Microscale Patterns Research Articles

Extracting Meso- and Microscale Patterns of Urban Morphology Evolution: Evidence from Binhai New Area of Tianjin, China

Understanding and recognizing urban morphology evolution is a crucial issue in urban planning, with extensive research dedicated to detecting the extent of urban expansion. However, as urban development patterns shift from incremental expansion to stock optimization, related studies on meso- and microscale urban morphology evolution face limitations such as insufficient spatiotemporal data granularity, poor generalizability, and inability to extract internal evolution patterns. This study employs deep learning and meso-/microscopic urban form indicators to develop a generic framework for extracting and describing the evolution of meso-/microscale urban morphology. The framework includes three steps: constructing specific urban morphology datasets, semantic segmentation to extract urban form, and mapping urban form evolution using the Tile-based Urban Change (TUC) classification system. We applied this framework to conduct a combined quantitative and qualitative analysis of the internal urban morphology evolution of Binhai New Area from 2009 to 2022, with detailed visualizations of morphology evolution at each time point. The study identified that different locations in the area exhibited seven distinct evolution patterns: edge areal expansion, preservation of developmental potential, industrial land development pattern, rapid comprehensive demolition and construction pattern, linear development pattern, mixed evolution, and stable evolution. The results indicate that in the stock development phase, high-density urban areas exhibit multidimensional development characteristics by region, period, and function. Our work demonstrates the potential of using deep learning and grid classification indicators to study meso-/microscale urban morphology evolution, providing a scalable, cost-effective, quantitative, and portable approach for historical urban morphology understanding.

Micro-scale flow simulation study of low-yield wells in tight gas reservoirs

Abstract The mechanism of gas-water flow in reservoirs has traditionally been characterized macroscopically based on flow experiments, but the microscopic mechanisms of gas-water flow in porous media cannot be precisely described experimentally. This paper categorizes low-yield gas wells into Types I, II, and III. With microscopic visualization principles, three different types of core thin-section photos were selected to construct a pore structure model, allowing for micro-scale flow simulation to examine micro-scale percolation patterns in various types of low-yield gas well reservoirs. The results show that there is a shorter displacement time in Type I reservoirs compared to Type II and III reservoirs which exhibit more pronounced fingering phenomena.

Focal point technology: Controlling treatment depth and pattern of skin injury by a novel highly focused laser

Selective photothermolysis has limitations in efficacy and safety for dermal targets. We describe a novel concept using scanned focused laser microbeams for precise control of dermal depth and pattern of injury, using a 1550nm laser that generates an array of conical thermal zones while minimizing injury to the epidermis. To characterize the conical thermal zones invivo and determine safe starting parameters to transition to a second phase to explore potential clinical indications. A focused toroidal (ring) laser beam was delivered through a cold sapphire window, sparing epidermal injury in a central zone. Pulse energy, lesion depth, density, and energy delivery were titrated in exvivo human skin and subsequently on the backs of 21 human subjects. Histology showed microscale patterns of thermal injury, which varied predictably with laser parameters. Time-course healing through histology and skin surface imaging demonstrated the ability of the device to deliver high energies without sequelae. Clinical data are currently being collected to further explore the safety and efficacy of the device. The 1550nm laser with focal point technology enables precise control of lesion depth while simultaneously sparing a large portion of the epidermis, lowering the risk of adverse effects.

Enhancing Bactericidal Properties of Ti6Al4V Surfaces through Micro and Nano Hierarchical Laser Texturing.

Orthopedic and dental implants made from Ti6Al4V are widely used due to their excellent mechanical properties and biocompatibility. However, the long-term performance of these implants can be compromised by bacterial infections. This study explores the development of hierarchically textured surfaces with enhanced bactericidal properties to address such challenges. Hierarchical surface structures were developed by combining microscale features produced by a microsecond laser and superimposed submicron features produced using a femtosecond laser. Microscale patterns were produced by the pulsed laser surface melting process, whereas submicrometer laser-induced periodic surface structures were created on top of them by femtosecond laser processing. Escherichia coli bacterial cells were cultured on the textured surface. After 24 h, a staining analysis was performed using SYTO9 and PI dyes to investigate the samples with a confocal microscope for live dead assays. Results showed bacterial colony formation onto the microscale surface textures with live bacterial cells, whereas the hierarchical surface textures display segregated and physically damaged bacterial cell attachments on surfaces. The hierarchical surface textures showed ∼98% dead bacterial cells due to the combined effect of its multiscale surface features and oxide formation during the laser processing steps. The efficacy of hierarchical surface textures in enhancing the antibacterial behavior of Ti6Al4V implants is evident from the conducted research. Such laser-based surface treatments can find potential applications in different industrial sectors.

