Method For Synthesis Research Articles

ФОРМУВАННЯ ІНФОРМАЦІЙНОЇ КУЛЬТУРИ НАУКОВИХ ДОСЛІДЖЕНЬ ЗДОБУВАЧІВ ВИЩОЇ ОСВІТИ

In the conditions of the information society, the modern education system must prepare conscious citizens of their country who are able to navigate in the information field, critically interpret what they hear, draw their own conclusions and seek answers to the questions posed. That is why higher education must contribute to the development of these skills and abilities. The purpose of the article is to find out the semantic meaning of the concept of “information culture” and to determine the methodology of its formation among students of higher education during scientific activity. During the writing of the article, general scientific methods of analysis and synthesis were used. The worldview and methodological principles of democratization, innovation, and flexibility of the educational process were also observed. The article defines the main approaches to understanding the essence of the concept of “information culture”. The importance of careful selection of information sources, the need for a critical understanding of the received information, and the importance of observing these principles in the course of scientific activity are emphasized. The obtained results of the research can be taken into account when planning training sessions, especially practical work. Conclusions. Thus, the concept of information culture has different definitions and is used for different fields of knowledge. The key feature of this concept is a critical attitude to the received information and its proper verification. The modern education system pays considerable attention to the formation of information culture, introducing special courses, including media education. Observance of information hygiene by students of higher education is an integral part of their educational process, especially during scientific activities. Completing a number of practical tasks for the development of critical thinking should contribute to the formation of the information culture of higher education graduates. Key words: information culture, information society, media education, critical thinking, scientific activity.

Preparation of the LiGa Intermetallic Alloy by Electrochemical or Thermal Method for Ammonia Synthesis

Preparation of the LiGa Intermetallic Alloy by Electrochemical or Thermal Method for Ammonia Synthesis

Configuration Design and Size Optimization of a High-Precision Novel Parallel Pointing Mechanism Based on Interference Separation

AbstractPointing mechanism is widely used in aerospace field, and its pointing accuracy and stability have high requirements. The pointing mechanism will be affected by external interference when it works. In order to eliminate the impact of interference forces on the output accuracy of the mechanism, firstly, this paper proposes a design method for high-precision pointing mechanisms based on interference separation, aiming at the high-precision pointing requirements of pointing mechanisms. Based on the screw theory, a synthesis method for inner compensation mechanisms has been proposed. And a new type of double-layer parallel mechanism has been designed to compensate for interference forces. Then, the kinematics and dynamics of the mechanism are carried out. An evaluation index for compensating external interference forces is proposed. The interference compensation analysis is conducted for the pointing mechanism. The correctness of the proposed interference force compensation coefficient is verified. Finally, in order to find the optimal solution for the workspace and interference force compensation coefficient of the pointing mechanism, multi-objective optimization design of the structural parameters of the mechanism was carried out based on the particle swarm optimization algorithm. This provides a theoretical basis for the prototype design of the subsequent double-layer parallel mechanism. This double-layer parallel mechanism combines the advantages of large load-bearing capacity, large workspace, and high output accuracy. It can be better applied in the aerospace field where high-precision pointing and force interference compensation are integrated.

In Silico Study of the Potential Inhibitory Effects on Escherichia coli DNA Gyrase of Some Hypothetical Fluoroquinolone–Tetracycline Hybrids

Background/Objectives: Despite the discovery of antibiotics, bacterial infections persist globally, exacerbated by rising antimicrobial resistance that results in millions of cases, increased healthcare costs, and more extended hospital stays. The urgent need for new antibacterial drugs continues as resistance evolves. Fluoroquinolones and tetracyclines are versatile antibiotics that are effective against various bacterial infections. A hybrid antibiotic combines two or more molecules to enhance antimicrobial effectiveness and combat resistance better than monotherapy. Fluoroquinolones are ideal candidates for hybridization due to their potent bactericidal effects, ease of synthesis, and ability to form combinations with other molecules. Methods: This study explored the mechanisms of action for 40 hypothetical fluoroquinolone–tetracycline hybrids, all of which could be obtained using a simple, eco-friendly synthesis method. Their interaction with Escherichia coli DNA Gyrase and similarity to albicidin were evaluated using the FORECASTER platform. Results: Hybrids such as Do-Ba, Mi-Fi, and Te-Ba closely resembled albicidin in physicochemical properties and FITTED Scores, while Te-De surpassed it with a better score. Similar to fluoroquinolones, these hybrids likely inhibit DNA synthesis by binding to enzyme–DNA complexes. Conclusions: These hybrids could offer broad-spectrum activity and help mitigate bacterial resistance, though further in vitro and in vivo studies are needed to validate their potential.

