Melt-mantle Interaction Research Articles

A 187Re-187Os and highly siderophile element study of diamondiferous kimberlite melt-mantle interactions and the inferred age of continental lithosphere

The ∼ 1.15-billion-year-old (Ga) Premier kimberlite pipe (Cullinan diamond mine), South Africa, is composed of several distinct kimberlite facies (Grey, Brown, Pale Piebald, Dark Piebald, Black Coherent [Type 3C], Blue/Brown Transitional, and Fawn). We report bulk rock Re-Os isotope data for Premier kimberlite facies, as well as for a suite of entrained peridotite and mafic xenoliths. These data are complemented by bulk rock highly siderophile element (HSE: Re, Pd, Pt, Ru, Ir, Os), major- and trace-element abundances. Measured 187Os/188Os for the kimberlite facies range from 0.1223 to 0.1672 (ΥOsi of −2.5 to + 17.4), peridotite xenoliths range from 0.1096 to 0.1244 (ΥOsi of −13.3 to −1.1), and pyroxenite xenoliths range from 0.1796 to 0.938 (ΥOsi of + 27 to + 419). A single measured amphibolite xenolith has the most radiogenic measured 187Os/188Os of 2.86 (ΥOsi of + 43). Harzburgite xenoliths yield time of rhenium depletion model ages (TRD) of ∼ 1.5 to 2.8 Ga, consistent with average TRD ages for Premier peridotites (2.4 ± 0.4 Ga). With these and published data, we considered the relationships between kimberlite and mantle xenoliths, compare estimates of relative peridotite incorporation to sampled diamond grade, and explore recratonization versus refertilization arguments with regards to TRD model ages. Kimberlite melt infiltration into Premier peridotite xenoliths is evident from melt veins accounting for ∼ 2 and ∼ 14 modal % of samples, and has led to incompatible element enrichment, including elevated Re. In turn, kimberlites show geochemical evidence for addition of peridotite xenolith fragments, with Type 3C having > 30 % more peridotite contribution than the Brown volcaniclastic facies. Kimberlites and peridotites plot on a 187Re/188Os versus 187Os/188Os mixing line (R2 = 0.92), with kimberlites having older apparent ages than the true age of crystallization. This mixing line provides estimates of lithospheric incorporation into the kimberlites, where the units with higher peridotite incorporation do not correlate with diamond grade. This is likely due to lithological and post-emplacement alteration heterogeneity within the kimberlite units, perhaps also reflecting the eclogitic paragenesis of many Premier diamonds. The peridotites provide evidence for the nature of the lithosphere beneath Premier prior to ∼ 1.15 Ga. Metasomatism of the peridotites is possibly linked to the Bushveld Igneous Event at ∼ 2 Ga, as well as to other magmatic events that affected the Kaapvaal craton from the Archean to the Mesoproterozoic. Premier peridotites do not suggest that the cratonic lithosphere beneath the region was completely replaced. Samples with Proterozoic TRD eruption model ages may represent Archean lithosphere that experienced alteration by metasomatism and modification, such as during the Bushveld Igneous Event.

Why are oceanic arc basalts Ca-rich and Ni-poor? Insights from olivine-hosted melt inclusions from Kibblewhite Volcano in the Kermadec arc

Ankaramites, which are clinopyroxene-rich basalts with primitive whole-rock compositions (Mg# >65), are common in oceanic arcs and are characterized by high whole-rock CaO/Al2O3 (>1.0) ratios and olivine crystals with anomalously low nickel contents (<0.2 wt% NiO). These geochemical characteristics cannot be explained by the melting of ordinary mantle peridotite. However, their origin is critical for understanding the formation of primary magmas in oceanic arcs. Here, we investigated olivine-hosted melt inclusions (MIs) from ankaramites and magnesian andesites of the Kibblewhite Volcano in the Kermadec arc. The MIs from the ankaramites have similar major and trace element characteristics to the host rocks, indicating that the ankaramites did not result from an accumulation of mafic minerals but rather represent the primary magma in the Kibblewhite Volcano. The MIs from the magnesian andesites were hosted in forsteritic olivine xenocrysts with a wide range of NiO contents (Fo90–92; 0.13–0.39 wt% NiO) and have similar major element compositions to the ankaramites but exhibit a wide range of CaO/Al2O3 (0.85–1.54). The trace element characteristics of the MIs from the magnesian andesites do not match those of the host rocks, indicating that they are not primary melts of the magnesian andesites but primitive basaltic melts generated before the magnesian andesites formed.Interestingly, the CaO/Al2O3 ratio of MIs from the magnesian andesites was negatively correlated with the NiO content of their host olivines. This correlation suggests that the composition of the primary basaltic magmas of the Kibblewhite Volcano changed continuously from peridotite-derived to ankaramitic. This correlation could not be explained by grain-scale process, crustal anatexis, or contribution of slab-derived carbonate-rich fluids. Instead, we propose that this correlation can be explained by the interaction of the ascending primary basaltic melts with the lithospheric mantle. During melt-mantle interaction, the assimilation of clinopyroxene and fractionation of olivine and orthopyroxene caused the CaO/Al2O3 ratio to increase in the melt and the Ni content to decrease. Furthermore, because the magnesian andesites have low CaO/Al2O3 ratios and could be derived from a clinopyroxene-poor mantle lithology, the interaction between the melt and mantle may also be closely related to the origin of the magnesian andesites at Kibblewhite Volcano. This interpretation provides a new perspective on the origin of the oceanic arc ankaramites and why primary andesitic and basaltic magmas coexist in the Kibblewhite Volcano.

