Metamorphic Ages Research Articles

When carbonatite met granite: A carbonatite magma- wall rock reaction origin for the Paleoproterozoic pyroxenite and syenite in Fengzhen, North China

A set of carbonatite dykes intruding into Paleoproterozoic granites are exposed in Fengzhen area, where the Trans-North China Orogen joined with the Khondalite Belt. Some pyroxenites and syenites were also developed close to the carbonatite dykes. But the genetic relationship between these rocks and carbonatite dykes has not been solved. The pyroxenites show low SiO2 (40–49 wt%), high CaO (>20 wt%), and are enriched in light rare earth elements, strongly depleted in high field strength elements (Nb, Ta, Zr, Hf), similar to the characteristics of carbonatite dykes. The zircon UPb ages of pyroxenites and syenites are 1789 ± 13 Ma and 1793 ± 14 Ma, respectively. The wall-rock granite yields a metamorphic age of 1839 ± 19 Ma, which is close to the magmatic age of the pyroxenites and syenites. The whole-rock εNd(t) values (−4.4 to −5.1) and εHf(t) values (−3.8 to −6.9) of the pyroxenites are both negative, which are similar to those of the syenites (−3.7 to −4.7 and − 4.1 to −5.3) but slightly lower than those of wall-rock granites (−3.5 and 1.9). The δ18O values of clinopyroxene in the pyroxenites fall in a range of 6.6–11.3‰, which are much higher than the mantle value. The calcite of the carbonatites and pyroxenites gave overlapped δ18O value ranges of 11.8–14.8‰ and 9.3–15.0‰, respectively. They are also higher than typical primary carbonatites. These lines of geochemical evidence indicate that the pyroxenites are not mantle xenolith or derived directly from mafic magma, but closely related to the carbonatite dykes and the wall-rock granites. Since the Ba/La and Ba/Mn ratios of the syenites are much higher than those of the carbonatite, an immiscibility origin is excluded. Mineral chemistry of clinopyroxene, olivine, calcite and phlogopite from the carbonatite, pyroxenite and syenite all suggest they are formed by different degrees of reaction between carbonatite magma and felsic crustal rocks. Modeling shows that the Nd isotope compositions and trace element compositions of the pyroxenites and syenites fall on the mixing trends between the carbonatite dykes and wall-rock granites. These results demonstrate that the pyroxenites and syenites in the Fengzhen area were formed when carbonatite magma intruded and reacted with felsic crustal rocks. This provides a canonical case for the formation of pyroxenite and syenite by carbonatite magma-wall rock reaction.

Re-evaluating metamorphism in the southern Natal Province, South Africa

Abstract The metamorphic conditions of the Natal Metamorphic Province (NMP) have been the focus of previous studies to assist with Rodinia reconstructions but there are limited constraints on the age of metamorphism. We use a combination of modern techniques to provide new constraints on the conditions and timing of metamorphism in the two southernmost terranes: the Mzumbe and Margate. Metamorphism reached granulite facies, 780–834°C at 3.9–7.8 kbar in the Mzumbe Terrane and 850–892°C at 5.7–6.1 kbar in the Margate Terrane. The new pressure and temperature constraints are supportive of isobaric cooling in the Margate Terrane as previously proposed. Peak metamorphism of the two terranes is shown to have occurred c. 40 myr apart, which contrasts strongly with previous assumptions of coeval metamorphism. While the age of peak metamorphism of the Margate Terrane (1032.7 ± 4.7 Ma) coincides with the tectonism and magmatism associated with the emplacement of the Oribi Gorge Suite ( c. 1050–1030 Ma), the age of metamorphism of the Mzumbe Terrane (987.4 ± 8.1 Ma) occurs c. 30–40 myr after tectonism is previously thought to have finished. We propose that models of advective cooling during transcurrent shearing can explain the metamorphic conditions and timing of the NMP.

Detrital zircon geochronology of quartzites from the Central Zone of the Limpopo Complex in southern Africa: Implications for different models and the timing of Zimbabwe Craton–Kaapvaal Craton amalgamation

