Metasedimentary Research Articles

Detrital zircon U–Pb ages and geochemistry of Devonian–Carboniferous sandstones and volcanic rocks of the Hida Gaien belt, Southwest Japan: Provenance reveals a Gondwanan lineage for the early Paleozoic tectonic evolution of proto-Japan

Devonian–Carboniferous strata in the Hida Gaien belt, Southwest Japan, are characterized by a change in the dominant lithology from clastic rocks and limestones to volcanic rocks. The sandstone compositions and detrital zircon U–Pb ages indicate that the Devonian sedimentary rocks were derived from various basement rocks, including granite and basalt, that were uplifted, exposed, and eroded during the Early–Middle Devonian (398–383 Ma). The source of sediment to these strata changed to basalts and rhyolites in the early Carboniferous (∼346 Ma). Early Carboniferous bimodal volcanic rocks are present in the Hida Gaien and South Kitakami belts, the southeastern margin of the South China block (Hainan), and the Jilin area (NE China) of the eastern Central Asian Orogenic Belt (CAOB). The Cambrian–Silurian zircon grains (540–480 Ma and 460–420 Ma) in the Hida Gaien belt were derived from arc basement of a similar age to the South Kitakami and Kurosegawa belts, the Jiamusi–Khanka–Bureya (NE China and the Russian Far East) and Songliao–Xilinhot (Inner Mongolia) blocks in the eastern CAOB, and the eastern South China and Indochina blocks. The Devonian strata also contain Precambrian zircon grains derived from Mesoarchean basement (∼3000 Ma) and the Grenvillian tectonothermal event (∼1000 Ma), suggesting sediment supply from NE Gondwana (the Thomson and Lachlan orogens of eastern Australia) or related continental remnants. Detrital zircon U–Pb age spectra similar to those of the Devonian strata of the Hida Gaien belt are also observed in Silurian–Devonian metasedimentary rocks in the Jilin area. During the early Paleozoic, the Hida Gaien belt, the eastern margin of the South China block, and the magmatic arcs and microcontinents in the eastern CAOB were located close to NE Gondwana along the western margin of the Paleo-Pacific Ocean.

Paleoproterozoic crustal evolution of the northern Borborema Province, NE Brazil: Insights from high-grade metamorphic rocks of the Canindé do Ceará Complex

Archean to Paleoproterozoic crustal segments are widely recognized as basement inliers within the Neoproterozoic orogenic belts of the Pan-African/Brasiliano orogeny. For example, the Canindé do Ceará Complex, in the northern Borborema Province, NE Brazil, comprises a large domain of Paleoproterozoic high-grade metamorphic rocks with a protracted tectonic history. This complex is dominantly represented by sillimanite- and graphite-bearing metasedimentary rocks with associated tonalitic to granodioritic orthogneisses. All these rocks are highly deformed and variably migmatized. Minor granitic intrusions and lenses of garnet amphibolites are also present. In this work, in order to discuss the tectonic evolution of the area, we present new U-Pb LA-ICPMS zircon dating, Sm-Nd isotopes, and whole-rock geochemistry for selected samples of the Canindé do Ceará Complex. The amphibolites show tholeiitic affinity and Sm-Nd TDM model ages of 2.22–2.52 Ga with positive εNd(t), attesting to an oceanic signature. The tonalitic/granodioritic orthogneisses show U-Pb ages of 2.19 to 2.12 Ga, Sm-Nd TDM model ages of 2.16 to 2.34 Ga, which probably reflect arc-related environments. The collisional event is marked by granitic intrusions (aplites) and diatexites, which display U-Pb ages ranging from 2.08 to 2.03 Ga. This event is also recorded in zircon recrystallized from tonalitic/granodioritic rocks, which show U-Pb age at 2.04 Ga. Therefore, from our results and literature information, the Rhyacian/Orosirian basement rocks of the Canindé do Ceará Complex show a protracted evolutionary history, ranging from 2.2 to 2.1 Ga arc-related environments, to 2.1–2.0 Ga continental collision and late Neoproterozoic metamorphic overprint.

