Microscopic Correlation Research Articles

Oleochemical carbonates: A comprehensive characterization of an emerging class of organic compounds

Dialkyl carbonates (DAC) with short-medium alkyl length - oleochemical carbonates – are attracting attention because of their appealing properties, including low viscosity, flammability, toxicity, environmental impact and wide range of applications: lubricants, personal care, fuel additives etc. However, not much is known concerning their chemical physical properties and, more importantly, on the nature of microscopic correlations that eventually determine bulk performances. In view of this paucity, we present a large exploration of a series of chemical physical properties of a set of DACs ranging from dimethyl up to didodecyl carbonate. This study extends previously determined databases, thus providing a complete picture of the temperature dependence of chemical physical properties around room temperature. Furthermore, we explored the microscopic morphology of DACs, by synergic exploitation of X-ray scattering and Molecular Dynamics techniques. These tools allow detecting the existence of a distinct degree of mesoscopic spatial segregation between polar carbonate moieties and apolar alkyl chains domains. The role of first neighbour carbonate moieties in driving the corresponding molecules towards weak hydrogen bonding interactions and alkyl chain alignment is described. Such an effect is related to the overall mesoscopic segregation of alkyl tails that isolate small droplets formed by stacked carbonate groups. Such a highly compartmentalised morphology can explain and potentially suggest applications of DACs in fields as relevant as separation, catalysis, lubrication etc.

Topical Formulation of Nano Spray-Dried Levocetirizine Dihydrochloride against Allergic Edema.

Levocetirizine dihydrochloride active ingredient was microencapsulated using nano spray-drying technology for preparing microparticles containing topical gel against edema. Hydroxyl propyl methyl cellulose (HPMC) was used as a carrier polymer during spray drying. The active ingredient content of the nano spray-dried products was 52.81% (w/w) and 51.33% (w/w) for ex vivo and in vivo experiments, respectively, and the average particle size was 2.6 µm. X-ray diffraction analysis indicated an amorphous state of the active ingredient embedded in the amorphous matrix of the polymer. Dermal oil gels composed of Miglyol 812 gelated by Dermofeel viscolid included 5% (w/w) (for ex vivo) and 10% (w/w) (for in vivo) active ingredient without or with 0.05% (w/w) menthol penetration enhancer. Qualitative ex vivo penetration studies using a confocal Raman microscopic correlation mapping were executed on human abdominal skin. The results showed that the active ingredient was enriched in the epidermis and upper dermis layer of the skin using oleogel loaded with the nano spray-dried drug-HPMC composite. Menthol addition to the oleogel resulted in the concentration of levocetirizine in the dermis. In vivo tests were performed on a mouse model of croton oil-induced ear edema. Negative control and Fenistil-treated groups were compared using the prepared oil gels with and without menthol. Without penetration enhancer, 20 µL of our oil gel loaded with nano spray-dried levocetirizine dihydrochloride composite showed similar effectiveness to the same volume of Fenistil gel, while 5 µL menthol containing sample was sufficient to eliminate the skin irritation similarly to 20 µL Fenistil.

The effect of vanadium on microstrain partitioning and localized damage during deformation of unnotched and notched DP1300 steels

