Transesterification Method Research Articles

Investigation of performance and emission values of new type of fuels obtained by adding MgO nanoparticles to biodiesel fuels produced from waste sunflower and cotton oil

Biodiesel was produced using the transesterification method from waste sunflower and cotton oil. As a result of the analysis of the new type of nanoparticle-added biodiesel fuels we produce, the parameters with a decrease in emissions are CO, HC, and smoke emissions. There is a partial increase in NOx emissions. In addition, nanoparticle addition made a positive contribution by increasing thermal efficiency. The produced MgO nanoparticle-doped biodiesel fuel samples were compared with diesel fuel. As seen in these comparisons, nanoparticle additives contributed positively to reducing emission values. These improvements were observed as a 31.25 % reduction in CO in the WSOB5+ 100 ppm MgO fuel sample, 41.6 % reduction in HC in the COB5+ 100 ppm MgO fuel sample and 36.92 % reduction in smoke (soot) in COB5+ 100 ppm MgO fuel sample. A comparison was made between the fuel samples in our study, biodiesel produced from waste sunflower and cotton, and fuels produced with nanoparticle additives of 50, 75, and 100 ppm. It was observed that the most efficient fuel sample in terms of emission values and performance was COB5 + 100 ppm MgO nanoparticle additive fuel. The biodiesel fuel sample produced with COB5 + 100 ppm MgO nanoparticle additives provided a 3.25 % improvement in thermal efficiency compared to biodiesel without additives. A positive effect on the heat transfer coefficient was observed as a result of the data on the new type of nanoparticle doped biodiesel. With the impact of this contribution, parameters such as positive contribution to in-cylinder temperature, ignition delay, and combustion time were positively affected in the same direction. Another positive effect of nanoparticle additive to biodiesel, thermal efficiency, increased by 1.1 % in the COB5 + 100 ppm MgO fuel sample. Depending on the decrease in emission rate, it was concluded that the nanoparticle additive added to the fuel greatly benefits the environment.

Synthesis and characterisation of waste-derived biodiesel and enhancement of its energy and environmental metrics using cetane improver: an experimental study

The primary objective of this study is to produce Bauhinia monandra biodiesel (BMB) using seed waste and improve its energy and environmental properties by integrating a cetane enhancer. The methyl ester of biooil was obtained using the transesterification method, and the properties were analyzed. Different quantities of BMB were combined with diesel fuel, and 2-ethyl hexyl nitrate (EHN) was introduced to the blend of 30% BMB-diesel fuel to improve both energy and environmental performance measurements. The research findings indicate that the FAME and physicochemical properties of BMB are comparable to those of diesel fuel. The brake thermal efficiency (BTE) of the engine decreases by 4.2% for 30% BMB blended fuel, whereas hydrocarbon (HC), carbon monoxide (CO), and smoke emissions decrease by 11.6%, 6.7%, and 10.5%, respectively. As the concentration of BMB increases, there is a reduction in both the maximum value of in-cylinder pressure and the net heat release rate. Conversely, brake-specific fuel consumption (BSFC) and NOx emissions increase by 5.7% and 4.7%, respectively. The incorporation of EHN in the test fuel enhances BSFC and BTE by 4.2% and 4.3%, respectively, whereas NOx, HC, and CO emissions are reduced by 5.2%, 9.2%, and 9.9%, respectively.

Determination of the effect of low concentration titanium dioxide nano fuel additive in biodiesel on performance and emissions

In this study, the effect of nanoparticle addition into rapeseed methyl ester (R0) produced by the transesterification method on engine performance and emissions was experimentally investigated. Titanium dioxide was used as a nano fuel additive and was added to the test fuels at rates of 50 ppm (RTi50) and 75 ppm (RTi75) using an ultrasonic mixer. The effect of titanium dioxide on engine performance and exhaust emissions was experimentally determined by taking advantage of its photocatalysis effect and chemical reaction accelerator properties. Additionally, titanium dioxide additive reduced the viscosity and density of biodiesel fuel, resulting in higher micro explosion. According to the test results carried out at 4 different engine loads, brake specific fuel consumption decreased by 7.51% and 8.62% in RTi50 and RTi75 fuels compared to R0 fuel. Brake thermal efficiency increased by 2.47% and 6.21%, respectively. The improvement in combustion achieved by the nano additive increased the conversion of CO emissions into CO2, increased NOX emissions, reduced smoke emissions and caused more complete combustion products to come out of the exhaust.

