Metal Mining Research Articles

Cadmium accumulation in farmlands through irrigation: evidence from multimedia fate modeling and scenario simulations

The studies of heavy metal input and output fluxes from farmland soils will contribute to sustainable agricultural practices. However, debate on the primary pollution to crops has not resulted in the emergence of practical remediation strategies. Hence, the flux should be identified with precision for targeted pollution control. In this study, a catchment downstream of a metal mining area was selected for investigation of Cadmium pollution in the topsoil of farmlands, including the input and output fluxes in different environmental media. The results showed that irrigation was the main input source of Cd to soil, accounting for more than 75%, in which the contribution of dissolved Cd in water was 1–2 orders of magnitude higher than that of Cd adsorbed on suspended particles. Crop harvesting, surface runoff, and leaching were the main Cd output pathways from this area. The dynamic prediction results under different scenarios showed that Cd in farmland soil would be in a cumulative state in the following years by 2050. Straw removing could significantly reduce Cd accumulation in farmland soil. In addition, the substantial increase of crop yield in the future would increase the Cd output flux. This work revealed the accumulation pattern of Cd in farmland soils, and will aid in the development of remediation strategies for cadmium contamination of agricultural soils.

Geology and Ore Mineralization Characteristics of the Selodong Prospect, Lombok Island, Indonesia

Abstract The Selodong prospect is located in the southwest sector of Lombok Island which tectonically lies within the W-E trending Sunda-Banda magmatic arc, which hosts various gold-base metal mineralizations including porphyry and epithermal deposits. Lombok Island, particularly southwestern portion of the island is known to hosts gold, silver and copper prospects, including Selodong prospect. The Selodong prospect is divided into several sub-prospect areas which include the Blongas, Montong Botek, Kekalik and Belikat. However, this study only focuses on the Blongas sub-prospect. The study is aimed to discusses the geology, characteristics of alteration and mineralization of the sub-prospect. To achieve the objective, some methods such as mapping and numerous laboratory works were conducted. Petrography to identify alteration minerals, ore microscopy to identify type of ore minerals, and fluid inclusion microthermometry to characterize ore fluid were performed. The geological conditions of the study area are composed of andesite lava, andesite breccia, diorite intrusion and alluvial deposit. Typical porphyry alteration type i.e., potassic is present. Argillic, silicic, advanced argillic, propylitic and phyllic alterations are also identified. The distribution of potassic and some argillic alteration is controlled by lithology, while silicic alteration, advanced argillic, propylitic and some argillic alterations are controlled by geological structures with an NW-SE and NE-SW trending patterns. Propylitic alteration is characterized by chlorite + epidote + calcite ± clay. Argillic alteration is marked by the presence of clay minerals such as clay + quartz. Advanced argillic alteration is typified by quartz + alunite + pyrolusite ± paragonite. Phyllic alteration is typified by sericite + quartz ± clay. Potassic alteration is marked by secondary biotite + quartz ± clay. Silicic alteration is marked by quartz + pyrolusite + epidote. Ore mineralization in the study area is associated with massive and stockwork vein textures. Ore and metalliferous minerals are found as magnetite, chalcopyrite, pyrite, hematite, goethite, jarosite, sphalerite, pyrrhotite, chalcocite and native gold. Generally, homogenization temperatures in the research area range from 543 - >600 °C, with salinity of 26.3 - 73.95 wt.% NaCl eq associated with potassic alteration, whereas homogenization temperatures range from 251 to 349 °C, with salinity of 5.46 - 8.38 wt.% NaCl eq. associated with silicic alteration. Based on those characteristics, the prospect in the study area indicates a porphyry deposit type, which is transition to high sulfidation epithermal.