The use of vanadium-microalloying in ultrahigh strength dual phase (DP) steels has been shown to yield a fine dispersion of nano-scale vanadium carbonitrides (V(C,N)) in ferrite along with a pronounced grain refinement, leading to enhanced micromechanical compatibility and increased local ductility. Here we present data on microstrain partitioning and the evolution of damage in vanadium-free (V-free) Fine-Grained (FG) and vanadium-added (V-added) Ultra Fine-Grained (UFG) DP steels, each with a UTS of about 1300 MPa (DP1300), using quasi in-situ tensile tests coupled with scanning electron microscopy, followed by microscopic Digital Image Correlation (µDIC). Quantitative analysis shows that the homogenization of microstrain between ferrite and martensite is locally enhanced and the strain gradients at the ferrite/martensite (F/M) interfaces reduced in the V-added steel. This trend was also evident in the V-added steel exhibiting different states of stress obtained with unique notched microtensile specimen designs. Three different µDIC-based computational techniques were used to quantify the extent of microstrain partitioning, in order to determine the mechanistic basis for the increase in true strain to fracture with vanadium-microalloying. This work was supplemented with damage evolution studies in both V-free and V-added materials using high resolution, field emission scanning electron microscope (FESEM) imaging, and X-ray computed microtomography (µXCT). These corroborate the microscopic analyses and confirm that both vanadium-microalloying and stress-state impacts the local strain gradient at ferrite/martensite (F/M) interfaces, and thereby changes the way damage is initiated and grows within the material.

Multi-temporal relations between runoff and sediment load based on variable structure cointegration theory

Microscopic and macroscopic multi-temporal correlations between runoff and sediment load were analyzed to reveal the relations between them in the source region of the Yellow River using the complete ensemble empirical mode decomposition with adaptive noise method (CEEMDAN) and cointegration theory. Subsequently, multi-temporal models of runoff and sediment load with structural breaks were developed. The results revealed the following points. (1) The runoff and sediment load relations differed at multi-time scales. Multi-temporal cointegration could reveal the relation between runoff and sediment load at micro scales. (2) A comparison of the original model, composite model 1, and composite model 2 revealed that the multi-temporal cointegration model is better than the original model. (3) The variable structure cointegration model of the runoff and sediment load relation had the highest simulation accuracy, and the smallest average relative error for the simulated runoff was 7.82%. Composite model 2 could more accurately reflect the long-term equilibrium and short-term fluctuating relations between the runoff and sediment load in the source region of the Yellow River.

In Situ Measurement of Cyclic Plastic Zone and Internal Strain Response of Q&P Steel near Fatigue Crack Tip Region Based on Micro-DIC.

The shape and internal dynamic response characteristics of the plastic zone near the fatigue crack tip region, especially the cyclic plastic zone (CPZ), are the main factors affecting the fatigue crack initiation and propagation behaviors of ductile metal materials. The existing methods for characterizing the CPZ have some problems, which include the complexity of the process, the difficulty of achieving in situ measurement, and the inability to characterize the dynamic response in the CPZ during the crack propagation process. Therefore, a novel method is proposed for the in situ measurement of the CPZ near the crack tip region based on image stitching and matching algorithms, a load–strain loop curve characteristic judgement algorithm, and the microscopic digital image correlation (DIC) method. A microscopic camera and a macroscopic camera are used to simultaneously capture the micro crack tip speckle images and the global crack image of the two sides of the Compact Tension (CT) specimen for calculating in situ crack length and crack tip strain fields. The proposed method was performed and verified by a fatigue crack growth (FCG) test and micro-hardness experiments with Quenching and Partitioning 980 (Q&P980) steel, and the results show that the method is feasible because the maximum error is less than 5%. A “butterfly wings” shape of the CPZ and a strain concentration phenomenon in the CPZ of the Q&P980 were observed. Moreover, as the fatigue crack propagates, the area of the CPZ and the degree of the strain concentration increase gradually. This method, which can obtain the in situ and tracking measurements of the crack tip CPZ, will help to increase our understanding of CPZ characteristics, the FCG mechanism, and the behavior of Q&P steel and the plastic metal materials similar to Q&P steel.

Research on the Evolution Law Physical Short Fatigue Crack and Tip Deformation Fields during Crack Closure Process of the Q&P Steel.