Preparation of Photocurable Organic-Inorganic Hybrid Composites for Continuous Manufacturing of 3D-Patterned Abrasive.

Photocurable hybrid organic-inorganic composites were prepared via surface modification and 3D-patterned structures were fabricated by utilizing a continuous roll-to-roll manufacturing strategy. The surfaces of nanocrystals were engineered with a bifunctional ligand that is a 2-carboxyethyl acrylate, which possesses a carboxylic acid moiety at one end and an acrylate functionality moiety at the other end, yielding acrylate-functionalized nanocrystals. Micro-scale 3D patterns (protruding pyramidal shapes with each side measuring 147 μm) were continuously manufactured at a speed of 2.5 m/min via UV curing with a soft engraved mold. The surface properties of the functionalized nanocrystals and their UV curing condition were explored with Fourier transform infrared spectroscopy. The morphology of the 3D film was measured using scanning electron microscopy. A pin-on-disk tribometer measurement revealed an improved interaction between the functionalized particles and resins.

Geometrically Controlled Microscale Patterning and Epitaxial Lateral Overgrowth of Nitrogen-Polar GaN.

In this Letter, we report on a novel two-step epitaxial growth technique that enables a significant improvement of the crystal quality of nitrogen-polar GaN. The starting material is grown on 4° vicinal sapphire substrates by metal-organic vapor-phase epitaxy, with an initial high-temperature sapphire nitridation to control polarity. The material is then converted to a regular array of hexagonal pyramids by wet-etching in a KOH solution and subsequently regrown to coalesce the pyramids back into a smooth layer of improved crystal quality. The key points that enable this technique are the control of the array geometry, obtained by exploiting the anisotropic behavior of the wet-etch step, and the use of regrowth conditions that preserve the orientation of the pyramids' sidewalls. In contrast, growth conditions that cause an excessive expansion of the residual (0001̅) facets on the pyramids' tops cause the onset of a very rough surface morphology upon full coalescence. An X-ray diffraction study confirms the reduction of the threading dislocation density as the regrowth step develops. The analysis of the relative position of the 0002̅ GaN peak, with respect to the 0006 sapphire peak, reveals a macroscopic tilt of the pyramids, probably induced by the large off-axis substrate orientation. This tilt correlates very well with an anomalous broadening of the 0002̅ diffraction peaks at the beginning of the regrowth step.

Mobile User Traffic Generation Via Multi-Scale Hierarchical GAN

Mobile user traffic facilitates diverse applications, including network planning and optimization, whereas large-scale mobile user traffic is hardly available due to privacy concerns. One alternative solution is to generate mobile user traffic data for downstream applications. However, existing generation models cannot simulate the multi-scale temporal dynamics in mobile user traffic on individual and aggregate levels. In this work, we propose a multi-scale hierarchical generative adversarial network (MSH-GAN) containing multiple generators and a multi-class discriminator. Specifically, the mobile traffic usage behavior exhibits a mixture of multiple behavior patterns, which are called micro-scale behavior patterns and are modeled by different pattern generators in our model. Moreover, the traffic usage behavior of different users exhibits strong clustering characteristics, with the co-existence of users with similar and different traffic usage behaviors. Thus, we model each cluster of users as a class in the discriminator’s output, referred to as macro-scale user clusters. Then, the gap between micro-scale behavior patterns and macro-scale user clusters is bridged by introducing the switch mode generators, which describe the traffic usage behavior in switching between different patterns. All users share the pattern generators. In contrast, the switch mode generators are only shared by a specific cluster of users, which models the multi-scale hierarchical structure of the traffic usage behavior of massive users. Finally, we urge MSH-GAN to learn the multi-scale temporal dynamics via a combined loss function, including adversarial loss, clustering loss, aggregated loss, and regularity terms. Extensive experiment results demonstrate that MSH-GAN outperforms state-of-art baselines by at least 118.17% in critical data fidelity and usability metrics. Moreover, observations show that MSH-GAN can simulate traffic patterns and pattern switch behaviors.