Mineralogy and Hydrothermal Fluids Characteristics of the Mekarbakti Low Sulfidation Epithermal Gold Prospect at Garut Regency, West Java, Indonesia

Abstract Mekarbakti prospect is situated in the western sector of Java Island which tectonically lies within the W-E trending Sunda-Banda magmatic arc. This arc hosts numerous prospects for ore mineralization with various types of mineral deposits, one of which is epithermal that found in the study area. The Mekarbakti prospect is located close to the Arinem prospect, about 8 km to the east, which is confirmed as a low sulfidation epithermal deposit type. Arinem is proven to be economical to mine, thus it becomes interesting to conduct study on the Mekarbakti prospect, to elucidate its mineralization model. This paper is dealing with the characteristics of hydrothermal alteration using petrographic and X-Ray Diffraction (XRD) to identify the alteration minerals, using ore microscopy analysis to identify the type of ore minerals, and fluid inclusion to reveal the hydrothermal fluid characteristics. The geological condition of the study area is composed of andesite lava, andesite breccia, tuff, lapilli, and andesite intrusion. The distribution of silicification alteration is controlled by geological structures with an NW-SE pattern, while argillic and propylitic alterations tend to have a gradient trend towards silicification alteration. Propylitic alteration is characterized by chlorite+illite+smectite±epidote. Argilic alteration is marked by the presence of clay minerals such as kaolinite+illite+smectite+quartz. Silicification alteration typified by quartz+kaolinite+diaspore+illite. Ore mineralization in the study area is associated with massive, brecciated, comb, cockade and, stockwork vein textures. Ore and metalliferous minerals are found as pyrite, hematite, goethite, chalcopyrite, sphalerite, galena, pyrrhotite, covellite, chalcocite, acanthite, native gold, and native silver. Generally, the mean homogenization temperature in the research area ranged from 248.05 – 266.12 °C, with salinity ranged from 1.01 – 1.68 wt.% NaCl eq. The epithermal deposit in the study area is classified as deep low sulfidation epithermal deposit specifically in transition between base metal and precious metal interval.

Trace metal accumulation through the environment and wildlife at two derelict lead mines in Wales

Trace metal pollution is globally widespread, largely resulting from human activities. Due to the persistence and high toxicity of trace metals, these pollutants can have serious effects across ecosystems. However, few studies have directly assessed the presence and impact of trace metal pollution across ecosystems, specifically across multiple environmental sources and animal taxa. This study was designed to assess the environmental health impacts of trace metal pollution by assessing its extent and possible transfer into wildlife in the areas surrounding two abandoned metalliferous mine complexes in Wales in the UK. Water, sediment, and soil at the mine sites and in areas downstream had notably elevated concentrations of Pb, Zn, and, to a lesser extent, Cd and Cu, when compared to nearby control sites. These high trace metal concentrations were mirrored in the body burdens of aquatic invertebrates collected in the contaminated streams both at, and downstream of, the mines. Wood mice collected in contaminated areas appeared to be able to regulate their Zn and Cu tissue concentrations, but, when compared to wood mice from a nearby control site, they had significantly elevated concentrations of Cd and, particularly, Pb, detected in their kidney, liver, and bone samples. The Pb concentrations found in these tissues correlated strongly with local soil concentrations (kidney: ρ = 0.690; liver: ρ = 0.668, bone: ρ = 0.649), and were potentially indicative of Pb toxicity in between 10 % and 82 % of the rodents sampled at the mine sites and in areas downstream. The high trace metal concentrations found in the environment and in common prey species (invertebrates and rodents) indicates that trace metal pollution can have far-reaching, ecosystem-wide health impacts long after the polluting activity has ceased, and far beyond the originating site of the pollution.

Groundwater well rehabilitation using hydropuls method: a case study in wonosobo groundwater well

Abstract Hydropuls is one of the groundwater well rehabilitation methods that involves pulsing highly compressed nitrogen gas through screen pipes at an adjustable interval. Nitrogen gas was chosen because of its colorless, odorless, and inert properties. The aquifer lithology of this groundwater well is sand, gravel and breccias (member of Sundoro Volcanics; Qsu) with silty clay as the impermeable layer that makes the aquifer type is confined aquifer. The following methods were used in this well rehabilitation: step tests before, borehole camera before, hydropuls, airlifting, borehole camera after and step test after well rehabilitation. Thin section analysis shows that sediment mostly consists of lithic fragments and plagioclase. The results of the polished section analysis reveal that most of the metallic minerals are magnetite and hematite. The XRF results show that the sediment mostly consists of SiO2, Al2O3 and Fe2O3. According to the XRD results, the sediment is mostly albite. The interpretation of sediment analysis shows that the clogging is caused by iron precipitation. The result is an average increase in specific capacity of 1.43 l/s/m (a 168% increase over the initial conditions) and an average drawdown improvement of 2.56 m (a 114% improvement compared to pre-hydropuls conditions). Borehole camera imaging confirmed that the precipitation on the screen was removed and the screen is in good condition.

