Metallic Structures Research Articles

Artificial intelligence in tasks of teaching students calculations and design of metal structures.

Various applications of artificial intelligence for design tasks and modeling of metal structures are being explored. Options for integrating artificial intelligence tools into calculations and principles of designing metal structures are considered. It is demonstrated that the integration of artificial intelligence technologies can both enhance students' understanding of engineering design concepts and structural analysis and lead to errors or misinterpretation of results. Directions for improving the outcomes of solving engineering tasks using artificial intelligence are discussed.

The influence of 3D printing mode on the chemical composition and structure of 30HGSA steel

The authors carried out the study of the influence of 3D printing modes on the structure and chemical composition of 30HGSA steel (chromansil) samples produced by the method of additive electric arc surfacing. To study the influence of the electric arc surfacing mode on the chemical composition of the steel under study, an optical emission analysis of the samples was carried out. The influence of the surfacing mode on the resulting structure was assessed over the entire height of the deposited walls at magnifications of ×50, ×100, ×200 and ×500. Optical emission analysis identified a change in the material chemical composition associated with the loss of chemical elements. It was found that the degree of loss of C, Cr and Si increases almost linearly and is directly proportional to the surfacing heat input (Q, J/mm). The exact influence of an increase in the surfacing heat input on the Mn content was not found, but a relationship between the degree of its loss and the voltage (U, V) during surfacing of samples was identified. Microstructural studies of all samples did not reveal a large number of systemically formed structural defects characteristic of cast and welded products (pores, shrinkage cavities, etc.), which confirms the high quality of the metal in goods produced by electric arc surfacing. Analysis of micrographs taken in different areas of the samples allowed determining that the metal microstructure does not undergo significant changes under different surfacing modes; the main tendencies in changes in the structure along the height of the sample are preserved. All samples demonstrated the formation of a highly dispersed structure, regardless of the 3D printing parameters. The most favorable metal structure, suitable for subsequent use in the production of goods using additive manufacturing, was recognized as the structure of the sample deposited using mode No.5 (I=160A, U=24V, Q=921.6J/mm). This mode can be used for further study of the problems of additive electric arc surfacing of 30HGSA steel.

Modern levels of structural strength assessment and the algorithm of implementation of the methodology of risk analysis of the operation of welded metal structures

Modern levels of structural strength assessment and the algorithm of implementation of the methodology of risk analysis of the operation of welded metal structures

In-plane crashworthiness study of bio-inspired metallic lattice structure based on deep-sea glass sponge

Inspired by the double-diagonal reinforced configuration of deep-sea glass sponges, a metallic bio-inspired lattice structure (BLS) was fabricated using additive manufacturing (AM) techniques. In-plane quasi-static compression tests demonstrated the energy absorption (EA) of BLS was improved by about 60 % compared to conventional lattice designs. Subsequent experimental and numerical investigations examined the effects of wall thickness, elucidating the corresponding variations in crashworthiness indicators. The study revealed that when the wall thickness increased from 0.40 mm to 0.60 mm, the EA and mean crushing force (Pm) exhibited a substantial increment of 58.1 % and 91.1 %, respectively. The finite element (FE) simulations underwent experimental validation, exhibiting satisfactory agreement. Parametric studies using the validated FE model explored the effects of geometric factors, such as diagonal distance, unit size, unit number and graded thickness on the crushing performance of BLS. Results indicated that enhancing the EA performance of BLS was achievable by concurrently reducing the unit size and increasing the unit number. The maximum EA achieved was 3535.5 J, representing a 62.9 % improvement compared to the initial configuration, which exhibited an EA of 2170.7 J. Additionally, the introduction of graded thickness facilitated a controllable collapse pattern, thereby improving the crashworthiness performance. Lastly, the in-plane dynamic crushing simulations were conducted, identifying three distinct collapse patterns, where the U-Mode exhibiting a negative Poisson's ratio (NPR) behavior. A deformation mode map and rigid-perfectly plastic-lock (R-PP-L) model were developed to evaluate the dynamic response of BLS under varying relative density (RD) and impact velocity (V). These findings provided valuable insights for designing sponge-inspired structures with enhanced crashworthiness performance.