In this paper, a novel dual microscopic fatigue-crack and tip-deformation-fields measurement method based on a hybrid image-processing technique is proposed that was used to research the physical short fatigue crack (SFC) closure effect and the evolution law of the tip deformation fields of Quenching–Partitioning (Q&P) steel during the crack-closure process. The measurement problems are solved, such as the small SFC tip region, large deformation gradient, and strong material anisotropy. Microscopic crack and speckle images are acquired simultaneously on both sides of a compact tensile (CT) specimen of Q&P steel by dual microscopic cameras. A digital image processing (DIP) method is used to identify crack-growth morphology and measure crack length in Q&P steel, and the SFC growth rates are analyzed under different stress ratios. Microscopic digital image correlation (Micro-DIC) is used to analyze displacement fields at the crack tip of SFC and, combined with virtual extensometer technology, analyze the evolution law of crack closure and the evolution of crack-growing morphologies during the closure process under different lengths and stress ratios. Accordingly, the evolution of strain fields at the crack tip in one load cycle for different crack lengths and stress ratios during the SFC closure process is analyzed. The results show that the stress ratio affects the crack-closure behavior and crack growth rate of Q&P steel in the physical SFC crack-growing stage. The crack-closure effect has an obvious influence on the evolution process of displacement and strain fields at the crack tip. The evolution of short-fatigue-crack-tip morphology and strain field of Q&P steel conforms to the crack-closure law. The research results provide experimental and theoretical support for the further study of the SFC growth mechanism and fatigue life prediction of Q&P steel.

In Situ Measurement of the Strain Field at the Fatigue Crack Tip Based on Sub-Image Stitching and Matching DIC.

Studying the in situ measurement and evolution of the strain field at the crack tip during fatigue crack growth (FCG) is of great significance for understanding the fracture characteristics of materials and predicting fatigue life. Herein, a new method is proposed for the in-situ measurement of the strain field at the fatigue crack tip based on microscopic digital image correlation (DIC). The method proposed solves the problem of the existing in situ strain field measurement method being unable to dynamically track the crack tip and take the crack tip image due to the limitation of the field of view of the microscopic camera. A macroscopic camera is used to capture the global crack images on one side of the compact tension (CT) specimen. Meanwhile, a microscopic camera is used to track and capture the crack propagation speckle image on the other side of the CT specimen. The proposed method was verified by experiments with Quenching and Partitioning 980 (Q&P980) steel, and the results showed that the method has high accuracy, with the average measurement error being less than 5% and the maximum error being less than 10%. A butterfly shape of the measured strain field and the strain concentration near the crack tip were observed. The success of this method will help to obtain better insight into and understanding of the fracture behavior of metal materials as well as precise prediction of the fatigue life of metal materials.

3D stress mapping reveals the origin of lithium-deposition heterogeneity in solid-state lithium-metal batteries

Solid-state lithium-metal batteries possess intrinsic advantages in terms of both safety and energy density. However, the fundamental origin of electrochemical lithium deposition heterogeneity in solid-state batteries is much less understood than that in lithium-metal batteries using a liquid electrolyte, partly due to the difficulties of directly mapping lithium-deposition reaction fronts and the associated changes in local stress of the solid-state electrolyte. Here, we trace the evolution of three-dimensional microscopic stress and demonstrate that the stress distribution is rather broad in a garnet solid-state electrolyte during processing and battery cycling using confocal Raman spectroscopy. We further discuss the effect of local stress variations on the overpotential of lithium deposition as the most likely origin of lithium-deposition heterogeneity in garnet systems. The ex situ stress-mapping tool developed in this work provides a strong basis for understanding the electromechanical effects, a prerequisite to fully unlock the potential of solid-state lithium-metal batteries. • A method for multi-dimensional microscopic stress mapping is established • Tensile regions are converted to compressive upon extended cycling • Local stress difference and lithium-deposition heterogeneity are quantitatively linked The microscopic correlation between mechanical stress and electrochemical lithium deposition remains elusive when studying the origin of lithium-deposition heterogeneity. Hu et al. gain insights with a newly developed 3D microscopic stress mapping method.