Potential biological applications of environment friendly synthesized iron oxide nanoparticles using Sageretia thea root extract.

The green synthesis of Iron oxide nanoparticles (IONPs) has shown numerous advantages over conventional physical and chemical synthesis methods as these methods non-ecofriendly and uses toxic chemicals and complicated equipments. In present study, Iron oxide nanoparticles (IONPs) were created using simple, sustainable, eco-friendly and green chemistry protocol. The roots of novel medicinal plant Sageretia thea was used as a bio-template for the preparation of IONPs. Further, the synthesis of IONPs was confirmed using different analytical tools like UV-Vis, FT-IR, XRD, EDX, and SEM. The average sizes of (NPs) were found to be 16.04nm. Further, asynthesized IONPs were evaluated for several biological potentials including antibacterial, antifungal Anti-radical potentials (DPPH) and cytotoxicity assays. Antibacterial potencies were investigated using bacterial strains (in the concentration range of 1000-31.25µg/mL) revealing significant antibacterial potentials. ABA and SAU was reported to be least susceptible while KPN was observed to be most susceptible strain in bactericidal studies. Further, different fungal strains were used to investigate the antifungal potentials of IONPs (in the concentration range of 1000-31.25µg/mL) and revealed strong antifungal potencies against different pathogenic strains. Furthermore, MRA, FA and ANI were most susceptible and ABA was least susceptible in fungicidal examination. Significant cytotoxicity potential was examined using brine shrimps cytotoxicity assay, thus revealing the cytotoxic potential of asynthesized IONPs. The IC50 for S. thea based IONPs was recorded as 33.85µg/mL. Strong anti-radical potentials (DPPH) assay was performed to evaluate the ROS scavenging potential of S.T@IONPs. The highest scavenging potential was noted as 78.06%, TRP as 81.92% and TAC as 84% on maximum concentration of 200µg/mL. In summary, our experimental results concluded, that asynthesized IONPs have strong antibacterial, antifungal, DPPH scavenging and cytotoxic potentials and can be used in different biological applications. In nutshell, our as-prepared nanoparticles have shown potential bioactivities and we recommend, different other in vitro and in vivo biological and bioactivities to further analyze the biological potentials.

Study of physical properties of zinc oxide thin films using the hydrothermal method

Zinc oxide (ZnO) is a versatile semiconductor material with unique physical, chemical, and optical properties. It has garnered significant attention in recent years due to its wide applications in electronics, photonics, sensors, and environmental devices. This paper provides a comprehensive review of the fundamental properties of ZnO, its synthesis methods, and the wide range of applications it enables. The focus is on the material’s electronic properties, optical characteristics, and how these features are being leveraged in innovative technologies such as transparent conductors, UV detectors, and gas sensors.

CRIMINAL, CIVIL AND SOCIO-ECONOMIC ASPECTS OF THE PROTECTION OF UNBORN LIFE IN THE REPUBLIC OF KOSOVO

Background: Human life is a natural right, and as a fundamental right, its loss entails the loss of all other rights. Consequently, human life is protected by international and national legal acts. This study will approach the chosen topic from a critical thinking angle. Its purpose is to present the basic notions of life, tackle the protection of life through positive legal norms, examine the legal treatment of the unauthorised termination of pregnancy, and provide an overview of data related to such terminations. Furthermore, we will examine whether current legal provisions in Republic of Kosovo effectively safeguard life or, instead, permit the termination of unborn life. The topic will be approached from the perspectives of civil law and the socioeconomic aspect of this phenomenon. Given that Kosovo was once an Autonomous Region of the Socialist Federal Republic of Yugoslavia, we will draw a comparative parallel in terms of legal reforms. The importance of this study will be evident based on the fact that studies of this interrelated nature of such a topic are lacking. Consequently, such a study will be relevant to legislation and legal practice. Methods: The selected topic will be treated by applying the historical-legal method, the normative method, the comparative method, the method of analysis and the synthesis method. Through the application of these study methods, an effort will be made to achieve the goal and the study objective, always with the aim of providing concrete answers to the research questions and validating the raised hypotheses. Results and Conclusions: While it must be accepted that termination of pregnancy is not murder, it is crucial to recognise that if it occurs at advanced stages of fetal development, it cannot be called anything other than murder. In addition to the legal fragility facing Kosovar society, there is also a notable weakness in the punitive policy. This policy, in its effort to be humane towards the perpetrators of criminal offences, may fail to achieve its intended objectives. Consequently, there is an urgent need for a shift in legislative policy concerning certain antisocial phenomena. Such a change would inherently lead to a reevaluation of punitive measures, especially considering that the criminal offence of unauthorised termination of pregnancy continues to be present in our society.

