Mid-infrared Absorber Research Articles

Dynamically Switchable Mid-Infrared Perfect Absorber Based on Grating-Assisted Graphene Plasmon Excitation

Dynamically Switchable Mid-Infrared Perfect Absorber Based on Grating-Assisted Graphene Plasmon Excitation

Tunable mid-infrared absorber based on Dirac metamaterials

Abstract In this paper, a tunable metamaterial absorber based on Dirac semimetal is proposed, which consists of three different structures, from top to bottom, namely a double semicircular Dirac semimetal resonator, a silicon dioxide (SiO2) substrate, and a continuous vanadium dioxide (VO2) reflector layer. When the Fermi energy level of the Dirac semimetal is 10\ meV, the absorber absorbs more than 90% in the 39.06-84.76\ THz range. Firstly, taking advantage of the tunability of the conductivity of the Dirac semimetal, the dynamic tuning of the absorption frequency can be achieved by changing the Fermi energy level of the Dirac semimetal without the need to optimise the geometry and remanufacture the structure. Secondly, the structure has been improved by the addition of the phase change material VO2, resulting in a much higher absorption performance of the absorber. Since vanadium dioxide is a temperature-sensitive metal oxide with an insulating phase below the phase transition temperature (about 68℃) and a metallic phase above the phase transition temperature, this paper also analyses the effect of vanadium dioxide on the absorptive performance at different temperatures, with the aim of further improving the absorber performance.

Dynamic nonlocal metasurface for multifunctional integration via phase-change materials

Abstract Non-local metasurface supporting geometric phases at bound states in the continuum (BIC) simultaneously enables sharp spectral resonances and spatial wavefront shaping, thus providing a diversified optical platform for multifunctional devices. However, a static nonlocal metasurface cannot manipulate multiple degrees of freedom (DOFs), making it difficult to achieve multifunctional integration and be applied in different scenarios. Here, we presented and demonstrated phase-change non-local metasurfaces that can realize dynamic manipulation of multiple DOFs including resonant frequency, Q values, band, and spatial wavefront. Accordingly, a metasurface integrating multiple distinct functions is designed, as a proof-of-concept demonstration. Utilizing the geometry phase of quasi-BIC and the tunability of vanadium dioxide (VO2), a dynamic meta-lens is achieved by tailoring spatial light response at quasi-BIC in the temperature range from room temperature to 53 °C. Simultaneously, the sharp Fano resonance of quasi-BIC enables the metasurface to serve as an optical sensor in the mid-infrared band, yielding a sensitivity of 7.96 THz/RIU at room temperature. Furthermore, at the metallic state of VO2 (80 °C), the designed metasurface converts into a mid-infrared broadband absorber, achieving higher than 80 % absorptivity and an average absorption of 90 % from 28.62 THz to 37.56 THz. The proposed metasurface enabling multifunctional performances in different temperatures can effectively improve the availability of devices and find more new and complex scenarios in sensing, imaging, and communications.

High sensitivity and high figure of merit graphene mid-infrared multi-band tunable metamaterial perfect absorber

In the research of this paper, we have devised a mid-infrared band metamaterial perfect absorber made of graphene material. The absorber is composed of a traditional three-layer structure of MPA. The top layer is a graphene layer with a specific structure, with SiO2 as the dielectric layer and the gold film as the substrate. In the wavelength range of 5500 – 13,000 nm, the graphene layer generates seven absorption peaks and shows ultra-high absorption efficiency. The respective absorption rates are 91.17 %, 99.41 %, 99.01 %, 95.69 %, 94.16 %, 96.89 %, and 95.01 %. By verifying the absorption spectra and the principle of effective impedance matching, analyze the electric field distribution image of the xoy plane based on the principle of surface plasmon resonance, we have proved that it conforms to the classical physical theory and expounded the reason why the absorption peaks were formed. The comparison of different graphene patterns has confirmed the superiority of this structure. By changing the relaxation time and Fermi level of graphene, the tunability of the absorber structure has been verified. Changing the incident angle has proved its insensitivity to the polarization angle (0° - 50°). Finally, by calculating and comparing the figure of merit (FOM) and the sensitivity (S), it is shown that this structure has significant sensitivity and excellent application ability and value. We firmly believe that our absorber can be well applied in high-sensitivity sensors, filters and detectors, and can contribute to fields such as photoelectric detection, optical communication and photoelectric sensing.

Multilayer thin film mid-infrared broadband absorber with high visible light transmittance

Few reports on absorbers achieve both high transmittance of visible light and strong absorption of mid-infrared light. Here a multilayered absorber with high visible light transmittance and strong broadband absorption in the mid-infrared band is proposed. The absorber is four-layer films of ITO/SiO2/ITO/SiO2 successively deposited on single-sided conductive glass by electron beam evaporation technology. The experiment shows that the integral transmittance in the 400–800 nm range is 82.8 %, and the integral absorption in the 3–5 μm band is 88.2 %.

