Helical Metal Research Articles

Thermally Drawn Highly Conductive Fibers with Controlled Elasticity.

Electronic fabrics necessitate both electrical conductivity and, like any textile, elastic recovery. Achieving both requirements on the scale of a single fiber remains an unmet need. Here, two approaches for achieving conductive fibers (107 S m-1 ) reaching 50% elongation while maintaining minimal change in resistance (<0.5%) in embedded metallic electrodes are introduced. The first approach involves inducing a buckling instability in a metal microwire within a cavity of a thermally drawn elastomer fiber. The second approach relies on twisting an elastomer fiber to yield helical metal electrodes embedded in a stretchable yarn. The scalability of both approaches is illustrated in apparatuses for continuous buckling and twisting that yield tens of meters of elastic conducting fibers. Through experimental and analytical methods, it is elucidated how geometric parameters, such as buckling pre-strain and helical angle, as well as materials choice, control not only the fiber's elasticity but also its Young's modulus. Links between mechanical and electrical properties are exposed. The resulting fibers are used to construct elastic fabrics that contain diodes, by weaving and knitting, thus demonstrating the scalable fabrication of conformable and stretchable antennas that support optical data transmission.

On the initiation and evolution of dielectric breakdown in auto-magnetizing liner experiments

Auto-magnetizing (AutoMag) liners are cylindrical tubes composed of discrete metallic helices encapsulated in insulating material; when driven with a ∼2 MA, ∼100-ns prepulse on the 20 MA, 100-ns rise time Z accelerator, AutoMag targets produced &amp;gt;150 T internal axial magnetic fields [Shipley et al., Phys. Plasmas 26, 052705 (2019)]. Once the current rise rate of the pulsed power driver reaches sufficient magnitude, the induced electric fields in the liner cause dielectric breakdown of the insulator material and, with sufficient current, the cylindrical target radially implodes. The dielectric breakdown process of the insulating material in AutoMag liners has been studied in experiments on the 500–900 kA, ∼100-ns rise time Mykonos accelerator. Multi-frame gated imaging enabled the first time-resolved observations of photoemission from dynamically evolving plasma distributions during the breakdown process in AutoMag targets. Using magnetohydrodynamic simulations, we calculate the induced electric field distribution and provide a detailed comparison to the experimental data. We find that breakdown in AutoMag targets does not primarily depend on the induced electric field in the gaps between conductive helices as previously thought. Finally, to better control the dielectric breakdown time, a 12–32 mJ, 170 ps ultraviolet (λ = 266 nm) laser was implemented to irradiate the outer surface of AutoMag targets to promote breakdown in a controlled manner at a lower internal axial field. The laser had an observable effect on the time of breakdown and subsequent plasma evolution, indicating that pulsed UV lasers can be used to control breakdown timing in AutoMag.

Slow waves on long helices

Slowing light in a non-dispersive and controllable fashion opens the door to many new phenomena in photonics. As such, many schemes have been put forward to decrease the velocity of light, most of which are limited in bandwidth or incur high losses. In this paper we show that a long metallic helix supports a low-loss, broadband slow wave with a mode index that can be controlled via geometrical design. For one particular geometry, we characterise the dispersion of the mode, finding a relatively constant mode index of sim 45 between 10 and 30 GHz. We compare our experimental results to both a geometrical model and full numerical simulation to quantify and understand the limitations in bandwidth. We find that the bandwidth of the region of linear dispersion is associated with the degree of hybridisation between the fields of a helical mode that travels around the helical wire and an axial mode that disperses along the light line. Finally, we discuss approaches to broaden the frequency range of near-constant mode index: we find that placing a straight wire along the axis of the helix suppresses the interaction between the axial and high index modes supported by the helix, leading to both an increase in bandwidth and a more linear dispersion.

The Role of Polymer–AuNP Interaction in the Stimuli‐Response Properties of PPA–AuNP Nanocomposites

Back Cover: In article number 2100616 by Félix Freire and co-workers, dynamic helical polymers such as poly(phenylacetylene)s interact and respond to external stimuli such as metal ions, due to the formation of a helical polymer metal complex (HPMC), which can further be transformed into a hybrid material by reducing the metal ion. The resulting nano-composites combine the properties of the metal nanoparticles and the dynamic helical polymers and show stimuli-responsive properties towards different stimuli such as metal ions, temperature or solvents. Moreover, these nanocomposites can be nanostructured into nanospheres that show a dynamic chiral shell and encapsulation properties.

