Metallurgical Defects Research Articles

Corrosion resistance and electrical conductivity of Ta-modified Titanium bipolar plates for PEMFC

Titanium alloy bipolar plates hold significant promise for proton exchange membrane fuel cells (PEMFC) due to their high specific strength, excellent machinability and low density. However, the surface oxide film readily reacts with fluoride ions (F−) in service environments, forming porous, layered fluorotitanium compounds that compromise service life and stability. To overcome these limitations, this study utilised magnetron sputtering to deposit a 1 μm-thick tantalum (Ta) coating on TA1 titanium alloy substrates. The microstructure, corrosion resistance and electrical conductivity of the Ta-coated samples were systematically investigated and the mechanisms underlying their enhanced performance were analysed. Results showed that the Ta coating featured a dense, uniform microstructure with strong adhesion to the substrate and no detectable metallurgical defects. A gradient distribution of elements within the diffusion layer further strengthened the coating-substrate interface. Moreover, the formation of a Ta2O5 passivation film on the coating surface effectively inhibited fluoride-induced corrosion, reducing the contact resistance from 69.9 to 31.7 mΩ·cm2. These findings provide critical theoretical insights and practical guidance for enhancing the corrosion resistance and electrical conductivity of titanium alloy bipolar plates, paving the way for their broader application in PEMFC systems.

Knowledge assisted machine learning to clarify pore influence on fatigue life of forging/additive hybrid manufactured Ti-17 alloy

Forging/additive hybrid manufactured Ti alloy parts suffer from relatively low fatigue life due to the existence of metallurgical defects in the transition zone, which also brings difficulty to fatigue life modeling. In this work, the synergistic effect of pore size and location on the rotating-bending fatigue life of hybrid manufactured Ti-5Al-2Sn-2Zr-4Mo-4Cr (Ti-17) samples was systematically investigated with the combination of machine learning approaches and physical knowledge. A machine learning framework with a back propagation neural network and generative adversarial network (GAN) was constructed and employed on sparse and limited datasets. A general and interpretable model was obtained with a high level of 90% confidence. In general, the fatigue life of hybrid manufactured Ti-17 alloys decreases with pore size and increases with its distance to surface. Specifically, critical sizes were obtained for near-surface and in-depth pores that have negligible influence on fatigue life of hybrid manufactured samples with respect to pore-free samples. The present work thus provides a systematic platform for the evaluation of the fatigue performance of hybrid manufactured titanium alloys.

Microstructure and mechanical properties of ultrasonically welded aluminum to Zn–Mg–Al coated and uncoated mild steels

The gaining popularity of aluminum alloys in the automotive industry demand the development of energy efficient joining methods of Al with other metals such as steel. Among such joining methods, ultrasonic welding is advantageous because it is cost effective and prevents metallurgical defects because of the low welding energy involved. This study evaluates the microstructural changes and mechanical properties of dissimilar ultrasonic welding of Al to Zn–Mg–Al-coated and uncoated mild steels. Various intermetallic compounds (IMCs), such as FeAl3, and Fe2Al5 with different thicknesses and morphologies were observed at the joint interfaces. The Al-to-Zn-Mg-Al-coated steel exhibited mechanical properties that are superior to those of Al-to-uncoated mild steel. The results are discussed in terms of microstructure evolution, joint characteristics, and interfacial reactions in the welds. This study contributes to the understanding of the mechanisms behind strong ultrasonic welding of dissimilar metals.