A Mid-Infrared Perfect Metasurface Absorber with Tri-Band Broadband Scalability.

Metasurfaces have emerged as a unique group of two-dimensional ultra-compact subwavelength devices for perfect wave absorption due to their exceptional capabilities of light modulation. Nonetheless, achieving high absorption, particularly with multi-band broadband scalability for specialized scenarios, remains a challenge. As an example, the presence of atmospheric windows, as dictated by special gas molecules in different infrared regions, highly demands such scalable modulation abilities for multi-band absorption and filtration. Herein, by leveraging the hybrid effect of Fabry-Perot resonance, magnetic dipole resonance and electric dipole resonance, we achieved multi-broadband absorptivity in three prominent infrared atmospheric windows concurrently, with an average absorptivity of 87.6% in the short-wave infrared region (1.4-1.7 μm), 92.7% in the mid-wave infrared region (3.2-5 μm) and 92.4% in the long-wave infrared region (8-13 μm), respectively. The well-confirmed absorption spectra along with its adaptation to varied incident angles and polarization angles of radiations reveal great potential for fields like infrared imaging, photodetection and communication.

Numerical investigation of tunable and switchable refractive index-based mid-infrared metamaterial absorber

Numerical investigation of tunable and switchable refractive index-based mid-infrared metamaterial absorber

High quality factor and unity circular dichroism enabled by dielectric-Weyl semimetal-dielectric stack

A mid-infrared (mid-IR) chiral absorber based on multilayer films of silicon (Si)/Weyl semimetal (WSM)/Si is proposed and numerically studied. The proposal exhibits high quality factor circular dichroism (CD) with different absorptance properties for right-hand circular polarization (RCP) and left-hand circular polarization (LCP) light. The absorption characteristics have been explored with the generalized 4 × 4 transfer matrix algorithm, and the effects of structural parameters on the circularly polarized (CP) absorptance are systematically investigated. The circular polarization efficiency (η) and CD are defined as crucial parameters for quantifying the chirality response. The results prove that the chiral absorber exhibits extraordinary efficiencies of 1 and 0 for LCP and RCP light at a wavelength of 11.5 μm, respectively. Thus a maximum CD in absorption of unity with a resonant quality factor (Q-factor) of 295 can be obtained. The performance of dual-band chiral responses can be engineered via the thickness of each layer. Moreover, it is identified that the design results in angle-independent performance, which is essential trait for an efficient chiral absorber.

Mid-infrared optical absorber based on anisotropic black phosphorus and magnesium fluoride

Mid-infrared optical absorber based on anisotropic black phosphorus and magnesium fluoride

Mid-infrared tunable absorber based on an Ag/SiO2/VO2/Ag/VO2 multilayer structure and its molecular sensing capability.

We present a design of middle-infrared modulation absorbers based on vanadium dioxide (VO2). By using the electron beam evaporation technique, the Ag/SiO2/VO2/Ag/VO2 multilayer structure can achieve double band strong absorption in the mid-infrared, and dynamically adjust the absorption performance through VO2. The simulation results demonstrate a remarkable absorption rate of 91.8% and 98.9% at 9.09 µm and 10.25 µm, respectively. The high absorption is elucidated by analyzing the field strength distribution in each layer. Meanwhile, based on the phase change characteristics of VO2, the absorber has exceptional thermal regulation, with a remarkable 78% heat regulation range in the mid-infrared band. The size altering of the absorbing layer is effective in enhancing and optimizing the structure's absorption performance. The structure is used to characterize probe molecules of CV and R6 G by mid-infrared spectroscopy, which illustrates an impressive limit of detection (LOD) of 10-7 M for both substances. These results provide valuable insights for designing future high-performance tunable optical devices.

Wavelength Tunable Infrared Perfect Absorption in Plasmonic Nanocrystal Monolayers.

The ability to efficiently absorb light in ultrathin (subwavelength) layers is essential for modern electro-optic devices, including detectors, sensors, and nonlinear modulators. Tailoring these ultrathin films' spectral, spatial, and polarimetric properties is highly desirable for many, if not all, of the above applications. Doing so, however, often requires costly lithographic techniques or exotic materials, limiting scalability. Here we propose, demonstrate, and analyze a mid-infrared absorber architecture leveraging monolayer films of nanoplasmonic colloidal tin-doped indium oxide nanocrystals (ITO NCs). We fabricate a series of ITO NC monolayer films using the liquid-air interface method; by synthetically varying the Sn dopant concentration in the NCs, we achieve spectrally selective perfect absorption tunable between wavelengths of two and five micrometers. We achieve monolayer thickness-controlled coupling strength tuning by varying NC size, allowing access to different coupling regimes. Furthermore, we synthesize a bilayer film that enables broadband absorption covering the entire midwave IR region (λ = 3-5 μm). We demonstrate a scalable platform, with perfect absorption in monolayer films only hundredths of a wavelength in thickness, enabling strong light-matter interaction, with potential applications for molecular detection and ultrafast nonlinear optical applications.

