Shape Memory Research Articles

In vitro evaluation of the biocompatibility and bioactivity of a SLM-fabricated NiTi alloy with superior tensile property

Because nickel-titanium (NiTi) alloys have unique functions, such as superelasticity, shape memory, and hysteresis similar to bone in the loading-unloading cycles of their recoverable deformations. They likely offer good bone integration, a low loosening rate, individual customization, and ease of insertion. Due to the poor processability of NITI, traditional methods cannot manufacture NiTi products with complex shapes. Orthopedic NiTi implants need to show an adequate fracture elongation of at least 8%. Additive manufacturing can be used to prepare NiTi implants with complex structures and tunable porosity. However, as previously reported, additively manufactured NiTi alloys could only exhibit a maximum tensile fracture strain of 7%. In new reports, a selective laser melting (SLM)–NiTi alloy has shown greater tensile strain (15.6%). Nevertheless, due to the unique microstructure of additive manufacturing NiTi that differs from traditional NITI, the biocompatibility of SLM-NITI manufactured by this new process requires further evaluation In this study, the effects of the improved NiTi alloy on bone marrow mesenchymal stem cell (BMSC) proliferation, adhesion, and cell viability were investigated via in vitro studies. A commercial Ti-6Al-4V alloy was studied side-by-side for comparison. Like the Ti-6Al-4V alloy, the SLM-NiTi alloy exhibited low cytotoxicity toward BMSCs and similar effect on cell adhesion or cell viability. This study demonstrates that the new SLM-NiTi alloy, which has exhibited improved mechanical properties, also displays excellent biocompatibility. Therefore, this alloy may be a superior implant material in biomedical implantation.Graphical

Aqua jet integrated fiber laser machining of quaternary NiTiCuZr alloy

ABSTRACT Low thermal diffusivity of NiTi-based smart alloy results in concentrated heat accumulation during laser beam machining which rises to adverse thermal effects like heat-affected zones, residual stresses, and alterations in microstructure of shape memory alloy (SMA) system. The addition of Cu and Zr can reduce the thermal hysteresis in the phase transformation of NiTi SMAs. Minimizing thermal hysteresis is desirable in SMA applications where precise control of the phase transformation temperatures is required, such as in actuators, sensors, and medical devices. Therefore, aqua jet integrated laser (AJ-FLBM) machining is a suitable choice for smart materials that need to be machined with high precision and low heat affected zone. In this current research, the NiTiCuZr SMA is machined using AJ-FLBM to investigate the effects of process variables on surface characteristics measured using RSM-BBD approach. The surface quality was enhanced by 68.93% with a gradual decrease in laser power (P), cutting speed (CS), and an increase in frequency (F). Aqua jet integrated FLBM technique may reduce heat affected zone due to the removal of heat in areas near the cutting location. This was confirmed by the DSC test which reveals that optimal machining inputs do not alter shape memory properties.

Facile Lithographic Fabrication of Closed‐Loop Reentrant Micromesh via Shape Memory Effect‐Induced Suspension for Robust Liquid‐Repellency

Facile Lithographic Fabrication of Closed‐Loop Reentrant Micromesh via Shape Memory Effect‐Induced Suspension for Robust Liquid‐Repellency

A Visualized Microstructure Evolution Model Integrating an Analytical Cutting Model with a Cellular Automaton Method during NiTi Smart Alloy Machining

In this study, a visualized microstructure evolution model for the primary shear zone during NiTi smart alloy machining was established by integrating an analytical cutting model with a cellular automaton method. Experimental verification was conducted using an invented electromagnet rotation-type quick-stop device. The flow stress curve during the dynamic recrystallization of the NiTi smart alloy, the influence of relevant parameters on the dynamic recrystallization process, and the distribution of dynamic recrystallization in the primary shear zone were studied via the model. The simulation results showed that strain rate and deformation temperature significantly affect the relevant parameters during the dynamic recrystallization process. Three typical shear planes were selected for a comparison between simulation results and experimental results, with a minimum error of 3.76% and a maximum error of 11.26%, demonstrating that the model accurately simulates the microstructure evolution of the NiTi smart alloy during the cutting process. These results contribute theoretical and experimental insights into understanding the cutting mechanism of the NiTi smart alloy.