Attention Pyramid Dilated Region-based Model for Metallurgical Defect Detection

Abstract Defect recognition is the key to realizing automatic visual inspection and quality control in intelligent manufacturing. Deep learning (DL) has been widely applied to locate damaged areas in images, characterize impurities of materials and further analyze the quality of products. However, automatic defect detection by DL in practical industrial applications is still a challenge due to the lack of sufficient datasets and appropriate recognition methods. Here, a novel Attention Pyramid Dilated Region-based Convolutional Neural Network (ADRCNN) is proposed to realize the multi-scale defect recognition and pixel-level instance segmentation of metallographic images. We also collected a dataset containing 900 images of commercial A356 aluminum alloy with different casting defects. The ADRCNN model is evaluated on our dataset with an average detection accuracy of 87.2% and 93.3% on validation and test sets respectively. To address the overfitting problem, a pretraining fine-tuning strategy is implemented by using the pretraining weights from large-scale datasets and temporarily freezing the weights of the backbone network during the training process. The experimental results show that the proposed model can achieve satisfactory defect segmentation in metallographic images, promoting the development of intelligent manufacturing in alloy industries.

Influences of friction stir processing on the microstructure and properties of TC4 titanium alloy by laser metal deposition

To enhance the properties of TC4 titanium alloy samples prepared by Laser Metal Deposition (LMD), while minimizing metallurgical defects and increasing relative density of the samples, the advanced Friction Stir Processing (FSP) technology was employed to conduct a refined secondary modification on the LMD-deposited TC4 titanium alloy samples. The comprehensive influences of FSP on the microstructure and properties of the as-deposited TC4 titanium alloy were emphatically investigated. The results reveal that the as-deposited TC4 titanium alloy exhibits a microstructure characterized primarily by columnar grains interspersed with a minor amount of equiaxed grains in the vertical section. After FSP treatment, the microstructure transforms into a new morphology where more refined equiaxed grains coexist with bimodal structures. Meanwhile, on the horizontal plane, the existing equiaxed grains are further refined, and the microstructure gradually transitions from the original Widmanstätten and basketweave structures to a more uniform laminar structure. Accordingly, the transformation of the microstructure leads to enhanced mechanical properties of the TC4 titanium alloy. Compared to the untreated as-deposited titanium alloy, the hardness of the FSP-processed samples significantly increases by 46.9 HV1 on the horizontal plane and 33.8 HV1 on the vertical plane. Additionally, the reduction in friction coefficient (from 0.47 to 0.41), a substantial decrease in wear mass (3.7 mg), and a slight improvement in the corrosion resistance of the titanium alloy collectively demonstrate the effectiveness of the FSP process in enhancing the performance of as-deposited TC4 titanium alloy.

Microstructure evolution and mechanical properties of bioinspired interpenetrating Ti2AlNb/TiAl matrix composite with a crossed-lamellar structure

TiAl alloys with low density, high creep resistance and high temperature performance are considered as candidate materials to replace nickel-based superalloys in the range of 700∼800 °C. However, the intrinsic brittleness of TiAl alloys has always been the biggest bottleneck restricting their development. In this paper, a bioinspired interpenetrating Ti2AlNb/TiAl composite with crossed-lamellar structure was prepared by combining selective laser melting (SLM) and vacuum hot press sintering (HPS) under the condition of 1150 °C/1 h/45 MPa, to improve the strength and toughness of the composite. Meanwhile, the metallurgical defects and microstructure of Ti2AlNb reinforcement skeleton printed under different volume energy densities (VEDs) were investigated, as well as the evolution of the microstructure at the interface region of the composite was systematically studied. What's more, we studied the mechanical properties of the composite including nanoindentation test, room temperature tensile and bending tests. The results show that the VED is 88.89 J/mm3, an almost completely dense reinforcement skeleton (∼99.8 %) is obtained. The interface region can be divided into four different reaction layers, namely LⅠ, LⅡ, LⅢ and LⅣ, due to the diffusion of elements. LⅠ is mainly composed of Othick/thin lath-like phase and O short rod-like phase. LⅡ is mainly composed of B2/β phase, acicular α2 phase and nanoscale ω-Ti3NbAl2 phase. The LⅢ mainly consists of B2/β phase. The LⅣ is composed of α2 phase. The deformability of each phase in the composite: B2/β phase > O phase >γ phase >α2 phase >ω phase. The tensile strength and fracture toughness of bioinspired interpenetrating Ti2AlNb/TiAl matrix composite are increased by 24.0 % and 89.0 %, respectively, compared with TiAl alloy, which is mainly contributed to the strong interfacial bonding between matrix and reinforcement as well as the synergistic effect of Ti2AlNb reinforcement with high strength and toughness.