Biofilm dispersal patterns revealed using far-red fluorogenic probes.

Bacteria frequently colonize niches by forming multicellular communities called biofilms. To explore new territories, cells exit biofilms through an active process called dispersal. Biofilm dispersal is essential for bacteria to spread between infection sites, yet how the process is executed at the single-cell level remains mysterious. Here, we characterize dispersal at unprecedented resolution for the global pathogen Vibrio cholerae. To do so, we first developed a far-red cell-labeling strategy that overcomes pitfalls of fluorescent protein-based approaches. We reveal that dispersal initiates at the biofilm periphery and ~25% of cells never disperse. We define novel micro-scale patterns that occur during dispersal, including biofilm compression and the formation of dynamic channels. These patterns are attenuated in mutants that reduce overall dispersal or that increase dispersal at the cost of homogenizing local mechanical properties. Collectively, our findings provide fundamental insights into the mechanisms of biofilm dispersal, advancing our understanding of how pathogens disseminate.

Rapid and versatile, micro-patterning and functionalization of complex structures on ultra-thin and flexible polymeric substrates

Microscale patterning on flexible substrates is important in many applications such as in wearable sensors and microfluidics-based diagnostics, therefore low-cost fabrication methods which are scalable and amenable to mass production have attracted the interest of many companies and research groups. Dry film resists (DFRs) are commercially available materials with properties compatible with their implementation on flexible substrates to cover a wide range of applications, which also offer environmental and sustainability benefits due to the low waste generation compared to the liquid resists. However, there are limited detailed reports in the literature regarding the use of DFRs for the fabrication of microfluidic channels or other micropatterns (i.e., posts) on thin and flexible substrates. Herein we present in detail the fabrication of: a) microfluidic channels of width ranging from 50 μm up to 800 μm, and depth ranging from 30 μm up to 270 μm and b) square posts 80 μm × 80 μm in size and 30 μm in height. Particularly, our method enables the fabrication of ultra-deep microchannels (depth > 250 μm), highly ordered post arrays over large area (appr. 60 cm2), as well as complex designs with hierarchical scale features (80 μm posts inside 800 μm microchannels or micro-nanotexturing inside microchannels) on ultra-thin flexible substrates. To demonstrate the versatility of the method, three different DFRs were used on ultra-thin (30 μm), flexible, single-sided copper-clad polyimide substrates. It is also demonstrated that DFRs can be effectively modified using plasma etching to tune the surface wetting properties towards applications such as pumpless capillary action, where such functionality is required.

A System Built for Both Deterministic Transfer Processes and Contact Photolithography

A home‐built compact system that functions as both a transfer stage for deterministic transfer processes and a mask aligner for contact photolithography, is constructed. The precision translation sample stage and optical microscope are shared between the two modes. In the transfer mode, assisted by either an adhesive or a heating element, the setup has been used to deterministically transfer freestanding semiconductors, 2D materials, and van der Waals electrodes. When configured in photolithography mode, the proposed instrument has been employed to fabricate various microscale patterns and devices, with minimum feature sizes of 1–2 μm achieved. The prototype instrument provides a feasible solution for performing high‐quality deterministic transfer and photolithography processes on one single tool in‐house.

