Melt Depth Research Articles

Melting conditions and mantle source composition from probabilistic joint inversion of major and rare earth element concentrations

The chemical composition of erupted basalts provides a record of the thermo-chemical state of their source region and the melting conditions that lead to their formation. Here we present the first probabilistic inversion framework capable of inverting both trace and major element data of mafic volcanic rocks to constrain mantle potential temperature, depth of melting, and major and trace element source composition. The inversion strategy is based on the combination of (i) a two-phase multi-component reactive transport model, (ii) a thermodynamic solver for the evolution of major elements and mineral/liquid phases, (iii) a disequilibrium model of trace element partitioning and (iv) an adaptive Markov chain Monte Carlo algorithm. The mechanical and chemical evolution of melt and solid residue are therefore modelled in an internally- and thermodynamically-consistent manner.We illustrate the inversion approach and its sensitivity to relevant model parameters with a series of numerical experiments with increasing level of complexity. We show the benefits and limitations of using major and trace element compositions separately before demonstrating the advantages of a joint inversion. We show that such joint inversion has great sensitivity to mantle temperature, pressure range of melting and composition of the source, even when realistic uncertainties are assigned to both data and predictions. We further test the reliability of the approach on a real dataset from a well-characterised region: the Rio Grande Rift in western North America. We obtain estimates of mantle potential temperature (∼1340 °C), lithospheric thickness (∼60 km) and source composition that are in excellent agreement with numerous independent geochemical and geophysical estimates. In particular, this study suggests that the basalts in this region originated from a moderately hot upwelling and include the contribution from a slightly depleted source that experienced a small degree of melt or fluid metasomatism. This component is likely associated with partial melting of the lower portions of the lithosphere. The flexibility of both the melting model and inversion scheme developed here makes the approach widely applicable to assessing the thermo-chemical structure and evolution of the lithosphere-asthenosphere system and paves the way for truly joint geochemical-geophysical inversions.

Selective laser melting of IN738 superalloy with a low Mn+Si content: Effect of energy input on characteristics of molten pool, metallurgical defects, microstructures and mechanical properties

IN738 superalloy with excellent high-temperature performance is of huge interest for hot-end component applications in aerospace, but its additive manufacturing via selective laser melting (SLM) is rather challenging due to the unsolved high crack susceptibility. Here, for the purpose of improving the formability of IN738 in SLM, Mn + Si content was then strictly controlled in raw powder. An orthogonal experiment was then carried out under different energy inputs to investigate the characteristics of the molten pool, metallurgical defects, microstructures, and mechanical properties of IN738 by SLM. The results showed that high laser power was more likely to shape large melting depth and depth-to-width ratio under the same linear energy density (LED), rather than scanning speed. Four morphologies of the molten pool were observed in the entire LED range. At lower LEDs, hot cracks were usually accompanied by irregular pores due to the stress concentration at the sharp corner of pores; at higher LEDs, cracks were located at the interface of grain boundaries with large misorientation angles. Energy dispersive spectrometry results revealed that the presence of Al-rich oxides and high Mn + Si content at the interface were the main reasons for cracking. The Scheil-Gulliver solidification modeling was used to examine the cracking susceptibility of Si and Mn elements. In addition, both dendrites and cellular dendrites were found in columnar grain structures. By reducing the Mn + Si content and optimizing process, crack-free and nearly fully dense samples of IN738 were obtained by SLM with excellent mechanical properties (ultimate tensile strengths = 1206 MPa, yield strength = 866 MPa and elongation = 16.5%), which were much higher than the mechanical properties of conventionally manufactured IN738.

A greedy algorithm for optimal heating in powder-bed-based additive manufacturing

Powder-bed-based additive manufacturing involves melting of a powder bed using a moving laser or electron beam as a heat source. In this paper, we formulate an optimization scheme that aims to control this type of melting. The goal consists of tracking maximum temperatures on lines that run along the beam path. Time-dependent beam parameters (more specifically, beam power, spot size, and speed) act as control functions. The scheme is greedy in the sense that it exploits local properties of the melt pool in order to divide a large optimization problem into several small ones. As illustrated by numerical examples, the scheme can resolve heat conduction issues such as concentrated heat accumulation at turning points and non-uniform melt depths.