Influence of dimensional deviation and thickness non-uniformity on the small-size specimen tensile results of CLF-1 steel

Tensile testing of small-size specimens has been widely used to evaluate the influence of neutron irradiation on the mechanical properties for structural materials of fusion reactors. In recent years, researchers have been trying to standardize small-size specimen tensile test method. In the present paper, we have investigated the influence of dimensional deviation and thickness non-uniformity on the tensile results of small-size specimen by both experiments and finite element simulations, based on one of the candidate structural materials of fusion reactor, i.e. CLF-1 steel. It was found that under the conditions of small grain size, small metallurgical defect size and suitable specimen preparation, the tensile results of SS-J3 specimen could be close to the results of large-size specimen. Slightly higher yield and ultimate strengths for small specimens may be caused by the surface treatment of the wheel grinding. The repeatability of ultimate strength was better than that of yield strength, and the repeatability of elongation was worse than that of strength. For tensile tests on eight SS-J3 specimens, the maximum difference in total elongation was about 3 %. With ±0.1 mm deviation of thickness and parallel width, the maximum variation in total elongation was about 1.8 %. The ductility properties were sensitive to specimen's thickness non-uniformity, the measured uniform and total elongations would obviously decrease even with 0.01 mm thickness non-uniformity.

The defects and compressive behavior of NiTi alloy fabricated by laser powder bed fusion under a wide process space

A wide process space with laser power (P) of 50 ～ 400 W and scanning speed (s) of 50 ～ 2400 mm/s with the energy density (ED) range of 93–556 J/mm3 has been employed to fabricate NiTi alloy using laser powder bed fusion (LPBF). The optimal process window for near-full dense materials free of geometrical and metallurgical defects was determined. The characteristics of microstructures and compressive behaviors were comprehensively investigated. The results have shown that the process combinations of “high P + low s” and “high P + high s” are prone to bulging and warping defects due to rapid heating and cooling, respectively. A combination of “low P + low s” produces a relatively shallow melt pool without keyhole formation even at ED as high as 556 J/mm3. The austenite-martensite phase transition temperature (TTs) variations of ～80℃ were obtained with the process window free of porosity. The pre-existing martensite lath probably formed by plastic distortion (bulging) was responsible for the lowest critical stress of induced martensite (σSIM). The texture and nano-sized NiTi2/Ni2Ti4Ox precipitates also contribute to the variation of σSIM and residual strain among the samples with the same level of TTs upon compressive loading.

Research Viewpoint on Performance Enhancement for Very-High-Cycle Fatigue of Ti-6Al-4V Alloys via Laser-Based Powder Bed Fusion

Additive manufacturing (AM) or 3D printing is a promising industrial technology that enables rapid prototyping of complex configurations. Powder Bed Fusion (PBF) is one of the most popular AM techniques for metallic materials. Until today, only a few metals and alloys are available for AM, e.g., titanium alloys, the most common of which is Ti-6Al-4V. After optimization of PBF parameters, with or without post processing such as heat treatment or hot isostatic pressing, the printed titanium alloy can easily reach tensile strengths of over 1100 MPa due to the quick cooling of the AM process. However, attributed to the unique features of metallurgical defects and microstructure introduced by this AM process, their fatigue strength has been low, often less than 30% of the tensile strength, especially in very-high-cycle regimes, i.e., failure life beyond 107 cycles. Here, based on our group’s research on the very-high-cycle fatigue (VHCF) of additively manufactured (AMed) Ti-6Al-4V alloys, we have refined the basic quantities of porosity, metallurgical defects, and the AMed microstructure, summarized the main factors limiting their VHCF strengths, and suggested possible ways to improve VHCF performance.