An examination of local strain fields evolution in ductile cast iron through micromechanical simulations based on 3D imaging

Microscopic digital volume correlation (DVC) and finite element precoalescence strain evaluations are compared for two nodular cast iron specimens. Displacement fields from \textit{in-situ} 3D synchrotron laminography images are obtained by DVC. Subsequently the microstructure is explicitely meshed from the images considering nodules as voids. Boundary conditions are applied from the DVC measurement. Image segmentation-related uncertainties are taken into account and observed to be negligible with respect to the differences between strain levels. Macroscopic as well as local strain levels in coalescing ligaments between voids nucleated at large graphite nodules are compared. Macroscopic strain levels are consistently predicted. A very good agreement is observed for one of the specimens, while the strain levels for the second specimen presents some discrepancies. Limitations of the modeling and numerical framework are discussed in light of these differences. A discussion of the use of strain as coalescence indicator is initiated.

Design of pure aluminum laminates with heterostructures for extraordinary strength-ductility synergy

• Pure aluminum laminates with various heterostructures were engineered via extrusion, rolling and annealing. • The designed laminates exhibited an excellent strength-ductility synergy. • The evolution of GNDs was observed using in-situ tension. • The strain gradient across the hetero-interface was revealed using DIC technique. • Hetero-deformation induced (HDI) strengthening and hardening contributed to the superior mechanical properties. Heterogeneous metals and alloys are a new class of materials with superior mechanical properties. In this paper, we engineered sandwich-structured pure aluminum laminates composed of middle coarse-grained layer and outer fine-grained layer via extrusion, rolling and annealing. By controlling the post-annealing regimes, a larger degree of microstructure heterogeneities such as boundary spacing, misorientation and texture across the hetero-interface were obtained, which resulted in obvious mechanical differences. Tensile tests indicated that the 300 °C/30 min annealed laminates enabled a relatively high tensile ductility while simultaneously retaining a high strength, which was better than prediction by the rule-of-mixture. To explain the reasons behind it, the evolution of geometrically necessary dislocations and strain gradient at the hetero-interface zone were detected using in-situ tension and microscopic digital image correlation technique. It was found that with the increasing applied strain, a significant strain gradient was developed near the interface, which was accommodated by geometrically necessary dislocations, thereby contributing to higher hetero-deformation induced (HDI) strengthening and hardening.

Magnetism of two-dimensional honeycomb layered Na2Ni2TeO6 driven by intermediate Na-layer crystal structure

The microscopic spin-spin correlations in the 2D layered spin-1 honeycomb lattice compound Na2Ni2TeO6 have been investigated by neutron diffraction and inelastic neutron scattering. The honeycomb lattice of spin-1 Ni2+ ions, within the crystallographic ab planes, are well separated along the c axis by an intermediate Na layer whose crystal structure contains chiral nuclear density distributions of Na ions. The chirality of the alternating Na layers is opposite. Such alternating chirality of the Na layer dictates the magnetic periodicity along the c axis where an up-up-down-down spin arrangement of the in-plane zigzag AFM structure is found. Besides, the above described commensurate (CM) zigzag AFM order state is found to coexist with an incommensurate (ICM) AFM state below the TN ~ 27.5 K. The ICM state is found to appear at much higher temperature ~ 50 K and persists down to lowest measured temperature of 1.7 K. Our reverse Monte Carlo (RMC) analysis divulges a two dimensional (2D) magnetic correlations (within the ab plane) of the ICM AFM state over the entire temperature range 1.7-50 K. Further, the spin-Hamiltonian has been determined by carrying out inelastic neutron scattering experiments and subsequent linear spin-wave theory analysis which reveals the presence of competing inplane exchange interactions up to 3 rd nearest neighbours consistent with the zigzag AFM ground state, and weak interplanar interaction as well as a weak single-ion-anisotropy. The values of the exchange constants yield that Na2Ni2TeO6 is situated well inside the zigzag AFM phase (spans over a wide ranges of J2/J1 and J3/J1 values) in the theoretical phase diagram. The present study, thus, provides a detailed microscopic understanding of the magnetic correlations and divulges the intertwining magneto-structural correlations.

