Metal Contamination In Sediments Research Articles

Risk evaluation and remedial measures for heavy metal contamination in lagoonal sediments of the Negombo Lagoon, Sri Lanka after the X-Press Pearl maritime disaster

Negombo Lagoon is a vital ecological and socio-economic resource in Sri Lanka that has become susceptible to anthropogenic heavy metal contamination. Therefore, short-core sediment samples from the Negombo Lagoon were analyzed to quantify heavy metal contaminants including both metals (Cr, Ni, Co, Cu, Cd, and Pb) and metalloid As; assess their ecological risk; identify critically polluted regions; and to investigate temporal variation in heavy metal concentration. According to the results, Ni is the most abundant heavy metal in lagoonal sediments. Ni, As, and Cr have severely contaminated the sediments as confirmed by their higher geo-accumulation indices (Igeo) and contamination factors (CF). The degree of contamination (Cdeg) indicated an exceedingly high overall heavy metal contamination, and the pollution load index (PLI) exhibited a prominent site quality decline. Individual potential ecological risk factor (Er) values revealed that Ni, As, and Cd pose a substantial ecological risk. Similarly, the potential ecological risk index (PERI) displayed that heavy metal contamination is a significant peril to this ecosystem. Spatial distributions of the heavy metals are governed mainly by the sediment grain size and freshwater influx. Ni concentration in lagoonal sediments has remarkably increased during the last six years (2016–2022) predominantly due to anthropogenic Ni sources, including the recent X-Press Pearl ship accident. In light of the severe heavy metal contamination in lagoonal sediments, the current study recommends a phytoremediation approach for the Negombo Lagoon.

Contamination and Risk of Heavy Metals in Sediments from Zhuzhou, Xiangtan and Changsha Sections of the Xiangjiang River, Hunan Province of China

This study focuses on the riverbed sediments in the Changsha-Zhuzhou-Xiangtan (CS-ZZ-XT) section of the lower reaches of the Xiangjiang River. Principal element analysis, ecological risk analysis, and early warning methods were used to explore the distribution pattern and risk assessment of various chemical elements in the sediments. The results indicated that the vertical distributions of Sc, Co, Th, and U were more homogeneous, while Cr, V, Cu, and Ni distributed heterogeneously with significant changes. Risk assessment of heavy metals was explored by using the Geoaccumulation index, potential ecological risk index, and ecological risk index, suggesting that the contamination levels followed: ZZ > XT > CS. ZU and ZX points in the ZZ section exhibited the higher ecological risk. The ecological risk of heavy metals followed the order of: Pb > Cu > Zn > Ni > Co > Mn > V > Cr, and the contamination of Cd and Mn was located at the severe warning condition. Additionally, it was suggested that Th, U, Pb, Zn, Cu, and Mn mostly originated from both anthropogenic activities and natural processes, while Ni, Cr, Co, V, Sc, and Ba were derived from natural processes. Therefore, the contamination of Cd, Th, U, Pb, Zn, Cu, and Mn, especially Cd and Mn, should be considered by the environmental protection strategies in the studied watershed.

Comparison of spatiotemporal burial and contamination of heavy metals in core sediments of two plateau lakes with contrasting environments: implication for anthropogenic-driven processes.

Investigating the impacts of climatic factors and human activities on sedimentary records of heavy metal (HM) contamination in lakes is essential for decision-making in global environmental monitoring and assessment. Spatiotemporal distributions of grain size (GS) and HM (Al, Cr, Mn, Ni, Cu, Zn, As, and Pb) concentrations have been conducted in core sediments that are collected from two adjacent plateau fault-bound lakes in southwest China with contrasting environments, i.e., deep oligotrophic Lake Fuxian (FX) and shallow hypertrophic Lake Xingyun (XY). Results showed that the average value of d50 in FX (4.61 μm) was lower than that in XY (8.35 μm), but the average concentrations of HMs (except Cr and Mn) in XY were higher than those in FX. Heavy metal burial rates (HMBR) were mainly controlled by sediment accumulation rates (SARs) rather than HM concentrations. The correlation coefficients between GS and HM concentrations became strong as the increasing water depths were associated with a stable sedimentary environment. Time-integrated enrichment factors (EF) and source identification of HMs between FX and XY represented that Cr, Ni, and Cu originated from natural sources but Mn, Zn, As, and Pb from anthropogenic sources, respectively. Regardless of FX and XY, the transition times of HMs from natural to anthropogenic sources occurred in the mid-1960s. Comparison of qualification impacts of climatic factors and human-induced factors on increased anthropogenic HMBR by the partial least squares path modeling (PLS-PM) implied that socio-economic activities, such as population density (PD) and gross domestic product (GDP), provided higher contributors to increased anthropogenic HMBR in XY (0.23/0.71) than FX (0.11/0.18). The comparative results of this study provided new insights into environmental monitoring and management of HM contamination for adjacent lakes with contrasting environments.