Investigation of high percentage of dimethyl ether on biodiesel usage in a diesel engine

Demand for cleaner energy sources both as additive and alternative fuels that can substitute or contribute to the usage of conventional fuels is growing. Researchers have mainly focused on improving or finding a renewable fuel from vegetable oil or addition of chemicals and alcohols for IC engine. This study analyzed the effects of a high percentage of dimethyl ether (DME) combined with biodiesel in a diesel engine. Transesterification method was selected for conversion of pure safflower oil to biodiesel. DME was blended with biodiesel at concentrations of 50% and 25% on a volume basis, respectively. Engine performance and emissions tests demonstrated that the thermal efficiency values were increased at high load operation when the engine was fueled with high percentage of DME. Furthermore, compared to conventional diesel, there has been a notable decrease in NOx emissions. Nevertheless, the introduction of DME blend had negligible effects on CO2 emissions. However, when using a high ratio of DME blend, HC emissions were found to increase, whereas a low ratio of DME blend resulted in decreased HC emissions. Apart from these, some irregularities were observed both on heat release rate and cylinder pressure especially for 50% of DME usage. Finally, the values for both brake-specific fuel consumption and mass fuel of DME-blended fuels were deteriorated.

Biodiesel Synthesis from Date Seed Oil Using Camel Dung as a Novel Green Catalyst: An Experimental Investigation

Biodiesel is seen as more environmentally benign than petroleum-based fuels. It is also cheaper and capable of creating cleaner energy, which has a good impact on increasing the bioeconomy. An investigation was conducted on a novel heterogeneous catalyst system utilized in the synthesis of eco-friendly biodiesel from date seed oil, a non-edible feedstock obtained through the calcination of desiccated camel manure at varying temperatures. X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) analysis, and scanning electron microscopy (SEM) were utilized to characterize this catalyst. As a result of raising the calcination temperature, the results showed that the pore size of the catalyst decreased. The biodiesel production was optimized to be 86% by using the transesterification method. The optimal reaction parameters included a catalyst with 4% loading, a molar ratio of 1:8 between date seed oil and ethanol, and a temperature of 75 °C for a reaction period of three hours. The confirmation of FAME generation was achieved by gas chromatography–mass spectrometry (GC–MS). The fuel qualities of fatty acid ethyl ester are in accordance with ASTM, suggesting that it is a suitable alternative fuel option. Utilizing biodiesel derived from waste and untamed resources to establish and execute a more sustainable and ecologically conscious energy plan is praiseworthy. The adoption and integration of green energy practices could potentially yield positive environmental outcomes, thereby fostering enhanced societal and economic development for the biodiesel sector on a broader scale.

Disposal of used oils as a prospective method of production of biodiesel

The article is devoted to the improvement of the production technology of diesel biofuel from waste oils, which are a significant source of environmental pollution. Environmental pollution is one of the biggest environmental problems of our time. Used oils that are not properly disposed of cause serious environmental problems, including water and soil pollution. The use of waste oils for the production of biofuel is a promising technology that allows reducing the amount of pollution and reducing dependence on fossil fuels. Biodiesel from waste oils has significant environmental, economic and sustainable advantages. The main goal of the article is a detailed analysis of modern technologies for the production of diesel biofuel from waste oils and an assessment of their improvements and impact on ecology, economy and society. The article discusses innovative approaches to the processing of used oils, their purification and preparation for further use. An analysis of the main methods of transesterification, hydrogenation, esterification and enzyme catalysis, as well as the latest technologies, such as ultrasonic and microwave intensification of biofuel production, was carried out. New technological solutions for the preliminary preparation of used oils with a high content of free fatty acids using a combination of acid catalysts are proposed, and a technological scheme of the full production cycle is developed. The rational parameters of the equipment for the preliminary preparation of used oils with a high content of free fatty acids have been determined. Recommended conditions include hydrogenation temperature not higher than 80°С, duration of the process not less than 40 minutes; separation of the water-protein part by centrifugation at a rotation frequency of the centrifuge rotor of 3000 rpm for 20 minutes; the esterification reaction temperature is no more than 60°C; molar ratio of alcohol to oil 9:1; acid catalyst concentration within 1-15%; the intensity of mixing in the reactor is 31.42 s-1; the duration of the process is not less than 120 minutes. It was established that it is advisable to use potassium hydroxide for the transesterification reaction. The use of potassium hydroxide is beneficial because the potassium salts formed during the technological process of diesel biofuel production can be used as mineral fertilizers. According to the results of the research, the optimal parameters for the transesterification reaction were chosen: the amount of methanol - 20% by mass. from the weight of the oil, the KOH 1 catalyst is 1.5%, the temperature of the process is 60°C and the duration is 60-70 minutes. Examples of successful implementation of these technologies in various countries of the world, in particular in Europe, the USA and Asia, are presented. Additionally, recommendations are provided for further research and technology development, including the need to improve waste oil purification methods, optimize transesterification processes, and integrate renewable energy sources. The prospects and challenges of the industry of biofuel production from waste oils are considered, in particular the issues of regulatory support, financial incentives and investment attraction.