Textures, in situ trace element and sulfur isotope of pyrite from the sediment-hosted Cu–Co deposits in the Zhongtiao Mountains, Trans-North China Orogen: Implications for ore genesis

Sediment-hosted Cu–Co deposits in the Zhongtiao Mountains are hosted by the metasedimentary rocks of the Paleoproterozoic Zhongtiao Group in the southern part of the trans-North China orogen, North China Craton. The ore genesis is still disputed with proposed genetic models including metamorphosed sedimentary exhalative (M−SEDEX), metamorphosed sediment-hosted stratiform copper (M−SSC) and metamorphogenic mineralization type. Pyrite occurs as a ubiquitous mineral throughout all ore-forming stages and is ideal for clarifying this issue via the integration of in situ (LA–ICP–MS and EPMA) elemental and LA–MC-ICP–MS sulfur isotope composition analyses. Two main types of pyrite are identified based on petrographic and SEM observations: fine- to medium-grained, variably deformed and inclusion-rich Py1 (including Py1a and Py1b subtypes) in the disseminated–veinlet mineralization stage (S1), and coarse-grained, fractured Py2 (including Py2a and Py2b subtypes) in the fracture-controlled vein-type mineralization stage (S2, main ore stage). Deformed and inclusion-rich Py1a is overgrown by inclusion-poor Py1b, and nonporous Py2a is rimed by porous Py2b. Geochemical results show that the studied pyrite samples have considerable contents of Co (mean > 1000 ppm) and Ni (mean > 100 ppm). These features could be related to both the Co and Ni-rich sedimentary environment (e.g., a volcaniclastic-rich sulfidic marine) and metamorphic enrichment. The content of Se (mean > 200 ppm) in Py2 is significantly higher than that in Py1, indicating the extensive interaction of mineralizing fluids with Se-bearing graphite schist. LA–ICP–MS mapping and textural studies indicate the presence of coupled dissolution-reprecipitation (CDR) reactions that could lead to trace metal compositions (e.g., Co, Ni, Se, Pb, Bi) in the product phases (Py1b, Py2b) that differ from those of their parent phases (Py1a, Py2a). These variations were most likely controlled by fluid temperature and precipitation of specific minerals. The grain-scale chemical zoning of Py2a revealed by elemental mapping indicates fluctuating fluid parameters (e.g., temperature, fS2, and/or parent fluid compositions). The bimodal distributions in Py1 (10–14 ‰ and 18–24 ‰) are consistent with the inheritance of sulfur from sedimentary pyrite and the input of thermochemical sulfate reduction (TSR) -related sulfur from reworked evaporite sulfates in an increasingly open system. The relatively lighter and wider variation in δ34S values (3.2–22.4 ‰, mean = 15.1 ‰) of Py2 implies that the evolution of the ore fluid in S2 was far more complicated, probably as a result of fluid–rock interactions and fluid cooling. During this process, hydrothermal rims with lighter δ34S values (8.4 ‰) grew on older metamorphic pyrite cores with relatively heavier δ34S values (17.4–18.2 ‰). Chalcopyrite displays overlapping S isotopic compositions with pyrite from different mineralization stages, suggesting that copper sulfides inherited reduced sulfur from earlier formed pyrite. Cooling and fluid–rock interactions serve as the critical controls triggering Cu precipitation from the fluid. The combined textural and compositional data of pyrite and chalcopyrite are suggestive of a syn-orogenic copper deposit model, in which all the ore-grade copper was introduced during the Zhongtiao orogeny.

Bhumichula plateau: A remnant high-elevation low-relief surface in the Himalayan thrust belt of western Nepal

The Himalaya is known for dramatically rugged landscapes including the highest mountains in the world. However, there is a limited understanding of the timing of attainment of high elevation and relief formation, especially in the Nepalese Himalaya. Anomalous high-elevation low-relief (HELR) surfaces, which exhibit geomorphic antiquity and are possibly remnants of formerly widespread high-elevation paleosurfaces, provide a unique opportunity to assess the attainment of regional high elevation in the Himalaya. The Bhumichula plateau is one such HELR surface (4300−4800 m) in the western Nepalese Himalayan fold-thrust belt. The Bhumichula plateau is situated in the Dadeldhura klippe (also called the Karnali klippe), an outlier of Greater Himalayan Sequence high-grade metasedimentary/igneous rocks surrounded by structurally underlying Lesser Himalayan Sequence low-grade metasedimentary rocks. We assess the origin of the Bhumichula plateau by combining regional geological relationships and zircon and apatite (U-Th-Sm)/He and apatite fission track thermochronologic ages. The HELR surface truncates pervasive west-southwestward dipping foliations, indicating that it post-dates tilting of rocks in the hanging wall of the Main Central thrust above the Lesser Himalayan duplex. This suggests that the surface originated at high elevation by erosional beveling of thickened, uplifted crust. Exhumation through the ∼180−60 °C thermal window occurred during middle Miocene for samples on the plateau and between middle and late Miocene for rocks along the Tila River, which bounds the north flank of the Bhumichula plateau. Cooling ages along the Tila River are consistent with erosional exhumation generated by early Miocene emplacement of the Main Central (Dadeldhura) thrust sheet, middle Miocene Ramgarh thrust emplacement, and late Miocene growth of the Lesser Himalayan duplex. The most recent middle-late Miocene exhumation took place as the Tila River and its northward flowing tributaries incised upstream, such that the Bhumichula plateau is a remnant of a more extensive HELR paleolandscape. Alpine glaciation lowered relief on the Bhumichula surface, and surface preservation may owe to its relatively durable lithology, gentle structural relief, and elevation range that is above the rainier Lesser Himalaya.