U–Pb geochronological analyses have been conducted on 765 detrital zircon grains from 11 quartzite samples in the Central Zone of the Limpopo Complex, southern Africa, for constraining the depositional age and provenance of the protolith quartz-sandstone and evaluating the effect of high-grade metamorphism on zircon age data in polymetamorphic terranes. The age data have also been used to evaluate two contrasting tectonic models for the evolution of the complex; collision of the Zimbabwe and Kaapvaal Cratons and diapir-driven intracratonic orogeny, both during the Neoarchean. Magmatic cores of the zircons from the Beit Bridge, Phikwe, and Motloutse Complexes in the Central Zone show a wide age range from 3828 Ma to 1995 Ma. Ages from the Beit Bridge Complex in Zimbabwe (ca. 3.6–3.1 Ga) and South Africa (ca. 3.5–2.4 Ga) are dominantly Paleoarchean to Neoarchean with minor Paleoproterozoic ages. Similar Eoarchean to Neoarchean ages were also obtained from the Phikwe Complex (ca. 3.8–2.6 Ga), whereas ages from the Motloutse Complex are slightly younger (early Mesoarchean to Paleoproterozoic; ca. 3.0–2.4 Ga). Although the age patterns from the three complexes are different, the distribution patterns of discordant and concordant data suggest Eoarchean to Mesoarchean (ca. 3.8–3.1 Ga) ages for magmatic cores of detrital zircon grains. Homogeneous zircon rims around magmatic cores gave metamorphic ages of ca. 2.61 Ga and ca. 2.27–2.02 Ga, probably formed by Neoarchean and Paleoproterozoic high-grade metamorphisms. Similar Neoarchean (ca. 2.7–2.6 Ga) and Paleoproterozoic concordant ages obtained from magmatic zircon cores are interpreted as reset ages due to Pb loss during the metamorphic events. The smaller peak of the Paleoproterozoic age population compared to that of the Neoarchean age data suggests the dominant high-grade metamorphism of the Central Zone took place at ca. 2.7–2.6 Ga, either by collision of the Zimbabwe and Kaapvaal Cratons or by diapir-driven intracratonic orogeny. Therefore, cratonization of the Azanian (Kalahari) Craton probably occurred before ca. 2.6 Ga. Based on the age patterns, the depositional age of the protolith quartz-rich sandstone is constrained as 3.1–2.7 Ga. The provenance of the Paleoarchean to Mesoarchean (3.6–3.1 Ga) detrital zircons has been inferred as orthogneisses and granitoids of the southern Zimbabwe Craton (e.g., Tokwe Segment). The oldest Eoarchean detrital zircon (3828 Ma) obtained from the Phikwe Complex suggests the presence of unknown older crust in this provenance.

Geochemistry and geochronology of the Bay of Islands metamorphic sole, Newfoundland, Canada: Protoliths and implications for subduction initiation

The Bay of Islands complex, Newfoundland, Canada, represents a fossil subduction system that was obducted onto the Laurentian margin during the Taconic Orogeny. We present whole-rock geochemistry and geochronology for the Bay of Islands metamorphic sole from the Table Mountain and North Arm Mountain massifs. The Bay of Islands metamorphic sole can be subdivided into three units: a high metamorphic-grade Grt-Cpx amphibolite and Grt-Cpx granulite unit, a medium metamorphic-grade common amphibolite unit, and a medium metamorphic-grade metasedimentary-dominated unit. Based on their major and trace element contents, two types of protoliths can be inferred for the Bay of Islands sole metabasites: cumulate gabbroic protoliths with high Mg numbers and depleted trace element contents, and basaltic protoliths with trace element contents defining a normal mid-oceanic-ridge basalt (N-MORB) affinity. Titanite in situ U-Pb analyses of two common amphibolite samples yield dates of 486 ± 7 Ma and 484 ± 4 Ma, which are interpreted as a metamorphic age (ca. 485 Ma). One sample from the metasedimentary unit yields detrital zircon dates that range from Archean to Ordovician, with the youngest dates defining the most dominant peak at ca. 490 Ma. This youngest peak is consistent with an arc-related source that may be linked with arc magmatism of the upper plate during the Taconic Orogeny. These observations suggest that (1) the subduction responsible for the formation of the Bay of Islands complex nucleated in an oceanic domain before ca. 485 Ma; and (2) the sediments that form the metasedimentary unit were partly sourced from the upper plate and were deposited on the lower plate while subduction was active.

Neoproterozoic amphibolite-facies metamorphism of the Douling complex in the northern Yangtze Craton and its tectonic implications: Constraints from petrology and zircon U-Pb-Hf-O isotopes

Neoproterozoic evolution of the Yangtze Craton has long been debated. The Douling complex, representing one of the oldest crystalline basements, records Neoproterozoic high-grade metamorphism and may provide pivotal clues into a reliable Neoproterozoic configuration of the Yangtze Craton. However, its metamorphic evolution and tectonic significance have not been well constrained. In this contribution, we conduct an integrated study of petrography, zircon U-Pb age and Hf-O isotopic compositions for two garnet amphibolites and one gneiss from the Douling complex. Phase equilibrium modeling and conventional geothermobarometry calculation define peak P-T conditions of 9–10 kbar and 670-690 °C, and shape a clockwise P-T path. Zircon grains from the gneiss mostly reveal core-rim structure. The cores display oscillatory zoning, high Th/U ratios and trace element contents, as well as HREE-enriched patterns, high 176Lu/177Hf ratios and δ18O values, consistent with a magmatic origin. They yield a weighted mean 206Pb/238U age of 868 ± 9 Ma, which is taken as the protolith age. The cores have strongly positive ƐHf(t) values of 7.0–15.6 and young two-stage Hf model ages of ca. 1310–760 Ma, indicating that the protolith was dominantly sourced from prompt reworking of Meso-Neoproterozoic juvenile crust. On the other hand, the zircon overgrowth rims in the gneiss exhibit no zoning patterns, low Th/U ratios and trace element contents, flat HREE patterns and pronouncedly negative Eu anomalies, variable 176Lu/177Hf ratios and comparable ƐHf(t) values to the magmatic cores, indicating their coeval formation with garnet and plagioclase under amphibolite-facies metamorphism and might be generated by dissolution-reprecipitation. Zircon crystals from the two amphibolites perform weak zoning patterns, low Th/U ratios and trace element contents, high formation temperatures, flat to weakly enriched HREE patterns, insignificantly and/or clear negative Eu anomalies, and low 176Lu/177Hf ratios and ƐHf(t) values, suggesting that they may form near the peak stage of amphibolite-facies metamorphism. Metamorphic zircon in the three samples yield homogeneously high δ18O values (10.81 ± 0.17‰, 11.45 ± 0.40‰, 10.92 ± 0.08‰), indicating the participation of external fluid originated from surrounding metasedimentary rocks. These metamorphic zircon grains together yield a weighted mean age of 817 ± 4 Ma (MSWD = 0.63), which is taken as the best estimated age for the upper amphibolite-facies metamorphism in the Douling complex. Considering the widespread contemporaneous magmatism in the northern Yangtze Craton, we propose that the Douling complex recorded a tectonic regime switch from compression to extension at ca. 830–820 Ma, in response to outboard oceanic subduction on the periphery of the Yangtze Craton and then tectonic extension and collapse of the thickened lithosphere.