Cryolite as a Reference Mineral of Rare Metal Mineralization: An Experimental Study

Abstract Phase relations and the distributions of rare earth elements (REE), Sc, Y, and Li between aluminofluoride and aluminosilicate melts in the model granite system Si–Al–Na–K–Li–F–O–H were experimentally studied at 700°C, 1 and 2 kbar, and water contents of 3 to 50 wt %. Our original and available literature experimental data on phase relations in the granite system saturated with water and fluorine and containing trace elements are compared with the mineral assemblages of rare-metal cryolite-bearing granites from the Zashikhinsky, Katugin, and Ulug-Tanzek deposits in eastern Siberia. Liquid immiscibility between granite and salt aluminofluoride melts, which occurs at high contents of fluorine and lithium in the system, is proved to facilitate the accumulation of rare elements in salt cryolite-like melts. At a temperature of 700°C and pressures of 1 and 2 kbar, aluminofluoride melt in the granite system crystallizes and forms cryolite. Fluorine-bearing minerals of trace and rare earth elements, such as pyrochlore and gagarinite, occur at these deposits in association with cryolite and lithium micas. Comparison of experimental data and natural observations provides arguments in support of the hypothesis that liquid immiscibility should play an important role in the formation of cryolite. Cryolite is thought to be able to serve as a reference mineral for rare metal-rare earth mineralization in granites with high lithium and fluorine content.

What Extra Information Can Be Provided by Multi-Component Seismic Data: A Case Study of 2D3C Prospecting of a Copper–Molybdenum Mine in Inner Mongolia, China

With the decrease in shallow mineral reserves, deep mineral resources have become the focus of exploration. Seismic exploration, renowned for its deep penetration and high spatial resolution and precision, stands as a primary technique in geophysical exploration. In comparison to traditional P-wave seismic exploration, multi-component seismic techniques offer the advantage of simultaneously acquiring P-wave and S-wave data, overcoming the limitations of single P-wave impedance in predicting lithology and enabling high-precision imaging of subsurface structures. Constrained by field survey costs, the reflection seismic illumination is lower and results in a poor signal-to-noise ratio of multi-component seismic data in metallic ore exploration, which poses great challenges in imaging converted S-waves. Based on the seismic and geological characteristics of metallic ores, this study conducts imaging research on metallic ore models through synthetic data and field multi-component seismic data from a copper–molybdenum mine in Inner Mongolia, China. The emphasis is given to PS-wave pre-stack time migration based on precisely sorting the commonly converted point so as to explore the feasibility and technical advantages of multi-component seismic exploration in metal mines. Synthetic data and field data testing demonstrate that PS-wave imaging contains more abundant structural and lithological information compared to PP-waves, indicating promising prospects for the application of multi-component seismic data in metallic ore exploration.

Integrated Geophysical Investigation for Potential Gold Mineralised Zone within Lower Part of Zuru Schist Belts, NW Nigeria

The study began with a reconnaissance survey that used high-resolution aeromagnetic data of the study area to identify suitable structure zones with the potential to trap mineral resources within the context of the gold exploration target. The findings of magnetic studies were followed up with detailed investigations using 2D electrical resistivity tomography (ERT) and induced polorisation (IP) techniques to reveal further details about gold mineral zones and other lithological boundaries. The airborne magnetic data of sheet 118_Yelwa was obtained from the NGSA; these datasets were processed and analyzed using Oasis Montaj's first vertical derivative (FVD) and center for exploration targeting (CET) techniques. Results of FVD and CET grid anomalies show that regions of major magnetic structures (lineaments) are associated with granite gneiss, migmatitic augen gneiss, and medium to coarse-grained biotite when compared to the geological settings of the area. The zones of major structures obtained in this study coincided with previous magnetic studies of the area, located in the eastern parts of Ngaski, Yauri (Yelwa), Shanga, Agwara, as well as Magama's northwest region. Some of the regions for lineament (in the eastern part of Ngaski/Yauri) were investigated further with 2D ERT and IP detailed geophysical methods in a dipole-dipole configuration. The results of geoelectric techniques along profiles 1, 2, and 3 identified the major gold mineralisation potential zones, which were labeled A1, A2, and A3. These regions have low/high resistivity (1.6 to 459 Ωm/1889 to 7773 Ωm) and chargeability signatures (≥ 20 msec), and could thus be interpreted as potential target zones for metallic mineral exploration, particularly gold mineralisation. The regions are located in the northern Mararraba and southwest of the Jinsani areas of Kebbi State. The results of integrated geophysical methods have produced updated structural features of the regions, as well as a database containing precise locations, lateral lengths,...