METHODOLOGICAL APPROACHES TO ASSESSING THE DEVELOPMENT OF CROSS-BORDER CO-OPERATION OF UKRAINIAN REGIONS

The research highlights the objective need and the problems of assessing the development of cross-border co-operation in Ukraine, especially in the conditions of critical economic and social instability caused by a full-scale invasion and its consequences. The purpose of the article is to scientifically substantiate methodological approaches to the assessment of cross-border territorial co-operation and the construction of a balanced and multi-level information and analysis system. In order to achieve this goal, the methods of analysis and synthesis, grouping of indicators, theoretical generalisation and content analysis were used. It has been established that there is no generally accepted methodology for evaluating these processes. Furthermore, the methodologies that do exist cover a range of spheres and mechanisms of interaction with European countries, with a particular focus on specific programmes and initiatives. Additionally, it was determined that Ukraine lacks a systematic approach to monitoring the aforementioned processes, despite the Ministry of Community and Territorial Development of Ukraine's obligation to regularly furnish data on the advancement of the goals set forth in the State Program for the Development of Cross-Border Co-operation of Ukraine for the 2021-2027 period. It is proposed to expand the system of indicators for relevant monitoring by adding a number of basic indicators (GRP, investment activity, international image of the territory). The findings of the study substantiate the issue of inadequate substantiation of the theoretical and methodological foundations of cross-border co-operation of Ukrainian territories in the context of war and the challenges posed by European integration. This proves the need to develop a multi-level system for monitoring cross-border co-operation at the level of the state, macro-raions, oblasts and hromadas (raions) with a list of clear criteria and evaluation indicators that would take into account the basic principles, main tasks and risks of such co-operation. It is of the utmost importance to acknowledge the invaluable experience of European countries in the assessment of cross-border relations, particularly in the construction of domestic methodology and the search for additional data sources. The foundation for future research in this area can be an evaluation of the extent to which the objectives set out by the Ukrainian state for the development of cross-border co-operation have been met, and an assessment of the potential for further progress.