Dispersion Control and Size Enlargement of Helical Slow-Wave Structure by Double-Positive Metamaterial Assistance

A novel dispersion control technique, using I-shaped double-positive metamaterial (MTM) as the helical slow-wave structure (SWS) support, exhibiting low-loss, broadband response, has been proposed for wideband traveling-wave tubes (TWTs). The proposed SWS provided the desired flat-to-negative wideband dispersion characteristics giving higher interaction impedance than that is obtainable by conventional vane-loaded helical SWS. A coaxial transmission line-based simulation model has been used to retrieve the effective relative permittivity and permeability of the I-shaped MTMs. The electromagnetic analysis in the sheath-helix model was validated against the CST Microwave Studio simulation with respect to the dispersion characteristics within 14&#x0025;&#x2013;16&#x0025; and interaction impedance versus frequency characteristics within &#x003C; 12&#x0025;. Moreover, the proposed structure can be made to exhibit positive, flat, or negative dispersion characteristics by controlling the dimensions of the I-shaped metal strips without altering the dimensions of the helical SWS and metal envelope of the structure. Furthermore, with the help of the proposed structure, the diameter of the structure could be increased without adversely affecting the shape of the dispersion characteristics and reducing the value of the interaction impedance. The structure will reduce the fabrication complexity at higher frequencies and make the structure suitable for high-power, high-gain, and high-efficiency wideband TWTs.

Chiroptical and colorimetric switches based on helical polymer-metal nanocomposites prepared via redox metal translocation of helical polymer metal complexes.

A helical copoly(phenylacetylene) that follows a dynamic chiral accord effect has been designed to further synthesize dynamic chiral nanocomposites. Its two pendants are benzamides of (L)-methionine methyl ester [(L)-1, 20%] and (L)-alanine methyl ester [(L)-2, 80%], the former being responsible for binding the copolymer to metallic nanoparticles (MNPs, M = Au, Ag) via the thioether. The two chiral comonomers have analogous dynamic behavior, and therefore, the copolymer-poly-[(L)-10.2-co-(L)-20.8]-adopts a preferred helical sense that can be amplified or inverted by stimuli acting simultaneously on both pendants. The formation of nanocomposites can be followed by different sequential chiroptical responses of the copolymer once the helical polymer metal-complexes are formed-M to P helix inversion by the formation of poly-[(L)-10.2-co-(L)-20.8]/Au3+ or poly-[(L)-10.2-co-(L)-20.8]/Ag+-and further reduction with NaBH4 to generate the corresponding nanocomposites-P to M helix inversion by the formation of poly-[(L)-10.2-co-(L)-20.8]-AuNPs (6 nm) and poly-[(L)-10.2-co-(L)-20.8]-AgNPs (5 nm). These nanocomposites exhibit the properties of both components, helix inversion in the PPA and a colorimetric response in the MNPs triggered by metal ions.

Self-assembled lanthanide-based helixes: synthetic control of the helical handedness by chirality of the ligand.

The control of the self-assembly of lanthanide helical chain and their helical handedness have been investigated for the first time. Δ- and Λ-form lanthanide chain complexes were obtained by introducing thiazolidine ligands that were synthesised from L- and D-cysteine, respectively, and shared the same formula: [Ln2(L)3(H2O)5]∞·3H2O (Ln: Sm and Eu) (L: 2-(2-hydroxy-3,5-dinitrophenyl)thiazolidine-4-carboxylic acid). The crystallographic, circular dichroism, and luminescence properties of these novel lanthanide chain complexes were studied.

Auxetics-Inspired Tunable Metamaterials for Magnetic Resonance Imaging.

Auxetics refers to structures or materials with a negative Poisson's ratio, thereby capable of exhibiting counterintuitive behaviors. Herein, auxetic structures are exploited to design mechanically tunable metamaterials in both planar and hemispherical configurations operating at megahertz (MHz) frequencies, optimized for their application to magnetic resonance imaging (MRI). Specially, the reported tunable metamaterials are composed of arrays of interjointed unit cells featuring metallic helices, enabling auxetic patterns with a negative Poisson's ratio. The deployable deformation of the metamaterials yields an added degree of freedom with respect to frequency tunability through the resultant modification of the electromagnetic interactions between unit cells. The metamaterials are fabricated using 3D printing technology and an ≈20MHz frequency shift of the resonance mode is enabled during deformation. Experimental validation is performed in a clinical (3.0 T) MRI system, demonstrating that the metamaterials enable a marked boost in radiofrequency field strength under resonance-matched conditions, ultimately yielding a dramatic increase in the signal-to-noise ratio (≈4.5×) of MRI. The tunable metamaterials presented herein offer a novel pathway toward the practical utilization of metamaterials in MRI, as well as a range of other emerging applications.