Tectono-magmatic response to the geometric evolution of slab breakoff in the Paleo-Tethys Ocean: Constraints from Late Triassic granites in the Qiangtang block, northern Tibet

Slab breakoff can explain the postcollisional igneous and metamorphic events in many collisional orogens and triggers the transition from initial continental collision to deep subduction. However, the relationship between the deep-seated geometry of slab breakoff and shallow tectono-magmatic events remains unclear. In this study, we report new geochronological, geochemical, and Hf isotope data for granitic rocks from the Qiangtang block. Three granitic samples yielded zircon U-Pb ages of 226−214 Ma and mostly gave negative zircon εHf(t) values of −20.1 to +0.57. These granitoids are K-rich, calc-alkaline, magnesian, and metaluminous to weakly peraluminous. We propose that the granites were generated by partial melting of compositionally heterogeneous lower crust in the Southern Qiangtang block. Our new data, along with previously published data for igneous and metamorphic rocks in the Qiangtang block, suggest that the Longmu Co−Shuanghu suture zone represents a remnant of the closure of the Paleo-Tethys Ocean, and that the Late Triassic tectono-magmatic evolution was controlled by slab breakoff after continental collision. The contrasting magmatic and metamorphic ages show that the two stages of tectono-magmatic activity in the Late Triassic were due to a change in the subduction angle of the continental lithosphere from steep (225−215 Ma) to shallow (215−205 Ma) during slab breakoff. Furthermore, we infer that slab breakoff of the oceanic lithosphere caused extensive crustal melting and reworking and initiated far-field subduction. Our results provide new insights into the slab breakoff processes that control the geometry of subducting continental lithosphere and related postcollisional magmatic and metamorphic events in collision zones.

Petrogenesis of the ~1.94 Ga Meta‐gabbronorites in Liangcheng: Implications for Tectonic Evolution of the Khondalite Belt, North China Craton

AbstractWe investigated the meta‐gabbronorites in Liangcheng and used detailed petrography, geochemistry, zircon geochronological and in‐situ Hf isotopic studies to clarify their formation and metamorphic ages, petrogenesis, tectonic setting and provide constraints on the tectonic evolution of Khondalite Belt (KB). The zircon U‐Pb dating results show that the meta‐gabbronorites crystallized at ~1.94 Ga and were metamorphosed at ~1.91–1.89 Ga. They can be subdivided into the low‐Mg and high‐Mg groups. The low‐Mg meta‐gabbronorites contain relatively lower MgO and higher SiO2 contents than high‐Mg meta‐gabbronorites. They are enriched in light rare earth elements and large ion lithophile elements, depleted in high field strength elements, and exhibit positive (high‐Mg meta‐gabbronorites) and negative (low‐Mg meta‐gabbronorites) Sr and Eu anomalies. The zircon in‐situ εHf(t) of meta‐gabbronorites is 0.07–4.12, with Hf model ages (TDM) of 2169–2400 Ma. The meta‐gabbronorites in Liangcheng originated from the asthenospheric mantle and experienced fractional crystallization of olivine, orthopyroxene, clinopyroxene, and plagioclase. They were contaminated by the crustal rocks (mainly khondalite series) during ascent, especially for low‐Mg gabbronorites. The ridge subduction is the most plausible tectonic setting for meta‐gabbronorites, indicating the eastern segment of KB was in a ridge subduction setting at ~1.94 Ga following an orogenic thickening event during a prolonged orogenic process.

