Microscale Fractures Research Articles

Development and Performance Evaluation of a New Conformance Control Agent Gel.

How to effectively plug the multi-scale fractured water channeling has always been the key to achieving efficient water flooding of fractured low-permeability oil reservoirs. In this paper, a new type of supramolecular-polymer composite gel is developed, which is suitable for plugging multi-scale fractured water channeling. The supramolecular-polymer composite gel is composed of a polymer (such as polyacrylamide), cross-linking agent (such as polyethyleneimine), supramolecular gel factor (such as cyclodextrin) and polarity regulator (such as ethyl alcohol). The mass fraction of polyacrylamide, polyethyleneimine, cyclodextrin and ethyl alcohol are 0.15%, 0.2%, 1% and 0.2%, respectively. At the initial state, the viscosity of the composite gelant system is less than 20 mPa·s. It has good injection performance in micro-scale fractures and can enter the deep part of a fractured reservoir. At 40 °C, the composite gelant system can form a gel with a double network structure after gelation. One of the networks is formed by the covalent interaction between polyacrylamide and polyethyleneimine, the other network is formed by the self-assembly of cyclodextrins under the action of the ethyl alcohol. The comprehensive performance of the composite gel is greatly improved. The strength of the composite gel is >5 × 104 mPa·s, and it has good plugging strength in large-scale fractures. The composite gel can be used as a conformance control agent for fractured low-permeability oilfields.

STUDY OF MICROSCALE PORE STRUCTURE AND FRACTURING ON THE EXAMPLE OF CHINA SHALE FIELD

Accurate characterization of pores and fractures in shale reservoirs is the theoretical basis for effective exploration and development of shale oil and gas. Currently, the scientific community has developed methods for determining the characteristics of the pore and fracture structure of shales with different resolutions, and also discussed the mechanisms of the influence of the characteristics of pores and cracks on the filtration of shale oil and gas. In this work, firstly, a three-dimensional model of a variable-scale pore-fracture structure was created. Secondly, on the basis of data obtained using computed tomography, the characteristics of the development of pores and cracks at different geometric sizes (25 and 2 mm) were statistically analyzed. Third, pore and fracture structures of mixed, felsitic and laminated felsitic shale have been relatively studied. The results show that: (a) the fractured porosity of group I felsite shale is 0.36–0.89 %; mixed shale of group I is 0.34–0.47 %; mixed shale of group III is 0.12–0.86 %; mixed shale of group III is 0.13–0.15 %. (b) Compared to mixed shale of group I, fracturing in felsite shale of the same group is more developed. In addition, the average fractured porosity of felsite shale is 0.28 % greater than that of mixed shale. After analyzing group III, it was noticed that the cracks of the mixed dolomite shale are less developed compared to the mixed shale of the same group, while the average porosity of the cracked shale is 0.33 % less than that of the cracks of the mixed shale (c). Various components of shale samples are distinguished on a gray scale. High density components are bright white (e.g. pyrite); medium density components — light gray (for example, quartz, carbonate and clay minerals); low-density components — dark gray (for example, organic matter); cracks — black (d). The volume of matrix components is relatively high and constitutes the bulk of the total volume of shale samples. The distribution of high-density minerals has a certain randomness. High-density ellipsoidal or irregular minerals (mainly pyrite) range in diameter from a few microns to hundreds of microns, and their volume is relatively small (e). Three types of microscale fractures are mainly developed in shale: microscale fractures within mineral particles (intragranular fractures), microscale fractures between mineral particles (intergranular fractures), and shrinkage fractures. Intragranular cracks are mainly microscale cracks formed by rigid particles that collapse in a certain direction under stress.