Mayodia ophiolitic complex of Arunachal Pradesh, India: a multistage evolutionary record during the Tethyan closure

ABSTRACT The Mayodia ophiolitic complex of Arunachal Pradesh, India is a highly dismembered body located close to the Namche Barwa syntaxis. It structurally represents a klippe and consists dominantly of serpentinite and dunite within which amphibolite and hornblendite occur. Detailed field observations indicate that amphibolites are concordant bodies within serpentinite, whereas hornblendite occurs as dykes. Geochemically, serpentinite samples indicate their abyssal/forearc origin showing refertilisation due to melt-mantle interactions. Massive dunite bodies, occurring as dykes within serpentinites, are replacive in origin and represent fossilized melt channels. The geochemistry of amphibolites is akin to gabbros formed at back-arc basin. Later, serpentinites were severely intruded by hornblendite dykes during the waning stage of back-arc spreading. Finally, the entire litho-package was obducted onto the passive margin of Indian plate as the Mayodia ophiolitic complex which subsequently got folded, deformed and metamorphosed during orogenesis. During this process, the crustal section of the complex was entirely eroded, preserving only the mantle section of this ophiolite.

Multistage and diverse melt-mantle interaction in dunite-harzburgite channel systems beneath oceanic slow-ultraslow spreading centers: Evidence from the Xigaze ophiolite (Tibet)

High-porosity, melt-focusing channel systems (comprising reactive dunite and its surrounding harzburgite) reflect an essential type of melt extraction within the mantle under mid-ocean ridges, proposed mainly by investigations of ophiolites produced in fast-spreading centers. However, relevant melt-migration processes from mantle wall rocks into dunitic channels under slow-ultraslow spreading centers and their effects are less well understood. We present systematic petrographic observations and whole-rock/mineral compositional analyses of a dunite-harzburgite channel system (∼250 m in width) within the Dazhuka mantle section (∼3–4 km thick) of the Xigaze ophiolite (South Tibet), produced in a Neo-Tethyan slow-ultraslow spreading center. The harzburgites, closely surrounding a dunite-rich zone, show large variations in pyroxene/olivine ratios (0.1–0.6), whole-rock MgO (41.2–45.9 wt%), Al2O3 (0.23–1.87 wt%) and CaO (0.38–2.80 wt%), as well as spinel Cr# (molar Cr3+/(Cr3++Al3+), 0.20–0.73) and pyroxene major and trace elements, almost covering the whole ranges of the Xigaze ophiolitic mantle. The harzburgites closer to the dunite-rich zone are gradually more depleted than those further ones, and finally replaced by the most depleted dunites. Modeling of decompressional melting from a depleted-MORB-mantle (DMM) source shows that the harzburgitic compositions correspond to melt depletion degrees of ∼6.9–19.2%, requiring a ∼30-km solely decompressional distance that is much greater than the sampling size of the channel system. It suggests that the wall-rock harzburgites can be produced by the reaction between high-fluxing, silica-undersaturated melts and the least-depleted harzburgites during the formation of reactive dunite-harzburgite channels. In addition, clinopyroxenes in dunites and some harzburgites show metasomatic enrichments, reflected in higher Na2O (up to 0.32 wt%), TiO2 (up to 0.17 wt%) and concentrations of Zr, Hf, light rare earth elements (LREE) and fluid-mobile elements relative to those in other harzburgites. These distinct signatures suggest the later localized metasomatism by batches of basaltic melts (some are volatile-rich) flowing through the harzburgitic wall rocks into the dunite-rich zone. We therefore propose that the dunite-harzburgite channel system archives at least the formation of reactive channels in deep upwelling asthenosphere during the high-melt-flux stage, and the subsequent metasomatic enrichments by basaltic melts reusing the channels in the shallow asthenosphere. The multistage and diverse melt-mantle interaction styles may characterize the melt extraction processes under oceanic slow-ultraslow spreading centers.

Pervasive Neoarchean melting of subducted sediments generating sanukitoid and associated magmatism in the North China Craton, with implications for the operation of plate tectonics

Abstract The Mesoarchean to Neoarchean period (ca. 3.0–2.5 Ga) is the most important stage during the emergence and evolution of plate tectonics. However, plate subduction at this time may have been less stable and perhaps more susceptible to the lubrication effect of sediments than the modern counterpart. Such predictions have not yet been verified by field-based investigations. In this work, we identified two types of rock units (i.e., sanukitoids and associated adakitic suites, exposed in the Eastern Hebei Complex of the North China Craton) and illustrated their petrogenesis and tectonic context through field, geochronologic, geochemical, and isotopic investigations. Laser ablation–inductively coupled plasma–mass spectrometry zircon U-Pb analyses suggest that the two magmatic suites formed within a relatively short time span of ca. 2596–2544 Ma and ca. 2559–2533 Ma, respectively. The sanukitoids are composed of meta-andesites and diorite porphyrites and characterized by relatively high MgO (3.94–5.62 wt%), Mg# (50–61), Cr (73–343 ppm), and Ni (37–111 ppm) values. The adakitic rocks are composed of granodiorite-granite gneisses and have relatively high Sr (316–1001 ppm) and low Y (7–13 ppm) and Yb (0.83–1.37 ppm) contents, and relatively high Sr/Y (36–89) and La/Yb (16–45) ratios. Rocks from both suites exhibit depletions of Nb, Ta, and Ti and have similar Sr-Nd-Hf-Zn isotopes: variable (87Sr/86Sr)i (0.7002–0.7053), weakly positive εNd(t) (+0.3 to +1.7) and εHf(t) (+1.8 to +6.8), and slightly heavy δ66Zn (0.30‰–0.36‰). These geochemical characteristics indicate that the sanukitoids were derived from the melting of subducted sediments followed by melt-mantle interaction, whereas the adakitic rocks were produced by direct partial melting of subducted plate (including tonalite-trondjhemite-granodiorite melts) under a garnet stability field with minor sediments. Such distinct magmatic rock associations, together with the coeval charnockites and tholeiites with diverse compositions in the adjacent area, can be best explained by a slab breakoff model. Further, events associated with slab breakoff are likely to represent a transition of a quasi-plate tectonic regime, characterized by multiple, continuous, and stagnant attempts to start the modern-style subduction on Earth. In addition, the emergence of sanukitoids and associated magmas symbolized the onset of supracrustal recycling into the mantle. Combined with the Nd-Hf-Zn isotopes of diverse magmatic rocks in the North China Craton that are comparable to other Precambrian magmatic rock suites worldwide, we suggest that supracrustal recycling symbolized the onset of plate tectonics since ca. 3.0 Ga, and by inference played a key role in the development of subduction-driven plate tectonics in addition to Earth’s secular cooling.