Lithological and glacial controls on sulfide weathering and the associated CO2 budgets in the Tibetan Plateau: New constraints from small catchments

The Tibetan Plateau, a region that hosts low to middle-latitude glaciers and a high density of metasedimentary rocks, is a hotspot of continental weathering and carbon cycling. However, quantitative estimations of sulfide oxidation and how it affects CO2 budgets from the plateau weathering are lacking. Here we use chemical and isotopic datasets from the studied small catchments in the Tibetan Plateau to estimate that 69.1% to 77.0% of stream SO42– originates from sulfide oxidation. Thus, more than 80% of the CO2 consumed by silicate weathering is counterbalanced by transient CO2 release from H2SO4-driven carbonate dissolution in the study area. In addition, the sulfide oxidation rate for glacial catchments is 5 times that of nonglacial catchments. The CO2 release rate from acid generated by sulfide oxidation in metasedimentary catchments is approximately 3 times that of granitic catchments. We propose that sulfide oxidation has greatly modified the CO2 budget of chemical weathering of the Tibetan Plateau. This study reveals new constraints on the CO2 budget in the Tibetan Plateau weathering, and will provide important insights into the carbon cycle during the plateau uplifting in Cenozoic.

Using monazite U-Pb geochronology of Precambrian shales to constrain fluid flow and hydrocarbon accumulation events of a petroliferous basin

Obtaining precise ages of the Phanerozoic fluid flow events of petroliferous basins is essential for understanding the tectonothermal histories, petroleum- and ore-forming processes. Conventional isotopic dating methods are often compromised by inheritance from detrital constituents and/or subsequent thermal resetting. Monazite is a trace mineral widely present in low-grade metasedimentary rocks, and as an excellent U–Th–Pb geochronometer it has great potential in dating fluid flow activities related to basin evolution. We present results of an in-situ monazite U-Th-Pb geochronology study on shale samples from the Neoproterozoic (651 Ma) Datangpo Formation intersected by a drill-hole in the Sichuan Basin, a typical petroliferous basin in western South China. We recognized two fluid flow events at ca. 450 Ma and ca. 263 Ma, and relate the former to the far-field effect of the Proto-Pacific Ocean subduction and the latter to emplacement of the Emeishan large igneous province. We infer that the ca. 450 Ma fluid flow event induced the first stage of oil charging in the paleo oil pools in the Sichuan Basin, as also recorded by the bitumen samples from the Anyue gas field which yielded re-Os isotopic ages of 458–492 Ma, whereas the ca. 263 Ma event triggered the gas generation of the Paleozoic marine strata in the Sichuan Basin. The results and findings of this study have important implications to reconstructing the complex histories of fluid flow, oil charging and gas generation events of petroliferous basins.

Thermal variation across collisional orogens: Insights from the hinterland–foreland transition zone of the Sardinian Variscan belt

AbstractUnravelling the architecture and evolution of orogenic wedges are often hampered by the presence of strongly deformed large‐scale nappes made by homogeneous metasedimentary rocks lacking diagnostic metamorphic phases. Involving nappes or tectonic units which occupy most of the chain, reconstructing the thermal architecture of the hinterland–foreland transition zone of collisional belts represents a key point to comprehend the orogenic wedge tectonics. This work provides new thermal data from Raman Spectroscopy on Carbonaceous Material (RSCM) carried out in the low‐grade metamorphic rocks of the hinterland–foreland transition zone in the Variscan belt of Sardinia. The obtained TRSCM highlighted a temperature difference, from ~470–440°C down to ~440–380°C, for the internal and external nappes, respectively. We propose that both nappes experienced syn‐nappe greenschist‐facies metamorphism with different TRSCM, further heating localized along the tectonic boundary in between, that is the Barbagia Thrust (BT), and finally, post‐nappe stacking regional‐scale folding, that deformed the TRSCM spatial distribution and drove the present‐day thermal architecture.