Evaluation of Metal Contamination of Sediments around an Industrial Gold Mine in Côte d’Ivoire: The Example of Arsenic

Evaluation of Metal Contamination of Sediments around an Industrial Gold Mine in Côte d’Ivoire: The Example of Arsenic

Assessment of heavy metal distribution, contamination, and ecological risk in mangrove sediments of the Nabq Protectorate, Gulf of Aqaba

Assessment of heavy metal distribution, contamination, and ecological risk in mangrove sediments of the Nabq Protectorate, Gulf of Aqaba

Vertical and Lateral Variation of Ecological Risk Index of Heavy Metals in the Euphrates River Sediments between Heet and Fallujah, Iraq.

The heavy metals (HMs) contamination of river sediments and their ecological risks is a global environmental problem that has attracted the attention of researchers and those interested in environmental protection. The study aims to investigate the ecological hazards of some HMs in sediments of Euphrates River between the cities of Heet and Fallujah, Iraq and their lateral and vertical variations. At three depths—0-30, 30-60, and 60-90 cm—samples of sediment were collected from five sites. Atomic Absorption Flame Emission Spectrophotometer (ASC.7000) was used to measure concentration of Cd, Cr, Cu, Ni, Pb, and Zn. The ecological risk index (ErI) values of metals in Euphrates River sediment in the study area take the following descending order: Cd > Ni > Cu > Cr > Pb > Zn. The ErI levels were low for Cr, Cu, Ni, Pb and Zn and considerable ecological risk for Cd. The obtained results did not show a common lateral variation pattern of the ecological risk of the measured metals. There is a high level of risk for the measured metals at the downstream sampling sites except for the risk from Cd on the contrary. The potential ecological risk of Cd, Cr, Pb and Zn showed a similar vertical variation pattern which in turn reflects a common source or origin for these metals, while copper and nickel showed a different common distribution pattern.

형산강 하천 퇴적물 내 중금속 오염도 및 생태위해성 평가

형산강 하천 퇴적물 내 중금속 오염도 및 생태위해성 평가

Improved Calculations of Heavy Metal Toxicity Coefficients for Evaluating Potential Ecological Risk in Sediments Based on Seven Major Chinese Water Systems.

Several methods have been used to assess heavy metal contamination in sediments. However, an assessment that considers both composite heavy metal speciation and concentration is necessary to accurately study ecological risks. This study improved the potential ecological risk index method and calculated the toxicity coefficients of seven heavy metals: Arsenic (As), Cadmium (Cd), Chromium (Cr), Copper (Cu), Nickel (Ni), Lead (Pb), and Zinc (Zn). The newly calculated toxicity coefficients were validated by using previously published heavy metal distribution data of the Henan section of the Yellow River. The calculation procedure is based on the principle that the abundance of heavy metals in the environment and their bioavailable forms affect the toxicity of heavy metals. The toxicity coefficients for the seven heavy metals were calculated as follows: As = 10, Cd = 20, Cr = 5, Cu = 2, Ni = 5, Pb = 5, Zn = 1. Ecological risk assessment of the Henan section of the Yellow River using the improved toxicity coefficients revealed that the ecological risk of Cd and total heavy metals is higher than previous calculations, reaching the strength and moderate risk levels, respectively. The improved potential ecological risk index method is more sensitive to heavy metal pollution and thus provides a better indication of ecological risk. This is a necessary improvement to provide more accurate pollution assessments.