RESOLVING CONFLICTS OF LAW DURING JUDICIAL PROCEEDINGS: AN EMPIRICAL STUDY OF UKRAINE

Background: Law is a key regulator of social relations. Its systemic nature is fundamental for proper, clear and comprehensive regulation of legal relations. As an integral system, law has its own logic, structure, order and purpose. This purpose is to properly regulate social relations, ensure law and order, and qualitatively and consistently satisfy the rights, obligations and interests of participants in legal relations. However, legal regulation is not without its flaws. One major issue of legal regulation is gaps in the law, where certain social relations lack proper legal regulation due to a lack of specific legislative or legal approaches. Other flaws include conflicts between laws, legislative gaps, qualified silence of the legislator, "darkness" of legal norms, and a "seeming" need for legal regulation and other legal phenomena similar in nature. This article addresses how judges resolve conflicts of law in the course of judicial proceedings, namely the construction of a mechanism to resolve conflicts within national legislation to ensure the right to a fair trial. This issue is of particular importance in the context of the war in Ukraine because, unlike in the relatively stable judicial practice of resolving disputes that arise in a society where there is no war, today, the courts now face unprecedented cases, such as those involving military medical commissions decisions, financial support of military personnel, and new wartime criminal prosecution. Additionally, judges must navigate the procedural norms for the administration of justice in wartime, which are changing rapidly. The study identifies specific cases of conflict in law, particularly in issues related to mobilisation. It highlights how inconsistencies in current legislation and the lack of uniform approaches to overcoming them often prevent citizens from exercising their rights. This situation directly contradicts the Sustainable Development Goals in terms of building peaceful and inclusive societies for sustainable development, ensuring access to justice for all, and building effective, accountable, and inclusive institutions at all levels. The authors of the article highlight the growing importance of legal principles in resolving conflicts within the law. Foundational concepts like the rule of law, legal certainty, and legality are recognised grounds for judicial decision-making. Accordingly, this allows courts to interpret conflicts in specific areas of legislation – such as tax legislation in favour of the taxpayer, child rights in favour of children, and labour law in favour of employees. Consequently, similar claims may be resolved differently depending on their subject matter. To support this analysis, the authors analysed 150 decisions of Ukrainian judges, studied the concept of conflicts, formulated a refined definition, assessed the role of judicial law-making in resolving legal conflicts, and developed a mechanism for addressing conflicts in law by judges. Methods: The authors employed a general dialectical analysis approach grounded in the doctrine of society and thinking, along with the historical method, to analyse the development of legal norms and institutions in different historical periods. This approach provides insights into their origins, evolution and impact on the modern legal system. Methods of analysis and synthesis of information were also utilised. To support the authors’ conclusions, relevant empirical information, including court decisions from the Unified State Register of Court Decisions, were referenced. A total of 150 court decisions containing collisions from 2015 to 2024 were analysed, 22 of which were cited in this article. Results and Conclusions: Conflicts in law are defined as subjectively caused phenomena involving the confrontation of several norms or their totality, resulting in the inability to apply legal norms effectively, clearly, and consistently to regulate social relations. A definition of conflicts in law from a judicial perspective is also proposed: they are contradictions within legal regulation, a negative legal phenomenon that a judge, with the authority vested in them, must resolve in a manner that upholds fundamental principles of law during the administration of justice.

Sulfur dioxide gas sensor based on vanadium oxide doped TiO2 nanopaper

Abstract The gas sensor based on TiO2 nanomaterials is promising for both industry and daily life because of its simple fabrication, low cost, high sensitivity, and easy application to micro-devices. However, its selectivity is relatively low and strongly influenced by the environment, thus limiting its practical application. In this work, we prepared TiO2 nanopaper by methods of hydrothermal synthesis and conventional paper preparation. To improve the selectivity, we added V2O5 by immersing the as-prepared nanopaper in an ammonium metavanadate (NH4VO3) solution evenly dispersed in ethanol. Nanopaper is a random array of long nanowires and nanofibers, which retains its shape and structure at high temperature, unlike pure nanowires, due to its high porosity and mechanical stability. V2O5 leads to a selective sensing performance with high catalytic activity for SO2 gas. The surface structure of the sensing material and its porosity were characterized by SEM, XRD, XPS. The improved sensing material exhibited a high response of about 22.6 for 100 ppm SO2 and a fast response and recovery of 9 s and 14 s, respectively. It also exhibited good reproducibility and selectivity in other interfering gases. Furthermore, the long-term sensing performance in the atmospheric environment was maintained for about 50 days.

Enantioselective synthesis of inherently chiral sulfur-containing calix[4]arenes via chiral sulfide catalyzed desymmetrizing aromatic sulfenylation.

Inherently chiral calixarenes hold great potential for applications in chiral recognition, sensing, and asymmetric catalysis due to their unique structures. However, due to their special structures and relatively large sizes, the catalytic asymmetric synthesis of inherently chiral calixarenes is challenging with very limited examples available. Here, we present an efficient method for the enantioselective synthesis of inherently chiral sulfur-containing calix[4]arenes through the desymmetrizing electrophilic sulfenylation of calix[4]arenes. This catalytic asymmetric reaction is enabled by a chiral 1,1'-binaphthyl-2,2'-diamine-derived sulfide catalyst and hexafluoroisopropanol. Various inherently chiral sulfur-containing calix[4]arenes are obtained in moderate to excellent yields with high enantioselectivities. Control experiments indicate that the thermodynamically favored C-SAr product is formed from the kinetically favored N-SAr product and the combination of the chiral sulfide catalyst and hexafluoroisopropanol is crucially important for both enantioselectivity and reactivity.

Offline supervisory control synthesis: taxonomy and recent developments

AbstractThis paper surveys recent advances in supervisory control theory since its 30th anniversary in 2017. We performed a systematic literature search and selected 272 relevant papers, with a focus on automata-based approaches. These were fitted into coherent narratives, based in part on a taxonomy of supervisor synthesis methods. The obtained papers show the fast and vast progress of the field, where recent research covers a wide range of new synthesis optimization techniques, different aspects such as fault tolerance, security, and timing, and new and diverse application domains. This survey refrains from in-depth descriptions of techniques, instead focusing on high-level contributions of recent works, how they relate to each other, and future directions for research.