A new type of clay-Li deposit: Fault-controlled hydrothermal alteration in southern Hubei Province, China

Clay-Li deposits are among the major Li deposits in the world and occur mainly in sedimentary and/or volcanic-sedimentary strata. The Li orebodies are generally stratiform and stratibound, and Li is mainly hosted in various clay minerals. Here, we report a new type of clay-Li deposit that occurs along fault zones developed in metasedimentary rocks with significant alteration, and Li is also hosted in clay minerals in the Jinyinshan area in Xianning, southern Hubei Province, China. The study area has no granitic rock outcrops, but approximately 15 km south is the Mufushan granite batholith, where large-scale rare metal mineralization, such as Li, Be, Nb and Ta granitic pegmatites, developed in the internal and outer contact zones of the granite batholith. In this study, high-Li clay minerals, including chlorite, kaolinite and smectite, were identified. The enrichment of Li is closely related to hydrothermal activity along the F9 fault in the region. Hydrothermal apatite coexisting with Li-clay in the orebody along the fault zone yielded an in situ U–Pb age of 135.2 ± 13.9 Ma, which is in good agreement with the ages of granites and Li-pegmatites around the Mufushan batholith. Petrographic, geochemical, and chronological evidence suggests that the ore-forming fluids and Li were likely sourced from the Mufushan granite batholith or a similar blind granite at the depth of the study area; that is, the granite-derived ore-forming fluids can travel long distances along fault zones, and during this pathway, Li from the metasedimentary rocks (i.e., the Lengjiaxi Group) may also have been leached by the fluids and contributed to the Li mineralization in the Jinyinshan clay-Li deposit. The close spatial relationships among different clay minerals indicate that fluid physical–chemical conditions (changes in temperature) may play a crucial role in controlling the formation of Li-rich clay minerals. Our study indicates that the Mufushan area has great potential for hydrothermal clay-Li mineralization occurring in the Lengjiaxi Group metasedimentary rocks around the Mufushan batholith.

Integrated Geophysical Investigation for Potential Gold Mineralised Zone within Lower Part of Zuru Schist Belts, NW Nigeria

The study began with a reconnaissance survey that used high-resolution aeromagnetic data of the study area to identify suitable structure zones with the potential to trap mineral resources within the context of the gold exploration target. The findings of magnetic studies were followed up with detailed investigations using 2D electrical resistivity tomography (ERT) and induced polorisation (IP) techniques to reveal further details about gold mineral zones and other lithological boundaries. The airborne magnetic data of sheet 118_Yelwa was obtained from the NGSA; these datasets were processed and analyzed using Oasis Montaj's first vertical derivative (FVD) and center for exploration targeting (CET) techniques. Results of FVD and CET grid anomalies show that regions of major magnetic structures (lineaments) are associated with granite gneiss, migmatitic augen gneiss, and medium to coarse-grained biotite when compared to the geological settings of the area. The zones of major structures obtained in this study coincided with previous magnetic studies of the area, located in the eastern parts of Ngaski, Yauri (Yelwa), Shanga, Agwara, as well as Magama's northwest region. Some of the regions for lineament (in the eastern part of Ngaski/Yauri) were investigated further with 2D ERT and IP detailed geophysical methods in a dipole-dipole configuration. The results of geoelectric techniques along profiles 1, 2, and 3 identified the major gold mineralisation potential zones, which were labeled A1, A2, and A3. These regions have low/high resistivity (1.6 to 459 Ωm/1889 to 7773 Ωm) and chargeability signatures (≥ 20 msec), and could thus be interpreted as potential target zones for metallic mineral exploration, particularly gold mineralisation. The regions are located in the northern Mararraba and southwest of the Jinsani areas of Kebbi State. The results of integrated geophysical methods have produced updated structural features of the regions, as well as a database containing precise locations, lateral lengths,...