Tunable broadband metamaterial absorber with voltage and temperature modulation

It is well known that VO2 has temperature-controllable phase transition properties, and that graphene surface conductivity's can be changed by applying a gate voltage to control the Fermi energy level. On the basis of temperature and voltage controllability, we numerically simulate a broad-band mid-infrared absorber. The metamaterial absorber (MA) operates in the mid-infrared band of 7∼30 μm, and when VO2 is in the metallic state, the absorption bandwidth can reach 9 μm and the average absorption can reach 98%. The absorption bandwidth is temperature-adjustable. By maintaining graphene's Fermi energy level (EF) at 0.4 EF. When VO2 transitions between insulating and metallic states, MA can achieve mid-infrared narrowband-broadband interconversion. When VO2 is in the insulating state, tuning the EF of graphene, MA can achieve single-peak and double-peak absorption in mid-infrared wavelength, respectively. When VO2 is in the metallic state, the EF can be used to dynamically modulate the absorption bandwidth. The MA reveals its thermal switching properties. This research is expected to have promising future applications in the fields of multiparameter tunable optical devices, temperature sensing, infrared detection, etc.

Ultra-broadband mid-infrared absorber based on hyperbolic α-MoO3

Owing to their broad operational bandwidth, broadband absorbers are extensively used in various applications, such as solar cells, microbolometers, and light modulators. To enhance energy harvesting, it is essential to achieve insensitivity to wide incident angles and polarization-independent absorption. α-MoO3 is a natural polar van der Waals crystal that hosts phonon polaritons in the mid-infrared spectral region. These polaritons can manipulate the infrared light at the nanoscale and break the diffraction limit, offering a great opportunity for the design of broadband absorbers. In this study, we propose a strategy based on an array of crossed the permittivity of α-MoO3 in [100] and [001] crystallographic axes to expand its broadband absorption. Triangular one-dimensional grating pattern is initially considered, which shows an ultra-broadband and wide-angle insensitive absorption within the range of 10.23–18.07 μm. Subsequently, square pyramidal two-dimensional arrays are investigated, which not only show ultra-broadband absorption and wide-angle insensitivity, but also exhibit polarization independence within the range of 10.46–18.32 μm. This remarkable broadband absorption is elucidated by the effective medium theory and the local power dissipation density. These results demonstrate an effective strategy for constructing ultra-broadband absorbers based on α-MoO3 for applications in solar thermal and photovoltaic systems.

Tunable Environment-Enhanced Mid-Infrared Absorber Based on Voltage Modulation

Tunable Environment-Enhanced Mid-Infrared Absorber Based on Voltage Modulation

High-damage-threshold mid-infrared saturable absorber enabled by tantalum carbide nanoparticles.

A stable mid-infrared saturable absorber with a high damage threshold is urgently required for high-performance optical modulation in the mid-infrared regime. Here, we demonstrate stable mid-infrared erbium-doped fiber laser generation modulated by tantalum carbide nanoparticles (TaC NPs) experimentally. The TaC NPs show high physicochemical stability, obvious nonlinear optical absorption, and a high damage threshold. By introducing the TaC-based saturable absorber into an erbium-doped fiber laser, stable nanosecond pulses can be successfully delivered with a minimum pulse duration of 575 ns and signal-to-noise ratio of over 40 dB. The experimental results show that TaC NPs can act as a stable mid-infrared pulse modulator, and may make inroads for developing highly stable broadband optoelectronic devices.

Numerical study of a near-infrared to mid-infrared perfect absorber based on tunable GaAs metamaterial

An infrared perfect absorber structure is designed based on GaAs/Au/SiO2 metamaterial with numerical simulation, in which gold split ring resonators (SRR) embedded in the GaAs layer. The absorption exceeds 99% at 1360 nm under the plane wave excitation with its polarization perpendicular to the opening direction of the SRR. When the polarization of the plane wave is parallel to the opening direction, the absorption exceeds 97% and 56% at 970 and 2070 nm, respectively, which realize dual-band absorption. The absorption peaks are effectively modulated by controlling surface current density distribution and resonant electromagnetic response. In addition, the resonant wavelengths are further manipulated by optimizing the resonant ring structural parameters, which achieve ultrawide-band absorption ranging from near-infrared to mid-infrared region. The absorber remains absorption peaks above 96% under wide-angle plane wave incidence, and the resonant peak positions are independent of the incident angle. This work exhibits the promise of GaAs-based metamaterial in practical applications in energy harvesting and night vision imaging.