Petrogenesis of Late Cretaceous gabbronorites in southwestern Lhasa Terrane, Tibetan Plateau, China: Sediment melt-mantle interaction and magmatic flare-up in response to Neo-Tethys slab roll-back

The geodynamic processes responsible for the Late Cretaceous magmatic flare-up in the southern Lhasa Terrane, Tibetan Plateau, have been a matter of debate. In this study, we have reported on newly identified Late Cretaceous gabbronorites in the Dajiacuo Area of the southwestern Lhasa Terrane. These rocks show ophitic textures comprising plagioclase, orthopyroxene, and clinopyroxene, while hydrous minerals, such as amphibole and biotite, are not observed. They display geochemical affinities for high-Mg andesites (HMAs) given their SiO2 (53.5–59.7 wt. %), Mg# (56.8–59.9), and Cr (up to 178 ppm). Combined with their high Th/Yb and low Ba/La ratios and similar Sr–Nd–Hf isotopes to those of the Neo-Tethyan sediments, it is likely that the Dajiacuo gabbronorites were formed by the interaction between sediment-derived melts and the mantle. The Dajiacuo gabbronorites have similar Zr/Hf ratios to the Neo-Tethyan sediments and present no negative Zr–Hf anomalies. This indicates that the zircons in the subducted sediments may have been fully destroyed. This requires specific dynamic conditions to provide a hot subduction geothermal gradient. This is consistent with the high-temperature affinity of the parent magma inferred from Ti-in-zircon thermometry and the presence of orthopyroxene. Based on this, coupled with the synthesis of existing tectonomagmatic data for the southern Tibetan Plateau, we propose that the Late Cretaceous magmatic flare-up in the southern Lhasa Terrane was likely triggered by the roll-back of the northwards subducted Neo-Tethyan lithosphere.

Petrogenesis of late Jurassic Mufushan high-Mg diorites and late Mesozoic tectonic evolution of the eastern South China Block

Abundant Mesozoic magmatic rocks are widely distributed in southeastern China, forming several remarkable magmatic-metallogenetic belts. However, the geodynamic mechanism for the Late Jurassic-Early Cretaceous magmatic processes and their relation to the rich polymetallic deposits of the region remain highly controversial. Here, we report zircon U-Pb ages, geochemistry, and Sr-Nd-Hf-Pb isotopic data for the high-Mg diorites in the Mufushan region, northeastern Hunan Province. The high-Mg diorites were emplaced in the late Jurassic (U-Pb ages of ∼151–155 Ma), contemporaneous with the surrounding granitic rocks which have ages ranging from 140 to 150 Ma. These high-Mg diorites are characterized by the enrichment of large-ion lithophile elements (LILEs, e.g. Ba, Pb, K and Rb) and depletion of high field strength elements (HFSEs, e.g., Nb, Ta, Ti), displaying typical geochemical features of continental-arc basalts (CAB). The relatively high Mg# values (71–76, average of 72), Cr contents (546–1562 ppm, average of 944 ppm) and Ni contents (211–519 ppm, average of 335 ppm) suggest that their derivation was likely from a relatively primitive magma, accompanied with weak crustal assimilation or fractional crystallization.The high-Mg diorites display isotopic characteristics similar to those of enriched mantle-derived mafic rocks, such as low 87Sr/86Sr(i) (0.70692–0.70789), εNd(t) and εHf(t) ranging from −2.4 to −4.3 and −3.8 to + 1.1 respectively, with single-stage Nd model ages (TDM1) of 1.3–1.5 Ga. In combination with a compilation of coeval magmatic rocks in eastern South China, a significant addition of ancient lithospheric mantle materials was likely involved in the Mesozoic magma genesis. The decreasing radiogenic Nd isotope compositions and negative Hf signatures suggest an increasing contribution of enriched components to the magma source from the Late Jurassic to Early Cretaceous. Our results suggest that the Mufushan high-Mg diorites were derived from mantle-derived magma, followed by the incorporation of slab-derived materials into mantle and subsequent sediment melting. Integrated with previous work, the widespread Late Jurassic-Early Cretaceous magmatic rocks in eastern South China formed within a continental back-arc setting that was formed by subduction-induced convection in the mantle wedge. The subsequent roll-back of subducted Paleo-Pacific slab (Izanagi plate) triggered extensive mantle upwelling and melt-mantle interaction, accounting for the production of contemporaneous felsic rocks and related polymetallic deposits in regions.