Recent Advances in Electrocatalytic C-N Coupling for Urea Synthesis.

Urea, one of the most widely used nitrogen-containing fertilizers globally, is essential for sustainable agriculture. Improving its production is crucial for meeting the increasing demand for fertilizers. Electrocatalytic co-reduction of CO₂ and nitrogenous compounds (NO₂-/NO₃-) has emerged as a promising strategy for green and energy-efficient urea synthesis. However, challenges such as slow reaction kinetics and complex multi-step electron transfers have hindered the development of efficient urea synthesis methods. This review explores recent advances in the electrocatalytic C-N coupling process, focusing on bimetallic catalysts, metal oxide/hydroxide catalysts, and carbon-based catalysts. The review also discusses the future prospects of designing effective catalysts for electrocatalytic C-N coupling to improve urea synthesis.

Advances in Green Synthesis of Silver Nanoparticles: Sustainable Approaches and Applications

In the rapidly evolving field of nanotechnology, the synthesis of silver nanoparticles (AgNPs) has shifted towards eco-friendly methodologies, aligning with the growing demand for sustainable practices. Biologically synthesized AgNPs, particularly noteworthy for their applications in medicine and materials science, exhibit exceptional efficacy against microorganisms. The unique physicochemical properties of AgNPs, including their small size and large surface area-to-volume ratio, contribute to their versatility in diverse sectors. The advantages of AgNPs, such as ease of production, low cost, and high carrier capacity, make them preferred for various applications, including drug delivery systems. Despite concerns about environmental hazards and toxicity, the benefits of AgNPs, such as controlled drug release and targeted delivery, position them as valuable contributors to advancements in nanotechnology. Green synthesis methods, emphasizing biological processes and natural compounds, gain prominence for their sustainability and reduced environmental impact. The regulatory oversight of nanoproducts ensures their safe use, balancing their advantages with environmental considerations. Ongoing research promises further innovations, solidifying AgNPs' role as key contributors to progress in nanotechnology and materials science. Keywords: Silver nanoparticles, Green synthesis, Sustainable approaches, Characterization, Applications, Eco-friendly methods.

A Near-Infrared Fluorescent Probe for Live-Cell Imaging of RNA in the Cancer Cells.

Ribonucleic acid (RNA), a biomolecular compound polymerized by many riboside monomers, is one of the most essential substances in life. Monitoring RNA changes within organisms will play an important role in the diagnosis and treatment of major genetically related diseases. Herein, we synthesized a novel compound QOT-NA as near-infrared probe for imaging RNA in cancer cells. The synthesis method and photophysical properties of the probe were presented. The titration and selectivity experiments demonstrated that the probe detected RNA in vitro. Moreover, the RNA imaging experiments indicated that the near-infrared RNA probe QOT-NA can locate RNA within cancer cells.

Parallel–Serial Robotic Manipulators: A Review of Architectures, Applications, and Methods of Design and Analysis

Parallel–serial (hybrid) manipulators represent robotic systems composed of kinematic chains with parallel and serial structures. These manipulators combine the benefits of both parallel and serial mechanisms, such as increased stiffness, high positioning accuracy, and a large workspace. This study discusses the existing architectures and applications of parallel–serial robots and the methods of their design and analysis. The paper reviews around 500 articles and presents over 150 architectures of manipulators used in machining, medicine, and pick-and-place tasks, humanoids and legged systems, haptic devices, simulators, and other applications, covering both lower mobility and kinematically redundant robots. After that, the paper considers how researchers have developed and analyzed these manipulators. In particular, it examines methods of type synthesis, mobility, kinematic, and dynamic analysis, workspace and singularity determination, performance evaluation, optimal design, control, and calibration. The review concludes with a discussion of current trends in the field of parallel–serial manipulators and potential directions for future studies.

Iridium-Catalyzed Chemo- and Enantioselective Hydrogenation of Cycloalkenones to Access Chiral Cycloallylalcohols.