Full-Scale Pore and Microfracture Characterization of Deep Coal Reservoirs: A Case Study of the Benxi Formation Coal in the Daning–Jixian Block, China

The pore-fracture structure of deep coal reservoirs is highly important for evaluating, exploring, and developing coalbed methane (CBM) resources. This study considers three coal samples from the DJ57 well in the Benxi Formation in the Daning–Jixian block on the eastern margin of the Ordos Basin as the research object. Based on the coal quality parameters of the coal samples, field emission scanning electron microscopy (FE-SEM), gas adsorption experiments, high-pressure mercury intrusion porosimetry (MIP), and microcomputed tomography (micro-CT) scanning were used to quantitatively characterize the nanoscale pores and microscale fractures in deep coal reservoirs and to evaluate the pore-fracture structure at different scales. The results reveal that the pore types in the Benxi Formation coal samples are diverse and include mainly organic matter (OM) pores, inorganic pores (intraparticle and interparticle pores), and microfractures. The organic pores are diverse in shape and mainly exhibit round, oval, and wedge shapes, while the microfractures exhibit slender stripes or serrated curves. The multiscale quantitative characterization of deep coal reservoir pores and fractures is based on a variety of pore characterization methods, and the pore and fracture volume distributions are mainly U-shaped, revealing the coexistence of micropores and microfractures. The volumes of micropores (0.3–2 nm), mesopores (2–50 nm), macropores (50 nm to 10 μm), and microfractures (>10 μm) account for 78.00%, 6.78%, 2.08%, and 13.14%, respectively, of the total pore volume (PV). Based on a full-scale pore-fracture splicing calculation, the total permeability of the Benxi Formation coal samples ranges from 5.77 to 28.22 mD. The observation results indicate that the microfractures are connected to each other, forming a network structure with strong connectivity. The microfractures are mainly associated with pore diameters>100 μm, accounting for approximately 95% of the total permeability. Moreover, micropores in deep coal reservoirs provide a large space for CBM adsorption, and microfractures enhance the seepage capacity of CBM.

Super-resolution reconstruction of 3D digital rocks by deep neural networks

Digital rock technology provides valuable insights into the pore structure and fluid flow properties of geoenergy resources. Artificial intelligence technology in vision and image processing, especially the image super-resolution, has great potential for digital rock reconstruction and resolution enhancement. However, the analyzed core samples are typically sandstones/carbonates in micro-scale resolutions and in two-dimensional (2D) space, whereas the shale rocks in nano-scale resolutions for unconventional resources or three-dimensional (3D) digital cores are rarely investigated. Additionally, previous studies primarily emphasized image quality from a computer vision perspective, with little consideration given to estimating physical properties of digital rocks using super-resolution techniques.This study presents a very deep super-resolution (VDSR) algorithm, specifically designed to generate high-resolution 3D digital rock images, for nano-scale shale matrix and micro-scale hydraulic fractures. We compare both image quality and permeability accuracy between the original high-resolution images and the super-resolution images reconstructed by the proposed method. The results reveal that the reconstructed images using the proposed method closely resemble the actual images, and effectively reduce errors in permeability computations. This study highlights the applicability of the proposed VDSR algorithm in establishing the detailed structures of 3D nano-scale shale matrix and hydraulic fractured rocks, thus advancing super-resolution techniques in digital core analysis for geoenergy resources development.

Fluid phase behavior in multi-scale shale reservoirs with nano-confinement effect

Shale reservoirs are featured by widely distributed micro-scale fractures and nano-scale pores. The phase behavior of reservoir fluids in these complex environments remains uncertain. Hence, an efficient model is developed to investigate the fluid phase behavior in multi-scale shale reservoirs based on a pore-size-dependent equation of state. The porous space is discretized into specific sizes of nanopores and fractures regions. Phase equilibrium calculations for pure components, binary mixtures and multi-component shale oils show that adsorption and critical properties shifts display opposite effects on a fluid distribution, and the shifts in the critical properties are the main reason for more lighter components present in nanopores. The nano-confinement effect enhances the ability of CO2 to enter nanopores. An innovative multi-scale model of partial equilibrium is developed to explore changes in fluid properties during pressure depletion. The results reveal that gas appears in the fracture region, while the confined fluids within nanopores are always kept in the oil phase. Lighter components within nanopores are rapidly released as pressure drops. However, the content of heavier components within nanopores gradually decreases if the pressure stabilizes for a while, meaning that a slow pressure drop is more conducive to the recovery of shale oil from nanopores.

