An inkjet printing process has been suggested for producing nylon 6 in an additive manufacturing approach and this paper reports on the jettability of molten reactive materials made by caprolactam with activator and catalyst to study the feasibility of the approach in an inkjet system. The materials physical properties which are important for jetting were characterized and then the melt supply behaviour in the system was studied and finally jetting trials were monitored to investigate the effect of parameter settings on the stability of the jet array. It was found that the surface tension and viscosity of all materials were within the suitable range. However, with the catalyst mixtures, microcrystals of the undissolved salt of the catalyst complex were found to influence the melt supply behaviour considerably. The mixtures had a narrower range of parameters where stability occurred compared with caprolactam. Monitoring the jet stability recommended a suitable range of jetting parameters for the deposition stage of researching the new approach. A higher level of instability was observed with the catalyst mixture especially when jetting with multiple nozzles due to the microcrystals.
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