Microporous active carbon with tunable pore structure and ultrahigh specific surface area of about 2210 m2 g−1 was synthesized from sustainable biomass precursor Metaplexis japonica via a facile carbonization-activation method, among which, micropores with pore size ranging from 1 to 2 nm occupy 87% of the pore volume. This Metaplexis japonica-derived active carbon (MJAC) exhibited high specific capacitance (287 F g−1 at 1.0 A g−1) with good rate capability and excellent cycling stability (capacitance retention of 99% after 20,000 cycles at 20 A g−1) in a three-electrode system. Notably, the interconnected hierarchical and open structure with a high specific surface area contributed to the wide operating voltage window of 2.2 V and high energy density of 29 W h kg−1 at a power density of 550 W kg−1 in a two-electrode system. Therefore, all the remarkable performance of MJAC makes it attractive for application in supercapacitor.
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