Microwave Plasma Source Research Articles

Design, development and test of single beamlet microwave ion source with spot-dense plasma system

In this paper, an efficient ion source with unique characteristics is introduced and proposed. It outlines the generation of a spot-dense plasma just below the plasma electrode aperture of the extractor system through the utilization of a 2.45 GHz microwave plasma source with a power of 1000 W, in the absence of a magnetic field. This source utilizes a 2.45 GHz microwave plasma generator operating at 1000 W, resulting in the generation of a spot-dense plasma just below the plasma electrode aperture of the extractor system, all achieved without the need for a magnetic field.The spot-dense plasma results in the extraction of an ion beam with high current density. Furthermore, the suggested ion source can be utilized in a smaller size using a higher frequency. Therefore, our findings indicate that the proposed method not only substantially enhances the extracted positive ion beam current but also significantly reduces the size of the ion beam source system. Based on the design and simulation results, an experimental model of the ion beam source is constructed. The diagnostic tools provided the beam current density and system efficiency values of 99mA/cm2 and 7×10−6A/W, respectively.

A high-performance microwave plasma source employing dielectric wedges

A high-performance microwave plasma source employing dielectric wedges

Development and Characterization of a Novel Microwave Plasma Source for Enhanced Healing in Wound Treatment

Our study explores the potential of a novel microwave plasma source for enhancing wound healing in BALB-C mouse models. Chronic wounds, particularly in diabetic individuals, present significant challenges due to impaired regenerative capacity. Cold Atmospheric Plasma (CAP) has emerged as a promising approach, offering diverse therapeutic benefits. However, its specific efficacy in the context of diabetic wounds remains underexplored. We developed and characterized a microwave plasma source optimized for wound treatment, inducing acute wounds and treating them with CAP in a controlled experimental setup. The treated group exhibited accelerated wound closure compared to controls, suggesting CAP’s potential to enhance the healing process. Our findings underscore CAP’s multifaceted impact on the wound healing cascade, highlighting its ability to promote angiogenesis, modulate inflammatory responses, and exhibit antimicrobial properties. These results position CAP as a promising intervention in acute wound management, paving the way for further exploration of its therapeutic potential in clinical settings.

A new 915 MHz coaxial-line-based microwave plasma source

Microwave plasma is known for its versatility in providing tailored operating conditions (pressure, working gas composition and residence time of reagents) for specific applications. Microwave plasma sources (MPSs) are vital in modern applications, demanding continuous improvement. This work introduces a coaxial-line-based nozzleless MPS that operates at atmospheric pressure at an unique frequency of 915 MHz. The measured electrodynamic characteristics in nitrogen of the MPS highlighted the need for improved energy efficiency of the device. The main novelty of this work lies in improving an energy efficiency of the presented MPS, which led to an advanced new version of the device. To achieve this, a dual strategy is employed. Firstly, numerical simulations are used to design a construction modifications to the MPS, which should increase the efficiency of transferring microwave energy from the microwave source to the generated plasma. In this step, a standard model for homogeneous plasma and a two-port equivalent method were used. Then, the theoretical results were experimentally validated by manufacturing a new energy improved version of the MPS. In the new MPS the achieved reflected microwave power (losses) was less than 3% of incident microwave power in the tested range of nitrogen flow rate (50–100 Nl/min). Compared to the MPS before improvement, this means a two-fold decreasing the reflected microwave power. To test the new MPS, the electrodynamic characteristics of the new device version and properties of the microwave plasma generated in nitrogen, using optical emission spectroscopy (OES), were investigated. The OES was used to determine the vibrational Tvib and rotational Trot temperatures of nitrogen molecules and molecular ions. In this work, the estimated Tvib and Trot temperatures for nitrogen molecules ranged from 4000 to 5300 K, depending on discharge conditions, while for nitrogen molecular ions, the temperatures changed between 4700 and 6100 K, respectively. Both the Tvib and Trot temperatures decrease linearly along the plasma flame.