Seasonal variation, contamination and ecological risk assessment of heavy metals in sediments of coastal wetlands along the Bay of Bengal

Functioning of coastal wetland habitats is essential for the ecosystem integrity and sustainability of coastal development that enables human progress along transitional waterways. However, these habitats are continuously being affected by a variety of pollutants including metallic elements. In this study, seasonal variation, pollution status and ecological risks of heavy metals (Cr, Mn, Co, Ni, As, Cu, Zn and Pb) in surface sediment of the several types of coastal wetlands (estuaries, mudflats, sandy beaches, mangroves, and saltmarshes) were detected by using X-ray fluorescence (EDXRF) spectrometry. The results showed that the mean concentration level of metals in the surficial sediment samples followed the order of Cu (84.06 ± 8.60 μg/g) > Zn (51.00 ± 8.97 μg/g) > Mn (38.25 ± 11.34 μg/g) > Cr (3.52 ± 0.91 μg/g) > Pb (0.27 ± 0.13 μg/g) > Co (0.24 ± 0.13 μg/g) > As (0.21 ± 0.12 μg/g) > Ni (0.16 ± 0.08 μg/g). In comparison to the pre-monsoon period, the post-monsoon season had higher concentrations of heavy metals while the overall accumulation level of metals in the wetlands exhibited a pattern of estuarine wetland (28.47 ± 31.35 μg/g) > mangrove (22.23 ± 30.79 μg/g) > mudflat (21.79 ± 29.71 μg/g) > sandy beach (21.47 ± 28.15 μg/g) > saltmarsh (21.28 ± 30.02 μg/g). Although, the pollution assessment indices e.g., contamination factor (CF), degree of contamination (CD), geoaccumulation index (Igeo) and pollution load index (PLI) showed minimal levels of contamination in the studied sites, enrichment factor (EF) suggested greater enrichment of the metals in the pre-monsoon season but with the lowest ecological risk (RI < 40) in both seasons. Cluster analysis, principal component analysis (PCA), and Pearson's correlation were performed to determine the sources of heavy metals in collected samples which specified that Pb, As, Co and Ni predominantly came from natural sources whereas Cu, Mn, Zn and Cr emerged from anthropogenic sources such as industrial effluents, domestic wastewater, fertilizer or pesticide consumption on farmland along the riverbank, vessel emissions, and the confluence of tributary rivers.

Level of Some Heavy Metal Contamination of Water and Sediments of River Pil-Gani Plateau State Nigeria

Level of Some Heavy Metal Contamination of Water and Sediments of River Pil-Gani Plateau State Nigeria

Probing the national development from heavy metals contamination in river sediments

Equal access to clean water for all is the 6th of the United Nations Sustainable Development Goals. River sediment is an important sink of heavy metals discharged by human activities, and also a critical risk source for drinking water safety. We compared the concentrations of heavy metals in the river sites of countries with various degrees of development, and obtained the distribution results that can fit the Environmental Kuznets Curve. The risk assessment of water sources can correlate or probe socio-economic feedback to the environment. We hope to focus on the environmental changes together with the global riverbeds, rather than just local case studies. Worryingly, humanity has not escaped the law of Environmental Kuznets Curve. There are more than 4 billion people living in the early stage of industrialization nowadays. With their increasing affluence and metal purchasing power, new heavy metal pollution problems will occur in the places with few reports. The development of the national economies, as revealed by donor-acceptor relation models in resource acting force, requires the search for innovative patterns to achieve global progress that is more equitable, efficient and sustainable.