A Study on the Performance of Self-Leveling Mortar Utilizing Tungsten Tailings as the Aggregate

A significant quantity of tailings is produced during the development of different metal mines in China. In particular, fine-grained tailings pose challenges to the sustainable development of the mining industry. This study examines the utilization of finely ground tungsten tailings as a replacement for natural aggregates in self-leveling mortar (SLM). The study examined the impact of the aggregate-cement ratio, cement mix ratio, and varying substitution levels of different grain sizes of tungsten tailings on the flow properties, mechanical properties, and dimensional change rate of SLM. Additionally, the role of tungsten tailings in SLM was analyzed using XRD, FTIR, and SEM methods. The findings demonstrated that the utilization of sulphoaluminate cement (SAC) had a notable impact on improving the initial strength of the SLM. Additionally, a high aggregate-cement ratio negatively affected the fluidity of the SLM. The doping of tungsten tailings improved the grading relationship of the SLM. Substituting tungsten tailings of 38–75 μm grain size for natural aggregates in the preparation of SLM did not have a negative impact on its performance. In fact, substituting 60% tungsten tailings had a positive effect on the 28-day mechanical properties of the SLM. The compressive and flexural strengths of the SLM after 28 days were 26.53 MPa and 9.06 MPa, respectively, which were enhanced by 18.81% and 26% compared to the control group (C0). According to the environmental leaching test, SLM can effectively fix the heavy metal ions in tungsten tailings, and the leaching concentration of heavy metals is significantly reduced after long-term curing. The doping of finely fragmented tungsten tailings accelerated the process of hydration, resulting in the creation of hydrocalcium zeolite crystals in the latter phases of hydration. Furthermore, an increase in tailings substitution resulted in the production of a greater amount of hydration products, specifically C-S-H gels.

The giant Baerzhe rare-earth-element–Nb–Zr–Be deposit, Inner Mongolia, China, an Early Cretaceous analogue of the Strange Lake rare-metal deposit, Quebec

The Baerzhe deposit represents world-class mineralization of rare metals, in particular rare earth elements (REEs) and Nb, and shares mineralogical and geochemical similarities with the Strange Lake deposit in Canada. However, the mechanisms responsible for the rare-metal enrichment at Baerzhe are still under debate. Mineralization at Baerzhe is characterized by multiple stages of dissolution, re-precipitation and enrichment of rare-metal elements, as with the Strange Lake deposit. Zirconium was concentrated during magmatic fractionation of elpidite in a transsolvus agpaitic granite (Stage I), and was redistributed into zircon–quartz pseudomorphs during Na-metasomatism (Stage II). Rare earth elements, Nb and Be occur as a variety of mineral assemblages, mainly as pseudomorphs after complete replacement of unknown precursor minerals that are disseminated through the hematized transsolvus granites and were precipitated in three sequential stages (Stages III–V): Stage III is characterized by the mineralization of hingganite, aeschynite-(Y), columbite-(Fe) and euxenite-group minerals, accompanied by hematite alteration; the following Stage IV is defined mainly by monazite-(Ce) crystallization, and Stage V by the preceding REE minerals being replaced by light REE minerals (i.e. bastnäsite-(Ce) and fluocerite-(Ce)). The formation of various pseudomorphs as replacement for precursor minerals is also a common feature documented at Strange Lake. Our results call for a re-evaluation of the timing and role of meteoric waters at Baerzhe, which were suggested by previous researchers to have entered the ore-forming system prior to the mineralization of zircon. New in situ O isotopic analyses on pseudomorph-hosted mineral pairs and investigation of silicate melt–fluoride melt immiscibility through observations and analyses of melt inclusions could provide further insights into the nature of the Baerzhe system.