Catalytic Potential of Singgora Roof Tiles in Transesterification for Sustainable Biodiesel

The study centred around the uitilization of Singgora roof tiles as a heterogeneous catalyst in the production of biodiesel via the transesterification process. The motivation behind this choice stems from the non-recyclable nature of Singgora roof tiles and their potential applicability in biodiesel synthesis. To enhance the catalytic properties, zinc oxide (ZnO) is incorporated using the wet impregnation technique during catalyst preparation. The catalyst was characterized by XRF and SEM-EDX. A two-step transesterification method is employed to mitigate the levels of free fatty acid (FFA) in waste cooking oil (WCO). The initial step involves treating the WCO with sulfuric acid (H2SO4) to reduce FFA. Subsequently, the Singgora roof tiles catalyst is utilized in the second step. A high yield of FAMEs, specifically 96.96%, was achieved under the optimal conditions, which included a methanol-to- oil ratio of 12:1, a catalyst concentration of 1 wt.%, a reaction temperature of 65 °C, and a reaction time of 2 hours. The quality of the biodiesel produced was analyzed according to biodiesel standards such as ASTM D6751, EN 14214, and AOCS, and it met all the required standards. The study demonstrates the potential of using Singgora roof tiles as a heterogeneous catalyst in biodiesel production, offering a promising approach to repurposing non-recyclable materials and advancing sustainable biodiesel production methods.

Electrolysis Approach of Fatty Acid Methyl Ester Production Using Alkali Hydroxides and Their Alkoxides

The depletion of fossil fuels and environmental concerns have led to the search for alternative fuels (biodiesel) derived from renewable resources. Electrolysis is a promising method of fatty acid methyl ester (FAME) synthesis that can be maintained at room temperature. Nevertheless, the low reaction rates have been commonly accelerated using a combination of catalysts and electrolytes. This work proposed a novel electrolyte-free electrolysis approach for biodiesel synthesis from soybean oil using alkaline hydroxide (NaOH, KOH) and alkaline methoxide (NaOCH3, KOCH3)catalysts. Though all of them demonstrated high biodiesel yield, KOCH3 exhibitedthe highest efficiency. Based on response surface methodology, the highest FAME yield of 97.11% was achieved at optimal electrolysis voltage of 18.76V, water amount of 1.97 wt.%, KOCH3 amount of 3.17 wt.%, and methanol/oil of 21.33:1 molar, and reaction time of 60 min. The fuel properties of synthesized biodiesel agreed with international standards.The findings of this work suggest that electrolyte-free electrochemical using alkaline hydroxides and alkaline methoxides as catalysts could be a useful alternative to conventional transesterification method for producing biodiesel. Keywords: Alkaline catalysts, Biofuel, Box–Behnken Design, Electrochemical approach

Outcome of novel combination of graphene nanoparticles and Moringa methyl ester fueled engine working under varying loads and compression ratios