In-situ hydrocarbon formation and accumulation mechanisms of micro- and nano-scale pore-fracture in Gulong shale, Songliao Basin, NE China

By conducting experimental analyses, including thermal pyrolysis, micro-/nano-CT, argon-ion polishing field emission scanning electron microscopy (FE-SEM), confocal laser scanning microscopy (CLSM), and two-dimensional nuclear magnetic resonance (2D NMR), the Gulong shale oil in the Songliao Basin was investigated with respect to formation model, pore structure and accumulation mechanism. First, in the Gulong shale, there are a large number of pico-algae, nano-algae and dinoflagellates, which were formed in brackish water environment and constituted the hydrogen-rich oil source materials of shale. Second, most of the oil-generating materials of the Qingshankou Formation shale exist in the form of organo-clay complex. During organic matter thermal evolution, clay minerals had double effects of suppression and catalytic hydrogenation, which expanded shale oil window and increased light hydrocarbon yield. Third, the formation of storage space in the Gulong Shale was related to dissolution and hydrocarbon generation. With the diagenesis, micro-/nano-pores increased, pore diameter decreased and more bedding fractures appeared, which jointly gave rise to the unique reservoir with dual media (i.e. nano-scale pores and micro-scale bedding fractures) in the Gulong shale. Fourth, the micro-/nano-scale oil storage unit in the Gulong shale exhibits independent oil/gas occurrence phase, and shows that all-size pores contain oils, which occur in condensate state in micropores or in oil-gas two phase (or liquid) state in macropores/mesopores. The understanding about Gulong shale oil formation and accumulation mechanism has theoretical and practical significance for advancing continental shale oil exploration in China.

Influence of shale bedding on development of microscale pores and fractures

The characteristics of bedding development have an important impact on the spatial distribution of shale pores and fractures. However, there is a lack of systematic study on the pore and fracture structure of bedding development characteristics. In this paper, the geological control mode of shale type on the development characteristics of pores and fractures is revealed; pore-throat models under different shale lithology conditions are constructed; the control mechanism of bedding development characteristics on the spatial distribution pattern of pores and fractures is clarified. Results show that: (a) The pore space size varies widely from nanoscale to micron-scale or even millimeter scale, and is mainly concentrated in the nanoscale range. (b) For shale samples No. 1-7-1 No. 21-7-1, although the proportion of organic matter and mineral area in different samples varies greatly, the difference between the proportion of organic pore area and the proportion of mineral pore area is not significant, and the proportion of organic pore area is much higher than that of mineral pore area. (c) The pore diameter of shale has strong heterogeneity; minerals have an important impact on throat diameter; maturity has an important impact on throat length; geological compaction and tectonism will have an impact on the tortuosity of shale reservoir pores; the controlling effect of pore connectivity on shale wettability is mainly reflected in the connectivity of hydrophilic and lipophilic pores.

Regional stratigraphically discordant dolomite mapping based on a dolomitization mechanism on the Arabian carbonate shelf

Dolomite mapping, as a first step of carbonate diagenetic modeling, is critical to understanding dolomitization mechanisms and predicting reservoir quality. Stratigraphically discordant dolomite bodies within the Upper Jurassic intervals have long been studied on the Arabian shelf. Our dolomitization mechanisms find that faults/fractures serve as migration conduits and determine dolomite distribution by controlling fluid flow. We establish an innovative approach based on the diagenetic mechanisms and comprehensive characterization of fracture systems at multiple scales to delineate dolomite in the study area. The complex fracture networks in the subsurface are categorized into macroscale, mesoscale, and microscale fractures. Macroscale fractures, i.e., faults, are much greater than the seismic wavelength and are easily observed in seismic sections due to their obvious seismic discontinuities. Mesoscale fractures are slightly greater than or equal to the seismic wavelength and are recognized using seismic attributes. Microscale fractures are significantly smaller than the seismic wavelength and are observed mainly on core samples and thin sections. The dolomite mapping workflow includes three steps: (1) calibrate the seismic response of multiscale fractures with borehole image logs and core interpretations, (2) implement multiscale fracture characterization using multiple seismic attributes, and (3) interpret dolomite bodies based on fracture characterization and log identification. The mapping results show that massive dolomite bodies are heterogeneously developed and distributed mainly in the northeastern part of the study area, with a southward decrease in dolomite content. The application demonstrates that multiscale fracture systems play critical roles in massive dolomitization, and multiscale fracture prediction provides an innovative solution to delineate complex dolomitization systems and the combination of reservoir and seal in diagenetic traps.