Atmospheric pressure microwave (915 MHz) plasma for hydrogen production from steam reforming of ethanol

This work presents experimental results on the energy efficiency in hydrogen production using atmospheric microwave plasma (915 MHz) through steam reforming of ethanol. Ethanol was chosen as a liquid hydrogen carrier due to its high hydrogen atom content, low cost, and wide availability. The experimental work began with the maximization of an energy efficiency of the used microwave plasma source. The process of maximization involved determining a position of a movable plunger that ensures the most efficient transfer of microwave energy from a microwave source to the generated plasma in the microwave plasma source. The aim of the investigations was to test the following working conditions of the microwave plasma source: absorbed microwave power PA by the generated plasma (up to 5.4 kW), the carrier gas volumetric flow rate (up to 3900 Nl/h), and the amount of the introduced ethanol vapours on the efficiency of hydrogen production (up to 2.4 kg/h). In the range of tested working conditions, the highest energy yield for hydrogen production achieved a rate of 26.9 g(H2)/kWh, while the highest hydrogen production was 99.3 g(H2)/h.

Microwave plasma-assisted hydrogen production via conversion of CO2–CH4 mixture

A method concerning re-use of the main greenhouse gases: CO2 and CH4 at the same time producing value-added chemicals (H2 + CO) is presented in this paper. The method involves the methane dry reforming using an atmospheric pressure operated 915 MHz microwave plasma source with a swirl gas flow. The effect of the CO2 to CH4 flow rates ratio, the total gas flow rate and the absorbed microwave power on the volume concentration of the gaseous plasma component in the outlet gas (%), CO2 and CH4 conversion rate (%), hydrogen production rate (g h−1) and energy yield of hydrogen production (g kWh−1) was investigated experimentally. The recorded results of the CO2 and CH4 conversion rate were about 82% and 88%, respectively. The best results in terms of the hydrogen production rate and energy yield of hydrogen production were equal to 156 g h−1 and 24 g kWh−1, respectively.

Improving the Power Efficiency of a Microwave Plasma Source by Using the Principle of a Variable-Impedance Waveguide

Microwave plasma sources are used in various applications, but inefficiency can limit their usefulness. Researchers have investigated a new approach with which to improve efficiency by using a waveguide with a special tuner. A standard waveguide was compared to one equipped with a stub tuner, which allows for the fine-tuning of the electrical properties. The experiment used a frequency of 2.45 GHz and tested input powers of 1 kW and 1.5 kW. Experiments showed that waveguides with tuners transferred power more efficiently, with fewer reflected and more transmitted microwaves. While peak temperatures remained similar, the tuned waveguide produced a hotter plasma flame (30–60 °C) at the same distance. Notably, increasing the input power further boosted the flame temperature by 300 °C. These findings suggest that stub tuners can significantly improve the efficiency of microwave plasma sources. This paves the way for more efficient plasma generation technologies and potentially allows for applications requiring even higher power.

Experimental investigations of plasma-assisted ammonia combustion using rod-electrode-type microwave plasma source

Ammonia have been attractive as one of the alternative fuels for reducing greenhouse gas (GHG) emissions. However, ammonia combustion has lower combustion performance than common hydrocarbon fuels. Furthermore, it may emit nitrous oxide (N2O), which is one of the GHGs. This paper presents the experimental investigations of plasma-assisted ammonia combustion (PAAC) using a rod-electrode-type microwave plasma source (MPS) at atmospheric pressure. The equivalence ratios of premixed ammonia/dry air (NH3/Air) gas are set below the stoichiometric combustion of NH3 to reduce toxic NH3 in the combustion gas. Under the condition of the equivalence ratios, the experiments are focused on reducing the unburned NH3 and produced N2O concentrations in the combustion gas. In the experiments, the unburned NH3, nitrogen oxide (NOx) (the sum of nitric oxide (NO) and nitrogen dioxide (NO2)), and N2O concentrations in the combustion gas are investigated in terms of the flow velocity of premixed NH3/Air gas inside the rod-electrode-type MPS and the transmission power to the rod-electrode-type MPS. In conclusion, the rod-electrode-type MPS is identified to be useful for PAAC. The NH3 and N2O concentrations in the combustion gas reach approximately 25 and 4 parts per million (ppm), respectively, under the conditions of the equivalence ratio of 1.0, flow velocity of approximately 0.167 m/s, and transmission power of about 84 W. At that time, the NOx concentration is approximately 4300 ppm, and the power transmission efficiency is approximately 68 %.