Eliminating metallurgical defects and achieving strength-ductility combination in selective laser melted martensitic stainless steel through high-pressure annealing

Due to high difficulty in fabricating and processing high-strength metals, additive manufacturing has been considered to have broad prospects compared to the traditional casting means. However, unavoidable metallurgical defects and strength–ductility trade-off dilemma have become Achilles' heels for their practical applications. In this work, one high-pressure annealing (HPA) strategy was introduced to process the selective laser melted (SLM) martensitic stainless steel. The microstructures and mechanical properties of as-built, high temperature annealing and HPA and as-rolled SLM samples were systematically investigated. It was found that the HPA treatment makes the stainless steel achieve the significant yield strength of 1828 MPa and the comparable plastic strain of 36.2% compared to other samples. The pores and laminar structures from the SLM process were eliminated by HPA. What is more, the HPA treatment results in uniform carbide precipitation, grain refinement and nanoscale heterogeneous structure comprising a series of coarse and fine grains. The physical mechanism for nanoscale heterogeneous structure induced by HPA was discussed from the perspective of the cooperative effect of temperature and pressure. Additionally, the strengthening contributions from grain refinement, carbide precipitation, dislocation hardening, heterogeneous structure and pore closure were quantitatively determined. The current study not only reveals the comprehensive effect of temperature and pressure on microstructure and mechanical properties, but also establishes HPA as an effective method to evade the strength-ductility trade-off in alloys fabricated by additive manufacturing.

The Analysis of the Compositional Uniformity of a Ti-Al Alloy during Electron Beam Cold Hearth Melting: A Numerical Study

The electron beam cold hearth melting (EBCHM) process is one of the key processes for titanium alloy production. However, EBCHM is prone to cause elemental volatilization and segregation during the melting of aluminum-containing titanium alloys such as Ti-6wt%Al-4wt%V. To gain deeper insights into the physical and chemical phenomena occurring during the EBCHM process, this paper establishes melting process models for the Ti-6wt%Al-4wt%V titanium alloy in a crystallizer with multiple overflow inlets. It examines the evolution of melt pool morphology, flow dynamics, heat transfer, and mass transfer during the casting process. The results indicate that the design of multi-overflow inlets can effectively suppress the longitudinal development of impact pits within the melt pool, thereby preventing the formation of solidification defects such as leaks in the melt. Concurrently, the diversion effect of multi-overflow inlets significantly enhances the elemental homogeneity within the melt pool. At a casting speed of 20 mm/min and a casting temperature of 2273 K, compared to a single overflow inlet, the design with three overflow inlets can reduce the depth of thermal impact pits within the crystallizer by 132 mm and decrease the maximum concentration difference in the Al element within the crystallizer by 0.933 wt.%. The aforementioned simulation results provide a theoretical basis for the control of metallurgical and solidification defects in large-scale titanium alloy ingots.

Diagnostics of Fatigue Failures of Internal Combustion Engine Crankshafts. Part 2. Metallurgical Defects—the Source of Fatigue Failure of Internal Combustion Engine Crankshafts

Diagnostics of Fatigue Failures of Internal Combustion Engine Crankshafts. Part 2. Metallurgical Defects—the Source of Fatigue Failure of Internal Combustion Engine Crankshafts

Metallurgical Defects and Roughness Investigation in the Laser Powder Bed Fusion Multi-Scanning Strategy of AlSi10Mg Parts

Laser Powder Bed Fusion is the most attractive additive manufacturing technology for its capability to produce metal components with complex geometry. One of the main drawbacks is the poor surface roughness. In this work, different scan strategies and process parameters were studied and their effect on surface roughness, alloy microstructure, and metallurgical defects were discussed. The results highlighted that only tailored process conditions could combine acceptable roughness and absence of metallurgical defects. For the upskin, it has been seen that, although by increasing the Volumetric Energy Density value the Ra decreases, Volumetric Energy Density values higher than 69 J/mm3 determine meltpool instability with consequent formation of gas defects in the subsurface area. Similarly, by increasing the Linear Energy Density value, the Ra of the lateral surfaces decreases, but above 0.37 J/mm, metallurgical defects form in the subsurface area. This study also highlighted that the proposed process involves only a contained increase of the production times. In fact, the evaluation of the increased production times, related to the adoption of this multi-scanning strategy, is of fundamental importance to consider if the proposed process can be advantageously applied on an industrial scale.