Cross-scale diffusion characteristics in microscale fractures of tight and shale gas reservoirs considering real gas – mixture – body diffusion – water film coupling

The mechanism of solid fluid coupling in unconventional oil and gas reservoirs is complex, and elucidating the characteristics of cross scale gas seepage has important scientific and engineering significance. This article focuses on the gas seepage characteristics in micro fractures of unconventional natural gas reservoirs, with three main innovations: (a) analyzing the coupling mode between real gas effects and mixed gases; (b) Explored the multi factor control mechanism of bulk gas diffusion in microscale fractures; (c) The mechanism of the influence of water film distribution characteristics in microscale fractures on gas seepage was elucidated. Results show that: (a) For the water saturation of 10% and the methane content of 80%, when the gas pressure in the crack increased from 0.2 MPa to 10 MPa, the continuous flow velocity and slippage flow velocity increased. (b) for the water saturation of 10% and the methane content of 80%, when the mixed gas pressure increases from 0.2 MPa to 0.8 MPa, the bulk gas diffusion rate drops relatively rapidly from 8.40E-22 kg/s to 8.18E-23 kg/s (c) for the water saturation of 10% and the methane content of 80%, when the mixed gas pressure increases from 0.2 MPa to 0.6 MPa, the modified slippage flow rate drops relatively rapidly from 7.47E-21 kg/s to 6.96E-21 kg/s.

Diffusion characteristics of shale mixed gases on the wall of microscale fractures

Shale reservoirs are rich in organic and inorganic matter, causing a large amount of gas to exist on the surface of microscale cracks in an adsorbed state. Revealing the surface diffusion characteristics of adsorbed gas is of great significance for the microscale numerical simulation of shale gas reservoir. In this paper, the unconventional gas reservoir is taken as the research object, and the characteristics of gas surface diffusion on surface wall of microscale fractures is systematically studied. There are two innovations in this paper: (a) the characteristics of gas surface diffusion inside the planar microscale fractures are analyzed; (b) The influence of mixed gas effect on gas surface diffusion is considered. Research results show that: (a) when the fracture opening is 2 nm or 5 nm, the influence of the opening of microscale fractures on the thickness of adsorption layer can be ignored. (b) The interaction between components refers to the frictional force generated by the relative motion of molecules. (c). The magnitude of frictional force is related to the Maxwell Stefan diffusion term and is proportional to the velocity difference. Due to the interaction between components, fast-moving molecules will accelerate the movement of slow-moving molecules.

Cross-Scale Seepage Characteristics of Fractured Horizontal Wells in Tight Gas Reservoirs.

Tight gas reservoirs are rich in microscale pores and fractures. The effect of microscale gas seepage in tight sandstone matrix on gas well productivity cannot be ignored. At present, the effect of microscale gas flow on the well testing model of fractured horizontal wells has not been systematically studied. In this paper, first, the coupling influence mechanism of "multicomponent gas effect-fracture geometry characteristics" is expounded, second, a seepage model coupling the flow in the fracture and the flow in the gas reservoir is established on the fracture wall surface, and third, an unsteady pressure analysis model for fractured horizontal wells in tight gas reservoirs is established. Results show that (a) when the microscale fracture is at a quite small level, the Knudsen diffusion plays a dominant role at a wide range of pressures; (b) the mass transfer rate of multicomponent shale gas through macrofractures increases with increasing CO2 fraction; (c) the unsteady flow process is divided into six stages in turn: microscale diffusion stage, linear flow stage in fractures, linear flow stage between fractures, early radial flow stage in gas reservoirs, linear flow stage in gas reservoirs, and late radial flow stage in gas reservoirs; and (d) with an increase of dimensionless bottom-hole storage coefficient, the second and third stages of flow are gradually covered up.