Continental crust delamination in a retreating subduction zone: A case study in the southern Alxa (Inner Mongolia, China), Central Asian Orogenic Belt

Carboniferous-Permian igneous rocks in the southern Alxa (Inner Mongolia, China) of the southern Central Asian Orogenic Belt exhibit an oceanward migration trend, which provides an ideal area to reconstruct the process of crust-mantle material exchange within a retreating subduction zone. This study presents new geochronological and geochemical data for the Shouji plutons from the southern Alxa to address crust-mantle material exchange process. All these diorite, granodiorite, and K-feldspar granite samples from the Shouji batholith exhibit Early Permian zircon U-Pb ages (ca. 282−270 Ma). These diorite and granodiorite are characterized by high Sr contents as well as low Y, and Yb concentrations, coupled with distinctively high Sr/Y values. They exhibit fertile Nd-Hf isotopic compositions with negative whole-rock εNd(t) values, and zircon εHf(t) values, similar to those of continental crust-related adakites, which might originate from partial melting of lower crust, and followed by melt-mantle interactions. These K-feldspar granite samples display peraluminous and high-K calc-alkaline compositions, and negative zircon εHf(t) and whole-rock εNd(t) values, and originated from partial melting of Paleoproterozoic igneous rocks, with additions of mantle-derived melts in their sources, in low-temperature, low-pressure conditions. Previously published zircon U-Pb age data show that numerous mafic igneous rocks were mostly generated during the Early Permian, marking the onset of mafic volcanism in the southern Alxa. Moreover, compiled detrital zircon U-Pb age data for Late Carboniferous−Permian sedimentary succession imply a regional topographic uplift during the Early Permian. Both of these two lines of evidence suggest an Early Permian lower crustal delamination in the southern Alxa. These Shouji adakitic plutons were most likely to be generated during the lower crustal delamination. Furthermore, Sr-Nd isotope data of Carboniferous-Permian igneous rocks show that the continental crust was recycled back into the mantle during Early Permian within the southern Alxa by means of subduction erosion and lower crustal delamination.

Slab break-off-related magnesian andesites and dacites with adakitic affinity from the early Quaternary Keçiboyduran stratovolcano, Cappadocia province, central Turkey: evidence for slab/sediment melt–mantle interaction and magma mixing

Slab break-off-related magnesian andesites and dacites with adakitic affinity from the early Quaternary Keçiboyduran stratovolcano, Cappadocia province, central Turkey: evidence for slab/sediment melt–mantle interaction and magma mixing

Generation of Nb-enriched mafic rocks and associated adakitic rocks from the southeastern Central Asian Orogenic Belt: Evidence of crust-mantle interaction

Melting of subducting oceanic lithosphere and associated melt-mantle interactions in convergent plate margins require specific geodynamic environment that allows the oceanic slab to be abnormally heated. Here we focus on the Early Mesozoic mafic rocks and granite porphyry, which provide insights into slab melting processes associated with final closure of the Paleo-Asian Ocean. The granite porphyry samples are calc-alkaline and distinguished by high Sr contents, strong depletion of heavy rare earth elements, resulting in high (La/Yb)N and Sr/Y ratios, and negligible Eu anomalies. Based on their high Na2O and MgO, low K2O contents, positive εHf(t) and εNd(t) and low (87Sr/86Sr)i values, we propose that the granite porphyry was likely derived from partial melting of subducting Paleo-Asian oceanic crust. The Nb-enriched mafic rocks are enriched in Rb, Th, U, Pb and K, and depleted in Nb, Ta, Ba, P and Ti, corroborating a subduction-related origin. Their heterogeneous Sr-Nd-Hf-O isotopic compositions and other geochemical features suggest that they were likely derived from partial melting of peridotitic mantle wedge interacted with oceanic slab-derived adakitic melts. Trace element and isotope modeling results and elevated zircon δ18O values suggest variable subducting sediments input into the mantle wedge, dominated by terrigenous sediments. Synthesizing the widely-developed bimodal rock associations, conjugated dikes, thermal metamorphism, tectonic characteristics, paleomagnetic constraints, and paleogeographical evidence along the Solonke-Changchun suture zone, we identify a slab window triggered by slab break-off, which accounts for slab melting and formation of the Nb-enriched mafic rocks and associated adakitic granite porphyry in southeastern Central Asian Orogenic Belt.

Petrogenesis of mantle peridotite and cumulate peridotite rocks from the Nagaland Ophiolite Complex, NE India