Metamorphic P-T paths and zircon U-Pb ages of Paleoproterozoic metabasic dykes in the Jiapigou area, South Jilin Province: Implications for the tectonic evolution of the North China Craton

The distribution and tectonic evolution of the Paleoproterozoic orogenic belts in the North China Craton (NCC) remain controversial. Especially, the extent of the Paleoproterozoic magmatic and metamorphic influences on the Archean Longgang Block needs further demonstration. This paper presents detailed petrographic and mineralogical analyses, phase equilibria modeling and zircon dating for three metabasic dyke samples in the Jiapigou area, South Jilin Province, in order to discuss their metamorphic evolution and tectonic implications. Petrographic observation and phase modeling using THERMOCALC suggest that these metabasic dykes have experienced the metamorphism with clockwise P-T paths under low-amphibolite facies, high-amphibolite facies and high-pressure granulite facies. Their peak P-T conditions were constrained to be 0.6–0.9 GPa/580–650 °C (JN1929), ∼0.95 GPa/757 °C (JN1918) and ∼1.15 GPa / 820 °C (JN1932), according to the stability fields of mineral assemblage and isopleths of Ti content in amphibole, anorthite component (XAn) in plagioclase, pyrope content (XPy) and grossular content (XGrs) in garnet. The peak conditions correspond to apparent geothermal gradients of 19–22℃/km, being medium-pressure type. Zircon U-Pb dating shows that the metabasic dykes have a protolith crystallization age of 2199 ± 5 Ma (MSWD = 0.43), and a metamorphic age of 1855 ± 41 Ma (MSWD = 0.21). The protolith ages, metamorphic characteristics and ages of the metabasic dykes in South Jilin can be well compared with those for metabasic dykes in East Hebei and North Liaoning, indicating that the northern part of the Longgang Block was extensively affected by the mid Paleoproterozoic magmatism, and was involved in an orogen to be metamorphically reworked during the late Paleoproterozoic (1.82–1.85 Ga). In addition, this orogeny mainly occurred along the northern margin of the craton, which is different from the ∼1.95 Ga orogeny in the NCC.

Paleoproterozoic high-pressure granulite facies metamorphism in the Yinshan Block, North China craton

The Yinshan Block located in the northern margin of the North China Craton (NCC) has been regarded as a typical Archean cratonic block, but it is argued whether the block had been affected by Paleoproterozoic tectonic and metamorphic events. This paper reports the late Paleoproterozoic high-pressure (HP) granulites for the first time from the Xiwulanbulang area in the Yinshan Block, and presents a systematic study on their petrography, mineral chemistry, phase equilibria modelling and zircon dating to confirm their metamorphic evolution and tectonic implications. Two representative samples contain the typical HP basic granulite assemblages involving garnet, clinopyroxene, plagioclase, amphibole and quartz, with garnet commonly occurring as coronae around clinopyroxene and plagioclase. Both samples show clockwise P–T paths with their peak conditions of ∼930 °C/∼15kbar (20NM01) and 970–980 °C/∼13.5 kbar (21NM05) respectively, constrained using the maximum Ti contents in amphibole and minimum anorthite (XAn) in the mantle of plagioclase on P–T pseudosections. Zircon dating yields a magmatic age of ∼ 2.3 Ga and metamorphic ages of ∼2.5 Ga and ∼1.8 Ga. The ∼2.3 Ga magmatic age represents the time of protolith gabbro crystallization, which can be comparative to the extension-related bimodal magmatism in the Khondalite Belt. The ∼ 1.8 Ga age was determined from metamorphic zircons that have flat HREE patterns with the presence of garnet, interpreted as the time of the post-peak cooling and uplifting of the HP granulite facies metamorphism. The ∼2.5 Ga is defined from the captured zircon grains by gabbroic intrusions from the country Neoarchean rocks. The HP granulite facies metamorphism registers a geothermal gradient of 19–20 °C/km, indicating a collision-related orogenic event that may have occurred at ∼1.85 Ga along the northern margin of the NCC. Therefore, the Yinshan Block may represent a weak deformation domain in the orogenic belt on the northern margin of the NCC.

Contrasting geological background based on the geochemistry of the mafic metamorphic rocks in central Dronning Maud Land

AbstractThis paper reports geochemical characteristics of mafic gneisses and granulites collected from four localities in central Dronning Maud Land to evaluate the tectonic setting of their precursor rocks. Precursor rocks for the mafic gneisses and granulites in central Dronning Maud Land were formed in different geological backgrounds and tectonic settings. The mafic gneisses and granulites in the Schirmacher Hills were derived from basaltic rocks in a back-arc setting. Published U–Pb zircon ages and the geochemical variation of the basement rocks indicate their emplacement between 800 and 650 Ma, close to peak metamorphism. While similar protoliths were recognized in the inland nunataks of Hochlinfjellet, in Filchnerfjella the mafic gneisses/granulites were derived from basaltic rocks formed in marginal continental arcs or island arcs. Highly disturbed trace-element patterns indicate that the metamorphic process influenced the geochemical composition during the prograde metamorphic stage. Our results imply that the outcrops in central Dronning Maud Land with different metamorphic ages contain mafic gneisses/granulites from precursor rocks formed under different tectonic settings.