Universal microscopic spectrum of the unquenched QCD Dirac operator at finite temperature

In the ε-regime of chiral perturbation theory the spectral correlations of the Euclidean QCD Dirac operator close to the origin can be computed using random matrix theory. To incorporate the effect of temperature, a random matrix ensemble has been proposed, where a constant, deterministic matrix is added to the Dirac operator. Its eigenvalue correlation functions can be written as the determinant of a kernel that depends on temperature. Due to recent progress in this specific class of random matrix ensembles, featuring a deterministic, additive shift, we can determine the limiting kernel and correlation functions in this class, which is the class of polynomial ensembles. We prove the equivalence between this new determinantal representation of the microscopic eigenvalue correlation functions and existing results in terms of determinants of different sizes, for an arbitrary number of quark flavours, with and without temperature, and extend them to non-zero topology. These results all agree and are thus universal when measured in units of the temperature dependent chiral condensate, as long as we stay below the chiral phase transition.

Random generators of Markovian evolution: A quantum-classical transition by superdecoherence.

Continuous-time Markovian evolution appears to be manifestly different in classical and quantum worlds. We consider ensembles of random generators of N-dimensional Markovian evolution, quantum and classical ones, and evaluate their universal spectral properties. We then show how the two types of generators can be related by superdecoherence. In analogy with the mechanism of decoherence, which transforms a quantum state into a classical one, superdecoherence can be used to transform a Lindblad operator (generator of quantum evolution) into a Kolmogorov operator (generator of classical evolution). We inspect spectra of random Lindblad operators undergoing superdecoherence and demonstrate that, in the limit of complete superdecoherence, the resulting operators exhibit spectral density typical to random Kolmogorov operators. By gradually increasing strength of superdecoherence, we observe a sharp quantum-to-classical transition. Furthermore, we define an inverse procedure of supercoherification that is a generalization of the scheme used to construct a quantum state out of a classical one. Finally, we study microscopic correlation between neighboring eigenvalues through the complex spacing ratios and observe the horseshoe distribution, emblematic of the Ginibre universality class, for both types of random generators. Remarkably, it survives both superdecoherence and supercoherification.

In-situ investigation of strain partitioning and microstructural strain path development up to and beyond necking

Multi-phase metallic materials exhibit significant levels of strain partitioning and localization when plastically deformed. Connecting these microstructural processes to macroscopic limits of uniform deformation, e.g., plastic instability and fracture, can reveal guidelines for damage-resistant microstructure design. This connection, however, is hindered due to the absence of strain partitioning and localization data from high strain levels, near and beyond necking. A parallel gap in our current understanding of the plasticity of multi-phase materials is regarding the spatial variations in strain path development at the micro-scale. Microscopic digital image correlation, the most powerful experimental method to provide such insights, is typically limited to low strain levels (< ~15%) due to crystal-plasticity- or damage-induced surface topography evolution. Here, we address these challenges by developing a practical method that relies on serial in-situ scanning electron microscope (SEM) mechanical tests of samples pre-strained to different levels. Applying this method to a dual-phase steel, we observe that ferrite and martensite on average exhibit a linear strain partitioning trend throughout the deformation. However, the highly-deformed ferrite regions (i.e., the top 4% most strained ferritic subsets) exhibit an exponential increase in the level of strain they accommodate, as well as sequential activation of the strain localization processes in different microscopic strain paths. Martensitic constituents play an important role in the strain localization processes and the resulting microscopic strain paths.

Mean-field theories for depinning and their experimental signatures.