3D characterization of localized shear failure in loess subject to triaxial loading

The reduction of shear strength of loess slopes is generally driven by localized failure in loess that lowers the trigger thresholds of major landslide geohazards in these materials. Shear failure is initially manifested as discontinuous microscale fractures that progressively develop into macroscale rupture surfaces. In this study, the development of localized shear failure in Malan loess is investigated through an approach combining laboratory triaxial shear test and X-ray micro-computed tomography (μ-CT). The spatial distribution and morphological evolution of fractures associated with the shear failure plane are observed at different loading stages in a non-destructive manner. It is found that, with ongoing strain, the number and persistence of multiple undulating fracture surfaces gradually increase after peak strength condition are reached until a single, dominant shear failure plane is formed. Most fracture surfaces are oblique to the major principal stress direction forming a shear band of finite thickness. Within this band it is possible to observe zones where varying strain magnitude is accommodated by a network of fracture surfaces. The effect of strain accumulation and local shear failure on the sample's macroporosity was determined by performing calculations on the CT images of each loading stage. Whereas the bulk sample underwent a reduction in macroporosity as a result of the triaxial compression, movement along undulating fracture surfaces results in the opening (and closing) of apertures with ongoing shear strain within a shear band of finite thickness. The overall result is an increase in macroporosity in this shear band with an estimated thickness of approximately 5 mm. Image analysis also allows characterization of changes in the 3D macropore network of the original loess fabric. Macropore network can be disconnected, dislocated and even destroyed when affected by shear failure development. These morphological variations of macropores serve as benchmarks that indicate the early initiation and expanding range of local shear failure and also allow the evaluation of the effect of local shear failure on seepage characteristics. The results of this study could provide important insights into multi-scale modelling of mechanical behaviour of loess.

Real Gas Effect and Bulk Diffusion Characteristics of Shale Mixed Gas Transport in Microscale Fractures.

Shale gas reservoirs are rich in microscale fractures. In this paper, the characteristics of gas percolation in microscale fractures are taken as the research object. By coupling the actual gas equation, the multi-component gas equation, and the bulk gas diffusion equation, analytical solutions of the comprehensive percolation equation are obtained. Through mathematical model research, the following conclusions are obtained: (a) after considering the slip flow of the solid surface, the mass flow rate of multi-component gas under different pressure conditions increases by about 20-10,000%. (b) Different from continuous flow and slip flow, the mass flow rate of bulk gas diffusion decreases with pressure increase. (c) The intersection pressure is 31 MPa. When the pressure increases from 0.5 MPa to the pressure at the intersection point, the mass flow rate of integrated flow increases with decrease of the methane content. (d) When the pressure continues to increase from the intersection point pressure, the mass flow rate of integrated flow decreases with decrease of the methane content.

Study on dynamic fracture growth mechanism of continental shale under compression failure

Microscale and nanoscale fractures induced by stress transfer can effectively improve pore connectivity, which can provide significant benefits by improving well productivity in shale reservoirs. In this research, representative samples of four shale lithofacies are investigated. The rock deformation and fracture propagation of shale samples under stress are numerically simulated by integrating various technical approaches, such as characterization of the mineral composition and distribution, digital core modeling, micromechanical tests, and finite element method-based simulations. The results show that the numerical model developed in this research can accurately replicate the microscale characteristics of the heterogeneity of shale and thus effectively clarify the effects of control of the composition, morphology, and distribution of minerals and structural defects on induced fractures in rock masses. Under uniaxial compression, the failure mechanism of rock is dominated by tensile fracturing, which generates tensile fractures parallel to the loading direction. However, compression‒shear fractures perpendicular to the loading direction also form due to the presence of lamination seams. The content of brittle minerals in different lithofacies is relatively stable, but the characteristics of the morphology and distribution of such minerals are highly differentiated, which leads to significant differences in mechanical properties and failure mechanisms. Both laminated felsic and diamictic shale (LFS and LDS) can present high fracture complexity in cases of low fracture energy. In argillaceous shale (AS), fractures initiate at low strengths, yet fracture propagation requires high energy. In contrast, the fracture initiation pressure and fracture propagation energy consumption of dolomitic shale (DS) are both high and unfavorable for the propagation of induced fractures. This research provides a technical approach for studying the formation mechanism and dynamic evolution of induced fractures, and the corresponding findings are of great theoretical significance for the identification of sweet spots and design of shale reservoirs for fracturing applications.