The widespread use of petroleum products in modern times has led to a search for alternative resources. Biofuel is a promising alternative to petroleum fuel, but biodiesel has a lower calorific value and is slightly more denser than diesel. To address this, a novel combination of GNA emulsified MME20 fuel is being investigated. This study aims to analyze the impact of a novel Nano additive blended biodiesel on engine performance and optimize the best compression ratio for the selected blend. The novelty of the study lies in the production of novel GNA emulsified MME fuel and its influence on a conventional CI engine. To achieve the objectives of the study, MME was produced using a two-phase transesterification method, and GNA was added to the MME20 at concentrations of 30, 60, and 90 ppm using the ultrasonication method. Engine experiments were then conducted using the prepared samples at CRs of 16, 17.5, and 19, and the results were compared with the standard diesel and MME20 blend. The results showed that the CP of the MME20 + GNA30 fuel at a CR 19 revealed a 14% increase compared to diesel. The ID of the fuel decreased by 20% compared to diesel at CR19, and there was a 23.5% increase in the CD for the MME20 + GNA30 blend compared to diesel at CR19. The BTHE for the MME20 + GNA30 fuel showed increases of 2.64% and BSFC and EGT decreases of 3.6% and 3.9%, respectively, at CR19 compared to the other blends. In summary, the study found that MME20 with GNA30, along with VCR, significantly enhanced the engine attributes compared to the pure diesel-operated standard CI engine conditions.

COCOFUEL: A Microcontroller-Based Biodiesel Production Machine

In the global landscape, the coconut stands out, with over 61 million tons harvested annually, yielding approximately 75 coconuts per tree annually. Recognizing its multifaceted benefits, including its suitability as a biofuel, various countries have endeavored to develop biodiesel production machines, each employing distinct methodologies and chemical compositions. Central to these efforts has been the drive to optimize production efficiency while minimizing costs, encompassing chemical inputs, procedural complexity, and energy consumption. This project undertook the design and implementation of a microcontroller-based machine tailored exclusively for biodiesel production via the transesterification method, utilizing coconut oil, methanol, and a catalyst. Adopting the Rapid Application Development framework, the project unfolded through iterative cycles, encompassing analysis, design, prototyping, testing, and refinement. The machine’s core functionalities were orchestrated by the Arduino Mega microcontroller, orchestrating the operation of washer motors, solenoid valves, and the heating rod, complemented by a relay, Bluetooth module, and voltage regulator. Thorough testing and evaluation underscored the machine’s reliability and efficacy in producing biodiesel from coconut oil, marking a significant stride toward renewable en ergy advancement. This accomplishment not only heralds progress in green energy solutions but also offers a compelling response to the environmental imperatives associated with conventional diesel fuels. The potential for reduced carbon emissions and the promotion of environmental sustainability amplifies the significance of this development, charting a course toward a greener future through the synergy of natural resources and cutting -edge technology.

Oilseed viability: A crucial factor for the success of the biodiesel industry

The oil derived from the seeds of the pongamia plant (Pongamia pinnata) has the potential to produce biodiesel. However, pongamia oil's high viscosity and conradson carbon residue make it unsuitable to use directly as a fuel in the already existing diesel engines. As a result, the experiments were carried out to determine the effectiveness of employing pongamia seeds with varying levels of seed viability for biodiesel production through transesterification process. The study looked at the relationship between seed physiological characteristics and extracted oil qualities in view of production of biodiesel through single step trasesterification process. The decreased seed viability was reflected in feedstock qualities such as free fatty acids (FFAs), saponification value (SV), iodine value (IV), cetane number (CN), and antioxidant enzyme activity. The pongamia seed lot exhibited >60 % germination rates contained oil with low FFAs, low SV and high IV. The oil's low free fatty acid content (1.8 %) aids biodiesel production via a single-step alkali-based trans-esterification method. Thus, seed lots with higher viability enhance fuel properties, but decreasing FFAs in pongamia oil increases fuel production capabilities of seeds. Seeds with good viability exhibited lower oil oxidation potential due to higher antioxidant enzyme activity. The rapid viability evaluation test kit can be used at any stage of seed storage to determine whether oilseeds are suitable for biodiesel production. These findings will enable energy plantation growers to increase their profits by providing the biodiesel sector with high-quality feedstock.