Environmental hazard assessment and metal contamination in coastal sediments

In order to reduce contamination levels from diverse sources, it is important to understand the factors affecting the natural ecosystems that are impacted by coastal and marine pollution. In this study, we used GIS and remote sensing techniques to investigate and evaluate the distribution of heavy metals (Fe, Mn, Zn, Cr, Pb, Co, and Cu) in surface sediments along Tamil Nadu's East Coast (from Besant Nagar to Sathurangapattinam). The CF and Igeo of metals indicate that sediments contain no evidence of Fe, Mn, or Zn metal pollution in the sediments, with only mild contamination from Co, Cu, and Pb. In contrast, the sediment samples were found to be significantly contaminated with Cr. Heavy metal contamination occurs in the following order, according to our research: Cr > Pb > Cu > Co > Mn > Zn > Fe. Except for sites 8, 10, 11, and 13, where PLI>1 implies that there is no pollution in this area, the PLI values show that most of the locations are contaminated. The ecological risk index (ERI) values for five metals in the study areas are as follows: Cr > Pb > Cu > Mn > Zn. The sediment samples fall into the low-risk and highly polluted to dangerous sediment categories for SPI, according to the Risk index (RI). Based on the Mean Effect Range-Median Quotient (M-ERM-Q), Cu, Pb, Zn, and Cr metals in the research region have a 9–21% probability of being harmful. Statistical approaches show that the majority of heavy metals in sediments are of natural origin. The spatial distribution of heavy metals in surface sediments provides the conceptual framework for practical strategies to protect coastal areas. Many shreds of evidence indicate that anthropogenic inputs from the surrounding land area are primarily responsible for the deposition of these heavy metals in the coastal zone.

Assessment of heavy metal contamination in the surface sediments of the Vedaranyam coast, Southern India

The marine sediments of the Vedaranyam coast were examined for their heavy metal contamination largely contributed by natural and anthropogenic activities. Sediment samples were collected and assessed for metals such as chromium (Cr), copper (Cu), manganese (Mn), iron (Fe), Nickel (Ni), zinc (Zn), and cobalt (Co). The individual toxic risk index (TRIi) of metals in this study is significantly variable for Cr (0.88–1.10), Cu (1.78–2.73), Zn (2.33–4.81) and Ni (1.10–4.62). TRIi in the sediments is below 5 for Cr, Cu, Zn, and Ni suggesting the absence of any toxic risk in the aquatic life. To assess the natural and anthropogenic contamination as well as to know the sediment quality, various indices such as the geo-accumulation index, enrichment factor, pollution load index, and contamination factor were computed. The enrichment factor result shows that the heavy metals are primarily from anthropogenic sources. There is a high positive correlation among the heavy metals, indicating a similar origin.

Heavy Metal Contamination and Potential Ecological Risk Assessment in Sediments of Lake Bafa (Turkey)

This study examined the spatio-temporality of heavy metal concentrations (Al, Cd, Co, Cr, Fe, Mn, Ni, Pb and Zn) in the sediments of Lake Bafa, one of the most important wetlands of Turkey’s Aegean region. The study evaluated sediment quality according to threshold effect concentration (TEC) and probable effect concentration (PEC) values based on sediment quality guidelines (SQG), and provided a potential ecological risk assessment (PERI) along with indices such as geoaccumulation index (NIgeo), enrichment factor (EF), contamination factor (CF), and pollution load index (PLI). For this purpose, surface sediment from 10 different points and core samples from three different points were seasonally collected and the concentrations of nine heavy metals were determined by ICP-MS. The findings indicated the following accumulation order of heavy metals in the sediment: Fe &gt; Al &gt; Mn &gt; Ni &gt; Cr &gt; Zn &gt; Pb &gt; Co &gt; Cd, with concentrations of Al, Mn, and Ni being high in the surface sediment samples. According to the NIgeo, surface sediment and core samples were very slightly polluted with Cr, Mn, and Co at most stations, while five stations were slightly polluted with Cd. Regarding EF, the lake was at risk in terms of Al and Pb accumulation. The CF results indicated that the lake was under pressure in terms of heavy metal pollution. The PLI results indicated a significant pollution hazard at all stations, while the PERI analysis indicated moderate risk of heavy metal pollution at some stations. As one of the most comprehensive studies applying such indices to Lake Bafa, the results are very significant in terms of evaluating the lake’s ecological sustainability.