Apatite records metamorphic and hydrothermal fluid evolution at the large Shuangqishan orogenic gold deposit, SE China

Orogenic gold deposits are currently the world’s major source of Au, but uncertainty exists in the timing of mineralization relative to the ages of host rocks, metamorphism, and magmatism. Consequently, the origin and detailed evolution of ore-forming fluids have long been elusive. Apatite occurs widespread in various types of mineral deposits and can provide valuable information on ore genesis. Here, we present textural, high-precision in situ U-Pb geochronological, trace elements, and Sr isotope data for metamorphic and hydrothermal apatite in the Shuangqishan gold deposit in southeastern China. These data, together with U-Pb dates of metavolcanic host rocks, granitic and mafic intrusive rocks, allow us to precisely constrain the timing of mineralization and reconstruct the history of the ore-forming fluids there. The apatite crystals within metamorphic and auriferous quartz veins can be grouped into three generations according to cathodoluminescence imaging and trace element concentrations: Ap1 precipitated in the pre-mineralization metamorphic stage, whereas Ap2 and Ap3 formed in the auriferous hydrothermal stage. Metamorphic Ap1 displays a negative Eu anomaly, indicating a predominance of Eu2+ and crystallization under relatively reduced conditions. On the other hand, syn-gold hydrothermal Ap2 and Ap3 have marked positive Eu anomalies. Radiometric ages for metamorphic Ap1 are at ca. 461 Ma, whereas hydrothermal Ap2 and xenotime from auriferous quartz gave U-Pb ages of 425 ± 15 Ma and 416 ± 15 Ma, interpreted as the time of gold mineralization. Emplacement ages determined by U-Pb zircon data are 439 ± 2 Ma for granitic intrusion and 427 ± 2 Ma for a mafic dike in the mining district. Mineralization, therefore, postdates the metamorphism of local host rocks and granitic magmatism by ∼35 ± 24 m.y. and ∼14 ± 17 m.y., respectively. The synchronism of gold genesis and mafic magmatism provides additional evidence for a mantle derivation of the ore-forming fluids. The highly radiogenic 87Sr/86Sr ratios obtained for Ap1 (0.7178−0.7302) are consistent with its precipitation from a metamorphic fluid. Higher Sr concentrations (Ap2 = 1228−2884 ppm, Ap3 = 2325−3169 ppm) and positive Eu anomalies (Eu/Eu*: Ap2 = 1.03−2.84, Ap3 = 2.00−4.30) but lower and variable 87Sr/86Sr ratios in hydrothermal Ap2 (0.7100−0.7165) and Ap3 (0.7086−0.7116) are mainly ascribed to extensive fluid-wall rock exchange of Sr during mineralization. It is therefore suggested that fluid-rock reaction played a vital role in the observed positive Eu anomalies of hydrothermal apatite. Our study highlights the usefulness of apatite as a novel and robust geochronological, geochemical, and isotopic indicator of complex mineralization processes in hydrothermal gold deposits.

Current knowledge of the Ordovician System in Antarctica

Abstract Evidence of Early Ordovician deposition and intrusion in East Antarctica is best known from the Ross Orogen, postdating the 495–489 Ma Ross Orogeny. Here, c. 490–475 Ma granites (with related dykes and sills) of the Granite Harbour Intrusives represent roots of a continental margin arc. Detrital zircon grains in the upper Byrd Group (Central Transantarctic Mountains) are of comparable Early Ordovician age. Contemporaneous fossils are rare. In northern Victoria Land they include latest Cambrian to earliest Ordovician conodonts and microbrachiopods in allochthonous limestones of the Handler Formation (Robertson Bay Group) in the Robertson Bay Terrane, and probable Early Ordovician trace fossils in the Camp Ridge Quartzite of the Leap Year Group in the Bowers Terrane. In the Shackleton Range of Coats Land, West Antarctica, the Blaiklock Glacier Group contains a diverse ichnofossil fauna of probable Ordovician age associated with undescribed bivalved arthropods and segmented crustacea. The Swanson Formation of the Ross Province in Marie Byrd Land (correlated with the Robertson Bay Group of the Ross Orogen) is a turbiditic unit dominated by quartz-rich sandstones. Its Ordovician age is based on a post-depositional whole rock K–Ar metamorphic age of 448–444 Ma, with detrital zircon grains indicating a late Cambrian maximum depositional age.

Pre‐Subduction Architecture Controls Coherent Underplating During Subduction and Exhumation (Nevado‐Filábride Complex, Southern Spain)

AbstractThe interplay between structural and metamorphic processes operating along the deep plate interface in subduction zones remains elusive as much of the geologic record is recycled into the mantle. In some cases, metamorphosed subducted rocks are underplated and exhumed to the surface, providing critical constraints on structural processes and the rheological evolution of subduction interfaces at convergent margins. One such exhumed high‐pressure/low‐temperature subduction complex is the Cenozoic Nevado‐Filábride Complex (NFC) in Southern Spain. This study presents new data from the NFC that elucidate the syn‐metamorphic deformation, stacking, and underplating of continental slivers along the subduction interface. The structurally lowest NFC dominantly comprises lithologically monotonous Paleozoic metamorphic basement rocks recorded by apatite U‐Pb ages and shows no evidence for large‐scale internal duplications suggesting it behaved as a coherent basement succession during subduction. In contrast, structurally higher levels of the NFC are characterized by the stacking of older‐on younger coherent slices and distinctly different metamorphic ages. These relationships document syn‐subduction structural repetitions and tectonic stacking of imbricate thin slivers (∼100s m) during subduction underplating. Structurally higher levels of the NFC exhibit both Eocene and Miocene metamorphic zircon rims and apatite ages, along with microstructures indicative of relatively higher temperature metamorphism. Large‐scale underplating and antiformal stacking of slivers in the subduction channel can provide buoyancy forces to underplate and assist exhumation. We demonstrate that the presubduction stratigraphic architecture is a key control on the style and timing of deformation and metamorphism, facilitating coherent subduction underplating.