Use of Submarine Tailings Disposal as Alternative Tailings Management System

The importance of the mining/milling industry in increasing the growth level and welfare of countries is quite high. However, at the end of mining/milling processes, huge amounts of waste (often known as tails) are inevitably produced that have no economic value and can even be considered dangerous due to some heavy metals they contain. These tails are highly problematic due to both their volume (difficult to manage environmentally) and toxicity (potential to cause acid/leach waters) and need to be handled outside of existing disposal methods. This article presents the effective and sustainable handling and application of tails resulting from the enrichment of copper–zinc ores, which are actively engaged in metallic mining activities in the northeast of Türkiye, with the submarine tails disposal (STD) method. In the mining operation under study, some (~55–60 wt.%) of the tails are employed as underground fill, even though the residual part is disposed of by the STD method. The characterization of ore beneficiation tails, their transportation to the subsea via a pipeline system, and discharge monitoring results are detailed in the present investigation. According to the limitations which are indicated by the Turkish Control of Water Contamination regulation, the concentration of Pb-Cu found in the results was under the allowable limit of 0.05 mg/L. The allowed 2 mg/L limit for Zn was not surpassed mainly by the concentration found in the collected samples. pH values were almost above the allowable limit of pH > 5. The results reveal that the STD technique works quite well as an integrated mine tails method in the mine under study.

Ore-forming process of the Xiaoyuzan gold deposit in the Western Tianshan, Northwest China: Constraints from mineralogy and S isotopes of sulfides

The Xiaoyuzan deposit is a typical intermediate-sulfidation epithermal Au deposit in the Boluokenu metallogenetic belt. The orebodies are hosted by the Lower Carboniferous Dahalajunshan Formation volcanic rocks and controlled by the NW- and NNW-striking faults. The metal minerals present in the ores mainly include pyrite, sphalerite, galena, chalcopyrite, and tetrahedrite. The non-metallic minerals are primarily composed of quartz, calcite, and sericite. Three ore-forming stages are distinguished based on mineral assemblages, wall-rock alteration, and vein crosscutting relationships, including the quartz-pyrite stage (I) with silicification and propylitization, quartz-sulfide stage (II) with phyllic alteration, and quartz-carbonate stage (Ⅲ) with carbonatization. Three different types of pyrite are classified: coarse-grained PyI with cubic from the wall rock, fine-grained PyII with a crystal form of pentagonal dodecahedron in the quartz-sulfide veins, and coarse-grained cubic PyⅢ in the quartz-carbonate veins. The in-situ δ34S value range of sulfides from stage I, stage II and stage Ⅲ are 5.0 ‰ to 5.5 ‰, 4.3 ‰ to 6.5 ‰ and 5.7 ‰ to 6.2 ‰, respectively. The composition of S isotopes indicates that the source of the sulfur is magmatic in origin, with main contribution from the host rock. All the types of pyrite are relatively enriched with Sb, Cu, Ag, Pb, Bi, and As. The composition of pyrite suggests that the Au in the pyrite present as lattice gold (Au+1). The gradual decrease in Co contents from in PyⅠ, PyⅡ to PyⅢ indicates a gradual decrease in temperature during fluid evolution. The contents of trace elements in sphalerite are relatively low, with Fe, Mn, Cd, and Cu being relatively enriched. Using the sphalerite geothermometer (GGIMFis), the calculated temperature falls within the range of 303.0 to 334.3 °C. Pyrite II is characterized by the occurrence of oscillatory zones, suggesting rhythmic changes in fluid physicochemical conditions and compositions. Although coexisting of liquid-rich and vapor-rich aqueous inclusions were locally observed in stage II quartz according to previous studies, the absence of crustiform/colloidal/lattice bladed quartz in the main stage suggests that slight or gentle fluid boiling has occurred. In summary, it is proposed that fluid-rock reactions made great contribution for the precipitation of gold and sulfides in the Xiaoyuzan deposit.

Prospecting Tungsten (Scheelite) Mineralization in the Djouzami Area (Adamawa Cameroon) Using Ultra-Violet (UV) Fluorescence and Landsat-8 OLI Images