Mean-field theory is an approximation replacing an extended system by a few variables. For depinning of elastic manifolds, these are the position u of its center of mass and the statistics of the forces F(u). There are two proposals how to model the latter: as a random walk (ABBM model), or as uncorrelated forces at integer u (discretized particle model, DPM). While for many experiments the ABBM model (in the literature misleadingly equated with mean-field theory) makes quantitatively correct predictions for the distributions of velocities, or avalanche size and duration, the microscopic disorder force-force correlations cannot grow linearly, and thus unboundedly as a random walk, with distance. Even the effective (renormalized) disorder forces which do so at small distances are bounded at large distances. To describe both regimes, we model forces as an Ornstein-Uhlenbeck process. The latter has the statistics of a random walk at small scales, and is uncorrelated at large scales. By connecting to results in both limits, we solve the model largely analytically, allowing us to describe in all regimes the distributions of velocity, avalanche size, and duration. To establish experimental signatures of this transition, we study the response function, and the correlation function of position u, velocity u[over ̇], and forces F under slow driving with velocity v>0. While at v=0 force or position correlations have a cusp at the origin and then decay at least exponentially fast to zero, this cusp is rounded at a finite driving velocity. We give a detailed analytic analysis for this rounding by velocity, which allows us, given experimental data, to extract the timescale of the response function, and to reconstruct the force-force correlator at v=0. The latter is the central object of the field theory, and as such contains detailed information about the universality class in question. We test our predictions by careful numerical simulations extending over up to ten orders in magnitude.

Holographic renormalization group flow effect on quantum correlations

We holographically study the finite-size scaling effects on macroscopic and microscopic quantum correlations deformed by excitation and condensation. The excitation (condensation) increases (decreases) the entanglement entropy of the system. We also investigate the two-point correlation function of local operators by calculating the geodesic length connecting two local operators. As opposed to the entanglement entropy case, the excitation (condensation) decreases (increases) the two-point function. This is because the screening effect becomes strong in the background with the large entanglement entropy. We further show that the holographic renormalization leads to the qualitatively same two-point function as the one obtained from the geodesic length.

Dehydration and Hemodynamic Changes as Causa Mortis Associated with Trichuris vulpis in a Dog

Background: Trichuris vulpis, a species that belongs to Trichuris and shows a cosmopolitan distribution, parasitizes the gastrointestinal system of dogs causing trichuriasis. The infection occurs owing to ingestion of larval eggs and subsequent fixation of their adult form in the large intestine of the host. The objective of this paper is to report the case of a Border Collie dog that arrived at the Veterinary Pathology Laboratory (LPV) of the Federal University of Jataí (UFJ) after exhibiting signs of intense dehydration and sudden death caused by severe T. vulpis infection, and to elucidate the macroscopic and microscopic histopathological correlations observed during necropsy.Case: A 7-year-old male Border Collie dog was referred for routine necroscopic examination on suspicion of death from intoxication. In the history, there were reports of bone ingestion, restlessness, and polydipsia for three days, followed by sudden death. Although the animal presented an adequate body state during the necroscopic procedure, enophthalmia and pale oral and ocular mucosa were observed, which are characteristic signs of severe dehydration and anemia. On opening the abdominal cavity, the visceral serosa were found to be stained and severely dry. Greenish mucous content was observed throughout the intestine, and in the large intestine, a moderate amount of mucus associated with high parasitic infestation by elongated parasites attached to the mucosa was identified. The parasites were harvested, stored in airtight vials containing 70% alcohol, processed, and subsequently identified as T. vulpis.Discussion: The necroscopic findings associated with the histopathology were compatible with T. vulpis infestation at high parasite intensity, with severe destruction of the intestinal mucosa and inability of water absorption, resulting in severe dehydration. In cases of parasitism, villous atrophy with crypt hypertrophy occurs, a fact observed in the present case. Possibly crypt hypertrophy occurs prior to villous atrophy, and occurs independently of previous lesions of the absorptive compartment. This results in poor absorption. Advanced loss of gastrointestinal tract fluids can usually be extensive and lead to progressive dehydration with loss of isotonic and hypertonic fluids, which can also be observed in the observation of blood components, severely accelerating changes such as hypovolemia and posterior hemoconcentration. Hypovolemia from severe dehydration also decreases renal perfusion and reduces the rate of glomerular filtration. Hypovolemia also leads to decreased blood pumping capacity, which may lead to heart failure and pulmonary circulatory disorders with notable effects on gas exchange, which may cause hypoxemia and possibly lethal metabolic acidosis. The necropsy performed on the animal found a severe dehydration that could be sustained mainly owing to signs of hypovolemia, associated with a series of pathophysiological events with the massive presence of parasites identified as T. vulpis. The damage caused to the intestinal mucosa by the oral stylet, the movement, and toxins of the parasites led to a severe condition of villosities destruction and tissue necrosis, leading to a large loss of the absorption function of nutrients in the intestines and especially of water, resulting in a condition of severe dehydration. This imbalance of system functioning also alters cardiac function because of increased blood viscosity generating possible lardaceous clots, which in turn are indicative of anemia. This cycle of deleterious changes can result in hypovolemic shock and consequent sudden death.