Robust palladium oxide nano-cluster catalysts using atomic ions and strong interactions for high-performance methane oxidation

Optimizing metal catalyst structures to achieve desired states is vital for efficient surface reactions, yet remains challenging due to the lack of well-defined precursor materials and weak metal-support interaction. Palladium-based catalysts, when not properly tailored for complete methane oxidation exhibit insufficient performance. Herein, we fabricate Pd oxide nano-clusters supported on SSZ-13 using atomic ions with strong metal-support interaction (SMSI). Steam treatment of Pd/SSZ-13 transforms Pd particles into ions and induces SMSI. Subsequently, CO reduction and O2 oxidation yield mildly sintered Pd oxide nano-clusters firmly anchored on extra-framework Alpenta sites of SSZ-13, facilitating superior activity. The robustness from SMSI prevents irreversible deactivation, and water-resistance by complete dehydration suppresses reversible degradation in wet conditions. This catalyst exhibits high performance in bench-scale reactions using monolith catalysts, ensuring applicability for industrial methane abatement. The results demonstrate that sequential treatment to Pd/SSZ-13 offers a promising approach for tailoring metal structures to enable high-performance methane oxidation.

Topological Dark Spots of the Electric Near Field in Metal Structures

Topological Dark Spots of the Electric Near Field in Metal Structures

Two stucco sculptures from the “Salone d’Ercole” in the Racconigi Castle (Cuneo, Italy): a case study

Non-invasive and micro-destructive diagnostic investigations were employed for the study of two stucco statues depicting Putti, from the “Salone d’Ercole” in the Racconigi Castle (Cuneo, Italy). The research made it possible to understand the construction technique, constituent materials, and the state of conservation of the statues. This information was useful for placing the artworks in the correct historical-artistic context and for conservation choices and restoration interventions. Different analytical investigations were applied, specifically: a) the internal metal structure was analyzed by cover meter relief combined with digital radiographic technique; b) the stucco composition and its stratigraphy were characterized by Polarized Optical Microscopy (POM), X-ray diffraction (XRD) and Electron Scanning Microscopy coupled with Energy-Dispersive X-ray spectroscopy (SEM-EDX); c) finally, the presence of organic compounds was observed by UV-Induced Visible Fluorescence (UVL) and then characterized by Fourier Transform Infrared Spectroscopy (FT-IR) analyses. The results show that the stucco Putti were made with the techniques and raw materials widely used by Ticino artists and plasterers' workshops active between the 16th and 17th centuries, in the current Canton Ticino region. As regards the state of conservation, decay phenomena such as exfoliation and loss of material were mainly attributable to the presence of epsomite.

Plasma‐electrified synthesis of atom‐efficient electrocatalysts for sustainable water catalysis and beyond

The downsizing of metal structures to the nano and atomic level, thereby creating nanoparticle catalysts (NPCs), sub‐nanometer cluster catalysts (SNCCs) or single atom catalysts (SACs), has gained significant interest. In particular, synthesizing these types of catalysts using low temperature plasma electrified methods is an emerging field which is highly applicable to electrochemical water splitting for the sustainable production of green hydrogen. Surface modification via plasma treatment provides a route for nanoparticle immobilization or single atom trapping which ensures high atom utilization during electrolysis reactions. Plasma can also be used to create NPCs, SNCCs and SACs from various precursors as well as modify their surface properties once formed which impacts significantly on the oxygen evolution reaction and hydrogen evolution reaction. Therefore, in this review we emphasize the role that low temperature plasma electrified synthetic strategies play in electrocatalyst development for water splitting reactions and explore the crucial relationship between the electronic and coordination environment of atom efficient catalysts and their resulting catalytic activity. We also discuss methods to characterize these types of catalysts and the possibility for scaling up this technology which will be required for commercial applications.

