Abstract Porous material batteries are a new type of battery technology that uses porous materials as electrode materials, with advantages such as long lifespan. In the present study, we manily propose a space-time meshfree method for heat transfer problems in porous material energy storage battery. The thermal behavior is demonstrated based on a numerical solution of the energy conservation equation. A simple space-time meshless collocation scheme, which is based on a new type space-time radial basis function, is presented to get the approximate solution of the energy conservation equation. The energy conservation equation was transferred into a system of linear algebraic equations. By introducing prescribed boundary conditions, the heat transfer analysis in porous material energy storage battery can be shown with numerical results. Numerical discussions show that the proposed meshless collocation method is appropriate to simulate thermal behavior in porous material energy storage battery, while the traditional finite element method failed to provide the reasonable results for the tested examples in this paper.