AGE AND SOURCES OF DETRITAL MATERIAL FOR THE METASEDIMENTARY ROCKS OF THE NILAN TERRANE OF THE MONGOL-OKHOTSK OROGENIC BELT

The paper presents the first results of U-Th-Pb (LA-ICP-MS) isotopic dating of detrital zircons from the Paleozoic (?) metasedimentary rocks of the Nilan Terrane of the Mongol-Okhotsk orogenic belt to refine the age estimates and determine their probable correlation with earlier dated sediments of this belt. It has been stated that the metasedimentary rocks of the Olga, Salarin and Rovnen formations and of the Sivak formation of the Nilan terrane are characterized by the almost complete absence of the Early Precambrian zircons, slightly negative ε Nd(t) values, and Mesoproterozoic t Nd(DM) and t Nd(С) values. The isotope dataset obtained shows that most of the detrital sediments were carried from continental massifs of the Amur superterrane.

Nature and evolution of the lower crust under central Spain: Inferences from granulite xenoliths (Calatrava Volcanic Field-Spanish central system)

So far, the nature and evolution of the lower crust under central Spain have been constrained mainly on the basis of a heterogeneous suite of granulite xenoliths from the Spanish Central System (SCS). In recent years, ultramafic volcanics from the Calatrava Volcanic Field (CVF) have also provided deep-seated crustal xenoliths which have not been studied in detail. Our data, combining mineral, whole-rock and isotopic geochemistry with U–Pb–Hf isotope ratios in zircons from the CVF and SCS xenoliths, highlight the felsic composition of the lower crust under central Iberia. A number of the Calatrava xenoliths represents Variscan igneous protoliths, which are a minor population in the SCS, and were likely formed by crystallisation of intermediate and felsic melts in the lower crust during the Variscan orogeny (leucodiorite protolith age of 314 ± 3 Ma and leucogranite protolith age of 308 ± 2.5 Ma). U–Pb data of metamorphic zircons show that granulite-facies metamorphism mainly occurred from 299 to 285 Ma in both areas. These ages are slightly younger than those of granitic intrusions that could be genetically related to the granulitic residue, which points to a main role of U–Pb isotope resetting in lower crustal zircons during HT or UHT conditions. The zircon U–Pb–Hf isotopic ratios support the idea that the lower crust in central Iberia consists mainly of Ordovician–Neoproterozoic metaigneous and metasedimentary rocks associated with the Cadomian continental arc of northern Gondwana. These rocks provide evidence of mixing between juvenile magmas and an enriched crustal component, ultimately extracted from an Eburnean crust. Other more evolved components present in detrital zircons are likely related to recycling of Archean crust derived from North Africa cratonic terranes.

Dissipation of Tungsten-182 Anomalies in the Archean Upper Mantle: Evidence from the Black Hills, South Dakota, USA

Most Eoarchean rocks are characterized by positive μ182W anomalies averaging ∼ +13 ppm (where μ182W values are the part per million difference in 182W/184W between a sample and a laboratory reference material presumed to be representative of the bulk silicate Earth, BSE). Prior studies have concluded that the positive 182W anomalies in the upper mantle disappeared by the end of the Archean, yet the timing, nature, and causes of the inferred transition remain poorly understood. In this study, we obtained SmNd mantle extraction model ages (TDM) and μ182W values for Neoarchean and Paleoproterozoic granitic and metasedimentary rocks from the Black Hills, South Dakota, USA. The rocks examined have TDM model ages ranging between ∼3.6 Ga and 2.3 Ga, permitting the tracing of the evolution of 182W in the upper mantle precursors to these rocks, during the purported period of isotopic transition. Of these crustal rocks, the 2.55 Ga Little Elk Granite, with an average TDM age of ∼3.2 Ga, is characterized by a well resolved positive anomaly (μ182W = +8.2 ± 3.1, 2SE). This observation is consistent with a modest diminution in the upper mantle μ182W value relative to the Eoarchean average. By contrast, the 2.60 Ga Bear Mountain Granite, with a slightly younger average TDM age of ∼3.0 Ga, exhibits no resolved anomaly. Most other individual rocks examined also lack resolved anomalies, although the group average μ182W value of +3.3 ± 1.3 (2SE) for the 1.72 Ga Harney Peak Granite, with the majority of TDM model ages ranging from ∼2.7 to 2.3 Ga, may indicate a small positive anomaly for their Neoarchean to Paleoproterozoic upper mantle precursors.The Black Hills rocks provide new evidence for the uneven dissipation during the Mesoarchean through Paleoproterozoic of the positive μ182W value that typified the Eoarchean upper mantle. When the new data are combined with data from prior studies, it becomes evident that the transition to a “modern” BSE W isotopic composition was not the result of a smooth linear decrease, but rather an irregular trend. Nevertheless, the collective data indicate that the positive anomalies in the upper mantle were nearly eliminated by the beginning of the Proterozoic, presumably by mantle mixing processes. The diminution in the scale of 182W anomalies during the Archean is similar to that of 142Nd, and requires a global-scale process that most likely involved vertical and/or lateral mixing within the mantle. The reasons for the delay in the initiation of this mixing process until the end of the Eoarchean, and the completion of mantle mixing by ∼2.4 Ga, awaits exploration via geodynamical modeling of different mixing scenarios.

