Objectives: This article investigates the continuous magnetohydrodynamics slip flow across an extending cylinder, including heat radiation and free stream velocity. The proposed model incorporated the Brownian motion parameter and thermophoresis. Methods: Applying the similarity transformation to a system of partial differential equations yields an ordinary differential equation of first order. Since, there is the nonlinear nature of the modified equations, these ordinary differential equations are addressed by employing mathematical modeling. The shooting process has been embraced to solve changed equations by implementing the following Runge-Kutta Fehlberg method. Findings: Graphical representations are used to show how several fluid factors, such as Casson fluid parameter, free stream velocity, thermophoresis, magnetic parameter, Brownian motion parameter, heat generation parameter, Lewis number, radiation parameter, chemical reaction and curvature parameter affect concentration, temperature and velocity. Results for physical quantity of interest are also computed and reported in tabular form. The study's main findings showed that nanoparticle temperatures rise with greater Brownian motion parameter values, whereas nanoparticle concentration falls with higher heat radiation parameter values. Additionally, it is found that with rise in Lewis number rises as 0.1, 0.4, 0.7, 1.0, 1.3, heat transfer rate falls down by 21.19%. The outcomes are calculated using the MATLAB software. Novelty: This technique's validity is defended by comparing its most recent findings to previously published results and successfully meeting the convergence criteria. The present work emphasizes the analysis of free stream flow in the cylindrical area, specifically in the existence of partial slip and heat radiation, under convective circumstances. This study has significant implications for electronic devices such as processors as well as many businesses and the field of biological and medical sciences. The present investigation aims to support production businesses in achieving the desired level of quality of their products by effectively managing the transport phenomena. Keywords: Stretching cylinder, Heat radiation, Brownian motion, Thermophoresis, Non-Newtonian nanofluid, Shooting technique