Mechanism of antibacterial property of micro scale rough surface formed by fine-particle bombarding

ABSTRACT Fine-particle bombardment (FPB) is typically used to modify metal surfaces by bombarding them with fine particles at high speed. FPB is not a coating technique but is used for forming microscale concavities and convexities on a surface. Previously, we reported that an FPB-treated surface showed antibacterial effects; however, the underlying mechanisms remain unclear. We hypothesized that the pitch size of concavity and convexity, and irregular microscale pattern of FPB-treated surfaces might contribute to the antibacterial performance. In this study, we applied FPB to stainless-steel surfaces and evaluated the antibacterial effects of the FPB-treated surfaces based on ISO 22,196:2007. The FPB-treated surfaces exhibited antibacterial activity against Escherichia coli, with an antibacterial activity value (R) of two or more. Furthermore, our experiments suggest that the antibacterial mechanism of the FPB-treated surface can be attributed to increased oxidative stress in bacteria owing to physical stress from the rough surface. The antibacterial effect of FPB-treated surfaces offers an effective measure against drug-resistant bacteria.

Micro-Scale Analysis and Optimization of Rural Settlement Spatial Patterns: A Case Study of Huanglong Town, Dayu County

Optimizing the spatial patterns of rural settlements is crucial for rural development and revitalization. Enhancing the internal spatial configuration of these settlements necessitates a comprehensive understanding of their micro-scale spatial characteristics. This study develops evaluation indicators and methodologies to quantify rural settlement spatial patterns by analyzing their multidimensional aspects. The research utilizes Huanglong Town in Dayu County, Jiangxi Province, as a case study for exploring micro-scale spatial patterns and proposing corresponding optimization models. The research employs remote sensing image processing and GIS spatial analysis to collect data on the study area. The results indicate that rural settlements in Huanglong Town generally form clustered patterns with moderate spatial structure intensity and order. Notably, spatial heterogeneity is observed across the northern mountainous area, the central plain and low hilly region, and the southern hilly area. Based on these findings, the study categorizes rural settlements in Huanglong Town into four optimization models: stable improvement, internal potential exploitation, controlled expansion, and relocation and withdrawal. Each model is associated with differentiated optimization strategies. By integrating analyses of spatial form, structure, and order, this study reveals the intrinsic spatial characteristics of rural settlements, offering a systematic approach to guide their spatial optimization.

Fully Biodegradable Elastomer-Based Device for Oral Macromolecule Delivery.

Oral devices, such as foil-type devices, show great potential for the delivery of poorly permeable macromolecules by enabling unidirectional release of the loaded pharmaceutical composition in close proximity to the epithelium in the small intestine or colon. However, one of the primary concerns associated with the use of foil-type devices so far has been the utilization of nonbiodegradable elastomers in the fabrication of the devices. Therefore, research into biodegradable substitute materials with similar characteristics enables drug delivery in a sustainable and environmentally friendly manner. In this study, a biodegradable elastomer, polyoctanediol citrate (POC), was synthesized via a one-pot reaction, with subsequent purification and microscale pattern replication via casting. The microstructure geometry was designed to enable fabrication of foil-type devices with the selected elastomer, which has a high intrinsic surface free energy. The final elastomer was demonstrated to have an elastic modulus ranging up to 2.2 ± 0.1 MPa, with strain at failure up to 110.1 ± 1.5%. Devices were loaded with acetaminophen and enterically coated, demonstrating 100% release at 2.5 h, following dissolution for 1 h in 0.1 M hydrochloric acid and 1.5 h in pH 6.8 phosphate-buffered saline. The elastomer demonstrated promising properties based on mechanical testing, surface free energy evaluation, and degradation studies.

Improved hydrodynamic properties and enhanced resistance to particle deposition and membrane fouling by millimeter-scale patterned membranes