Remote sensing technology and X-rays fluorescence are largely used in the applied geology field. In this study, we combine field observations and petrography, remote sensing applications through the processing of the Landsat-8 OLI, and Ultra-violet fluorescence to map geological structures, hydrothermal alteration minerals, and characterize tungsten mineralization in the Djouzami area (Adamawa, Cameroon). Landsat-8 OLI satellite imagery, was processed to detect both hydrothermal alteration zones and regional structural lineaments associated with tungsten mineralization. Fieldworks and petrography revealed hydrothermal mineral assemblage made of muscovite, chlorite, tourmaline, hematite, calcite and sericite associated to metallic minerals including tungsten and pyrite hosted in quartz veins. This hydrothermal mineral assemblage is also identified in the gold-bearing quartz veins reported in several areas along the Lom group. Band Ratio (BR) and Principal component analysis (PCA) were implemented to extract spectral information related to alteration minerals. The Band Ratios 6/7, 4/2, and 6/5 have permits to map clay, iron oxide/hydroxides, and ferrous minerals, respectively. This study demonstrates the significant potential of fieldwork and multispectral remote sensing data processing for tungsten prospecting as a mineral exploration technique in the Djouzami region. The mapping led to the detection of 1334 lineaments which show four main directions. The ENE-WSW directions corresponds to the trending of the Sanaga shear zone; the NE-SW direction represents the trending of the Djouzami and the Bétaré-Oya shear zones or the main shear zone which underline the Lom group; the N-S and E-W directions are equivalent to the trending of the foliation in the Meiganga area. Most of the high hydrothermal zones and tungsten-bearing quartz veins are located along the NE-SW lineaments or shear zone. Gold-related NE-SW trending Djouzami shear zone is also proposed. The NE-SW structure constitute certainly pathway for mineralizing fluids and ground water circulation, and control tungsten mineralization. Results proposed in this work provide important information for research of characteristic hydrothermal minerals assemblage that accompany tungsten mineralization, and for identify structures that control this mineralization in the area.

An echellograms-based quantitative analysis method of laser-induced breakdown spectroscopy

The high-resolution broadband LIBS spectrum is typically acquired using an echelle spectrometer and array detectors. However, the full frame (i.e., echellogram) captured by detector is commonly converted to 1D spectrum for the further analysis, which would both limit the detection speed of LIBS and potentially degenerate the analytical performance. In this work, we propose an echellograms-based analysis method for the quantification of minor metal elements in steel. Two metal elements, Mn and Ti, are chosen to validate the feasibility of the analytical method. The LASSO algorithm is used to build the multivariate regression model using LIBS spectra and echellograms respectively. The analytical performance obtained with the echellograms-based model is compared with that of spectra-based model. The efficiency of the echellograms-based quantitative analysis method is demonstrated with better prediction accuracy and precision. Notably, the echellogram-based regression model involves only tens to thousands of pixels from the echellogram, which can be selectively read out using a CMOS detector. The combination of echellogram-based quantitative analysis method and CMOS detector provides new ideas for high-frequency LIBS detection.

High-carbon wood ash biochar enhances native tree survival and growth on sand-capped mine tailings.

Use of waste wood biomass for bioenergy produces wood ash as a by-product; this ash is typically landfilled, but can potentially play an important role in soil improvement and forest restoration. In particular, high-carbon wood ash biochar (HCWAB) could supply nutrients, improve substrate water-holding capacity and pH, and emulate the ecosystem benefits of wildfire residues. Thickened tailings sites at metal mines across Canada are subject to stringent restoration regulations that entail planting of native trees to promote rapid reforestation. While HCWAB may prove beneficial in this context, field trials have been very limited to date. We conducted a large-scale, replicated field trial on sand-capped tailings at an operational gold mine in the Canadian boreal forest to assess the impact of HCWAB (at dosages of 0, 6.4, 12.8, and 19.1 t/ha) on survival and growth of four native tree species, as well as substrate chemical properties and element uptake in tree tissues. After 2years, the survival of planted, native trees was highest at low to moderate application rates; HCWAB dosages above 13 t/ha presented reduced tree survival to levels comparable to unamended substrates. Tree growth was higher across all HCWAB doses relative to growth in samples planted on untreated substrates; tree species and initial size also had large impacts on final tree survival and aboveground growth. The survival of Betula papyrifera was significantly higher than other species, while smaller transplanted trees in general survived in greater numbers compared to larger size classes. Volunteer herbaceous vegetation significantly increased at the higher HCWAB application dosages and tree performance was negatively correlated with vegetation cover, consistent with a resource competition effect. HCWAB additions to sand-capped mine tailings did not significantly alter tree tissue concentrations or substrate availability of potentially toxic metals (Cd, Cu, Al). We conclude that low to moderate dosages of HCWAB on sand-capped tailings, particularly between 6.4 and 12.8 t/ha, may offer benefits to early tree survival, growth, and substrate nutrient status without causing significant risks of phytotoxicity and recommend future field trials focus on strategies to reduce tree competition with competing vegetation.