Control of phase, polarization, and amplitude based on geometric phase in a racemic helix array

The Pancharatnam–Berry geometric phase has attracted great interest due to the elegant phase control strategy via geometric transformation of optical elements. The commonly used geometric phase is associated with circular polarization states. Here, we show that by exploiting the geometric phase associated with the two elliptical eigen-polarization states in a racemic metallic helix array, exotic features including full range phase modulation for linear polarization states, diverse polarization conversion, and full complex amplitude modulation can be obtained with rotation of the helices. As a proof of concept, several devices for implementing polarization conversion, vortex beam generating, and lateral dual focusing are built with a racemic helix array in the microwave regime. The calculated and experimental results validate our proposals, which can stimulate various advanced metadevices.

Axial Motion Characterization of a Helical Ionic Polymer Metal Composite Actuator and Its Application in 3-DOF Micro-Parallel Platforms

In this work, a helical ionic polymer metal composite (IPMC) was fabricated by thermal treatment in a mold with helix grooves. The axial actuation behaviors of the helical IPMC actuator were observed, and the electromechanical and electrochemical characteristics were evaluated. The experimental results showed that as the voltage increased and the frequency decreased, the axial displacement, axial force, and electric current of the actuator all increased. Compared with square wave and sinusoidal signals, the actuator exhibited the most satisfactory motion under the direct current (DC) signal. For the electrochemical test, as the scanning rate decreased, the gravimetric specific capacitance increased. Within a suitable voltage range, the actuator was chemically stable. In addition, we coupled the Electrostatics module, Transport of Diluted Species module, and Solid Mechanics module in COMSOL Multiphysics software to model and analyze the helical IPMC actuator. The simulation data obtained were in good agreement with the experimental data. Finally, by using three helical IPMC actuators as driving components, an innovative three-degree-of-freedom (3-DOF) micro-parallel platform was designed, and it could realize a complex coupling movement of pitch, roll, and yaw under the action of an electric field. This platform is expected to be used in micro-assembly, flexible robots, and other fields.

AZIMUTHAL SURFACE WAVES IN LOW-DENSITY PLASMA LOADED, COAXIAL HELIX TRAVELING-WAVE-TUBE-LIKE WAVEGUIDES

The dispersion properties of flute electromagnetic waves propagating across an external axial static magnetic field in traveling-wave-tube-like waveguides with low-density plasma filling are investigated. The cylindrical structure consists of a central dielectric rod, placed inside a plasma coaxial layer with a metallic helix sheath on its outer interface, and a metal screen separated from the helix by another dielectric layer.

Fabrication of silver helix microstructures in a large area by a two-photon absorption DLW method

Large-area helix microstructures intended for metamaterials were fabricated using a negative photoresist, SU-8 using a two photon absorption direct laser writing (TPA-DLW). Two types of helix structures were fabricated. One type is those with no neighboring distance. In this case, compact helix structures with radius of 2.5 and 1.0 μm were fabricated. Another type is those with enough neighboring distance. The helix structures with shorter neighboring distance below 6.0 μm were collapsed, whereas those with longer neighboring distance more than 6.5 μm, free-standing helix structures could successfully be built. To stabilize the fabricated free-standing helix microstructures with a 1 μm radius, circular foundations with a radius of 1.3 μm and elevation angle of 10, 12, or 14° were built in advance. The foundation is useful to avoid collapsing the helix microstructures. Due to the useful foundation, over 18,000 helical structures were fabricated in a large area. The fabricated helical structures were coated with silver using an electroless plating method to produce 3D metallic helix structures. Silver coating was measured using a EDX measurement. The obtained helical structures have the potential for metamaterials to control the handedness of a circularly polarized infrared beam.

2D and 3D Structuring of Freestanding Metallic Wires Enabled by Room-Temperature Welding for Soft and Stretchable Electronics.

In this work, a facile and cost-effective approach to assemble metallic wires into two-dimensional (2D) and three-dimensional (3D) freestanding geometries by room-temperature welding is demonstrated. The low melting point of gallium (29.8 °C) enables the welding at room temperature without the aid of high-energy sources required for high-melting-point metals and alloys. The welding enables assembly of solid gallium wires into 2D and 3D geometries that could create freestanding architectures with multiple junctions along any inclined direction. These 2D and 3D freestanding metallic structures are freeze-cast in soft elastomers to obtain stretchable and soft devices: a 2D stretchable resistive and capacitive sensor patterned with parallel metal lines, a 2D stretchable capacitive sensor patterned with an interdigitated metal structure with capacitive changes on stretching in both x- and y-axes, and a 3D compressive sensor by assembly of liquid metal helices, which could sense foot pressure compression. We also developed a facile method to interconnect between soft circuits and external electronics, suppressing stress during mechanical deformation.

Spontaneous chiral self-assembly of CdSe@CdS nanorods

Spontaneous chiral self-assembly of CdSe@CdS nanorods

Development of a terahertz wave circular polarizer using a 2D array of metallic helix metamaterial.