Achieving high strength and fatigue performance of wire-arc additive manufactured 6061 aluminum alloy via interlayer friction stir processing and heat treatment

Interlayer friction stir processing (IFSP) has been proved to be an effective method for addressing metallurgical defects and modifying the microstructure of 6061 aluminum alloy produced by wire-arc additive manufacturing (WAAM). In this study, the effect of T6 post-heat-treatment on the microstructure, tensile properties and fatigue behavior were systematically investigated. The results show that the WAAM + IFSP-T6 component has excellent mechanical properties matching wrought counterparts, despite the abnormal grain growth in the stir zone, but there are no defects and a large number of nanometer β'' phases precipitate within the grains in the component. The mechanical properties of WAAM + IFSP-T6 component are isotropic, and the average yield strength, ultimate tensile strength, elongation and fatigue strength are 314 MPa, 336 MPa, 13% and 127 MPa, respectively.

Research status of laser powder bed fusion Al–Li alloys and its improvement measures

Laser powder bed fusion (LPBF) Al–Li alloy technology demonstrates adaptability to the development requirements of structural complexity and functional integration, making it a promising area of research in additive manufacturing for the aerospace, defense industry, and other fields. However, challenges such as microstructure anisotropy and metallurgical defects inevitably arise during the LPBF process of lightweight alloys, significantly impeding further enhancements in their formability properties. Some improvement measures offer a viable solution to enhance the microstructure, mitigate metallurgical defects, and optimize residual stress distribution in additive structures, thereby enabling high–performance Al–Li alloy production by LPBF. This paper first introduces the fundamental principle of LPBF and discusses the process of parameter optimization for LPBF Al–Li alloys. It then describes the typical microstructures and common metallurgical defects of LPBF Al–Li alloys, along with examining the evolution process of microstructures and formation mechanism of metallurgical defects. Specifically, it focuses on discussing the influence of Li element on solidification structure. On this basis, it presents the mechanical properties and anisotropy of mechanical properties for LPBF Al–Li alloys. Afterward, a comprehensive review is provided of the current research status regarding LPBF improvement measures, including powder alloying, heat treatment, and other technologies. Emphasis is placed on improvements in microstructure anisotropy and reductions in metallurgical defects through these improvement measures. Finally, this article summarizes the research progress made in LPBF Al–Li alloys and its improvement measures while also prospecting future research work.

Revealing the failure mechanism of industrial Fe-25Cr-20Ni stainless steel plate: Fine-grained segregation band and brittle phase induced delamination cracking

The use of heat-resistant stainless steel thick plates in industrial production often presents challenges due to the presence of uneven microstructure and segregation, which can pose a persistent challenge for the prolonged safe operation of critical components made from such materials. This study aimed to investigate the fracture mechanism of an industrial Fe-25Cr-20Ni stainless steel plate at room temperature through uniaxial tensile experiments and fully reversed strain-controlled tension-compression fatigue experiments. Delamination cracks were observed on the fracture surfaces of both experiments. The specimens with fracture delamination were systematically studied by detailed microstructural evolution, and the failure mechanism and main reasons of fracture delamination were analyzed. The results show that the fracture delamination is related to the fine-grained segregation band (FGSB) consisted of fine grains and sigma phase located at the center of the thickness of the stainless-steel plate. The FGSB demonstrates low transgranular and intergranular fracture modes and exhibits bamboo knobs crack during plastic deformation, leading to a mixed fracture mode of ductile and brittle fracture. Furthermore, FGSB, as an anisotropic microstructure, which has a high stress concentration with nearby grains during plastic deformation. The sigma phase fracture and the weakening of the interface strength of the microstructure in FGSB provide a potential initiation site for fatigue crack initiation, thereby contributing to the possibility of aggravating fatigue damage and deteriorating fatigue performance. It is concluded that FGSB, as a metallurgical defect in stainless steel plates, is responsible for delamination failure.