Surface modification of NiTi alloy by ion and gas cluster ion irradiation. The role of chemical segregation

Nitinol is an alloy of roughly equiatomic nickel and titanium, having shape memory and widely used in many applications, such as aerospace, automotive, biomedical and others. One of techniques for its treatment is plasma or ion beam irradiation. In the work we investigated surface composition and topography of the alloy formed by ion and cluster ion bombardment. A strong enrichment of the surface with nickel is detected, which does not agree with contemporary ideas about preferential sputtering. The results were compared with other known results in the area, and the processes occurring under ion irradiation of compound materials were discussed. The role of ambient oxygen in the steady state surface composition establishing is described.

SMST 2024: Shape Memory and Superelastic Technologies Conference and Exposition

SMST 2024: Shape Memory and Superelastic Technologies Conference and Exposition

Dynamic Covalent Bond-Based Polymer Chains Operating Reversibly with Temperature Changes.

Dynamic bonds can facilitate reversible formation and dissociation of connections in response to external stimuli, endowing materials with shape memory and self-healing capabilities. Temperature is an external stimulus that can be easily controlled through heat. Dynamic covalent bonds in response to temperature can reversibly connect, exchange, and convert chains in the polymer. In this review, we introduce dynamic covalent bonds that operate without catalysts in various temperature ranges. The basic bonding mechanism and the kinetics are examined to understand dynamic covalent chemistry reversibly performed by equilibrium control. Furthermore, a recent synthesis method that implements dynamic covalent coupling based on various polymers is introduced. Dynamic covalent bonds that operate depending on temperature can be applied and expand the use of polymers, providing predictions for the development of future smart materials.

Shape memory polymer composite hinges for solar sails

Smart hinges for self-deployable solar sails have been prototyped by using shape memory polymer composites (SMPCs). During hinge lamination, a shape memory (SM) epoxy resin is deposited between carbon fiber reinforced (CFR) plies, and consolidation is obtained by an out-of-autoclave (OOA) process. The smart hinges have been assembled with CFR booms to prototype a small self-deployable square sail. Polymeric supports, made by fused deposition modelling (FDM), have been added for correct assembly and to drive the recovery of the SMPC hinges. Flexible heaters have been used as heating elements for SMPC hinge activation. The sail consisted of a polyimide membrane which was connected with the composite booms by flexible joints. The solar sail prototype size has been limited to 260 × 260 mm2 for on-Earth testing, with 4 hinges at the middle length of the composite booms. Recovery tests have shown the ability of the smart hinges to overcome the sail weight and additional friction forces, and the small sail has been successfully deployed in laboratory. Full recovery has been achieved in less than 3 min under different configurations.

A Novel Technique for Improving Cyclic Behavior of Steel Connections Equipped with Smart Memory Alloys.

Residual drifts are an important measure of post-earthquake functionality in bridges and buildings, and can determine whether the structure remains fit for its intended purpose or not. This study aims at investigating numerically, through finite element (FE) analysis in ABAQUS, the cyclic response of exterior steel I beam-hollow column connection using welded shape memory alloys (SMA) bolts and seat angles. This is followed by validating the numerical model using an accredited experimental data available in the literature through different techniques, (1) SMA bolts, (2) SMA angles, (3) SMA bolts and angles. The parameters investigated included: SMA type, SMA angle thickness, SMA bolt diameter, SMA angle stiffener and SMA angle direction. The cyclic performance of the steel connection was enhanced further by varying the bolt diameter, plate thickness, angle type and direction. The results revealed that the connections equipped with a combination of SMA plates and SMA angles reduced the residual drift by up to 94%, and doubled the self-centering capability compared to conventional steel connections. Moreover, the parametric analysis showed that Fe-based SMA members could be a good alternative to NiTi based SMA members for improving the self-centering capability and reducing the residual drifts of conventional steel connections.