Application of 3D structure of carbon nanotube-interwoven metal–organic frameworks in solid-phase microextraction of trace polychlorinated biphenyls from tea beverages

A three-dimensional (3D) structure of multiwalled carbon nanotubes (MWCNTs) interwoven metal–organic frameworks (MOFs) was synthesized. The MWCNTs was utilized to bridge the neighboring MOF nanocrystals. The hybrid material MOFs/MWCNTs was used for SPME coating to extract six PCBS in tea beverages samples by gas chromatography coupled to tandem mass spectrometry. MOFs/MWCNTs coating materials were characterized by thermogravimetric analysis (TGA), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and N2 adsorption–desorption analysis. The response surface method was utilized to systematically optimize the main extraction factors. Under the optimized conditions, the developed method demonstrated wide linear ranges (0.01–1000 ng·L−1), low limits of detection (0.003–0.009 ng·L−1) and high enrichment factors (701–2361) for extracting and determining six PCBS. The six PCBS concentration in environmental tea beverages samples was detected with this method. These results display that MOFs/MWCNTs hybrid materials are potential sorbents in the SPME of PCBS in environmental tea beverages samples.

Laser Metal Printing from Nanoparticles Prepared by a Gas Aggregation Source.

This study demonstrates the use of nanoparticles prepared by a gas aggregation source for fabricating structures by combining laser sintering and ablation. At first, the morphology and optical properties of prepared nanoparticle coatings were characterized. Then, the response of coatings to laser irradiation at different powers or exposure times was studied by in situ time-of-flight mass spectrometry, followed by scanning electron microscopy measurements of the resulting structures. By comparing the numbers of detected Ag ions, that were ablated and desorbed, with changes in morphology after irradiation, the optimum conditions for laser sintering and ablation of Ag nanoparticle coatings were found. As a proof of concept we fabricated micromirrors from sintered metal, microwires from both sintered metal and interconnected nanoparticles, and arbitrary metallic bulky or nanoparticle patterns. Vacuum compatibility and the possibility of fabrication of both metallic and nanoparticle structures in one step predetermines applications of developed method in electronics or sensing.

Eddy Current Mechanism Model for Dynamic Magnetic Field in Ferromagnetic Metal Structures

The degaussing process is crucial for ensuring magnetic protection in ships. It involves the application of oscillating and attenuating magnetic fields to eliminate residual magnetism in the ship’s structure. However, this process can lead to the generation of distorted magnetic fields within the ship’s cabin, posing a potential threat to electronic equipment performance. Therefore, it is essential to have a comprehensive understanding of the dynamic magnetic field response in ship structures to develop effective degaussing systems. To address this need, this paper proposes an eddy current model for analyzing the dynamic magnetic field response in ferromagnetic metal structures. This model focuses on the role of eddy currents in shaping the magnetic field response and provides valuable insights into the underlying mechanisms. Using the proposed eddy current model, the effects of key system parameters such as thickness, conductivity, and the length-scale of the ship structure can be analytically investigated. This analysis helps in understanding how these parameters influence the dynamic magnetic field response and aids in the design and optimization of degaussing systems. The effectiveness and applicability of the proposed eddy current model are demonstrated through comprehensive investigations involving two simulation cases of varying complexity. The model accurately predicts the changing trends of the dynamic magnetic field response, as confirmed through finite element simulations. This validation highlights the model’s ability to reproduce simulation results accurately and its potential as a powerful tool for analyzing and optimizing dynamic magnetic field responses. In summary, the proposed eddy current model represents a significant advancement in the field. It provides a valuable theoretical framework for understanding and analyzing the dynamic magnetic field response in ferromagnetic metal structures. By offering insights into the underlying mechanisms and the influence of key parameters, this research contributes to the development of improved degaussing systems and enhances the overall magnetic protection capabilities of ships.

