The chemiresistive sensors have enabled the sensing of diverse organoamines, but the low-temperature detection of highly carcinogenic and combustible dibutylamine (DBA) has not been achieved to date. Herein, based on the concept of waste reuse and sustainable development, the discarded willow catkins were served as biotemplates and soaked into zinc or iron nitrates and their mixed solution. The above precursors were calcined at 500 °C in the air to controllably synthesize two homo-tubes and two ZnFe2O4/ZnO hetero-tubes, all of which are assembled by uniform nanoparticles. Among, the 1.25 at% ZnFe2O4/ZnO hetero-tubes possess uniform mesoporous distribution, high content of adsorbed oxygen species, and catalytic sites of high-valent Fe4+ Lewis acid, thus realizing the first metal oxide-based sensor with excellent trace DBA sensing at low temperature. The 1.25 at% ZnFe2O4/ZnO sensor exhibits high response of 79–100 ppm DBA at low 133 °C, which is 1.4, 1.8 and 2.3 times higher than those of 3.2 at% ZnFe2O4/ZnO, ZnO and ZnFe2O4 tubes, respectively. Furthermore, it also behaves rapid response kinetics (11 s∼10 ppm), good humidity resistance, reliable long-term stability (60 days), and the ability to actually detect prometryn herbicide. In addition, its response mechanism for the enhanced DBA sensing was investigated.