Improved Provenance Constraints for Nanaimo Group Sediments, British Columbia, Canada, Through Zircon LA‐ICP‐MS Depth‐Profiling

AbstractDetrital zircon from Late Cretaceous rocks of the Insular Superterrane have become an important constraint on Cordilleran paleogeography. These interpretations are largely based on the occurrence of a unique detrital zircon facies characterized by a broad Paleoproterozoic (mode 1.70 Ga) and narrow Mesoproterozoic mode (1.38 Ga) in Cordilleran sedimentary rocks. However, uncertainty about the provenance of this facies and the broad geographic distribution of rocks in which it is found limits its usefulness in constraining paleogeography. Detrital rims found on Mesozoic, Proterozoic, and Archean‐aged zircon cores from the Late Cretaceous Nanaimo Group of Western British Columbia, Canada provide constraints into its provenance. Depth‐profiling of a large population of grains (N = 16; n = 3,000), combined with observations regarding zircon external morphology, internal growth textures, U/Th ratios, and U concentrations, indicate high‐grade metamorphism occurred in the sediment source area between 99 Ma and 72 Ma. Rapid cooling of the metamorphic source area at rates of 35 to over 100°C/m.y. between 84 and 63 Ma was required to supply these metamorphic zircon to the basin. The geological history of the sediment source region defined by the rim populations (age of metamorphism and exhumation rate) is inconsistent with previously proposed sediment source areas for the Nanaimo Group in southern (Mojave region) or northern Laurentia (Lehmi Subbasin). We hypothesize that the sediment source area was the adjacent Coast Mountains Batholith and a metasedimentary rock, similar to the Pelona‐Orocopia‐Rand‐type schists, that was exhumed during the Late Cretaceous.

Geochemistry of Triassic metasediments from easternmost part of Sakar Unit, Sakar-Strandzha Zone, SE Bulgaria

Triassic metasediments from the easternmost part of Sakar Unit, Sakar-Strandzha Zone, SE Bulgaria, show a high variety in their mineral and chemical composition from shales, wakes, litharenites to arkoses. Geochemical signatures suggest low to moderate weathering degree at their source and upper continental crust composition. The Triassic metasedimentary rocks were derived from felsic to intermediate igneous rocks with some recycled sediment input. On tectonic setting discrimination diagrams, based on immobile trace elements, the studied metasediments fall in the fields of continental island arc and active continental margin.

Protolith and metamorphic age of the Sieggraben Eclogites: Implications for the Permian to Cretaceous Wilson cycle in the Austroalpine unit

The Austroalpine eclogite-bearing Sieggraben Complex, exposed at the eastern margin of the Eastern Alps, is considered to represent a subducted and then exhumed fragment of the continental rift, which led to the formation of the Meliata oceanic basin. Combined zircon U-Pb dating, whole rock geochemistry and Hf isotope analysis of the Sieggraben Complex revealed that the eclogite sample shows a protolith age of 242.3 ± 2.6 Ma (Middle Triassic) and displays tholeiitic basalt/N-MORB geochemical characteristics. Associated ultramafic rocks as part of oceanic or subcontinental mantle lithosphere suggest a depleted mantle source and a deep subduction environment. Two zircon grains of eclogites with low Th/U ratios yield ages of 113 ± 2 Ma and 86 ± 4 Ma and represent the approximate age of eclogite metamorphism during Cretaceous. A trondhjemite dike cutting through eclogite gives a crystallization age of 82.19 ± 0.4 Ma and formed by partial melting during decompression. The host metasedimentary rocks are interpreted as old continental crust close to the margin of the Meliata basin were affected by Permian migmatitic metamorphism. The results of this study combined with previous results from the Sieggraben Complex are used to present an updated model for the tectonic evolution of the distal Austroalpine unit associated with the oceanic Meliata relics The Austroalpine Sieggraben Complex represents a location on the distal continental margin during Permian rifting. This piece of continental crust of an inferred paleotectonic position adjacent to the Meliata oceanic lithosphere subducted during Early Cretaceous times to mantle depth. The subducted continental crust was then exhumed incorporating even ultramafic mantle rocks. During exhumation and decompression of mafic rocks, partial melting took place forming the trondhjemite dike in Late Cretaceous times. • A Middle Triassic ptotolith age was found for eclogites of the Sieggraben Complex. • A Cretaceous-aged trondhjemite dike report formed by decompressional melting after eclogite metamorphism. • Paragneiss hosts a Panafrican detrital zircon memory and was affected by Permian migmatization. • A new tectonic model for the distal Austroalpine unit relates with the Meliata Ocean in a Wilson cycle.