Preparation and Properties of Multi-Responsive Liquid Crystalline Poly(urethane-acrylate)s and Its Composite Membranes.

In this work, a kind of side chain liquid crystalline poly(urethane-acrylate)s was synthesized by free polymerization based on self-made liquid crystalline monomers, and a series of liquid crystalline polyurethane/shape memory polyurethane composite membranes were prepared by electrospinning. The synthesized liquid crystalline poly(urethane-acrylate)s have excellent thermal stability. Due to the regular arrangement of azobenzene on the side chains, polymers can rapidly undergo a photoinduced transition from trans-isomerism to cis-isomerism in THF solution and restore reversible configurational changes under visible light. The composite membranes prepared by electrospinning can also undergo photoinduced deformation within 6 s, and the deformation slowly returns under visible light. Meanwhile, the composites have shape memory, and after deformation caused by stretching, the membranes can quickly recover their original shape under thermal stimulation. These results indicate that the composites have triple response performances of photoinduced deformation, photo-, and thermal recovery.

A Processible and Ultrahigh‐temperature Organic Photothermal Material through Spontaneous and Quantitative [2+2] Cycloaddition–Cycloreversion

AbstractEnergy conversion, particularly light to heat conversion, has garnered significant attention owing to its prospect in renewable energy exploitation and utilization. Most previous efforts have focused on developing organic photothermal materials for low‐temperature applications, whereas the importance of simplifying the preparation methods of photothermal materials and enhancing their maximum photothermal temperature have been less taken. Herein, we prepare an organic near‐infrared (NIR) photothermal material namely ATT by a spontaneous [2+2] cycloaddition‐cycloreversion reaction. In addition to the solution‐based method, ATT could also be readily preapred by ball milling in a high yield of 90 % in just 15 min. ATT powder exhibits a broad absorption extending beyond 2000 nm, excellent processability, and thermal stability. Remarkably, ATT powder can reach an unprecedently temperature as high as 450 °C while maintaining excellent photostability upon photoirradiation. Leveraging its extraordinary photothermal and processable properties, ATT was used in the high‐temperature applications, such as photo‐ignition, photo‐controlled metal processing and high‐temperature shape memory, all of which offer spatiotemporal control capabilities. This work provides a new approach to prepare organic photothermal materials with high temperatures, and pave the way for their applications in extreme environments.

Correction to “Heat‐responsive shape memory Eucommia ulmoides gum composites reinforced by zinc dimethacrylate”

Correction to “Heat‐responsive shape memory <i>Eucommia ulmoides</i> gum composites reinforced by zinc dimethacrylate”

Patterned Photonic Actuators with Dynamic Shape‐Morphing and Color‐Changing Capabilities Fabricated by Athermal Embossing Technology

AbstractStimuli‐responsive patterned photonic actuators, characterized by their patterned nano/microscale structures and capacity to demonstrate synergistic color changes and shape morphing in response to external stimuli, have attracted intense scientific attention. However, traditional patterned photonic actuator systems still face limitations such as cumbersome and time‐consuming preparation processes and small‐scale deformations. Herein, we introduce a facile approach involving an athermal embossing technique to rapidly fabricate patterned photonic actuators based on near‐infrared (NIR) light‐responsive liquid crystal elastomers. The resulting patterned photonic actuators demonstrate remarkable features, including brilliant angle‐dependent structural color, complex three‐dimensional actuation, and good color durability under NIR light stimulation. As illustrative demonstrations of the proof‐of‐concept, we fabricate two light‐fuelled patterned photonic soft actuators: a butterfly‐inspired actuator that can produce wing‐flapping dynamic changes in structural color, and an origami crane‐shaped actuator with shape memory, structural color information storage, and dynamic display properties. This strategy provides distinct insights into the design and fabrication of various patterned photonic soft robotic devices and intelligent actuators.