Characterization of fatigue crack growth in directed energy deposited Ti-6Al-4V by marker load method

Fatigue crack growth properties of materials are crucial for evaluating damage tolerance in additive manufacturing (AM) metallic structures. However, the unique microstructures and defects of AM materials result in highly complex fatigue crack growth behaviors. Currently, there is a lack of systematic fatigue crack growth rate measurement methods specifically targeting this characteristic. Therefore, taking directed energy deposited Ti-6Al-4V titanium alloy as the object of the study, fatigue crack growth tests were conducted in three orthogonal build orientations of the material using marker load method. Additionally, the visual measurement and compliance methods were also employed to measure fatigue crack growth rates, and the anisotropy of fatigue crack growth property was analyzed. Subsequently, anisotropic fatigue crack growth behaviors were characterized by optical microscope, scanning electron microscope, confocal microscope, and electron backscatter diffraction, suggesting that the microstructure is the primary factor affecting overall fatigue crack growth. Furthermore, nanoindentation tests were conducted to obtain the micromechanical properties within and among columnar grains in different build orientations, clarifying the homogeneity and anisotropy of mechanical properties. Finally, a fatigue crack growth rate measurement method based on marker load method was established, and the advantages of this method in AM materials and structures were summarized by comparing the results with those obtained using these two mature methods.

Unveiling the charge density wave mechanism in vanadium-based Bi-layered kagome metals

The charge density wave (CDW), as a hallmark of vanadium-based kagome superconductor AV3Sb5 (A = K, Rb, Cs), has attracted intensive attention. However, the fundamental controversy regarding the underlying mechanism of CDW therein persists. Recently, the vanadium-based bi-layered kagome metal ScV6Sn6, reported to exhibit a long-range charge order below 94 K, has emerged as a promising candidate to further clarify this core issue. Here, employing micro-focusing angle-resolved photoemission spectroscopy (μ-ARPES) and first-principles calculations, we systematically studied the unique CDW order in vanadium-based bi-layered kagome metals by comparing ScV6Sn6 with its isostructural counterpart YV6Sn6, which lacks a CDW ground state. Combining ARPES data and the corresponding joint density of states (DOS), we suggest that the VHS nesting mechanism might be invalid in these materials. Besides, in ScV6Sn6, we identified multiple hybridization energy gaps resulting from CDW-induced band folding, along with an anomalous band dispersion, implying a potential electron-phonon coupling-driven mechanism underlying the formation of the CDW order. Our finding not only comprehensively maps the electronic structure of V-based bi-layer kagome metals but also provides constructive experimental evidence for the unique origin of CDW in this system.

Exploration of a Novel Electric-Fuse Device with a Simple Structure of Ni Metal on a SiO2 Dielectric for Electrostatic Discharge Protection under a Human Body Model.

On-chip electrostatic discharge (ESD) protection poses a challenge in the chip fabrication process. In this study, a novel electric fuse (E-fuse) device featuring a simple structure of Ni metal on a SiO2 dielectric for ESD protection was proposed, and the physical mechanism of its operation was investigated in detail. Experimental evaluations, utilizing transmission line pulse (TLP) testing and fusing performance analyses, reveal that the E-fuse, constructed with a Ni metal layer measuring 5 μm in width, 100 μm in length, and 5 nm in thickness, achieved a significant ESD protection voltage of 251 V (VHBM) and demonstrates low-voltage fusing at a bias voltage of 7 V. Compared to traditional ESD protection devices, the E-fuse boasts a smaller size and removability. To assess fusing performance, devices of varying sizes were tested using a fusing lifetime model. This study supports both theoretical and empirical evidence, enabling the adoption of cost-effective, straightforward E-fuse devices for ESD protection.