Exploring the resonance absorption of subwavelength-patterned epitaxial-grown group-IV semiconductor composite structures.

We experimentally and theoretically demonstrate a mid-infrared perfect absorber with all group-IV epitaxial layered composite structures. The multispectral narrowband strong absorption (>98%) is attributed to the combined effects of the asymmetric Fabry-Perot (FP) interference and the plasmonic resonance in the subwavelength-patterned metal-dielectric-metal (MDM) stack. The spectral position and intensity of the absorption resonance were analyzed by reflection and transmission. While a localized plasmon resonance in the dual-metal region was found to be modulated by both the horizontal (ribbon width) and vertical (spacer layer thickness) profile, the asymmetric FP modes were modulated merely by the vertical geometric parameters. Semi-empirical calculations show strong coupling between modes with a large Rabi-splitting energy reaching 46% of the mean energy of the plasmonic mode under proper horizontal profile. A wavelength-adjustable all-group-IV-semiconductor plasmonic perfect absorber has potential for photonic-electronic integration.

High-quality factor mid-infrared absorber based on all-dielectric metasurfaces.

The absorption spectrum of metasurface absorbers can be manipulated by changing structures. However, narrowband performance absorbers with high quality factors (Q-factor) are hard to achieve, mainly for the ohmic loss of metal resonators. Here, we propose an all-dielectric metasurface absorber with narrow absorption linewidth in the mid-infrared range. Magnetic quadrupole resonance is excited in the stacked Ge-Si3N4 nanoarrays with an absorption of 89.6% and a Q-factor of 6120 at 6.612 µm. The separate lossless Ge resonator and lossy Si3N4 layer realize high electromagnetic field gain and absorption, respectively. And the proposed method successfully reduced the intrinsic loss of the absorber, which reduced the absorption beyond the resonant wavelength and improved the absorption efficiency of Si3N4 in the low loss range. Furthermore, the absorption intensity and wavelength can be modulated by adjusting the geometric parameters of the structure. We believe this research has good application prospects in mid-infrared lasers, thermal emitters, gas feature sensing, and spectral detection.

Design and analysis of Matts-shaped perfect metamaterial absorber using equivalent circuit model

A mid-infrared perfect metamaterial absorber (PMA) consisting of well-engineered unit cells, composed of metallic backed layer (Cu), dielectric layer (Al2O3), matts-shaped meta cell (Cu), and an anti-oxidation layer from bottom to top, is proposed in this paper. The electromagnetic response of the designed PMA is analyzed using 3D full-wave computational model. Our analysis demonstrates that the maximum absorption is enhanced to 99.9% at the resonance wavelength of 7.35 µm, which is caused by magnetic polaritons (MPs) resonance between the incident beam and magnetic polaritons formed by three fluxing currents. Specially, a three-circulation equivalent circuit model is proposed to predict the resonant wavelength of the designed PMA, which comprehensively considers the influence of coupling capacitance not only between neighboring unit cells, but also between the metal lines inside the top metal pattern for the first time. The influence of geometrical parameters on resonant wavelength is predicted by the equivalent circuit model proposed in this paper, and the prediction error is less than 5% as compared with that of computational analysis. With well-engineered plasmonic meta-atoms, the designed PMA presents the characteristics of angle and polarization- independent with a smaller relative size (0.245λ) and a thinner relative thickness (0.053λ). Besides, an obvious red-shift of the resonance frequency of PMA is observed as the permittivity of dielectric layers is increased. The approach of establishing equivalent circuit model will provide methods for the analysis of PMA based on MPs with complex electromagnetic behavior.

Ultra-broadband and tunable infrared absorber based on VO2 hybrid multi-layer nanostructure

We propose an ultra-broadband near- to mid-infrared (NMIR) tunable absorber based on VO2 hybrid multi-layer nanostructure by hybrid integration of the upper and the lower parts. The upper part is composed of VO2 nanocylinder arrays prepared on the front illuminated surface of quartz substrate, and VO2 square films and VO2/SiO2/VO2 square nanopillar arrays prepared on the back surface. The lower part is an array of SiO2/Ti/VO2 nanopillars on Ti substrate. The effects of different structural parameters and temperature on the absorption spectra were analyzed by the finite-difference time-domain method. An average absorption rate of up to 94.7% and an ultra-wide bandwidth of 6.5 μm were achieved in NMIR 1.5–8 μm. Neither vertical incident light with different polarization angles nor large inclination incident light has a significant effect on the absorption performance of the absorber. The ultra-broadband high absorption performance of this absorber will be widely used in NMIR photodetectors and other new optoelectronic devices.