Cold Atmospheric Plasma Improves the Colonization of Titanium with Primary Human Osteoblasts: An In Vitro Study.

Several studies have shown that cold atmospheric plasma (CAP) treatment can favourably modify titanium surfaces to promote osteoblast colonization. The aim of this study was to investigate the initial attachment of primary human osteoblasts to plasma-treated titanium. Micro-structured titanium discs were treated with cold atmospheric plasma followed by the application of primary human osteoblasts. The microwave plasma source used in this study uses helium as a carrier gas and was developed at the Leibniz Institute for Surface Modification in Leipzig, Germany. Primary human osteoblasts were analyzed by fluorescence and cell biological tests (alkaline phosphatase activity and cell proliferation using WST-1 assay). The tests were performed after 4, 12, and 24 h and showed statistically significant increased levels of cell activity after plasma treatment. The results of this study indicate that plasma treatment improves the initial attachment of primary human osteoblasts to titanium. For the first time, the positive effect of cold atmospheric plasma treatment of micro-structured titanium on the initial colonization with primary human osteoblasts has been demonstrated. Overall, this study demonstrates the excellent biocompatibility of micro-structured titanium. The results of this study support efforts to use cold atmospheric plasmas in implantology, both for preimplantation conditioning and for regeneration of lost attachment due to peri-implantitis.

Deposition of vertical carbon nanostructures by microwave plasma source on nickel and alumina

Vertical carbon nanostructures on metal and ceramic substrates are deposited successfully using planar microwave plasma source at frequency of 2.45 GHz. The PECVD (Plasma Enhanced Chemical Vapor Deposition) with microwave surface wave discharge is applied because it produces a dense plasma providing efficient decomposition of the methane and creation of a large number of reactive particles which results in lower substrate temperature for graphene deposition compared to CVD method. Optimization of the gas mixture of H2, Ar and CH4, and the gas pressure in the chamber results in a homogeneous graphene structures deposition on the substrates of Ni-foil, Ni-foam and alumina ceramics at substrate temperatures ∼600 °C. The plasma parameters of surface wave discharge such as gas temperature, electron temperature and density are obtained by measuring OH-band and Ar-lines using optical emission spectroscopy. The morphology of the vertical carbon structures is obtained using SEM analysis and the characteristics of the graphene layers were determined by Raman spectroscopy.

Pure ammonia direct decomposition using rod-electrode-type microwave plasma source

This paper presents the experimental results of ammonia (NH3) decomposition without catalyst and dilution using a rod-electrode-type microwave plasma source (MPS) at atmospheric pressure. The direct decomposition ratio of pure NH3 was investigated in relation to the flow rate into the rod-electrode-type MPS and the average transmission power to the rod-electrode-type MPS. The decomposition ratio increased with decreasing the flow rate and with increasing the average transmission power. For example, the decomposition ratio was demonstrated to exceed 40 % at the flow rate of 0.2–0.8 L/min and the average transmission power of about 63–166 W. The highest decomposition ratio was approximately 84 % at the flow rate of 0.2 L/min and the average transmission power of approximately 112 W, and the hydrogen yield was approximately 90 %.

Three-dimensional modeling of microwave discharges in a waveguide-based plasma source with experimental comparison.

This paper proposes a transient three-dimensional model to simulate microwave-induced discharges in a waveguide-based plasma source under intermediate pressures. A plane-symmetric simplification method is applied to simplify half of the microwave plasma source in the calculation domain, dramatically reducing the demand for computational resources and calculation time. Meanwhile, the numerical simulations remain in three dimensions without dimensionality reduction, which allows us to directly calculate the efficiency of power coupling from the incident microwave to the plasma. Besides, the computation decrease improves the convergence performance of the mathematical model, making it possible to model the entire discharge process from 1×10^{-9} to 1×10^{4}s. This period covers the instantaneous microwave breakdown to the formation of a stable plasma column near steady state. The results have revealed the electromagnetic waveguide structure change of the microwave plasma source during the discharge process. Several microwave power-coupling efficiencies of the waveguide-based plasma source with different thicknesses and permittivities of the glass tube are calculated and compared with the experimentally measured data. Furthermore, the effects of the glass tube on the electromagnetic modes of the traveling microwave propagating along the plasma column and the discharge properties are also investigated. The numerically obtained results generally agree with the theoretical analysis and the experimental data in our previous studies, demonstrating the validity of the proposed mathematical model and the plane-symmetric simplification method.