Production of biodiesel from Pistacia atlantica (PA) oil seeds using nano-catalyst of alumina/sludge of stone cutting factory (Al2O3/SSCF) and separation of biodiesel and glycerol phases by high voltage

Biodiesel is a renewable fuel and a suitable alternative to fossil fuels. However, the cost of its production and purification has prevented the commercialization and industrialization of this fuel. One economic solution for producing biodiesel fuel is the profit from the sale of glycerin, which is produced as a side product in various processes. In addition to the economic aspects, there are problems caused by the presence of glycerin residues in raw biodiesel before the purification process and the low speed of its separation from biodiesel. Biodiesel is produced by the transesterification method from Pistacia atlantica (PA) oil seeds of the Lorestan Mountains and methanol (1:6) using nano-catalysts of alumina/sludge from a stone cutting factory (Al2O3/SSCF). In this study, to investigate cost reduction and pure and quick separation of glycerin from biodiesel produced, a high-voltage electric method has been used. In this method, negative charges are absorbed by glycerin, separating it from biodiesel. The resulting biodiesel is produced in 10 min with 99% efficiency. The Fourier-transform infrared spectroscopy (FTIR) spectrum of biodiesel is investigated to ensure the formation of the reaction. This method can replace traditional methods.

Biodiesel Production from Waste Cooking Oil Using Ethanol Produced from Sugar or Dates Syrup

Abstract Global oil prices have risen due to rising energy usage and petroleum depletion. Waste cooking oil is a potential source of biodiesel raw materials. Biodiesel is a source of renewable energy and a fuel that could replace petroleum-derived diesel in the future. The novelty of this study was to investigate the production of biodiesel from waste cooking oil using ethanol produced from dates syrup. In this study biodiesel was made from used cooking oil and various alcohols by the transesterification method with different catalysts for comparison. To produce biodiesel from used the transesterification process was carried out by mixing 3 g of the catalyst with 60 ml of alcohol (70%) and adding 300ml of waste cooking oil at a temperature of 60°C. The best result, that had the highest biodiesel yield, which was 302.5 ml, was the biodiesel made from using commercial ethanol as alcohol and KOH as a catalyst. This study indicated that there was no significant difference in the yields of biodiesel and the by-product glycerin between groups, but the density and viscosity of petroleum diesel were much lower than the biodiesel produced from waste cooking oil, meaning that the biodiesel could have more applications than petroleum diesel. It was concluded that the biodiesel produced from waste cooking oil and dates syrup ethanol could be used as an alternative fuel and source of renewable environmentally friendly energy. However, it is considered that more studies are needed to determine the effects of using biodiesel produced on engine performance.

Experimental investigation of engine performance and emissions, and characterization, of waste transformer oils and diesel blends with biodiesel produced from olive oil wastes in a CI engine

In this study, five different fuel blends were prepared by mixing biodiesel obtained from olive oil wastes using transesterification method, waste transformer oil, and Euro diesel in different ratios. The important physicochemical properties of the prepared fuel blends and produced biodiesel were determined by gas chromatography, Fourier transform infrared spectroscopy, and thermogravimetric analysis/differential scanning calorimetry analyses, and their characterizations were carried out. Then, the effects of the prepared fuel blends on engine performance and emission characteristics were investigated in a compression ignition engine. The experiments were performed with five different fuel blends (TD30, TD30B10, TD30B20, TD30B30, and D100) at 1000, 1500, 2000, and 2500 rpm. At all speeds, each fuel blend produced an average torque value that was highest for D100 fuel and lowest for TD30 fuel The average BP value produced by each fuel at all engine speeds was highest in D100 fuel and lowest in TD30 fuel. The results of the experiments showed that there was a 23.98% decrease in the average NOx emissions of TD30 fuel blend compared to the average NOx emissions of D100 fuel at all engine speeds. It was observed that all important fuel properties such as density, kinematic viscosity, and pour and cloud points of all fuel blends met the fuel standards.