Digital-Rock Construction of Shale Oil Reservoir and Microscopic Flow Behavior Characterization

In shale oil reservoirs, nano-scale pores and micro-scale fractures serve as the primary fluid storage and migration space, while the associated flow mechanism remains vague and is hard to understand. In this research, a three-dimensional (3D) reconstruction of the shale core and micro-pore structure description technique is established; digital core technology for shale reservoirs was developed using X-ray computed tomography (X-CT), scanning electron microscope (SEM) and a focused ion beam scanning electron microscope (FIB-SEM). Microscopic oil–water two-phase flow is mimicked using the lattice Boltzmann method (LBM), a well-acknowledged approach to exploring nanoconfined fluid dynamics. In addition, coupled with digital cores, the flow characteristics of shale reservoirs are characterized. The total porosities of bedding fractures in shale and lamellar shale are 2.042% and 1.085%, respectively. The single-phase oil flow inside bedding fractures follows Darcy’s linear flow principle. This work can deepen the understanding of the microscopic flow characteristics of continental shale reservoirs and provide a reference for similar problems that may be encountered.

An analytical model for multi-component shale gas transport through micro-scale fractures in shale gas reservoirs

An analytical model for multi-component shale gas transport through micro-scale fractures in shale gas reservoirs

Investigation of cleat and micro-fracture and its aperture distribution in the coals of different ranks in North China: Relative to reservoir permeability

The apertures of cleats and micro-fractures in coal play an important role in the permeability of the coal bed. In this study, optical microscopy and scanning electron microscopy were used to investigate the morphology of cleats and micro-fractures and their apertures, distribution of minerals, and matrix/fracture interactions. The neighboring mineralized and unmineralized cleats suggest the possibility of multi-stage evolutionary processes of cleat formation during the coalification process. The micro-fracture distribution of coals is closely related to their components, including organic macerals and inorganic minerals. Micro-fractures are prone to developing at the junction surface of organic macerals or the surface of organic and inorganic minerals. A mineral-genetic micro-fracture can be classified as an intra-crystal micro-fracture, an extra-crystal micro-scale fracture, or a grain-edge micro-scale fracture. Compared with the low- and middle-ranking coals, cleat and micro-scale fractures in high-ranking coal are usually filled with carbonate minerals and clay minerals. Statistical analysis reveals that the aperture distribution of cleat and micro-fracture in coal shows a log-normal distribution. The aperture of cleat and micro-fracture shows a decreasing trend with increase in coal rank. For low-ranking coal, cleats contribute more to the permeability than micro-fractures. However, for the middle- and high-ranking coals, the contribution of cleats and micro-fractures to the coal reservoir permeability will be close. As the rank of coal increases, the degree of cleat contribution to reservoir permeability decreases, while the degree of micro-fracture contributing to the reservoir permeability increases. Possible reasons for the extremely low reservoir permeability in China may be the following: 1) subsurface cleats and micro-fractures close their apertures significantly due to the in situ geo-stress or 2) cleats and micro-fractures have better permeability in the geological history, which makes the precipitation of minerals decrease the coal reservoir permeability. Therefore, the acid solvent (e.g., HAc, HCl, and HF) added to the drilling or hydraulic fracturing fluid or the geo-stress relief technologies may be an effective way of enlarging the cleat or micro-fracture aperture and enhance the reservoir permeability for coalbed methane production.