Petrogenesis of the Early Jurassic Longtang and Menglong Peraluminous Granites in Tengchong Terrane, and their Tectonic Implication

AbstractA comprehensive study of zircon U‐Pb geochronology, in situ Hf isotopes, whole‐rock major and trace element geochemistry, and Nd isotopes was carried out for two Early Jurassic two‐mica granites (Longtang and Menglong) in the southern part of the Tengchong terrane, which is in the northern part of the larger Sibumasu terrane. We assess the origin of the granites and explore their possible genetic relationship to the Paleo‐Tethyan regime. LA‐ICP‐MS zircon U‐Pb dating shows that they were simultaneously emplaced in the Early Jurassic (ca. 199 Ma). They have SiO2 contents of 69.7–75.1 wt% and are mainly strongly peraluminous with alumina saturation index (ASI) values ranging from 1.06 to 1.46. They show similar Mg# (0.29–0.42) to experimental partial melts of metasedimentary rocks under continental pressure‐temperature (P‐T) conditions. They are enriched in light rare earth elements (LREEs) relative to heavy rare earth elements (HREEs), with moderately negative Eu anomalies and flat HREEs patterns. They show negative εNd(t) values (–9.0 to –12.4) and εHf(t) values (–8.0 to –9.1). Elemental and isotopic data suggest that they most likely to formed by muscovite‐dehydration melting of a metapelitic source at lower temperatures in the range of 700°C to 750°C. The granites might represent a post‐collisional tectonic setting response to Paleo‐Tethyan regime.

Petrography and geochemistry of metasedimentary rocks from the Paleoproterozoic Birimian at the Chagupana area, North-West Ghana: implications for provenance and tectonic setting

Petrography and geochemistry of metasedimentary rocks from the Paleoproterozoic Birimian at the Chagupana area, North-West Ghana: implications for provenance and tectonic setting

Petrogenesis and geodynamic implications of Oligocene A-type granite in the Guadalcazar area, San Luis Potosi, central Mexico

The Guadalcazar is located in the Mesa Central (MC) province, which is mainly composed of granitic rocks and is known for its metallogenetic. The granitic rocks contain complex Sn-Hg-Ag-F mineralization and were emplaced during Eocene to Oligocene. However, the source, origin, and evolution of magma and the tectonic setting of this magmatic area have never been explained. In this study, we have conducted petrology, whole-rock geochemistry, and U–Pb zircon geochronology on granitic rocks from the Guadalcazar to constrain the petrogenesis and tectonic environment. LA-ICP-SF-MS zircon U–Pb dating shows that the Guadalcazar granite was emplaced ca. 31 Ma. These rocks are characterized by high (SiO2) contents (64–75 wt%), low CaO (0.28–1.78 wt%), with relatively high (FeOt)adj/(FeOt + MgO) values ranging from 0.90 to 0.98. The geochemical diagrams of SiO2 vs [(FeOt)/(FeOt + MgO)] and SiO2 vs [(Na2O + K2O) − CaO] show the ferroan and mostly alkali-calcic nature of these rocks. The granite shows an A2-type affinity and is strongly peraluminous, with ASI (molar Al2O3/[CaO + Na2O + K2O]) values of 1.13 to 2.60. These granitic rocks are characterized by enrichments in rare earth elements (REE) and high field strength elements (HFSE), and depletion in Ba, Nb, Sr, Ti, and Eu. These features suggest that these A-type granites were derived from the metasedimentary rocks and evolved through extensive fractional crystallization. The multidimensional discrimination diagrams showed a continental rift or within-plate setting. By combining previous and new data, we proposed a new magmatic evolution model that supports an extension during ca. 34–28 Ma in the Guadalcazar, central Mexico.

Mineralogical, lithogeochemical and sulfide trace element characteristics of the Hirvilavanmaa Au-only and the base metal-rich Naakenavaara orogenic gold deposits in the Central Lapland belt, northern Finland