A method for the efficient synthesis of chiral cycloallylalcohols has been developed, achieving excellent yields and enantioselectivities (>99% conversion, turnover number of ≤50 000, and >99% ee). This approach accommodates a variety of cycloalkenones with different aryl substituents and is tolerant of a broad range of functional groups. The synthetic utility of this method has been demonstrated through gram-scale synthesis and subsequent transformations into diverse enantioenriched oxygen-containing compounds.

A Review on Chemistry and Methods of Synthesis of 1,2,4-Triazole Derivatives.

This review provides a comprehensive overview of research on 1,2,4-triazoles conducted over the last fifteen years. 1,2,4-Triazoles are highly significant in the pharmaceutical industry, with numerous compounds from this class used clinically as antifungal, antiviral, antibacterial, anti-inflammatory, and antitubercular agents. Beyond their pharmaceutical relevance, this review also explores their role in material science and agriculture. In material science, 1,2,4-triazoles are gaining prominence, particularly in the development of energetic materials (EMs), due to their exceptional properties such as thermal stability, coordination ability, and performance comparable to well-known explosives. Their applications extend to polymers, corrosion inhibitors, and metal-organic frameworks (MOFs), and they play a significant role in the development of functional materials for sensors, catalysis, and energy storage. Additionally, the review addresses general aspects and synthetic methodologies for the functionalization and construction of the 1,2,4-triazole ring. Synthetic methods discussed include metalation synthesis, cyclization of hydrazine derivatives, multicomponent reactions, cyclization of amides and amidines, and microwave-assisted synthesis. Given the significance of the triazole scaffold, its synthesis has garnered considerable attention due to its wide-ranging applications across various industrial sectors.

New emerging materials with potential antibacterial activities.

The increasing prevalence of multidrug-resistant pathogens is a critical public health issue, necessitating the development of alternative antibacterial agents. Examples of these pathogens are methicillin-resistant Staphylococcus aureus (MRSA) and the emergence of "pan-resistant" Gram-negative strains, such as Pseudomonas aeruginosa and Acinetobacter baumannii, which occurred more recently. This review examines various emerging materials with significant antibacterial activities. Among these are nanomaterials such as quantum dots, carbon quantum dots, metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and layered double hydroxides, all of which demonstrate excellent antibacterial properties. Interestingly, including antibacterial agents within the structure of these materials can help avoid bacterial resistance and improve the long-term efficacy of the materials. Additionally, the antibacterial potential of liquid solvents, including ionic liquids and both deep eutectic solvents and natural deep eutectic solvents, is explored. The review discusses the synthesis methods, advantages, and antibacterial efficacy of these new materials. By providing a comprehensive overview of these innovative materials, this review aims to contribute to the ongoing search for effective solutions to combat antibiotic resistance. Key studies demonstrating antibacterial effects against pathogens like Escherichia coli, Staphylococcus aureus, and multidrug-resistant strains are summarized. MOFs have exhibited antibacterial properties through controlled ion release and surface interactions. COFs have enhanced the efficacy of encapsulated antibiotics and displayed intrinsic antibacterial activity. Other nanomaterials, such as quantum dots, have generated reactive oxygen species, leading to microbial inactivation. This review aims to provide insights into these new classes of antibacterial materials and highlight them for addressing the global crisis of antibiotic resistance. KEY POINTS: • Nanomaterials show strong antibacterial effects against drug-resistant bacteria • Emerging solvents like ionic liquids offer novel solutions for bacterial resistance • MOFs and COFs enhance antibiotic efficacy, showing promise in combating resistance.

Electronic Properties of Polyaniline-Graphene Nanocomposites Synthesized via Solution Mixing Method.

A key advantage of combining the exceptional properties of graphene with conducting polymers, lies in their remarkable property tunability through filler additions into polymer matrices, with synthesis routes playing a crucial role in shaping their characteristics. In this work, we examine the electronic properties of polyaniline(PANI) and graphene nanocomposites synthesized via a simple solution mixing method, which offers advantages such as ease of use and efficiency. Increasing graphene content enhances nanocomposite conductivity, and a percolation effect is observed. The percolation threshold is high and is consistent with a strong role played by voids in the structure. Temperature-dependent conductivity measurements highlight three distinct conduction regimes: insulating, critical, and metallic. These findings underscore the significant influence of synthesis method and structural disorder on shaping electronic properties, paving the way for engineering multifunctional nanocomposites with exceptional versatility and performance.