Comparison of photocatalytic vs conventional transesterification for biodiesel preparation from fish waste oil using green TiO2/SiO2 catalyst

This work has focused on various aspects that include environmental beingness, conservation of energy, and compatibility of TiO2 over the porous material SiO2. The current work describes the single pot green synthesis of TiO2/SiO2 photocatalyst using pongamia pinnata leaf extract. Core shell formation of TiO2 over SiO2 was displayed in SEM pictures confirming the uniform coating of TiO2 on SiO2. Fish waste oil was employed as the bioresource for the FAME preparation through phototransesterification and conventional transesterification methodologies using the composite catalyst. At the fixed reaction conditions (catalyst weight = 30 mg, and oil: methanol = 1:5), TiO2/SiO2 catalyst showed good catalytic activity in both photoinduced and conventional transesterification methods (97.5% and 98.6% respectively into 94.5% and 95.65% FAME respectively). The resulting biodiesel was tested according to ASTM standards which showed the viscosity of the photocatalytic biodiesel (5.6 mm2/S) and transesterification biodiesel (4.5 mm2/S) was higher and calorific value (<45 MJ/kg) was also marginally less compared to fossil diesel. The future scope of the work would be to increase the HHV and studies on automobile parameters of the prepared biodiesel.

Determination of Some Physicochemical Properties of Binary Biodiesel and Binary Biodiesel-Diesel Blend Fuels Obtained from Waste Pumpkin Seed- Camelina Oils

The primary aim of utilizing biodiesel is to reduce dependency on fossil fuels, decrease harmful emissions, and promote the use of renewable energy sources. Studies on biodiesel commonly revolve around singular biodiesel-petroleum diesel blends. Binary biodiesel is generally obtained by mixing different types of biodiesel or blending these mixtures with petroleum diesel. The combination of these diverse feedstocks with distinct properties can offer varying characteristics and benefits. Many studies regarding liquid biofuels primarily focus on blends of singular biodiesel with diesel. Raw materials constitute a substantial portion of the cost in biodiesel production. Hence, efforts have been made to favor non-edible and waste products as raw materials. Additionally, products that are suitable for cultivation in Turkey and easy to obtain as raw materials, supporting domestic biofuel production, have been chosen. Biodiesels obtained from waste pumpkin seeds and linseed oils through the transesterification method were blended at volumetric ratios of 1:1 and 1:3 to obtain binary biodiesel fuels (C50P50, C25P75, and C75P25). The binary biodiesel-diesel blend fuels were achieved by blending different volume ratios of binary biodiesel fuels (C25P25D50 and C10P10D80) with traditional petroleum diesel after their preparation. Subsequent analyses focused on determining the physicochemical properties (density, kinematic viscosity, flash point, water content, calorific value, cold filter plugging point, and copper strip corrosion) of the prepared binary biodiesel and binary biodiesel-diesel blend fuels. Compliance with biodiesel standards (EN 14214, ASTM D-6751) was observed for all fuels, and the results were compared with the reference fuel, diesel (petroleum). According to the analysis results, all the tested fuels met the standards, with the C10P10D80 blend fuel displaying the closest resemblance to diesel.

Prospect of Biodiesel from Sludge Palm Oil in Malaysia

High feedstock costs make biodiesel production impractical and economically unfeasible, particularly as most feedstocks are unknown for performance. Waste oil, such as sludge palm oil (SPO), may be used to produce biodiesel. This study examined the efficiency and prospect of Sludge Palm Oil Biodiesel (SPOB) production from SPO through transesterification. One-step and two-step transesterification methods were performed for SPOB conversion. However, only a two-step method was effective in converting SPO into SPOB. SPO's high free fatty acid (FFA) content necessitated a two-step process to reduce FFAs to less than 4% before SPOB conversion. Step 1 yielded 78% SPOB at 2 hours, 0.03:1 acid catalyst–to–oil, and 8:1 alcohol–to–oil. The optimal SPOB yield for step 2 at 4 hours, 0.01:1 alkaline catalyst–to–oil, and 9:1 alcohol–to–oil was 78%. SPOB components were analyzed using FTIR with SPOB having a 1435.04 cm-1 methyl peak. The diesel engine performance test mixed SPOB with mineral diesel at different concentrations with 30% SPOB blends in mineral diesel offers the lowest fuel consumption (0.1089 ml/s), maximum braking horsepower (24.9266 rpm), and best mechanical efficiency. Density, flash point, and heating value were also tested to identify SPOB's physical characteristics and discussed in detail.