Petrogenesis of the ca. 2.5 Ga dioritic-TTG and granitic gneisses from the Huai'an Complex and its implications for crustal evolution and tectonic settings of the North China Craton

The diversity and petrogenesis of Archean granitoid rocks, including tonalite-trondhjemite-granodiorite suites (TTGs), sanukitoids, and K-rich granites, is essential to understanding the geodynamic process of crust-mantle interaction and the origin and evolution of the continental crust. In this study, we investigate the petrogenesis, geochronology, and Sr-Nd-Hf isotopes of Neoarchean granitoids from the Huai'an Complex in the North China Craton (NCC) to gain insight into the crustal evolution during the Late Neoarchean–Early Paleoproterozoic. Five groups of plutonic gneisses of dioritic-tonalitic-trondhjemitic (DTT) and granitic gneisses in the Huai'an Complex are distinguished by their compositions. LA-ICP-MS zircon U-Pb dating constrains their emplacement ages from ca. 2.53 to 2.47 Ga and metamorphic ages at ca. 2.46 Ga and 1.86–1.82 Ga. The ca. 2.5 Ga DTT gneisses have consistent Sr-Nd-Hf isotopic compositions with positive whole-rock ɛNd(t) (+1.0 to +5.1), zircon εHf(t) (0.0 to +6.2) values, and older two-stage Hf model ages of 2.7–3.0 Ga, indicating they are cogenetic and derived from the partial melting of preexisting mafic crust. The dioritic gneisses with elevated MgO (3.09–4.94 wt%) and compatible element compositions (e.g., Cr and Ni) originated from a mafic crustal source modified by mantle-derived melts. The high Sr/Y values (104–661) and positive Eu anomalies (Eu/Eu⁎ = 1.05–2.76) of trondjemitic gneisses are controlled by plagioclase accumulation. The granitic gneisses are slightly peraluminous with high K2O (5.00–6.29 wt%) and low FeOT and MgO contents, indicating they were formed from the remelting of preexisting tonalitic crusts. The DTT and granitic plutonic gneisses in the Huai'an Complex were likely derived from crust-mantle interaction and crustal reworking in a subduction-related arc setting. The diverse geochemistry of these ca. 2.5 Ga granitoids is significantly controlled by source compositions, magmatic mixture, and accumulation. The prominent ca. 2.5 Ga TTG and granitic magmatism in the NCC likely represent a dominated internal reworking of the continental arc crust with subordinate crustal growth involving a subduction environment.

Spatial Relationship between Eclogite and Copper-Nickel Mineralization in East Kunlun, China

In recent years, Cu-Ni deposits have been discovered at different localities in the Eastern part of the Kunlun orogenic belt such as Xiarihamu, Langmuri, Shitoukengde, and Wenquan. Eclogites are usually exposed in the areas associated with these deposits, thereby implying a certain coupling relationship between the Cu-Ni deposits and eclogite distribution. In this study, eclogite samples from the Xiarihamu and Langmuri areas were analyzed using petrogeochemistry, U-Pb zircon geochronology, and electron probe microanalysis (EPMA). Further, eclogite protolith properties, the formation environment, and the metallogenic mechanism were also investigated. Geochemically, eclogite is rich in MgO and FeO and low in alkali and SiO2. Its m/f ratios are 0.72 to 1.53 and Mg# values of 42 to 61. Overall, the chondrite-normalized rare-earth elements (REE) patterns showed characteristics of weak enrichment with LREE, weak negative Eu anomalies, relative enrichment of large-ion lithophile elements such as K and Rb, active incompatible element Th, the depletion of high-field strength elements Nb, Ta, Zr, and Hf, and V-shaped valleys caused by depletion in Sr, P, and Ti. These geochemical characteristics indicated that the protolith is highly differentiated Fe gabbro that formed in a continental margin type of rift environment. The EPMA analyses showed that the composition of garnet consists of almandite and grossularite, and omphacite often contains augite. Geochronological investigations showed that the peak metamorphic age of eclogite in Xiarihamu and Langmuri is 415.6 ± 2.7 Ma (MSWD = 0.43, n = 16) and 449.1 ± 8.5 Ma (MSWD = 0.88, n = 19), which are related to the early Paleozoic orogenic cycle and formed slightly earlier than the formation of the magmatic liquation type of Cu-Ni deposits in this area. On the basis of spatial coupling, formation age approximation, and geochemical correlation between eclogite and mafic rock masses, in combination with the previous research results of earlier work, it has been considered that the Cu-Ni ore deposits in the East Kunlun Range were formed in the post-collisional extension environment after the deep subduction of the continental crust. The ultra-high-pressure metamorphic melange formed by continental deep subduction or the enriched mantle formed by crust-mantle metasomatism was partially melted to form sulfur-rich mafic–ultramafic magmas in the post-collision extension environment. During the deep subduction of the continental crust, a large amount of crust-derived sulfur was brought into the mantle, which is the key factor for the mineralization of Cu-Ni ore in the region.