Current Advances in Agriculture, Environment, and Chemistry with Technological Applications

Soil contaminated with heavy metals has a negative impact on plant development and survival. On the other hand, plants have developed intricate physiological mechanisms to resist these kinds of environmental stimuli. Anthropogenic sources of emissions are the many industrial point sources, including transporters, smelters and foundries, present and former mining sites, and combustion byproducts. Mercury is released via the degassing of the earth's crust, whereas lead is emitted during its mining and smelting operations, from automotive exhausts by burning petroleum fuels coated with tetraethyl lead antiknock, and from old lead paints. The process of refining zinc releases cadmium as a byproduct and occasionally lead. Emissions are generally released during the mining and processing of metals. Stress from heavy metals affects plants absorb nutrients through interactions with other essential elements. Chromium restricts the quantity of nutrients the soil may absorb by forming insoluble compounds. An intriguing method for managing plastic waste, particularly micro/nano plastics, is photocatalysis. Through the use of suitable light energy, nanostructured semiconductors are excited, producing exciton pairs that react with surrounding water or moisture to produce highly reactive species like superoxide’s and hydroxyl radicals that can effectively oxidize organic species, including polymers. Climate variability affects the sustainability of human and environmental health together with other man-made and natural stresses.

Alternatywne podejście do usuwania/odzyskiwania wybranych metali z wody kopalnianej wypływającej z zalanej kopalni syderytu Nižná Slaná

The objective of this work was the application of innovative method for metals recovery from metalliferous mine water released from the flooded siderite ore deposit Nižná Slaná. Although the metals contained in mine drainage are considered environmental pollutants, they may also be recognised as valuable resources. Several techniques can be used to obtain them by precipitation. Conventional processes using alkaline reagents produce huge amounts of mixed sludge with appropriate storage and management requirement, void of possibility of individual metals subsequent processing. This study examined the feasibility of Fe and Mn selective retrieval from real mine water. After oxidation and partial precipitation of iron using hydrogen peroxide, precipitation by sodium hydroxide was applied to the residue iron removal from mine water. In the next step potassium permanganate was used to eliminate manganese by oxidative precipitation. ORP and pH values of processed mine water was recorded in the course of oxidation/precipitation processes. The morphology and elemental composition of obtained products were studied by scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDX). The recovery efficiencies of Fe and Mn from mine water reached 99.87 % and 99.25%, respectively. Target metals were removed with high selectivity to levels that comply with environmental requirements.

Sustainable bioleaching of heavy metals from coal tailings using Bacillus inaquosorum B.4: Mechanistic insights and environmental implications

Coal tailings are byproducts of the coal washing process and pose significant environmental pollution issues due to the release of heavy metal elements. In this study, a sustainable bioleaching method was proposed, and a Bacillus inaquosorum B.4 strain with high Extracellular Polymeric Substances(EPS) production characteristics was isolated through mutagenesis. The importance of EPS in the adsorption of free heavy metals was validated, as EPS-covered (EPS-C) cells exhibited significantly higher removal rates of Cu (71.30 ± 1.10 %), Pb (79.90 ± 1.02 %), and Zn (64.90 ± 1.00 %) compared to EPS-removed (EPS-R) cells. The adsorption kinetics followed pseudo-second-order kinetics models. The significant bioleaching efficiency of this strain for heavy metals Pb, Zn, and Cu in coal tailings was investigated. Through shake flask experiments under conditions of a particle size of 45–74 μm, pH of 7, and a bacterial concentration of 15.00 %, the bioleaching rates of Pb, Zn, and Cu were found to be 91.88 mg/kg、23.21 mg/kg、8.06 mg/kg, respectively. The B.4 strain's mechanism of action was determined using techniques like SEM, XRD, FT-IR, and LA-ICP-MS. It involves absorbing organic compounds, disrupting the lattice structure of heavy metal minerals, and releasing metal ions. These metal ions are then immobilized by forming complexes with functional groups on the bacterial surface. The bioleaching process was primarily subject to a combination of chemical reaction and diffusion control. This research offers a practical bioremediation strategy to manage heavy metals in coal tailings and has important implications for environmental protection and sustainable resource utilization.