Here, we report new geochemical data from mantle peridotite (spinel lherzolite, dunite, and harzburgite) and cumulate peridotite (websterite) rocks from the northernmost portion of the Nagaland Ophiolite Complex. Based on detailed textural, mineral (major element) chemistry, and whole‐rock (major and trace element) chemistry, we reveal the origin of these rocks in different tectonic settings and their modification via the melt–mantle interaction process. The spinel lherzolite rocks with low Cr# (0.16–0.25) chrome spinel are mantle residues formed after low degrees (~10–15%) of partial melting in a mid‐oceanic ridge setting, which has been subsequently modified in a subduction zone setting. However, the dunites and harzburgite samples are interpreted to be depleted mantle residue formed in a supra‐subduction zone (SSZ) setting. Additionally, the dunites are inferred to be of replacive origin representing former harzburgites. Based on Cr# of chrome spinel, the dunites are classified into low Cr# (0.53–0.57), medium Cr# (0.73–0.79), and high Cr# (0.89–0.90) dunites. High Cr# dunite with low‐TiO2 (0.01–0.06 wt%) possibly formed by interaction with a boninitic melt, whereas low‐medium Cr# dunite with high TiO2 (0.14–0.34 wt%) formed by interaction with a high‐Ti melt in an SSZ setting. Harzburgite samples with their highly resorbed orthopyroxene grain boundaries contain chrome spinels (Cr# = 0.84–0.88; TiO2 = 0.00–0.06 wt%) similar to the high Cr# dunite samples and are also interpreted to be formed by interaction with a boninitic melt. The websterite samples with their low Mg# (0.79) olivine and low Ni (345–413 ppm) content are interpreted to be of cumulate origin formed in an SSZ setting. However, the interstitial chrome spinel blebs with low Mg# (0.18–0.19), high Cr# (0.60–0.61), Fe3+ (0.20–0.21), and very high TiO2 (2.03–2.04 wt%) are interpreted to be a result of post‐cumulus interaction of interstitial chrome spinel with high‐Ti intercumulus melt. These mantle peridotites and cumulates of different tectonic origins were obducted and juxtaposed during the final stages of the India‐Asia collision.

Distribution of mantle-melt interaction zone: A petrological exploration tool for podiform chromitite deposits in the Kalaymyo ophiolite, Myanmar

Podiform chromitite deposits in the Kalaymyo ophiolite, Myanmar, are hosted by replacive dunites and harzburgites with varying degrees of mantle-melt interaction. Combining petrography and spinel and whole-rock compositions of harzburgites from the Bophi-Vum area, one of the ultramafic massifs of the Kalaymyo ophiolite, we investigated petrological and geochemical indicators of the mantle-melt interaction in the harzburgites and their spatial relationship with the location of chromitites.Two end-member types of mantle harzburgites with distinct textures and compositions are recognized in the study area. Low-Cr# (Cr-spinel Cr# < 30; Cr# = molar Cr/(Cr + Al) × 100) harzburgites represent residual mantle peridotites after low degree of partial melting. They are characterized by high whole-rock Al2O3, CaO, and TiO2 contents with a negative correlation between spinel Cr# and TiO2 contents, following the partial melting model trend of the depleted mid-ocean ridge basalt (MORB) mantle. The Cr-spinels from the low-Cr# harzburgites are lobate and vermicular and occur in association with orthopyroxenes, which is typical features of residual harzburgites. On the other hand, the high-Cr# (Cr-spinel Cr# > 30) harzburgites mostly have lower whole-rock Al2O3 (< ~1.4 wt%), CaO (< ~1.3 wt%), and TiO2 (< ~0.04 wt%) contents than the low-Cr# harzburgites, indicating lower modal abundances of pyroxenes. The positive correlation between spinel Cr# and TiO2 contents in the high-Cr# harzburgites suggests their metasomatic origin from the interaction between the low-Cr# harzburgite and island-arc tholeiitic or boninitic melts. The Cr-spinels from the high-Cr# harzburgites, recrystallized during the mantle-melt interaction, are mostly euhedral and associated with olivine.Geochemical maps of the spinel Cr#, whole-rock Al2O3, and CaO contents for the mantle harzburgites show that the distribution of the high-Cr# harzburgites, i.e., the mantle-melt interaction zone, is closely associated with the locations of the dunite and chromitite outcrops. This spatial relationship suggests the potential use of the distribution of mantle-melt interaction zone for podiform chromitite exploration in the study area.

Remarkably fresh abyssal peridotites from Sibuyan island, Romblon Island Group, Philippines: Markers of young arc-continent collision

The bulk of Sibuyan island in the Romblon Island Group, Philippines is underlain by remarkably fresh spinel lherzolites, harzburgites and dunites collectively called as the Sibuyan Ultramafics. Based on petrographic and geochemical characteristics, the Sibuyan Ultramafics can be classified into: (1) Group I peridotites composed of spinel lherzolites and harzburgites with spinel Cr# < 0.35, (2) Group II harzburgites and dunites with intermediate spinel Cr# = 0.40–0.65, and (3) Group III dunites with very high spinel Cr# (>0.75). Increase in spinel Cr# is accompanied by decreasing Al2O3 contents and increasing Mg# in the pyroxenes from the Group I to Group II and Group III peridotites. Chondrite-normalized clinopyroxene data revealed various trace-element patterns for the three groups suggestive of different processes (e.g. anhydrous and hydrous melting, mantle-melt interaction) involved in their formation. The Sibuyan Ultramafics is closely associated with the similarly fresh Calaton Hill metamorphic/plutonic complex in Tablas island which is thought to be representative of the lower crust of the Philippine island arc. At a more regional context, the Sibuyan Ultramafics and the Calaton Hill metamorphic/plutonic complex can be used as markers for the young arc-continent collision in western Philippines. Rapid uplift and emplacement due to the collision of the Philippine Mobile Belt and the Palawan Microcontinental Block during the Miocene or even later may have led to the remarkably fresh state of these lithologies. This occurrence is similar to the Horoman peridotite complex in the Hidaka metamorphic belt in Northern Japan. The Sibuyan Ultramafics and the Calaton Hill metamorphic/plutonic complex therefore provide a rare and fresh glimpse into the upper mantle and lower crust in the Philippines due to their young ages of emplacement.