Late Neoarchean plate subduction in Western North China Craton: Evidence from ca. 2.51 Ga to 2.46 Ga basement rocks in Northern Ordos Basin

The most poorly exposed and least understood in the North China Craton (NCC) lies largely hidden beneath the Ordos Basin, severely limiting the cognition of the Precambrian tectonic evolution in the western NCC and the tectonic division. Diverse orthogneiss samples collected from four boreholes drilled into the basement of the north side of Hangjinqi Fault Zone (HFZ) in the North Ordos Basin (NOB) are investigated by integrating zircon U-Pb dating, Hf-Nd isotopes, and whole-rock geochemical analyses. The TTG gneiss, quartz-monzonite gneiss, granodiorite gneiss, and amphibolite were emplaced at ca. 2.51–2.46 Ga, of which the amphibolite also recorded the metamorphic age of ca. 1.95 Ga. The TTG gneisses display low MgO, Mg#, Cr, and Ni, high HREE and Rb/Sr, enrichment of LILEs and depletion of Nb, Ta, and Ti, and positive εNd(t) (2.04–4.06) and εHf(t) (3.04–7.59) values, suggesting that they were mainly originated from partial melting of the tectonically thickened mafic island-arc crust. In contrast, the quartz monzonite gneisses and granodiorite gneisses show the geochemical features of Archean sanukitoids with higher MgO, Mg#, Cr, and Ni, and similar εNd(t) (1.34–3.82) and εHf(t) values (3.94–7.32), suggesting that they were derived from the partial melting of the mantle metasomatized by fluids and melts of the subduction. The amphibolites exhibit a mixed characteristic of E-MORB and arc-like geochemical affinities resembling the Mariana back-arc basin, which was derived from the partial melting of spinel lherzolite. The arc and arc-back lithological assemblages suggest that the north margin of the NOB might be in a geodynamic transition period from a compressional regime correlated with plate subduction to an extensional regime correlated with slab rollback during ca. 2.51–2.46 Ga. Combined with previous analytical results, the northern margin of the NOB was most likely in a long-term active continental margin setting during 2.51–1.95 Ga and involved in the collision event between the Yinshan Block and Ordos Block at ca. 1.95 Ga.

First finding of continental deep subduction in the Sesia Zone of the Western Alps and implications for subduction dynamics.

Continental deep subduction after the closure of large oceanic basins is commonly ascribed to the gravitational pull of the subducting oceanic slab. However, it is not clear how continental lithosphere adjacent to small oceanic basins was subducted to mantle depths. The Sesia Zone in the Western Alps provides an excellent target for exploration of subduction dynamics in such a tectonic setting. Here we report the first finding of coesite in a jadeite-bearing orthogneiss from the Sesia Zone, providing the first evidence for deep subduction of the continental crust to mantle depths for ultrahigh-pressure (UHP) metamorphism in this zone. Three coesite inclusions were identified by laser Raman spectroscopy in two garnet grains. Based on zircon U-Pb dating and trace element analysis, the UHP metamorphic age was constrained to be 76.0±1.0 Ma. The phase equilibrium modeling yields peak metamorphic pressures of 2.8-3.3GPa, demonstrating the continental deep subduction to mantle depths of >80km. The subducted continental crust was a rifted hyperextended continental margin, which was converted to the passive continental margin during seafloor spreading and then deeply subducted during the oblique convergence between the Adria microplate and Eurasian plate in the Late Cretaceous. Because the slab pull could only play a limited role in closing small oceanic basins for continental collision, the distal push of either continental breakup or seafloor spreading is suggested as the major driving force for the deep subduction of continental crust in the Western Alps. Therefore, deep subduction of the continental crust bordering small oceanic basins would have been induced by the far-field stress of compression, whereas that bordering large oceanic basins was spontaneous due to the oceanic slab pull. This provides a new insight into the geodynamic mechanism of continental deep subduction.

Crustal evolution of the Laurentian continental margin from the Paleo- through Mesoproterozic: A zircon U–Pb and Hf transect through the western Grenville Province, Ontario, Canada

The Great Proterozoic Accretionary Orogeny along the southern and southeastern margin of Laurentia is arguably the first long-lived, modern-style active plate margin on Earth, representing significant crustal growth and reworking. Here, we present new detrital zircon U–Pb and Hf data, along with zircon and monazite metamorphic ages, from tectonic domains in the southwestern Grenville Province that represent depositional basins formed and reworked during a series of events between 2.2 and 1.2 Ga. As such, the data allow a glimpse into the evolution and assembly of this extensive margin. The Nepewassi domain contains Archean basement overlain by mature sandstone characterized by near-unimodal, ca. 2.7–2.6 Ga detrital zircon peaks and likely correlative with Superior Province basement and its Huronian cover. The Nepewassi domain underwent both Archean (ca. 2.65 Ga) and Killarnean (ca. 1.76 Ga) metamorphism. In addition, all units preserve evidence of Grenvillian high-grade metamorphism between ca. 1.05 and 0.99 Ga. The structurally highest parts of the Nepewassi domain also contain younger sedimentary rocks that received detritus from Killarnean sources, with evolved Hf isotopic compositions indicative of reworked Archean crust. Sedimentary rocks in the Tomiko domain preserve detrital zircon of Penokean and Killarnean age (1.9–1.7 Ga) with evolved Hf compositions, along with Labradorian (1.7–1.6 Ga) grains of more juvenile composition. Detrital zircon from the Kiosk domain yield Penokean through Labradorian ages, with Hf compositions ranging from evolved to juvenile. In contrast to the sedimentary rocks found in these Laurentia-derived parautochthonous domains, similar rocks from younger, more allochthonous units, including the Shawanaga and basal Parry Sound domain, dominantly contain zircon ranging from Pinwarian (ca. 1.45 Ga) through ca. 1.20 Ga that show exclusively juvenile isotopic compositions. The data show that sedimentary basins received detritus from nearby active sources as well as from the nearby Superior continent, and that successively younger sources and basins became increasingly less influenced by continental input as the margin grew wider. The data add to a growing database of similar data from other parts of this several thousand-kilometer-long margin that seemingly displayed little along-strike variation in overall evolution, implying the existence of a vast, Pacific-scale ocean.

