Perovskite oxides with large specific surface areas present a promising avenue for enhancing supercapacitor efficiency. This study investigates the remarkable charge storage capabilities of strontium titanate (SrTiO3, STO) synthesized via sol-gel and hydrothermal techniques for electrochemical energy storage applications. The cubic crystal structure of STO, confirmed from X-ray Diffraction analysis, synthesized at lower temperatures through both methods, provides three-dimensional diffusion channels for oxygen anion movement, which is crucial for improving charge storage capacity. X-ray photoelectron spectroscopy confirmed the elements’ oxidation states and their spin-orbit splitting. The spherical nanoparticle morphology was observed in the FESEM images, BET characterization revealed a high specific surface area contributing to more charge storage and mesoporous nature facilitates excellent mass transfer rates of electrolytic ions. Electrochemical measurements and calculations confirmed that sol-gel and hydrothermally synthesized STO electrodes exhibit maximum specific capacitances of 130 F g−1 and 156 F g−1 at 10 mV s−1, respectively. A fabricated flexible supercapacitor device in an aqueous medium maintains a constant voltage of 1.2 V, capable of powering a digital watch. Hence, this study demonstrates the potential of STO electrode-based supercapacitors for a wide range of electrochemical energy storage applications.