Membrane fouling is considered a persistent challenge in membrane technology for water and wastewater treatment. Membrane surface patterning is a chemical-free means of controlling membrane fouling. Previous studies mainly focused on nano- and micro-scale patterns, with little attention paid on millimeter-scale patterns on the membrane surface. In this study, the millimeter-scale patterned microfiltration membranes with different pattern heights (PM50, PM55 and PM60) were fabricated, the performances in resisting particle deposition and membrane fouling with synthetic wastewater were examined compared with flat-sheet membrane (FM), and the underlying hydrodynamic mechanism was unveiled using computational fluid dynamics (CFD). CFD simulation results reveal that compared to micro- and nano-scale patterns, millimeter-scale patterns exert a notable increase in maximum velocity, average shear stress and maximum shear stress. All the three millimeter-scale patterned membranes exhibit superior resistance to both particle deposition and membrane fouling than FM, owing to the improvement of hydrodynamic properties instead of enlarged membrane area. PM55 shows the lowest flux decline ratios and least particle/foulant deposition among the three millimeter-scale patterned membranes in both particle deposition and membrane fouling experiments. Pattern height plays a crucial role, as small pattern height cannot generate significant vortices, while high pattern height leads to flow separation. For PM55, the vortices form in the valley regions and locate close to bulk flow, which help transport the deposited particles or foulants back to the bulk flow. The design of pattern configuration is suggested to be tailored based on particle size. Future research can focus on the pilot testing of millimeter-scale patterned membranes, as well as the long-term stability with actual influent.

Identification and extraction of cementation patterns in sand modified by MICP: New insights at the pore scale.

Microbially induced calcium carbonate precipitation (MICP) is an environmentally friendly technology that improves soil permeability resistance through biocementation. In this study, 2D microscopic analysis and 3D volume reconstruction were performed on river sand after 24 cycles of bio-treatment based on stacked images and computed tomography (CT) scanning data, respectively, to extract biocementation patterns between particles. Based on the mutual validation findings of the two techniques, three patterns in the biocemented sand were identified as G-C-G, G-C, and G-G. Specifically, 2D microscopic analysis showed that G-C-G featured multi-particle encapsulation and bridging, with a pore filling ratio of 81.2%; G-C was characterized by locally coated particle layers, with a pore filling ratio of 19.7%; and the G-G was marked by sporadic filling of interparticle pores, with a pore filling ratio of 11.7%. G-C-G had the best cementation effect and permeability resistance (effective sealing rate of 68.5%), whereas G-C (effective sealing rate of 2.4%) had a relatively minor contribution to pore-filling and flow sealing. 3D volume reconstruction showed that G-C-G had the highest pore filling rate, followed by G-G and G-C. The average filling ratios of area and volume for G-C-G were 83.979% and 77.257%, respectively; for G-G 20.360% and 23.600%; and for G-C 11.545% and 11.250%. The analysis of the representative element volume (REV) was conducted, and the feasibility and reliability of the micro-scale pattern extraction results were confirmed to guide the analysis of macro-scale characteristics. The exploration of the effectiveness of cementation patterns in fluid sealing provides valuable insights into effective biocementation at the pore scale of porous media, which may inspire future research.

Nondestructive Direct Optical Patterning of Perovskite Nanocrystals with Carbene-Based Ligand Cross-Linkers.

Microscale patterning of colloidal perovskite nanocrystals (NCs) is essential for their integration in advanced device platforms, such as high-definition displays. However, perovskite NCs usually show degraded optical and/or electrical properties after patterning with existing approaches, posing a critical challenge for their optoelectronic applications. Here we achieve nondestructive, direct optical patterning of perovskite NCs with rationally designed carbene-based cross-linkers and demonstrate their applications in high-performance light-emitting diodes. We reveal that both the photochemical properties and the electronic structures of cross-linkers need to be carefully tailored to the material properties of perovskite NCs. This method produces high-resolution (∼4000 ppi) NC patterns with preserved photoluminescent quantum efficiencies and charge transport properties. Prototype light-emitting diodes with patterned/cross-linked NC layers show a maximum luminance of over 60000 cd m-2 and a peak external quantum efficiency of 16%, among the highest for patterned perovskite electroluminescent devices. Such a material-adapted patterning method enabled by designs from a photochemistry perspective could foster the applications of perovskite NCs in system-level electronic and optoelectronic devices.