RESEARCH OF THE METHODS OF STRENGTHENING REINFORCED CONCRETE COLUMNS DURING THE RECONSTRUCTION OF INDUSTRIAL BUILDINGS

Over the past two years, Ukraine has noted significant losses of the state's residential and non-residential stock as destroyed or partially damaged. Damaged or destroyed buildings must be restored, reconstructed and dismantled and new ones erected in their place.Industrial facilities suffered significant destruction. In addition, the condition of the structures of many old enterprises is extremely unsatisfactory.Currently, only in Kyiv, about 30% of the city's territory is industrial territory.Depending on the level of reconstruction of the object, it is possible to perform certain structural and enclosing elements. Any intervention in the structural elements of buildings must be preceded by an examination of both the building as a whole and these structures themselves.Repair, dismantling or strengthening of frame structures are among the typical types of work during the reconstruction of industrial facilities. The vast majority of old industrial buildings in our country have a reinforced concrete frame, especially the buildings that were erected in the 60s of the 20th century and in later periods. These are those buildings whose structural condition still allows for reconstruction or repair in order to continue their intended use. Buildings of an earlier stage, as a rule, are subject to reconstruction (if they are monuments of culture and architecture) or dismantling.The article investigates various methods of reinforcing reinforced concrete columns, which are key structural elements of industrial buildings, during their reconstruction. The technological and organic features of reinforcement are presented. The destabilizing factors that affect the efficiency of work are systematized. Modern technologies are studied, including changing the structural scheme, increasing the cross section, injecting into the body of the structure and external gluing of metal reinforcing structures.The effectiveness of each method is analyzed, which allows to assess their advantages and disadvantages, costs and duration of the reconstruction process. In particular, attention is focused on methods that increase the bearing capacity and durability of structures without significant interference with the overall structural scheme of the building.The results of the study allow us to identify optimal solutions for different types of industrial buildings, which helps engineers and designers ensure the sustainability and safety of reconstructed facilities.

Molecular Dynamics Simulation Model of Alkali Metal Reduction of Gaseous Halides and Reaction Mechanism Analysis.

The reaction of gaseous hydrogen halides with alkali metals provides a new pathway for producing hydrogen. The structure and reactivity of alkali metals are crucial for the reduction of gaseous halides. However, traditional gas-phase reaction models fail to provide insights into the dynamic processes occurring during alkali metal reactions. In this paper, based on the reaction between Hydrogen fluoride (HF) and alkali metal sodium (Na), we have established a metallic Na slab. HF molecules were randomly inserted above the surface of the Na slab, creating a reaction model for the reduction of HF by metallic Na. The reaction of HF on the Na surface was calculated using first-principles molecular dynamics. The configuration and reaction of the Na surface and HF molecules at different times were judged by analyzing the radial distribution function and mean squared displacement. Na atoms reacted with HF to produce intermediate NaFH, and then the F-H bond broke to form NaF and H. The F-H bond breaking of intermediate NaFH was the key step, and the kinetic parameters of this key step were calculated.

Laser-based directed energy deposition of Monel K-500 and Stellite 6 multi-materials

ABSTRACT Laser-based directed energy deposition (L-DED) offers significant advantages for repairing metal structures, particularly in the marine and offshore industry where corrosion-resistant materials like Monel K-500 (a Ni-Cu alloy) lack strength and wear resistance. This study addresses this issue by producing Monel K-500 with high-strength Stellite 6 (a Co-Cr alloy). Two types of multi-material samples were created using L-DED: interlayered and mixed powder samples. The interlayered samples experienced cracking at the material interface, while the mixed powder samples were crack-free and exhibited improved mechanical properties, with yield strength increasing from 208.3 MPa to 490.2 MPa and ultimate tensile strength from 429.7 MPa to 887.0 MPa compared to single Monel K-500 samples. This research demonstrated the potential of in-situ alloying during the L-DED process to enhance alloy properties and highlighted the challenges of abrupt compositional changes leading to cracking, suggesting mitigation strategies for successful production.

Structure Remodeling Strategy for Open-Cage NiFe@Fe-bis-PBA with Enhanced Peroxidase-like Activity To Monitor Tumor Markers.

