A simple procedure was developed for the direct determination of As(III) and As(V) in water samples by flow injection hydride generation atomic absorption spectrometry (FI–HG–AAS), without pre-reduction of As(V). The flow injection system was operated in the merging zones configuration, where sample and NaBH 4 are simultaneously injected into two carrier streams, HCl and H 2O, respectively. Sample and reagent injected volumes were of 250 μl and flow rate of 3.6 ml min −1 for hydrochloric acid and de-ionised water. The NaBH 4 concentration was maintained at 0.1% (w/v), it would be possible to perform arsine selective generation from As(III) and on-line arsine generation with 3.0% (w/v) NaBH 4 to obtain total arsenic concentration. As(V) was calculated as the difference between total As and As(III). Both procedures were tolerant to potential interference. So, interference such as Fe(III), Cu(II), Ni(II), Sb(III), Sn(II) and Se(IV) could, at an As(III) level of 0.1 mg l −1, be tolerated at a weight excess of 5000, 5000, 500, 100, 10 and 5 times, respectively. With the proposed procedure, detection limits of 0.3 ng ml −1 for As(III) and 0.5 ng ml −1 for As(V) were achieved. The relative standard deviations were of 2.3% for 0.1 mg l −1 As(III) and 2.0% for 0.1 mg l −1 As(V). A sampling rate of about 120 determinations per hour was achieved, requiring 30 ml of NaBH 4 and waste generation in order of 450 ml. The method was shown to be satisfactory for determination of traces arsenic in water samples. The assay of a certified drinking water sample was 81.7±1.7 μg l −1 (certified value 80.0±0.5 μg l −1).