Failure analysis of stainless steel metal hose used for welding

While using ammonia (NH3) gas at 10 bar/500℃, a stainless steel 304 metal hose used as a bellow expansion joint was fractured. It was observed that the fracture of the metal hose started near the weld between the hose and the flange, and progressed to approximately 1/4 of the circumference of the weld.No metallurgical defects were found in the weld where the crack occurred. However, the folded part of the metal hose is welded to the flange, which can cause cracks. In other words, when the metal hose is forcibly compressed or stretched in order to weld it to the flange, the stress concentration due to cold work, including residual stress cause the metal hose to become brittle or crack. It is determined that when a high strain cyclic load or torsional deformation is applied to a high-hardness metal component, the metal hose will reach fatigue failure in a short period of time.

Numerical Modeling of Electron Beam Cold Hearth Melting for the Cold Hearth

The electron beam cold hearth melting (EBCHM) process is one of the key processes for titanium alloy production. The unique characteristic of this pyrometallurgy process is the application of the cold hearth, which is responsible for controlling the Low-Density Inclusions (LDIs) and High-Density Inclusions (HDIs) in the melt. As a key process of inclusion removal, the information such as melt residence time in the cold hearth is directly related to the control of metallurgical defects in the ingot, and may also affect the composition distribution of the ingot. In this paper, the details for the physical phenomena, namely the evolution of the pool, the evolution of the flow, and the evolution of the component in the cold hearth during EBCHM are investigated using a modified multi-physical numerical model. The effects of melting temperature and melting speed on these phenomena were investigated. The purpose is to provide more fundamental knowledge and to further enhance the applications of EBCHM for more titanium alloys.

High-performance functional coatings manufactured by integrated extremely high-speed-rate laser directed energy deposition with interlayer remelting

Extremely high-speed-rate laser directed energy deposition has attracted considerable attention for large-scale industrial component manufacturing owing to its outstanding fabrication efficiency. However, interlayer metallurgical defects and thickness fluctuation stacking caused by the previous non-uniform rough surface layer hinder the preparation of customized thicknesses of large-scale components with high performance. Herein, an integrated extremely high-speed-rate additive manufacturing technology, that is, extremely high-speed-rate laser-directed energy deposition accompanied by extremely high-speed-rate laser remelting, is proposed to eliminate porosity and reconstruct the microstructure of multilayer parts. The remelted specimens exhibited uniform roughness and ultrafine grains when defocusing amount was less than zero. The relatively lower temperature gradient G and morphology factor G/R in the remelting process led to more favorable subcooling, which further promoted more nucleation sites and contributed to grain refinement and columnar-to-equiaxed transition. A multilayer 316 L stainless steel material with an interlayer remelting treatment was further prepared, and a typical heterogeneous structure dominated by ultrafine equiaxed grains was obtained. The multilayer specimen characterized by such a special structure exhibited a higher yield strength of 546 MPa, along with a ductility of 49.1 %. This novel integrated manufacturing technology highlights a new strategy that can expand the extremely high-speed-rate additive manufacturing window and achieve simultaneous improvements in the manufacturing efficiency and performance of large-scale components.

Laser Wobble Welding Process: A Review on Metallurgical, Mechanical, and Geometrical Characteristics and Defects

Laser Wobble Welding Process: A Review on Metallurgical, Mechanical, and Geometrical Characteristics and Defects