We developed a broadband terahertz wave circular polarizer that consists of a two-dimensional (2D) array of three-dimensional metallic helices. Each helix operates in an axial mode of operation where the wavelength of resonance is comparable to the dimensions of the helix. We evaluated the performance of the polarizer using standard terahertz time domain spectroscopy, and we confirmed that the array of helices transmits a circularly polarized terahertz wave with opposite handedness as that of the helices. The polarizer covers the frequency range from 117 GHz to 208 GHz, close to one octave. We obtained the ellipticity of the circularly polarized terahertz wave close to unity in this frequency band.

Zeroth radial modes of azimuthal surface waves in dense plasma-loaded, coaxial helix traveling-wave-tube-like waveguides

An analytical model of coaxial traveling-wave-tube-like waveguides with plasma filling has been justified and utilized to analyze the eigenmodes. Very often, introducing plasma into vacuum electronic devices leads to essential advantages as compared with evacuated tubes. The cylindrical structure under the present consideration consists of a central dielectric rod, placed inside a plasma coaxial layer with a metallic helix sheath on its outer interface, and a metal screen separated from the plasma by another dielectric layer. The dispersion properties of electromagnetic waves propagating across the external axial static magnetic field in such traveling-wave-tube-like waveguides are studied and summarized. The presence of a dense plasma coaxial layer makes the media nontransparent for waves in the electron cyclotron frequency range. However, surface type electromagnetic waves can propagate in this case. These waves are called azimuthal surface waves (ASWs). The helix sheath causes coupling of ordinarily and extraordinarily polarized ASWs. The zeroth radial ASW modes have been found to be most dangerous for parasitic wave excitation in dense plasma-loaded, coaxial traveling-wave-tube-like waveguides.

Mid-infrared flat-topped broadband chiral helix metamaterials based on indium tin oxide and their chiral properties

We proposed a periodic mid-infrared broadband chiral structure. Its unit cell consists of four indium tin oxide (ITO) helix subunits with different radii. The simulation results show that the flat-topped broadband circular dichroism (CD) can be achieved in the mid-infrared band by optimizing the parameters of helix structures. The simulation results also show that compared with the metallic (Ag and Au) helix structures, the ITO helix structure proposed exhibits evidently better broadband CD and optical activity, which provides a new idea for the design of broadband polarization state control devices in the mid-infrared band.

Anatomical and physical properties of tendril perversion of Coccinia grandis (L.) Voigt

The structure of biomaterial is interest in biomimetic and biomechanics research. The physical properties, mechanical, characteristic of twisting and bending of plant tendrils are also thought-provoking to study. In this study, we proposed an innovative biomaterial spring device for holding an object and providing support. The device uses Coccinia grandis (L.) Voigt tendril as inspired by the relations of left-hand (LH) and right-hand (RH) climbing tendrils with a single branch. To study the morphology and anatomy, testing stress, length, number of the helix of the tendril which relation of mimic string material Coccinia grandis (L.) Voigt tendril and helical metal which have two helixes, three helixes and four helixes were tested by using food texture analysis. The anatomical showed many cell types and slight differences between straight and coiled tendrils. The result showed the tendril of two helixes has the highest stress and four helixes the least. Also, tensile testing showed that the number of helixes does not affect the stress of the tendril models.

Polarization Control with Helical Metasurfaces

The ability to fully control the polarization of light using chiral metadevices has drawn considerable attention in various applications of integrated photonics, communication systems, and life sciences. In this work, we propose a comprehensive approach for the design of metasurfaces with desired polarization properties for reflected and transmitted waves based on the proper spatial arrangement of chiral inclusions in the unit cell. Polarization conversion is achieved by engineering induced electric and magnetic dipole moments of the metasurface inclusions. We show that under a proper arrangement, the same inclusion can be used as a building block of metasurfaces with drastically different wave-transformation functionalities. The horizontally and vertically oriented metallic helices were used as simplest chiral inclusions, which can be manufactured by the established 3D fabrication techniques from THz up to the visible spectral range. The proposed metadevices provide a deep understanding of the light–matter interaction for polarization conversions with helix-based structures and opens the way to new possibilities of electromagnetic polarization control with advanced chiral metadevices in communication and imaging systems.

Cover Feature: Structural Characterization and Lifetimes of Triple‐Stranded Helical Coinage Metal Complexes: Synthesis, Spectroscopy and Quantum Chemical Calculations (Chem. Eur. J. 47/2020)

Cover Feature: Structural Characterization and Lifetimes of Triple‐Stranded Helical Coinage Metal Complexes: Synthesis, Spectroscopy and Quantum Chemical Calculations (Chem. Eur. J. 47/2020)