Study of Multi-Resolution Microscopic Correlation Imaging Based on Optimized Hadamard Matrix

Study of Multi-Resolution Microscopic Correlation Imaging Based on Optimized Hadamard Matrix

Residual Intensity as a Morphological Identifier of Twinning Fields in Microscopic Image Correlation

In the microscopic observation of deforming metals, it is well known that crystallite defects that accommodate strain can occasionally become visible, namely, they introduce image contrast to their locality. For microscopic digital image correlation (DIC) applications, this is typically known as a disturbance. Here, we explore a potential upside of these image-intensity offsets, to present a new mode of differential imaging that exclusively displays the underlying plasticity agents. For this, the intensity-offset signal is isolated with residual intensity, essentially the differential between reference- and deformed-configuration intensity of each material point. The premise is showcased over an autocatalytic twin band in Magnesium AZ31, with an advanced DIC instrument that utilizes bright-field optical microscopy. With robust area-scanning that utilizes in-situ corrective measures, a material field of around 5000 grains (13 μm average size) is sampled with a maximal intragranular resolution (~250 data points per grain) for this technique. For added robustness against the intensity alterations, a DIC algorithm (Augmented Lagrangian DIC) that enforces global kinematic compatibility constraints is utilized. The calculated residual intensity map yields a detailed image of the twin networks that show a strong positional alignment with the strain localizations. At the band boundary, the twins (and their accompanying strain localization) protrude into the dormant material in a comb-like pattern. With a combination of high-resolution optics and defects that alter the surface topography, residual intensity presents a new in-situ microscopy mode that is tied to the DIC analysis. This principle also offers potential micro-deformation imaging capabilities for various other material-microscopy combinations.

Multi-scale study on the heterogeneous deformation behavior in duplex stainless steel

The heterogeneous deformation behavior of austenite and ferrite in the 2205 duplex stainless steel was subjected to multiscale analysis based on the in situ synchrotron-based high energy X-ray diffraction, microscopic digital image correlation, electron backscatter diffraction, and transmission electron microscopy. It is found that the heterogeneous deformation triggers from the yielding of austenite. During this deformation stage, austenite experiences greater strain in the area near the phase boundaries because of the impeded function of the phase boundaries to dislocations. Owing to the relatively small difference in hardness between the constituent phases, the strain in austenite grains extends into the adjacent ferrite grains when entering into the ferrite yielding stage. In addition, the strain distribution of the austenite grains is more homogeneous than that of the ferrite grains because of the lower stacking fault energy of austenite, which results in a planar slip, and higher stacking fault energy in case of ferrite, causing cross slip. The interaction between austenite and ferrite becomes considerably obvious when the strain further increases after both constituent phases yielding because of the back stress and forward stress in austenite and ferrite, respectively, which are generated by the pile-up of the geometrically necessary dislocations.