The Hirvilavanmaa (Au-only) and Naakenavaara (Cu-Co-Au-Ni) deposits, located only 5 km apart in the Paleoproterozoic Central Lapland belt (CLB) in northern Finland, represent two types of orogenic gold mineralization that dominate the CLB: (1) Au-only and (2) Au with atypical metal association, respectively. In this study, we compare these deposits in order to pinpoint the origin of differences in their metal associations. The pyrite-rich Hirvilavanmaa and the pyrrhotite- and chalcopyrite-rich Naakenavaara deposits are hosted primarily by ultramafic metavolcanic and metasedimentary rocks respectively. Similarities in the deposits include pre-ore albitization of host rocks and ore mineralization-related carbonate and chlorite alteration and quartz‑carbonate veins. Ore-related sericite and biotite alteration is prominent only at Naakenavaara. Pyrite and chalcopyrite from the two deposits have a distinct trace element geochemistry; pyrrhotite from Naakenavaara hosts significant Co and Ni concentrations. At Hirvilavanmaa, three pyrite generations with distinct Co/Ni ratios represent the gradual evolution of ore deposition. Hirvilavanmaa can be confidently classified as an orogenic Au deposit with evidence pointing to a mafic metavolcanic rock source for the ore-forming components. At Naakenavaara, our results reveal a complex evolution involving two distinct but spatially coincident mineralizing events. The earliest base metal-rich event started as Co-rich and gradually developed into the main Cu-rich stage; two pyrite types (mean Co/Ni ratios of 12.5 and 762 respectively) are associated with these stages. Subsequently ore zones were overprinted locally by an orogenic Au event that deposited pyrite with low Co/Ni ratios (mean of 0.3). The presence of late gold deposition overprinting earlier base metal-rich ore fits with observations from other base metal‑gold deposits from northern Finland.

Geochemistry, Lu–Hf garnet ages, and P–T conditions of blueschists from the Meliatic and Fatric nappes, Western Carpathians: Indicators of Neotethyan subduction

Basaltic rocks from ophiolitic mélanges provide information on geodynamic setting, origin, and later tectonometamorphic conditions. This paper resolves the P–T conditions and timing of high-pressure metamorphism in an accretionary wedge that formed during the Late Jurassic closure of the Neotethyan Meliata Basin. Blueschist-facies metabasites of the Meliatic Bôrka Nappe and the Albian conglomerate pebbles of the Fatric Klape Nappe contain rare assemblages of garnet in association with glaucophane, phengite, rutile, and epidote (±albite). Here, we compare a Lu–Hf garnet age from the Meliatic Bôrka Nappe in the southern margin of the Inner Western Carpathians (IWC) with a garnet age from inferred Meliatic blueschists of the Klape Nappe overlying the IWC northern margin. The Hačava type locality of the Bôrka Nappe hosts calc-alkaline type metabasite (∼VAB-C; εNd(245) = +0.9) embedded within Middle to Upper Triassic marbles of the Neotethyan Meliata Basin northern continental margin. The investigated Klape Nappe island arc tholeiite (∼VAB-T; εNd(240) = +5.9) blueschist pebble, and associated deepwater metasedimentary rock pebbles were found in a conglomerate layer of unmetamorphosed Albian flysch. The garnet ages of 153.95±0.69 Ma and 152.1±1.5 Ma correspond to closure of the Meliata Basin during southward intraoceanic and continental margin subduction. This was followed by the exhumation of HP blocks in serpentinite mélange and the formation of an accretionary wedge with included anchimetamorphosed Jurassic flysch. The P–T conditions of the blueschists were constrained by Perple_X modelling to be 520°C and 1.55 GPa for the Bôrka Nappe, and 490–510°C and 1.68–1.72 GPa for a pebble from the Klape Nappe conglomerate. The similarity of garnet dates and metamorphic conditions between the two samples suggest that the blueschists formed during the Late Jurassic Meliatic subduction. The north-vergent Meliatic nappes are the inferred source of the Albian flysch conglomerates deposited in the foreland Fatric Basin. This material was subsequently transported by the Fatric Klape Nappe to the IWC orogenic front during the Turonian, following the closure of the Fatric Basin.

Deciphering the tectonometamorphic history of subducted metapelites using quartz‐in‐garnet and Ti‐in‐quartz (QuiG–TiQ) geothermobarometry—A key for understanding burial in the Scandinavian Caledonides