Drilling fluid for stabilizing the wellbore in compound-salt formation based on multiple-synergism-method

The complex features of the compound-salt formation result in wellbore instability during drilling operations. The mechanism of wellbore instability in compound-salt formation is studied by the analysis of mineral compositions, microstructures, physical-chemical properties, and interface mechanical properties of compound salts from different areas. The results show that the existing micro-scale pores and fractures, creep and dissolution of salt, hydration of gypsum-mudstones are the key causes of wellbore instability in compound-salt formation. In order to stabilize the wellbore in compound-salt, we propose the drilling strategies based on the synergism of multiple methods of strengthening the wellbore by the sealing and consolidating effect of drilling fluid, inhibiting the dissolution of salt and the hydration of gypsum-mudstones, balancing the water activity between rocks and drilling fluid, providing effective stress to support the wellbore. Based on the effect of water activity on the shale hydration swelling and dispersion properties, the design basis of the safe window of water activity for drilling fluids is determined. According to the wellbore instability problems when drilling in compound-salt formations in M Oil Field in the Middle East, H-S Oil Field of Uzbekistan, and Xinjiang Uygur Autonomous Region of China, the drilling fluids are designed respectively based on the proposed wellbore stabilizing technology. The field applications show that the drilling fluid technology greatly improves the wellbore stability in compound salt formations and reduces downhole problems, thereby improving drilling efficiency.

Multiscale Pore Structure Evolution of Longmaxi Shale Induced by Acid Treatment

SummaryHydraulic fracturing to generate complex fracture networks is essential for shale reservoir development. However, the recovery of shale oil and gas is still low due to various engineering and geological factors. Acid treatment has been approved as a potential approach to enhance stimulated reservoir volume (SRV) by changing petrophysical and mechanical properties. Understanding the multiscale pore structure evolution behind the macro-performance change is critical in the application of acid treatment in shale reservoirs. In this study, cylindrical and powder shale samples from the Longmaxi formation are treated with 15 wt% hydrochloric acid (HCl) for 10 days. Before and after acid treatment, X-ray computed tomography (CT) and N2 adsorption techniques are used to characterize shale pore structure at microscale and nanoscale, respectively. Combined with the determination of variations in chemical compositions of shale samples and acid solutions, the mechanism of multiscale pore structure evolution induced by acid treatment is discussed. The N2 adsorption results uncover a considerable increase in volume and size of nanopores. All the nanopores increase in carbonate-rich shale, whereas the micropores and mesopores undergo a decrease in clay-rich shale. Reconstructed 3D CT images reveal the generation of large volumes of microscale pores and fractures, which leads to an increase in porosity of about 9%. The pore structure evolution in shale due to acid treatment is controlled by both mineralogy and microstructure. These findings demonstrate the promise of acid treatment for enhanced SRV and long-term productivity of shale oil and gas reservoirs in China.

Characterization and Modelling of Multiscale Natural Fractures in Shale Reservoirs: A Case Study from a Block in the Southern Sichuan Basin

Natural fractures are vital to the efficiencies of drilling and completion operation. The purpose of this paper is to characterize and model multiscale natural fractures in shale reservoirs. Based on the seismic and log responses, as well as outcrop and core observations, we divide natural fractures into Macro, Meso, and Micro three scales. Macroscale fractures are the faults picked directly in seismic profiles. Also, Mesoscale fractures are the natural fracture corridors analyzed by ant tracking technique in 3D seismic data. Furthermore, Microscale fractures are the fractures observed in imaging logs and cores. The fracture intensity is obtained by the correlation between ant tracking attributes and fracture density in borehole. The fracture aperture, dip, and azimuth are three main parameters, which are recognized by the loggings and cores. Stochastic modelling is applied to factures. We find that faults identified by the ant tracking result are excellent in line with Macroscale faults interpreted directly from seismic data. In addition, Mesoscale fractures are indicated from the ant tracking result, which are in accord with breakpoint in the well and in keeping with tectonic history of the area. Such high consistency indicates the ant tracking result is reliable. Moreover, image logs and cores reveal that it mainly develops high angle natural fractures and the fracture aperture is about 1 mm. The fracture strike includes three sets (NNW-SSE, NE-SW, and NNE-SSW). The distribution of the natural fractures in discrete fracture network (DFN) system is distributed controlled by the ant tracking result. Comparing the histograms of DFN results and fracture characterized by seismic and logging responses, as well as outcrop and core observation, it suggests that the major part of the observed natural fractures is retained into our DFN model.