A Coaxial Atmospheric Microwave Plasma Source With Low-Generating Power

A Coaxial Atmospheric Microwave Plasma Source With Low-Generating Power

Experimental Progress in the Development of a Metal Foil Pump for DEMO

Experimental findings to contribute to the preliminary design of a metal foil pump for fuel separation in the Direct Internal Recycling loop of the DEMO fusion device are presented. In parametric studies on a small-scale superpermeation experiment with a microwave plasma source and two different metal foil materials, niobium Nb and vanadium V, a substantial increase in permeation with plasma power and with a decrease in pressure was observed. To ease operation in the typical fusion environment, in-situ heating procedures were developed to recover from impurity contamination. The temperature independence of plasma-driven permeation from 600 to 900 °C metal foil temperature was demonstrated. No proof of an isotopic effect for plasma-driven permeation of protium and deuterium could be found. The highest repeatable permeation flux achieved was 6.7 Pa∙m3/(m2∙s) or ~5.5 × 10−3 mol H/(m2∙s). The found compression ratios do safely allow the operation of the metal foil pump using ejector pumps as backing stages for the permeate. In a dedicated experimental setup, the operation of the plasma source in a strong magnetic field was tested. Parametric studies of pressure, power input, magnetic flux density, field gradient and field angle are presented.

Design and Study of a Large-Scale Microwave Plasma Torch with Four Ports

The microwave plasma torch (MPT) has gained popularity in industrial applications due to its high energy density, ionization levels, and high temperature. However, the non-uniform and unstable plasma generated by microwave plasma sources has limited the production of large-scale MPTs. This paper proposes a novel MPT device utilizing a four-port microwave source (2.45 GHz, 4 kW) to address these issues. The improved plasma uniformity and stability are achieved through the new structure, and the microwave efficiency is enhanced by introducing the focusing dielectric in the coupled cavity. Using a 3D electromagnetic field model, microwave plasma model and fluid model, the paper optimizes the geometry and inlet mode of the MPT device. Experimental results show that the novel MPT device can generate a plasma torch with a maximum height of 545 mm, a working range of 10–95 L/min, and a microwave efficiency up to 86%. The proposed device not only competently meets industrial requirements, but also provides design ideas and methods for future MPT devices.

High Entropy Borides Synthesized by the Thermal Reduction of Metal Oxides in a Microwave Plasma.

Metal oxide thermal reduction, enabled by microwave-induced plasma, was used to synthesize high entropy borides (HEBs). This approach capitalized on the ability of a microwave (MW) plasma source to efficiently transfer thermal energy to drive chemical reactions in an argon-rich plasma. A predominantly single-phase hexagonal AlB2-type structural characteristic of HEBs was obtained by boro/carbothermal reduction as well as by borothermal reduction. We compare the microstructural, mechanical, and oxidation resistance properties using the two different thermal reduction approaches (i.e., with and without carbon as a reducing agent). The plasma-annealed HEB (Hf0.2, Zr0.2, Ti0.2, Ta0.2, Mo0.2)B2 made via boro/carbothermal reduction resulted in a higher measured hardness (38 ± 4 GPa) compared to the same HEB made via borothermal reduction (28 ± 3 GPa). These hardness values were consistent with the theoretical value of ~33 GPa obtained by first-principles simulations using special quasi-random structures. Sample cross-sections were evaluated to examine the effects of the plasma on structural, compositional, and mechanical homogeneity throughout the HEB thickness. MW-plasma-produced HEBs synthesized with carbon exhibit a reduced porosity, higher density, and higher average hardness when compared to HEBs made without carbon.