Protracted eclogite‐facies metamorphism of the Dulan area, North Qaidam ultrahigh‐pressure terrane: Insights on zircon growth during continental subduction and collision

AbstractContinental subduction and collision are recorded by ultrahigh‐pressure (UHP) terranes; UHP terranes that form at early stages of an orogeny tend to be small and experience short residence at eclogite‐facies depths, whereas terranes that form at mature stages of an orogeny tend to be larger and experience longer residence at these depths, but accurately determining eclogite‐facies residence time requires a large geochronologic dataset tied to metamorphic conditions (via trace elements and/or inclusions). In the Dulan area, North Qaidam UHP terrane, China, it remains unclear whether the terrane experienced a long residence at eclogite‐facies depths, marking the mature stage of an orogeny or two distinct (ultra)high pressure ([U]HP) events (with short residence times), interpreted as the transition from oceanic subduction to continental collision, where one (U)HP event is related to the former and second (U)HP event to the latter. To address this issue, we report new zircon U–Pb ages and trace‐element data from eclogite and host paragneiss from the Dulan area and show that this terrane records ~42 Myr of eclogite‐facies metamorphism at (U)HP conditions, similar to other large UHP terranes. Zircon from 11 eclogite and 2 gneiss samples yields weighted mean ages of 463–425 Ma, flat heavy rare earth element (HREE) patterns without negative Eu anomalies, and eclogitic mineral inclusions, indicating eclogite‐facies conditions. Paragneiss metamorphic ages overlap with ages from eclogite but are generally younger, suggesting that a lack of internally generated fluids may have inhibited zircon growth and/or recrystallization until early decompression and white mica consumption in felsic gneiss generated fluids; thus, we interpret that these felsic rocks record the later stages of continental collision. Dataset patterns from all new and previously published analyses for the Dulan area (34 eclogite and 14 gneiss) suggest that metamorphic zircon in eclogite records prograde, peak and possibly early retrograde conditions, in contrast to the prediction from mass balance models that metamorphic zircon should only grow during exhumation and cooling. We reconcile our observations with these model predictions by recognizing that differential solubility can lead to grain‐scale zircon growth or recrystallization over a large segment of the pressure–temperature (P–T) path even where zircon abundance decreases at the whole‐rock scale.

U-Pb zircon ages from metasedimentary and plutonic rocks in the Bras d'Or terrane of Cape Breton Island, Nova Scotia, Canada: insights into the Ediacaran–Cambrian tectonomagmatic evolution of Ganderia

The Bras d'Or terrane of central Cape Breton Island, Nova Scotia, Canada, contains a well-preserved record of the Ediacaran to early Cambrian evolution of Ganderia, a Gondwana-derived terrane in the northern Appalachian orogen. A complex assemblage of low- to high-grade metasedimentary rocks has varied detrital zircon signatures from laser ablation inductively coupled plasma mass spectrometry U-Pb zircon dating, but combining three or more samples yielded representative age spectra that support correlation of the low- and high-grade metasedimentary rocks throughout the Bras d'Or terrane and the corresponding Ganderian Brookville terrane of southern New Brunswick. In quartzite samples from the McMillan Flowage Formation in the northwestern Bras d'Or terrane, the youngest detrital zircons have ages >900 Ma, in contrast to previously studied psammitic and semipelitic samples from correlative units in the eastern Bras d'Or terrane in which youngest detrital ages are 620–600 Ma. Both quartzite and semipelitic samples from the McMillan Flowage Formation contain Neoproterozoic dates from zircon rims, which reflect metamorphic overgrowths during peak metamorphism at ca. 550 Ma, providing a robust age for peak metamorphism in the Bras d'Or terrane that supports similar, albeit sparse, ages reported previously from monazite and titanite samples. This metamorphism is coeval with the emplacement of voluminous dioritic to granitic plutons that occur throughout the Bras d'Or terrane and form in an Andean-type continental margin subduction zone. New U-Pb zircon ages presented here from plutons in the northern Bras d'Or terrane, combined with previously published ages, are consistent with subduction-related magmatism and associated metamorphism between ca. 575 and 540 Ma.