Adakitic rocks at convergent plate boundaries: Compositions and petrogenesis

Adakitic rocks are intermediate-acid magmatic rocks characterized by enrichment in light rare-earth elements, depletion in heavy rare-earth elements, positive to negligible Eu and Sr anomalies, and high La/Yb and Sr/Y ratios. Cenozoic adakitic rocks generated by partial melting of subducted oceanic crust (slab) under eclogite-facies conditions (i.e., the original definition of “adakite”) occur mainly in Pacific Rim volcanic arcs (intra-oceanic, continental, and continental-margin island arcs), whereas those generated by partial melting of thickened lower crust occur mainly in Tethyan Tibetan collisional orogens. In volcanic arcs, adakitic melts derived from the melting of subducted oceanic crust metasomatize the mantle wedge to form a unique rock suite comprising adakite-adakite-type high-Mg andesite-Piip-type high-Mg andesite-Nb-rich basalt-boninite. This suite differs from the basalt-andesite-dacite-rhyolite suite formed from mantle wedge metasomatized by fluids derived from subducted oceanic crust. Previously published data indicate that partial melting of mafic rocks can generate adakitic magmas under pressure, temperature, and hydrous conditions of 1.2–3.0 GPa, 800–1000°C, and 1.5–6.0 wt.% H2O, respectively, leaving residual minerals of garnet and rutile with little or no plagioclase. Cenozoic Au and Cu deposits occur proximally to adakitic rocks, with host rocks of some deposits actually being adakitic rocks. Adakitic rocks thus have important implications for both deep-Earth dynamics and Cu-Au mineralization/exploration. Although studies of Cenozoic adakitic rocks have made many important advances, there remain weaknesses in some important areas such as their tectonic settings, petrogenesis, magma sources, melt-mantle interactions of pre-Cenozoic adakitic rocks, and their relationship with the onset of plate tectonics and crustal growth. Future research directions are likely to involve (1) the generation of adakitic magmas by experimental simulations of partial melting of different types of rock (including intermediate-acid rocks) and magma fractional crystallization at different temperatures and pressures, (2) the relationship between magma reservoir evolution and the formation of adakitic rocks, (3) the tectonic setting and petrogenesis of pre-Cenozoic adakitic rocks and related geodynamic processes, (4) interactions between slab melts and the mantle wedge, (5) the formation of Archean adakitic tonalite-trondhjemite-granodiorite and its link to the onset of plate tectonics and crustal growth, and (6) the relationship between the formation of adakitic rocks and metal mineralization in different tectonic settings.

Tracking the magmatic response to subduction initiation in the forearc mantle wedge: Insights from peridotite geochemistry of the Guleman and Kızıldağ ophiolites, Southeastern Turkey

The initiation of subduction is associated with sequential magmatic responses that lead to the formation of the forearc lithosphere, yet the detailed characteristics of these magmatic activities are not well constrained. Here we use mineral chemistries and bulk-rock trace-element contents of highly-depleted harzburgites from the Guleman and Kızıldağ ophiolites in Southeast Turkey to examine mantle wedge melting dynamics during subduction initiation. We focus on how different components from the subducting slabs potentially contribute to various stages of magmatism throughout the process. Mineral and bulk-rock compositions of these harzburgites are significantly different from those of abyssal peridotites, suggesting that our harzburgites cannot be explained as residues of anhydrous adiabatic melting and melt-rock interaction at mid-ocean ridges alone. This implies that the petrogenesis of SE Turkey harzburgites involves additional processes and components. Harzburgites with the most depleted heavy-rare earth element (HREE) contents are the ones with the highest abundance of strongly incompatible elements, which can be explained by open-system processes where the peridotites in the mantle wedge experienced melting and infiltration of enriched components simultaneously. Open-system dynamic melting models with continuous flux of sediment-derived melts can account for the observed correlation, but are numerically too low compared to the measured values. Based on the observed fractionation between Zr, Hf, and elements with similar incompatibility (middle REEs), we hypothesized the involvement of amphibolite-derived melt and modeled its numerical trace-element contents. Binary mixing between this hypothetical melt and residues of the former open-system model can coherently account for the majority of the obtained trace-element data. This indicates that magmatic events during subduction initiation likely involve multiple components and occur in multiple stages, and that melt-mantle interaction plays a significant role in oceanic forearc lithosphere formation. Based on our model, we suggest the high (Zr/MREE)N signatures in some boninites and depleted harzburgites found in modern forearcs and ophiolites could be inherited from amphibolite-derived melts. Moreover, the existence of slab melts agrees with current constraints on the reconstructed geothermal gradients during subduction initiation based on the petrology and geochemistry of metamorphic soles.

Geochronological and geochemical evidence for a Late Ordovician to Silurian arc–back-arc system in the northern Great Xing’an Range, NE China