Patterned Photonic Actuators with Dynamic Shape-Morphing and Color-Changing Capabilities Fabricated by Athermal Embossing Technology.

Stimuli-responsive patterned photonic actuators, characterized by their patterned nano/microscale structures and capacity to demonstrate synergistic color changes and shape morphing in response to external stimuli, have attracted intense scientific attention. However, traditional patterned photonic actuator systems still face limitations such as cumbersome and time-consuming preparation processes and small-scale deformations. Herein, we introduce a facile approach involving an athermal embossing technique to rapidly fabricate patterned photonic actuators based on near-infrared (NIR) light-responsive liquid crystal elastomers. The resulting patterned photonic actuators demonstrate remarkable features, including brilliant angle-dependent structural color, complex three-dimensional actuation, and good color durability under NIR light stimulation. As illustrative demonstrations of the proof-of-concept, we fabricate two light-fuelled patterned photonic soft actuators: a butterfly-inspired actuator that can produce wing-flapping dynamic changes in structural color, and an origami crane-shaped actuator with shape memory, structural color information storage, and dynamic display properties. This strategy provides distinct insights into the design and fabrication of various patterned photonic soft robotic devices and intelligent actuators.

Ethylene-vinyl acetate/poly (propylene carbonate) nanocomposites: effects of graphene oxide on microstructure, shape memory, and mechanical characteristics

Ethylene-vinyl acetate/poly (propylene carbonate) nanocomposites: effects of graphene oxide on microstructure, shape memory, and mechanical characteristics

Microstructural characterization and analysis of nitinol-based self-healing metals matrix composite of A356 alloy produced by high-pressure die casting

A self-healing non-ferrous metal-matrix composite is prepared by the high-pressure die-casting process. It includes casting set-up, sample preparation of metal matrix composite (MMC), microstructural characterization, and analysis of its ability to close the crack. Aluminum alloy (A356) is deployed as a matrix material in the MMC. Nitinol is a smart alloy produced by a combination of Nickel and Titanium in equal mass proportion. Apart from excellent mechanical properties it also exhibits super-elasticity and shape-memory effect. The wire of the Nitinol is integrated as reinforcement within the matrix of A356 alloy through a high-pressure die-casting process. The recovery percentage of the metal matrix composite and microstructural evaluation are reported. The deployment of shape memory wire provides the ability to recover the matrix material even from plastic strain by just heating the sample slightly above the activation temperature of the Nitinol wire. Microstructural evaluation indicates fair integration of the reinforcement within the matrix material. Gaining the ability for 30.27% angular restoration and 19.37% crack closer is a very positive sign for designing self-healing metallic materials.

Development of a fishbone camber morphing airfoil actuated by SMA wires

This paper investigates the design and aerodynamic efficiency of a bio-inspired variable camber morphing airfoil featuring NACA0012 ribs with a deformable fishbone trailing edge. The deformation mechanism uses smart memory alloy wires arranged on the ribs to deflect the trailing edge upwards or downwards based on the set of wires actuated. Experimental validation of the designed system demonstrates two distinct angles up to 30 degrees. Subsequent aerodynamic investigations were conducted to compare the performance of the morphing trailing edge concept with conventional flap configurations. Results indicate a notable aerodynamic efficiency, surpassing conventional flap designs by more than double at a deflection angle equal to 24 degrees.

Ferroelasticity in Two-Dimensional Hybrid Ruddlesden-Popper Perovskites Mediated by Cross-Plane Intermolecular Coupling and Metastable Funnel-like Phases.

