciting new avenue toward precise laser-based thermal ablation.

Theoretical design of mid-infrared interband cascade lasers in SiGeSn system

By carefully analyzing the latest composition-dependent parameters of SiGeSn alloys, we come to realize that this system could provide type-II energy band alignment at direct bandgap condition. The discovery inspires us to explore the mid-infrared interband cascade laser (ICL) in SiGeSn system. Based on the eight-band k ⋅ p model, we theoretically design three schemes of ICL, in which the active region and the carrier injectors are optimized simultaneously. Afterward, the properties of TE-mode optical gain spectrums and differential gain are investigated individually for each scheme. Furthermore, the spontaneous emission spectrums and radiative current density are also calculated. Our theoretical results indicate that the active region composed of double-electron and triple-hole quantum wells has the best gain performance, reaching 660 cm−1 for a single period of the ICL under 7.8 × 1018 cm−3 injected electron density. This work opens up another type of infrared lasers that can be developed from the group-IV system, offering a new pathway to achieving the monolithic integration in Si photonics.

Unveiling quantum-limited operation of interband cascade lasers

A comprehensive experimental analysis of the frequency fluctuations of a mid-infrared interband cascade laser, down to the quantum-limited operation, is reported. These lasers differ from any other class of semiconductor lasers in their structure and internal carrier generation and transport processes. Although already commercially available, a full evaluation of their potential has not been possible, until now, mainly because their internal dynamics are not yet understood well enough. The measured intrinsic linewidth, down to 10 kHz, ranks them in between quantum cascade and bipolar semiconductor lasers. Understanding the noise features is especially important for demanding applications and is a necessary step for a deeper knowledge of the physical behavior for this class of lasers, in view of the development of novel designs for improved performance.

Near-infrared frequency comb generation in mid-infrared interband cascade lasers.

The interband cascade laser (ICL) is an ideal candidate for low-power mid-infrared frequency comb spectroscopy. In this work, we demonstrate that its intracavity second-order optical nonlinearity induces a coherent up-conversion of the generated mid-infrared light to the near-infrared through second-harmonic and sum-frequency generation. At 1.8 µm, 10 mW of light at 3.6 µm convert into sub-nanowatt levels of optical power, spread across 30 nm of spectral coverage. The observed linear-to-nonlinear conversion efficiency exceeds ${3\;{\unicode{x00B5} {\rm W/W}}^2}$3µW/W2 in continuous wave operation. We use a dual-band ICL frequency comb source to characterize water vapor absorption in both spectral bands.

Picosecond pulses from a mid-infrared interband cascade laser

The generation of mid-infrared pulses in monolithic and electrically pumped devices is of great interest for mobile spectroscopic instruments. The gain dynamics of interband cascade lasers (ICL) are promising for mode-locked operation at low threshold currents. Here, we present conclusive evidence for the generation of picosecond pulses in ICLs via active mode-locking. At small modulation power, the ICL operates in a linearly chirped frequency comb regime characterized by strong frequency modulation. Upon increasing the modulation amplitude, the chirp decreases until broad pulses are formed. Careful tuning of the modulation frequency minimizes the remaining chirp and leads to the generation of 3.2 ps pulses.

High-Precision 13CO2/12CO2 Isotopic Ratio Measurement Using Tunable Diode Laser Absorption Spectroscopy at 4.3 μm for Deep-Sea Natural Gas Hydrate Exploration

For the detection of deep-sea natural gas hydrates, it is very important to accurately detect the 13CO2/12CO2 isotope ratio of dissolved gas in seawater. In this paper, a 13CO2/12CO2 isotope ratio sensor is investigated, which uses a tunable diode laser absorption spectroscopy (TDLAS) technique at 4.3 μm. The proposed sensor consists of a mid-infrared interband cascade laser (ICL) operating in continuous wave mode, a long optical path multi-pass gas cell (MPGC) of 24 m, and a mid-infrared mercury cadmium telluride (MCT) detector. Aiming at the problem of the strong absorption intensity of the two absorption lines of 13CO2 and 12CO2 being affected by temperature, a high-precision temperature control system for the MPGC was fabricated. Five different concentrations of CO2 gas were configured to calibrate the sensor, and the response linearity could reach 0.9992 for 12CO2 and 0.9996 for 13CO2. The data show that the carbon isotope measurement precision was assessed to be 0.0139‰ when the integration time was 92 s and the optical path length was 24 m. The sensor is combined with a gas–liquid separator to detect the 13CO2/12CO2 isotope ratio of CO2 gas extracted from water. Results validate the reported sensor system’s potential application in deep-sea natural gas hydrate exploration.

Mid-infrared heterodyne phase-sensitive dispersion spectroscopy in flame measurements

We present the first demonstration of heterodyne phase-sensitive dispersion spectroscopy (HPSDS) for in situ, non-intrusive and quantitative CO2 concentration measurements in flames. Dispersion spectroscopy retrieves gas properties by measuring the refractive index in the vicinity of a molecular resonance. The HPSDS scheme features a significant diagnostic advantage of the intrinsic immunity to laser power fluctuations caused by beam steering, thermal radiation and soot scattering in combustion environments, and thus no extra calibration process is required. In this work, we described the spectroscopic fundamentals for measuring heterodyne phase signals in flames. As a proof of principle, we used a mid-infrared interband cascade laser (ICL) near 4183 nm to exploit the strong CO2 transitions in the R-branch of the v3 fundamental band. The HPSDS signals of four CO2 lines, R(76), R(78), R(80) and R(82), were measured in CH4/air flames to obtain CO2 concentrations at different equivalence ratios (Φ = 0.8–1.2), yielding a good agreement with the simultaneous laser absorption measurements using the same ICL. With its immunity to laser power fluctuations verified experimentally, the HPSDS sensor was successfully implemented to measure CO2 concentrations in C2H4/air sooting flames (Φ = 1.78–2.38). Laser dispersion spectroscopy proves to be a promising and alternative diagnostic tool for combustion measurements.