AbstractThe Seve Nappe Complex is a subduction‐related high‐grade metamorphic unit that was emplaced onto the margin of Baltica during Caledonian orogenesis. In this paper, the tectonometamorphic evolution of the Lower Seve Nappe in the Scandinavian Caledonides was characterized with the help of the continuous Collisional Orogeny in the Scandinavian Caledonides (COSC‐1) drill core, using a combination of various P–T estimation techniques based on garnet–quartz mineral pairs (quartz‐in‐garnet and Ti‐in‐quartz [QuiG–TiQ]), conventional thermobarometry and thermodynamic modelling of phase equilibria. This multi‐method approach yields complementary results and delivers critical data to constrain a comprehensive pressure–temperature–deformation–time (P–T–D–t) evolutionary path for the metasedimentary rocks of the Lower Seve Nappe. In the garnetiferous metasedimentary rocks, quartz inclusions in garnet preserve the P–T conditions of three distinct garnet growth stages corresponding to three metamorphic stages Ms1 to Ms3, including prograde and peak metamorphic conditions. Ms1 and Ms2 stages were constrained via quartz inclusions in garnet core and mantle. They are relatively close in the P–T space and could be considered as one single continuous prograde event occurring at epidote–amphibolite facies conditions of 460–520°C and 0.6–0.85 GPa. The growth of the garnet outermost rim defines the Ms3 stage at amphibolite facies conditions of 590–610°C and 1.13–1.18 GPa and corresponds to the peak metamorphic conditions. The microstructural analysis shows that the finite ductile strain pattern of the Lower Seve Nappe results from the superposition of four deformation phases. The initial phase D1 is defined by the S1 foliation that is still preserved as a curved inclusion trail in the garnet core. The D2 phase initiated contemporaneously with garnet core growth and the development of muscovite–biotite–plagioclase S2 foliation. Garnet outermost rim growth marks the end of the prograde path and peak metamorphic conditions. This stage is overprinted by the D3 phase and Ms4 stage associated with the development of the main regional metamorphic and mylonitic fabric S3 associated with C′‐type shear bands along the retrograde path. Ms4 stage, which was constrained using traditional thermobarometric techniques, corresponds to the chemical re‐equilibration of the metasedimentary minerals and occurred under amphibolite facies conditions at ~570–610°C and 0.78–1.00 GPa. The D3 phase is then generally weakly to strongly overprinted by later lower grade deformation D4 phase at greenschist facies conditions (Ms5). 40Ar/39Ar ages of syn‐kinematic white mica and biotite indicate that the final stage of the thrusting of the Lower Seve Nappe and thus the timing of its emplacement onto the Offerdal Nappe occurred at c. 423 Ma. Collectively, these results are consistent with previous estimates of the timing and conditions of metamorphism derived from the Lower Seve Nappe especially in west‐central Jämtland. However, application of QuiG–TiQ thermobarometry demonstrated that quartz inclusions in garnet can preserve different aspects of garnet growth, which are not accessible by traditional methods especially in complex terranes, and therefore provided new significant insights into the Lower Seve prograde evolution.

Geological framework of the concealed East Tennant area constrained by SHRIMP U–Pb zircon geochronology: Implications for Paleoproterozoic stratigraphic correlations in northern Australia

The fundamental geological framework of the concealed Paleoproterozoic East Tennant area of northern Australia is very poorly understood, despite its relatively thin veneer of Phanerozoic cover and its position along-strike from significant Au–Cu–Bi mineralisation of the Tennant Creek mining district within the outcropping Warramunga Province. We present 18 new U–Pb dates, obtained via Sensitive High Resolution Ion Micro Probe (SHRIMP), constraining the geological evolution of predominantly Paleoproterozoic metasedimentary and igneous rocks intersected by 10 stratigraphic holes drilled in the East Tennant area. The oldest rocks identified in the East Tennant area are two metasedimentary units with maximum depositional ages of ca. 1970 Ma and ca. 1895 Ma respectively, plus ca. 1870 Ma metagranitic gneiss. These units, which are unknown in the nearby Murphy Province and outcropping Warramunga Province, underlie widespread metasedimentary rocks of the Alroy Formation, which yield maximum depositional ages of 1873–1864 Ma. While parts of this unit appear to be correlative with the ca. 1860 Ma Warramunga Formation of the Warramunga Province, our data suggest that the bulk of the Alroy Formation in the East Tennant area is slightly older, reflecting widespread sedimentation at ca. 1870 Ma. Throughout the East Tennant area, the Alroy Formation was intruded by voluminous 1854–1845 Ma granites, contemporaneous with similar felsic magmatism in the outcropping Warramunga Province (Tennant Creek Supersuite) and Murphy Province (Nicholson Granite Complex). In contrast with the outcropping Warramunga Province, supracrustal rocks equivalent to the 1845–1810 Ma Ooradidgee Group are rare in the East Tennant area. Detrital zircon data from younger sedimentary successions corroborate seismic evidence that at least some of the thick sedimentary sequences intersected along the southern margin of the recently defined Brunette Downs rift corridor are possible age equivalents of the ca. 1670–1600 Ma Isa Superbasin. Our new results strengthen ca. 1870–1860 Ma stratigraphic and ca. 1850 Ma tectono-magmatic affinities between the East Tennant area, the Murphy Province, and the mineralised Warramunga Province around Tennant Creek, with important implications for mineral prospectivity of the East Tennant area.