Microwave ion source with dual helical antenna for diagnostics neutral beam of ALBORZ tokamak

An efficient ion source of the diagnostic neutral beam injection (DNBI) is designed and simulated for Alborz Tokamak, based on the microwave plasma source. The diagnostic neutral beam is designed for use in some diagnostics system such as charge-exchange recombination spectroscopy (CXRS), Rutherford Scattering (RS), and Motional Stark Effect (MSE) of Alborz Tokamak. In this work, a new helical antenna is designed and simulated for a microwave plasma source, to reach a plasma density of order8.23×1017m−3. The microwave plasma source is employed by the high-efficient ion beam accelerator. In this simulation, three-electrodes in different potentials of 20 kV, −2 kV, and grounded respectively, are used as extraction system of the ion beam source. According to our design, nine apertures grids are considered for the accelerator system. The simulation results show that, the system can extract an ion beam with energy and current of 20 keV and 60 mA respectively. The extracted ion beam consists of nine beamlets, where the beam waist and the current of each of them are calculated about 3 mm and 6.5 mA, respectively. The results of this work indicate that the ion beam with minimum divergence angle of 32 mrad can be generated by the proposed ion beam source.

Hydrogen production by the steam reforming of synthetic biogas in atmospheric-pressure microwave (915 MHz) plasma

This paper is a contribution to the development of microwave plasma-based technology aimed at efficient hydrogen (H2) production from a so-called synthetic biogas, considered a mixture of methane (CH4) and carbon dioxide (CO2), which can contain up to 70% CH4. In this work, we tested the performance of a waveguide-supplied metal cylinder-based microwave plasma source (MPS) operating at 915 MHz at atmospheric pressure as a tool for the efficient production of H2 in the steam reforming of the synthetic biogas. The test showed that the steam reforming of the synthetic biogas could be carried out under a wide range of working parameters without soot formation and extinction of the microwave discharge. We found that there is a minimal H2Osteam consumption rate for a given CH4 input volume content, which ensures stable operation of the MPS (no soot). The experiments did not show that increasing the amount of H2Osteam rate above the minimal value for a given CH4 input volume content results in an increase in the H2 production rate, energy yield, CH4 conversion degree, and H2 output concentration. To describe the MPS performance, which also takes into account a factor of the utilization of the CH4 feedstock, we introduced a new parameter, called an energy–CH4 feedstock consumption yield. The best results in terms of the H2 production rate, the energy yield, and the CH4 conversion degree were 239 g[H2]/h 36.8 g[H2]/kWh, and 74.3%, respectively. This shows that the application of the steam reforming, instead of the dry reforming, resulted in a 1.5-fold increase of the H2 production rate and the corresponding energy yield.

Design and simulation of 2450 MHz microwave cavity for resonance and off-resonance plasma diagnosis in-situ plasma irradiation facility

The microwave plasma diagnosis in-situ irradiation system has been developed at the Central University of Punjab, Bathinda. The final design is achieved by a combination of analytical and simulation methods using CST and Comsol Multiphysics software. Simulations outcome reveals the electric field profile at the center of the microwave plasma chamber is strong and dense. A strong electric field profile inside the microwave cavity has been verified by the confinement of the plasma in the absence of an external magnetic field. The magnetic field profile for the 2450 MHz microwave facility is simulated and confirmed experimentally. Different RF powers and working gas pressures have been used with Langmuir probes to record the plasma signal. As a second stage, we studied the practicality of using a plasma cavity to treat materials with plasma for materials science experiment in plasma environment. This work shows the results of a thorough computational analysis of a microwave plasma source that has been tested in lab.

Improvement in Wear Resistance of Grade 37 Titanium by Microwave Plasma Oxy-Carburizing

Grade 37 titanium is widely used in racing applications thanks to its oxidation resistance up to 650 °C, but it suffers from poor wear and fretting resistance, especially at high temperature. In this paper, different surface modification techniques, namely, carburizing, coating by PVD-ZrO2 and a novel microwave plasma oxy-carburizing treatment, are investigated in terms of hardness, wear resistance and scratch hardness, compared to the untreated substrate. Numerical simulation allowed optimization of the design of the microwave plasma source, which operated at 2.45 GHz at atmospheric pressure. The proposed microwave plasma oxy-carburizing treatment is localized and can serve to improve the tribological properties of selected regions of the sample; compared to untreated Grade 37 titanium, the oxy-carburized layer presents a decrease in the wear rate at 450 °C against alumina of 54% and an increase in scratch hardness of more than three times.