Particle-based nutrients and metal contaminants in the habitat of Unionidae mussels in the Tisza River (Hungary)

Introduction:Unioniade is a species-rich family of freshwater mussels with an almost worldwide distribution. In Central European rivers Unio crassus, Unio tumidus and Unio pictorum have relatively high populations. In order to characterize the habitats of these suspension feeders, their nutrient supply and potential metal contaminants were investigated in near-bottom suspended (NBS) sediments and bottom sediments (BS) collected at four sampling locations along the Tisza River.Methods: The grain size distribution of sediments was determined by laser-diffraction technique. The total organic carbon (TOC) and the total Kjeldahl nitrogen (TN) were measured by a TOC analyzer and automated colorimetry, respectively. The phosphorous and metal concentrations were determined by inductively coupled plasma mass spectrometry following a microwave assisted acidic extraction of sediments with aqua regia.Results: The NBS sediments contained smaller grains than the BS samples, with roughly 85%–90% of the particles being less than 60 μm, allowing these mussels to catch them. Contrarily, only 2.47%–51.8% of BS samples were less than 60 μm. The NBS sediments contained 30, 23, and 15% more organic carbon, nitrogen, and phosphorous, respectively, than the BS samples. The rounded C:N:P molar ratios in the NBS sediments were 60:4:1, whereas they were 45:3:1 in the bottom sediments. The concentration of metals was also greater in the NBS sediments with the exception of Zn at Tokaj and Fe, Al, Mn, and Cr at Szeged, where prior contaminations transported by the tributaries Bodrog and Maros are stored in the top 10 cm of BS.Discussion: On basis of the measured C:N:P molar ratios it can be stated that soil-derived organic materials are the main sources of the nutrient elements in the habitats of suspension feeders in the Tisza River. The finer NBS sediments have higher specific surface area than the BS and thereby contain more biofilms on the grains resulting in higher proportion of organic nutrients and metal ions bounded as complexes or chelates. Comparing the measured metal concentrations of sediments with the concentration limits summarized in the Consensus-Based Sediment Quality Guidelines developed for evaluation of potential risk of metal contaminants in sediments for the benthic-dwelling organisms, it can be established that only the Hg concentration exceeded the probable effect concentration.

Evaluation of human health and ecological risk of heavy metals in water, sediment and shellfishes in typical artisanal oil mining areas of Nigeria.

Heavy metal contamination in water and sediment is a serious concern in nations that depend heavily on natural resources such as Nigeria. In most coastal communities around oil mining areas in Nigeria, drinking water quality, staple food, and livelihoods are primarily dependent on ecological systems and marine resources (e.g., fish). Thus, humans and other receptors are exposed to heavy metal risks through ingestion and dermal contact. This research evaluated the potential ecological risks of heavy metals including Cadmium (Cd), Chromium (Cr), Nickel (Ni), and Lead (Pb) in water, sediments, and shellfishes (Callinectes amnicola, Uca tangeri, Tympanotonus fuscatus, Peneaus monodon) along the Opuroama Creek in Niger Delta, Nigeria. The concentrations of heavy metals were measured in three stations using the Atomic Absorption Spectrophotometer and their relative ecological (geo-accumulation index and contamination factor) and human health risk (hazard index and hazard quotient) analysed. The toxicity response indices of the heavy metals indicate that the sediments pose significant ecological risk particularly with Cd. None of the three exposure pathways to heavy metals in the shellfish muscles and age groups pose a non-carcinogenic risk. Total Cancer Risk values for Cd and Cr exceeded the acceptable range (10-6 to 10-4) established by USEPA in children and adults, raising concerns of potential cancer risks following exposure to these metals in the area. This established a significant possibility of heavy metal risks to public health and marine organisms. The study recommends conducting in-depth health analysis and reducing oil spills while providing sustainable livelihoods to the local population.

Ecological risk characteristics of sediment-bound heavy metals in large shallow lakes for aquatic organisms: The case of Taihu Lake, China

