Enantiopure and highly functionalized cyclohexanes may be accessed in a single step and with high stereocontrol from the 7-oxo-2-enimides 1 with use of the title reactions (see scheme). The bifunctional substrates 1 are available by a thermal [3.3]-sigmatropic rearrangement of aldol products. Xc=chiral auxiliary; M=Cu, Al.