Ferroelasticity is a phenomenon in which a material exhibits two or more equally stable orientation variants and can be switched from one form to another under an applied stress. Recent works have demonstrated that two-dimensional layered organic-inorganic hybrid Ruddlesden-Popper perovskites can serve as ideal platforms for realizing ferroelasticity, however, the ferroelastic (FE) behavior of structures with a single octahedra layer such as (BA)2PbI4 [BA = CH3(CH2)3NH3+] has remained elusive. Herein, by using a combined first-principles and metadynamics approach, the FE behavior of (BA)2PbI4 under mechanical and thermal stresses is uncovered. FE switching is mediated by cross-plane intermolecular coupling, which could occur through multiple rotational modes, rendering the formation of FE domains and several metastable paraelastic (PE) phases. Such metastable phases are akin to wrinkled structures in other layered materials and can act as a "funnel" of hole carriers. Thermal excitation tends to flatten the kinetic barriers of the transition pathways between orientation variants, suggesting an enhanced concentration of metastable PE states at high temperatures, while halogen mixing with Br raises these barriers and conversely lowers the concentration of PE states. These findings reveal the rich structural diversity of (BA)2PbI4 domains, which can play a vital role in enhancing the optoelectronic properties of the perovskite and raise exciting prospects for mechanical switching, shape memory, and information processing.

Bioinspired on-off switchable multi-level responsiveness for ultralong fire-warning, super-sensitive solvent/humidity and light-driven behaviors

The prospects of endowing the omnipresent hazardous substances with sensitive, safe, and stable life-like behaviors poses significant for the development of on–off switchable smart materials. Herewith, based on material-structural synergistic design, a multi-level responsiveness smart structures (VBGO) inspired by phospholipid biomolecules is self-assembled through asymmetric swelling and smart supramolecular nano-structures. Due to the outstanding sensitive of fire-warning nano-hybrid of functionalized cyclodextrin-graphene and highly stable substrate of vermiculite, the designed VBGO exhibits the high-sensitively fire alarm time (only 0.17 s) and super-along sustained fire alarm time (up to 249 s). Moreover, the VBGO displays significant increment in thermal stability and film-forming properties. Besides, given the asymmetrical and self-assembled smart structures, the VBGO exhibits the unique fast responses in their surrounding environments like fire, heat, light, humidity, and solvent vapor. Additionally, the on–off switchable mechanisms of fire-warning responsiveness, solvent-/humidity-/light-driven, shape memory and environmental awareness are presented systematically. This work introduces a sensitive, safe, and stable approach to designing multi-level responsive smart materials by modifying fire-warning bioinspired structures.

An approach to describe the twinning and detwinning processes of the martensitic structure in ferromagnetic alloy with shape memory in magnetic and force fields

In the article, based on the theory of micromagnetism, a special case of the moment theory of elasticity for an anisotropic material and the Hadamard compatibility condition for deformations, a microstructural model of the behavior of the Heusler alloy with shape memory in magnetic and force fields is constructed. The dynamics of the magnetic process is described by the Landau-Lifshitz-Gilbert equation. Using the Galerkin procedure, variational equations corresponding to the differential relations of the magnetic problem are written out and the finite element method is used for numerical realization of these equations. Considering the problems of the moment theory of elasticity we come to a special case of this theory in which, under the action of force and magnetic fields, the tensor of moment stresses initiated only by the magnetic field is zero. Using this result, the general expression for the state equation is constructed that describes, within the framework of small deformations, the behavior of an anisotropic material under force and magnetic influences. The stress tensor in this equation consists of a symmetric part and a skew-symmetric part, depending only on the magnetic field. For the problem of deformable solid mechanics with such a state equation, the Lagrange variational equation was constructed, which made it possible to reduce the requirements for the smoothness of the desired solution by an order of magnitude. The general expression for the state equation has been concretized for an anisotropic material having one axis of symmetry of the fourth order and two axes of symmetry of the second order. The solution of the Hadamard compatibility equation for deformations made it possible to determine the sliding surfaces and sliding directions in a tetragonal crystal cell of a ferromagnetic material in the martensitic state, along which a shift occurs, leading to the appearance and dissipation of a twinned structure. The microstructural model, constructed using all these positions, is used to describe experimental results on the combined action of magnetic and force fields on the Heusler alloy.