The early Paleozoic tectonic evolution of the Xing’an–Mongolian Orogenic Belt is dominated by two oceanic basins on the northwestern and southeastern sides of the Xing’an Block, i.e., the Xinlin–Xiguitu Ocean and the Nenjiang Ocean. However, the early development of the Nenjiang Ocean remains unclear. Here, we present zircon U–Pb geochronology and whole-rock elemental and Sr–Nd isotopic data on the gabbros in the Xinglong area together with andesitic tuffs and basalts in the Duobaoshan area. LA-ICP-MS zircon U–Pb dating of gabbros and andesitic tuffs yielded crystallization ages of 443–436 ​Ma and 452–451 ​Ma, respectively. The Early Silurian Xinglong gabbros show calc-alkaline and E-MORB affinities but they are enriched in LILEs, and depleted in HFSEs, with relatively low U/Th ratios of 0.18–0.36 and εNd(t) values of −1.6 to +0.5. These geochemical features suggest that the gabbros might originate from a mantle wedge modified by pelagic sediment-derived melts, consistent with a back-arc basin setting. By contrast, the andesitic tuffs are characterized by high MgO (>5 ​wt.%), Cr (138–200 ​ppm), and Ni (65–110 ​ppm) contents, and can be termed as high-Mg andesites. Their low Sr/Y ratios of 15.98–17.15 and U/Th values of 0.24–0.25 and moderate (La/Sm)n values of 3.07–3.26 are similar to those from the Setouchi Volcanic Belt (SW Japan), and are thought to be derived from partial melting of subducted sediments, and subsequent melt-mantle interaction. The Duobaoshan basalts have high Nb (8.44–10.30 ​ppm) and TiO2 contents (1.17–1.60 ​wt.%), typical of Nb-enriched basalts. They are slightly younger than regional adakitic rocks and have positive εNd(t) values of +5.2 to +5.7 and are interpreted to be generated by partial melting of a depleted mantle source metasomatized by earlier adakitic melts. Synthesized with coeval arc-related igneous rocks from the southeastern Xing’an Block, we propose that the Duobaoshan high-Mg andesitic tuffs and Nb-enriched basalts are parts of the Late Ordovician and Silurian Sonid Zuoqi–Duobaoshan arc belt, and they were formed by the northwestern subduction of the Nenjiang Ocean. Such a subduction beneath the integrated Xing’an–Erguna Block also gave rise to the East Ujimqin–Xinglong igneous belt in a continental back-arc basin setting. Our new data support an early Paleozoic arc–back-arc model in the northern Great Xing’an Range.

Genetic classification, distribution and ore genesis of major PGE, Co and Cr deposits in China: A critical review

Major platinum-group element (PGE), cobalt (Co) and chromium (Cr) deposits in China are commonly associated with mafic-ultramafic rocks regardless magmatic or hydrothermal origins. Nearly all PGE and half of Co resources in China are from magmatic Ni-Cu-(PGE) sulfide deposits hosted in mafic-ultramafic intrusions. Major resources of Cr are from podiform chromite deposits associated with the mantle sequences of ophiolites, including the Luobusha chromite deposit in Tibet and the Sartohay chromite deposit in Xinjiang. However, there is a lack of large PGE and chromite deposits related to layered mafic-ultramafic intrusions. Sedimentary rock-hosted stratiform Cu deposits and Ni-Co laterites are two dominant types of Co-bearing deposits among terrestrial Co resources and are sporadically distributed in China, although these are insignificant. Platinum-group elements from three Ni-Cu-(PGE) sulfide-bearing mafic-ultramafic intrusions that formed within-plate settings account for 74% of the total PGE reserves of China. Among these, the Jinbaoshan and Yangliuping intrusions are parts of the Emeishan large igneous province (LIP) in SW China, and the Jinchuan intrusion emplaced in a rifting margin of the southern North China Craton. The Jinbaoshan intrusion hosts the only PGE-dominated deposit in China, but has not yet been mined due to the difficulty for access. In the Jinchuan and Yangliuping Ni-Cu deposits, PGEs are by-products. The Jinchuan intrusion is by far the largest PGE producer in China. Cobalt resources are from deposits associated with mafic-ultramafic rocks in China, including Ni-Cu sulfide deposits, Ni-Co laterites, volcanogenic massive sulfide (VMS) deposits and magmatic Fe-Ti oxide deposits, which make up 41% of total Co reserves of China. Major Ni-Cu sulfide deposits in both within-plate and convergent margin settings contain economic Co resources, such as the Jinchuan intrusion and those in the Emeishan LIP, and the Xiarihamu intrusion in the East Kunlun orogenic belt, the Jianchaling intrusion in a Neoproterozoic subduction zone in the northern margin of the Yangtze block and those in the central Asian orogenic belt. Ni-Co laterites that contain economic Co resource have been only discovered locally in Hannan, Yunnan and Taiwan. The Derni Cu-Co deposit in the A’nyemaqen suture zone of the East Kunlun orogenic belt is a special type of VMS deposits closely associated with ophiolite suites, which is also very rare worldwide. Magmatic Fe-Ti oxide deposits in the Emeishan LIP and hydrothermal iron oxide deposits in the East Tianshan orogenic belt have likely potential Co resources. Podiform chromite deposits in China occur in ophiolites, such as the Sartohay, Hegenshan and Suolunshan ophiolites in the central Asian orogenic belt, the Dadao Erji and Yushi ophiolites in the Qilian-Qinling orogenic belt, the Dongqiao ophiolite in the Bangong-Nujiang suture zone and Luobusha ophiolite in the Yarlung-Zangbo suture zone. Understanding the mechanisms of PGE enrichment in major Ni-Cu-(PGE) sulfide deposits such as the Jinchuan and Jinbaoshan intrusions has been a focus of studies in the past. The dissolution and re-precipitation processes that may lead to the enrichment of PGE and Co during hydrothermal overprints on magmatic Ni-Cu sulfide deposits have gained popularity. The origin of podiform chromite deposits is generally thought to be triggered by melt-mantle interaction and melt mixing. But it appears that such a traditional thought is challenged by the discoveries of various high-pressure and hydrous minerals that are trapped in chromite. Given PGE, Co and Cr are all strategic and critical metals to China, it is very important to conduct new exploration projects near active mines, such as those in the Emeishan LIP and the Jinchuan intrusion. However, additional experimental and mineralogical studies on the enrichment processes of PGE, Co and Cr are desired to make breakthroughs in order to better understand the behaviors of PGE, Co and Cr in magmatic-hydrothermal systems. Main issues that are worthy to be closely examined in the future include (1) micro- to nano-scale occurrence of PGE, (2) enrichment mechanism and occurrence of Co in mafic-ultramafic rocks and related ore deposits, and (3) mobilization and enrichment processes of Cr in the formation of podiform chromite deposits.