Heavy metal contamination in the surface sediments of large shallow lakes in China is becoming increasingly serious. However, more attention has been paid to the human health risk of heavy metals in the past, while little consideration has been given to aquatic organisms. Taking Taihu Lake as an example, we explored the spatial and temporal heterogeneity of the potential ecological risks of seven heavy metals (Cd, As, Cu, Pb, Cr, Ni, and Zn) to species at different taxonomic scales using an improved species sensitivity distribution (SSD) method. The results showed that all six heavy metals, except Cr, were exceeded to some extent compared to background levels, with Cd being the most severe exceedance. Based on the hazardous concentration for 5% of the species (HC5), Cd had the lowest HC5 value, implying the highest ecological risk of toxicity. Ni and Pb had the highest HC5 values and the lowest risk. Cu, Cr, As and Zn were at a relatively moderate levels. For the different groups of aquatic organisms, the ecological risk of most heavy metals was generally lower for vertebrates than for the whole species. The risk for invertebrates and algae was higher than that for all species. Zn and Cu had the highest potentially affected fractions (PAFs) for all classification cases, with mean PAFs of 30.25% and 47.2%, respectively. Spatially, the high ecological risk of sediment heavy metals was significantly related to the spatial characteristics of the type and intensity of human activities in the catchment. Administratively, the environmental quality standards for freshwater sediments proposed by America and Canada are insufficient to protected against the ecological risks of heavy metals in Taihu Lake. In the absence of such standards, China urgently needs to establish an approptiate system of environmental quality standards for heavy metals in lake sediments.

Hot and heavy: Responses of ragworms (Hediste diversicolor) to copper-spiked sediments and elevated temperature

Sediment contamination and seawater warming are two major stressors to macrobenthos in estuaries. However, little is known about their combined effects on infaunal organisms. Here we investigated the responses of an estuarine polychaete Hediste diversicolor to metal-contaminated sediment and increased temperature. Ragworms were exposed to sediments spiked with 10 and 20 mg kg−1 of copper at 12 and 20 °C for three weeks. No considerable changes were observed in the expression of genes related to copper homeostasis and in the accumulation of oxidative stress damage. Dicarbonyl stress was attenuated by warming exposure. Whole-body energy reserves in the form of carbohydrates, lipids and proteins were little affected, but the energy consumption rate increased with copper exposure and elevated temperature, indicating higher basal maintenance costs of ragworms. The combined effects of copper and warming exposures were mostly additive, with copper being a weak stressor and warming a more potent stressor. These results were replicable, as confirmed by two independent experiments of similar settings conducted at two different months of the year. This study suggests the higher sensitivity of energy-related biomarkers and the need to search for more conserved molecular markers of metal exposure in H. diversicolor.

Assessment of heavy metals contamination of sediments and surface waters of Bitter lake, Suez Canal, Egypt: Ecological risks and human health

The concentrations of heavy metals in the surface waters and sediments of Bitter Lake were investigated to assess the level, distribution, and source of pollution and the associated ecological and human health risks. The ecological indices of the lake water indicate low contamination degrees by heavy metals. A dermal exposure-based health risk evaluation revealed no carcinogenic or non-carcinogenic impact on human health. The contamination factor (CF) for Cu, Ni, Pb, Mn, Fe, and Zn (CF < 1) indicate low contamination levels, while Cd reaches very high contamination in most sediment sites (CF ranges from 6.2 to 72.4). Furthermore, the potential ecological risk factor (Eri) and modified hazard quotient (mHQ) indicate low ecological risk for all metals except Cd, revealing high to very high-level ecological risk in most sites (Eri ranges from 185 to 2173 and mHQ from 1.8 to 6.3). This emphasizes the urgency of prompt actions to improve the environment in Bitter Lake.

Ecological and health risk assessment of heavy metals contamination in mangrove sediments, Red Sea coast

Due to the significance of mangroves for the diversity of marine and terrestrial life along the Red Sea coast, the present work aimed to evaluate the environmental and health risk of heavy metals in Wadi el-Gemal sediments. The findings of single and integrated indices demonstrated no significant pollution with Fe, Cu, Zn, Ni, Co, and Cd, while the sediments showed severe and minor enrichment with Mn and Cd, respectively, which might be attributed to the presence of some mining activities in the mountains near the study area. The possible carcinogenic and non-carcinogenic risks due to their dermal absorption from the sediments were analyzed and the findings demonstrated that the non-carcinogenic health hazards were within tolerable and safe limits. Moreover, the evaluation of chronic daily intake and the overall cancer risk (LCR) for adults and children for Pb and Cd both ruled out any current potential carcinogenic health risks.