The inherent metal elements and structures of Prussian blue analogue (PBA) nanozymes have restricted their enzyme-mimicking activity. Therefore, the rational regulation of PBA nanozymes to improve their catalytic activity is highly desirable for biosensing applications. Herein, we propose a structure remodeling strategy to construct an open-cage Fe PBA-anchored NiFePBA (NiFe@Fe bis-PBA) nanozyme with significantly enhanced enzyme-mimicking activity. The formation process and mechanism for this bis-PBA nanozyme were studied in detail. Specifically, a cubic NiFePBA precursor was first synthesized and modified with polyvinylpyrrolidone (PVP). With the aid of hydrochloric acid, the added potassium ferricyanide was reduced by PVP and re-coordinated on the surface of NiFePBA to form the NiFe@Fe bis-PBA nanozyme with a special open-cage core-shell structure. The resultant NiFe@Fe bis-PBA nanozyme was further exploited to immobilize secondary antibodies, serving as a novel signal probe for developing highly sensitive electrochemical immunosensors for monitoring tumor markers. The constructed electrochemical immunosensor possesses a very wide linear range of 0.005-100 ng/mL and a low detection limit of 0.89 pg/mL for alpha-fetoprotein with high specificity and acceptable reproducibility and stability. This work offers a general and promising strategy for remodeling PBA nanozymes with a very favorable structure and metal element distribution, which enhances their enzyme-mimicking properties for applications in different fields.

Working conditions and health status in workers in boiler and welding production in power engineering

Introduction. Preserving the health of qualified workers of older age groups is especially important under conditions of exposure to occupational hazards. The purpose of the study was to assess the influence of occupational hazards on the development of occupational and somatic diseases among workers of various age groups in the main occupations of mechanical engineering. Materials and methods. The study tested the results of hygienic research at workplaces of an enterprise in the power engineering industry in the manufacture of welded metal structures. We assessed the health status in workers based on the results of an in-depth medical examination and ultrasound examination of the vessels of the upper extremities with assessment of blood flow indices. Using a survey method, data were obtained on assessing the influence of production factors on the health status in workers. Results. The working conditions in the main occupational workers groups were assessed as harmful grades 1–3, the priority occupational hazards were: increased noise, and at the workplaces of electric gas workers there were also fibrogenic aerosols, chemical substances, and heavy physical work. Electric and gas welders and boilermakers work in the most unfavourable conditions, about 30% of whom continue to work after reaching retirement age. We have established a significant gain in the incidence of arterial hypertension and sensorineural hearing loss among workers over 40 years of age and an increase in the prevalence of all chronic diseases in the age group over 60 years. Limitations. The study is limited by the number of workers examined and the lack of ability to assess the health status of the studied contingent of workers over time. Conclusion. In conditions of exposure to elevated noise and other occupational hazards, there is an enhancement in the prevalence of work-related and somatic diseases in workers over 40 years of age. With advancing age, the rise in the vascular resistance index is observed, however, the first signs of peripheral blood flow disturbance are often recorded at a young age. In this regard, it is necessary to introduce methods of early diagnosis and prevention of occupational and work-related pathology.

Nonlinear ultrasonic Lamb wave phased array imaging based on hybrid array and time-reversal of harmonic

Fatigue cracks, as one of the early performance deteriorations of plate-like structures, are critical to be detected in a timely manner to prevent further failures and disastrous accidents. But the intimate contact of crack interfaces is difficult to form a significant scattering field of traditional ultrasonic Lamb waves, resulting in the insensitivity of Lamb wave phased array-based imaging methods to crack imaging. To break through the detecting limitations of conventional Lamb wave phased array, the nonlinear Lamb wave-based phased array method is first proposed to realize fatigue crack imaging, which is achieved by a new form of phased array with hybrid elements, signal processing for harmonic enhancement and time-reversal based harmonic field focusing. The hybrid array is designed for efficient transmission and capture of fundamental wave and harmonics, and Pulse-inversion technology and continuous wavelet transform filter are used to extract and enhance second harmonic response, and the images are obtained by the time domain topological energy imaging algorithm. Finally, the imaging results of barely visible fatigue cracks and through-holes in metallic plate structures using linear and nonlinear Lamb wave-phased array are compared. The nonlinear ultrasonic Lamb wave-phased array demonstrates excellent capability of fatigue crack imaging.