Unraveling the Effects of Melt–Mantle Interactions on the Gold Fertility of Magmas

The oxidation state of the Earth’s mantle and its partial melting products exerts a fundamental control on the behavior and distribution of sulphur and chalcophile and siderophile elements between the mantle and crust, underpinning models of ore deposit formation. Whether the oxidized nature of magmas in inherited from the asthenospheric mantle source or acquired during ascent and differentiation is vigorously debated, limiting our understanding of the mechanisms of extraction of sulphur and metals from the mantle. Here, we focused on the redox-sensitive behavior of sulphur in apatite crystallized from quenched alkaline basaltic melts preserved within a peridotite xenolith from the El Deseado Massif auriferous province in southern Patagonia. We took advantage of this unique setting to elucidate the redox evolution of melts during their ascent through the subcontinental lithospheric mantle, and grasp the inner workings of the Earth’s mantle during gold metallogenesis. Our data reveal that an initially reduced silicate melt (ΔFMQ -2.2 to -1.2) was oxidized to ΔFMQ between 0 and 1.2 during percolation and interaction with the surrounding peridotite wall-rock (ΔFMQ 0 to +0.8). This process triggered changes in sulphur speciation and solubility in the silicate melt, boosting the potential of the melt to scavenge ore metals such as gold. We suggest that large redox gradients resulting from the interaction between ascending melts and the surrounding mantle can potentially modify the oxidation state of primitive melts and enhance their metallogenic fertility. Among other factors including an enriched metal source and favorable geodynamic conditions, redox gradients in the mantle may exert a first-order control on the global-scale localization of crustal provinces endowed with gold deposits.

Mg isotope fractionation during partial melting of garnet-bearing sources: An adakite perspective

Garnet that has a distinctly light Mg isotopic composition compared to other mafic minerals is commonly present in deep crustal and mantle sources. Whether partial melting of these garnet-bearing sources can lead to significant Mg isotope fractionation or not remains poorly understood. In order to investigate Mg isotope fractionation during partial melting of garnet-bearing sources, we report Mg isotopic data of 17 well-characterized low-Mg adakitic rocks (LMA) from the Dabie orogen, central China. These LMA are known for derivation from mafic sources leaving eclogitic residua with variable abundance of garnet. Our data together with previously published results show that fresh Dabie LMA have homogeneous Mg isotopic compositions, with an average δ26Mg of −0.22 ± 0.08‰ (2SD, N = 18), except that two samples display higher δ26Mg (−0.05‰ to +0.01‰) due to alteration during sericitization and chloritization of biotite. The lack of correlation between δ26Mg and (Dy/Yb)N of the Dabie LMA indicates an unresolvable residual garnet effect. Given that Mg isotopic compositions of the Dabie LMA are identical with local mafic basement within the current precision, Δ26Mgmelt-cpx is estimated to be around −0.02‰. Limited isotope fractionation of the Dabie LMA could be attributed to the dilution effect of residual clinopyroxene co-existing with garnet. The estimated Δ26Mgmelt-cpx is then applied to predict the possible isotope fractionation that may occur during hydrous and dehydration melting of subducted oceanic crust. With a lower melting temperature and more abundant garnet in the residua, slab-derived melts may have δ26Mg higher than their sources by up to +0.36‰, which, however, can be easily erased by later melt-mantle interaction. In this regard, Mg isotopes can serve as a powerful tracer of recycled supracrustal materials.

Neoproterozoic and Cretaceous mantle oxidation states: Controls and heterogeneity through time

To estimate the oxygen fugacity (fO2) of the Neoproterozoic and Cretaceous suprasubduction zone mantle, and to evaluate the possible secular changes in the upper mantle oxidation state, the compositions of spinel, olivine and orthopyroxene of Neoproterozoic (Egypt and Saudi Arabia) and late Cretaceous (Iran) mantle rocks were determined. For accurate estimation of fO2, spinel ferric iron was calculated after correcting the electron microprobe data using a set of spinel standards for which the ferric iron content was measured by Mӧssbauer spectroscopy. The Neoproterozoic samples record strongly heterogenous fO2 values ranging from moderately oxidized (FMQ +0.54) to ultra-reduced (FMQ -4.73) for harzburgites, from highly oxidized (FMQ +1.49) to moderately reduced (FMQ -0.60) for dunites as well as one highly reduced (FMQ -1.61) value for chromitite. Such heterogeneity is not apparent in the late Cretaceous harzburgites that record fO2 values ranging from slightly oxidized (FMQ +0.45) to moderately reduced (FMQ -0.85). The fO2 of the Neoproterozoic forearc mantle is most easily explained by melt-mantle interaction and deep-mantle recycling, while that of the late Cretaceous forearc mantle can be attributed to variable degrees of melt-mantle interaction. The estimated fO2 values of Neoproterozoic/Cretaceous mantle unaffected by melt-rock interaction and deep-mantle recycling, and published values of Precambrian and Modern mantle suggest a consistent upper mantle oxidation state from Proterozoic to present day.