Synthesis of Methyl Ester from Microalgae Chlorella sp. TAD Using the In-Situ Transesterification Method

Synthesis of methyl ester from Chlorella sp. TAD microalgae was carried out using the in-situ transesterification method. This study aims to determine the methyl ester composition of Chlorella sp. TAD microalgae using the in-situ transesterification method. The in-situ transesterification method is a modified method that allows extraction and transesterification into methyl ester products in one process simultaneously. The in-situ transesterification process lasted 8 hours, followed by a distillation process to remove the n-hexane content and an oven for 2 hours to evaporate the remaining water. The results of the analysis using GC-MS to determine the chemical content of the methyl ester compound from Chlorella sp. TAD, showed the methyl ester composition of 7,10-hexadecanoic methyl ester, 8,11,14-docosatrienoic methyl ester, 9-hexadecanoic methyl ester, hexadecanoic methyl ester, heptadecanoic methyl ester, 10-octadecenoic methyl ester, octadecenoic methyl ester, 9,12-octadecadienoic methyl ester, 10-octadecenoic methyl ester, 2-hexyl cyclopropaneoctanoic methyl ester, eicosanoic methyl ester, 10-heptadecen-8-ynoic acid methyl ester, nonahexacontanoic methyl ester, and tetracosanoic methyl ester.

The Impact of Utilizing Waste Sunflower Oil as a Biodiesel Blend on Four-Stroke Engine Performance and Emissions

The blending of biodiesel with petroleum diesel attracts much attention due to its high potential in reducing emissions. In this work, waste sunflower oil was converted to biodiesel by the trans-esterification method, and it was blended with petroleum diesel in three ratios (10, 30, and 50%). The impact of using these blended fuels in a four-stroke engine on engine performance and exhaust emissions at three engine loads (2, 4, and 6 N.m) was investigated and compared with the use of petroleum diesel and biodiesel. The engine performance was evaluated by determining the brake-specific fuel consumption (BSFC), engine effective power (Ne), brake-specific energy consumption (BSEC), brake thermal efficiency (BTE), and noise intensity. The evaluation of emissions from the engine exhaust was carried out by measuring the levels of carbon oxides (CO and CO2), hydrocarbons (HC), nitrogen oxides (NO and NO2), and particulate matter (PM). The results show that blending diesel with up to 30% biodiesel can reduce CO, HC, and PM emissions by 29.6 ± 1%, 26.0 ± 4%, and 31.0 ± 3%, respectively. However, this decrease is associated with increasing CO2 and NOx emissions by 18.5 ± 2.5% and 29.0 ± 6%, respectively. In addition, the engine showed acceptable performance when using up to 30% biodiesel, where the increase in fuel consumption was limited to 5.8 ± 0.3%. In addition, the engine’s effective power increased with the blending ratio of 10% by 2.0 ± 0.6%, but then decreased with the blending ratio of 30% by only 2.0 ± 0.6%. The noise intensity was also decreased by 2.4%, while BSEC and BTE were reduced by only 2.9 ± 0.9% and 3.5 ± 1%, respectively. The results of this work provide deep insights regarding the utilization of waste sunflower oil as biodiesel to be blended with petroleum diesel, which is a considerable novel approach in the energy and environmental sectors.

Research on the preparation and quality control process of cattle liquid tallow

Liquid butter is a special process with unique flavor, which has strong commercial value in the deep processing of animal fat. In this paper, the preparation of liquid butter was based on centrifugal supernatant as the main raw material, and the process of preparing liquid butter by ultrasonic-assisted transesterification method was used to optimize the preparation of liquid butter by single factor and orthogonal experimental design according to the sensory, freezing point and iodine value of the product. The experimental results showed that the optimal formula of liquid butter was as follows: liquid-to-material ratio of 1:1, ultrasonic temperature of 50°C, and ultrasonic time of 50min. Using this ratio, the sensory score of liquid butter prepared from centrifugal supernatant was 87 points, the freezing point was 22.9°C, and the iodine value was 67.5g/100g. The liquid butter prepared by this process is clear and translucent, with unique flavor, and has certain nutritional and health care effects, which has certain reference value for future application in the field of deep processing of animal fat.