Advances in laser-based surface texturing for developing antifouling surfaces: A comprehensive review

Surface fouling is a major challenge faced within various engineering applications, especially in marine, aerospace, water treatment, food and beverage, and the energy generation sectors. This can be prevented or reduced in various ways by creating artificial surface textures which have fouling resistance properties. Ultrafast laser texturing provides an efficient method for the texturing of surfaces of different materials with high accuracy, precision, and repeatability. Laser texturing methods can enhance the production of well-defined surface nano- and microscale patterns. These surfaces with nano- and micro-scale patterning can be tailored to have inherent properties such as hydrophobicity, hydrophilicity, and resistance to fouling. This review gives an overview of the various types of fouling that can occur, the properties affecting a surface's fouling resistance, as well as the latest physical and chemical strategies for the generation of antifouling surfaces. Surfaces architectures which have inherent antifouling capabilities are presented. This review focuses on the utilization of the higher precision laser-based texturing offered from femtosecond laser systems for enhance fouling resistance. The process parameters to fabricate these textures and the current state of art femtosecond laser sources are presented and discussed. The challenges and future research requirements in the field of laser-based methods to fabricate antifouling surfaces are presented.

Bionic Micro-Texture Duplication and RE3+ Space-Selective Doping of Unclonable Silica Nanocomposites for Multilevel Encryption and Intelligent Authentication.

High-capacity optical data storage and information encryption by using glass substrates are fascinating due to merits of expanding the functionality and applicability of the optoelectronic field. However, the development of glass substrate-based multi-dimensional information encryption methods has remained a challenge because of the high hardness, brittleness and melting temperature of glasses. Herein, inspired by the unique natural structure of plant leaves, multicolor micro-texture-based physical unclonable functions (PUFs) fluorescence glass labels (MTPLs) are exploited by using ultraviolet photocurable silica nanocomposites and soft replication method. It is the first time that simultaneous rare-earth ion (RE3+ ) space-selective doping and bionic micro-texture replication onto transparent glass have been realized, in which the doping position and fluorescence color of RE3+ and height information of unclonable micro-texture can be selectively equipped for multilevel information encryption. The prepared micro-scale MTPLs are endowed with tunable multilevel authentication models, including macro-scale multicolor fluorescent 2D patterns, micro-scale pattern, color 3D information and intelligence authentication. A high-performance anti-counterfeiting platform with interactive authentication is also established based on the high robustness and security of MTPLs. Such unclonable bionic MTPLs based on RE3+ space-selective doping and micro-texture duplication provide an effective and potentially universal approach for multilevel encryption and intelligent authentication.

In situ metrology of direct-write laser ablation using optical emission spectroscopy

Direct-write laser ablation is an effective manufacturing method for etching complex microscale patterns, especially on hard ceramics such as sapphire that are difficult to machine using traditional mechanical or micromachining methods. However, the variability of the laser–matter interaction causes inconsistencies that prevent this process from moving beyond the research realm. This work presents the real-time monitoring of the ablation process in sapphire using optical emission spectroscopy to assess the key wavelengths that exhibit strong correlations to the fabricated features. In this process, a focused ultrafast laser is used to create microscale features and morphological changes in sapphire substrates, which are studied by a subsequent wet etching in a hydrogen fluoride solution. The etched sapphire samples are observed to have amorphous sapphire removed, resulting in microstructures with higher profile fidelity. Furthermore, principal component analysis of the measured spectral obtained during the etch process indicates that the emission from a few key wavelengths exhibits strong correlations to the etched sapphire patterns. This result indicates that the use of data-driven techniques to assess the spectral emissions of direct-write laser ablation can be a useful tool in developing in situ metrology methods for laser-matter interactions.

Enhanced erosion resistance of HVOF-deposited laser-textured TiC coating with PTFE

ABSTRACT This research explores the enhanced slurry erosion behaviour of a composite coating comprising Titanium Carbide (TiC) deposited via High Velocity Oxy-Fuel (HVOF) spraying process. The study integrates laser texturing and Polytetrafluoroethylene (PTFE) spraying techniques to improve the coating's performance. TiC coating is applied to SS316 substrates using HVOF, followed by laser surface texturing to create micro-scale circular patterns. A thin layer of PTFE is then sprayed onto the textured surface, enhancing static contact angle and anti-adhesive properties. Slurry erosion tests reveal significant improvements in the coating's resistance. The findings offer promising applications in slurry erosion-prone industries. Further investigations aim to study the erosive mechanism of the different samples and evaluate their long-term performance.