High–μ signature in lavas of Mt. Oku: Implications for lithospheric and asthenospheric contributions to the magmatism of the Cameroon Volcanic Line (West Africa)

This study presents geochemical data for mafic lavas from Mt. Oku to investigate the mantle source for Mt. Oku lavas and regional variations in isotopic ratios along the Cameroon Volcanic Line (CVL). The investigated mafic lavas present trace element and isotope signatures akin to ocean island basalts (OIB) and cover the entire range of the CVL. Major and trace element compositions of the studied lavas indicates that they have undergone fractionation of olivine + clinopyroxene + Fe-Ti oxide ± Cr–spinel with insignificant crustal contamination. The lavas were generated by <2% partial melting from a heterogeneous source containing less than 4% garnet. Major and trace elements abundances indicate the presence of hydrous minerals indicative of modal metasomatism.The highest value of radiogenic 206Pb/204Pb (20.7) so far measured along the CVL is reported in this study. The isotopic features of the lavas suggest that the HIMU signatures are dominantly inherited from the asthenosphere (primary source) and melting of enriched components hosted in the subcontinental lithospheric mantle (SCLM; secondary source). Lavas from Mt. Oku present more comprehensive ranges of Sr–Nd–Pb isotopic composition than those from the continent-ocean-boundary (COB). The isotopic composition of Mt. Oku lavas with 206Pb/204Pb > 19.5 differs from those of the COB but are similar to FOZO.The isotopic composition of Mt. Oku lavas (87Sr/86Sr = 0.7030–0.7036, 143Nd/144Nd = 0.5127–0.5129, 206Pb/204Pb = 17.9–20.7) suggest that the lavas are the result of contributions from the asthenosphere and the SCLM. Using a combination of Sr–Nd–Pb isotope display on a 3D plot and Sm/Yb, we identify four essential components denoted; A, B, C and D involved in the petrogenesis of Mt. Oku lavas and the approximate melting depth. While A and B are from the asthenosphere with HIMU mantle flavour, C and D owe their origin from the SCLM with EM1 and DMM characteristics, respectively. Although depleted in Sr-Nd isotopes, D is radiogenic in 206Pb/204Pb, indicating the influence of metasomatism. Therefore, the petrogenesis of Mt. Oku lavas involves the mixing of at least three mantle end-members: HIMU–DMM–EM1. The “fanning” of samples from”A" towards the other components (B, C and D) indicates a HIMU–like end–member dominance in Mt. Oku magmatism.Considering the geophysical studies on mantle convection and plumes, we have developed a schematic model that explains the petrogenesis of the CVL lavas. The continuous spectrum from relatively depleted to HIMU characteristics of CVL lavas is associated with the progressive change in source components (i) SCLM with ± pockets of enriched metasomes to (ii) SCLM + asthenosphere sources and finally to (iii) typically asthenospheric source material ± pockets of enriched metasomes. Lavas derived from stage (i) exhibit geochemical variability involving DMM–like and EM1–like signatures. The magma generated at Stage (iii) is dominated by the HIMU mantle component and accounts for over 85% of CVL lavas.

Interaction of Yb2Si2O7 environmental barrier coating material with Calcium-Ferrum-Alumina-Silicate (CFAS) at high temperature

Experimental investigations of Yb2Si2O7 pellet exposed to Calcium-Ferrum-Alumina-Silicate (CFAS) at 1400 °C in ambient air were carried out to reveal corrosion reaction between molten silicate deposit and Yb2Si2O7. Phase transformation, microstructure evolution and reaction mechanism were evaluated. Results indicated that the corrosion process was accompanied by the infiltration of CFAS melt, the dissolution of Yb2Si2O7 and the reprecipitation of Yb2Si2O7 and Ca2Yb8(SiO4)6O2 apatite as reaction product. The formation of apatite decreased the concentration of Ca2+ in the melt. After CFAS exposure at 1400 °C for 30 h, the thickness of the apatite layer stopped increasing due to insufficient Ca2+ content, and remained at about 115.4 μm. However, the infiltration depth of CFAS melt increased with the extending corrosion duration and increasing deposit content. And the infiltration rate was preliminarily found to first decrease and then increase with time. Most of the residual CFAS were crystallized into garnet (Ca3Fe2(SiO4)3 and Yb3Fe5O12) and mayerite (Ca12Al14O33), while a small volume of amorphous glass was dispersed among the garnet and mayerite grains.

Carbon concentration increases with depth of melting in Earth’s upper mantle

Carbon concentration increases with depth of melting in Earth’s upper mantle

Model Predictive Control of Melt Pool Size for the Laser Powder Bed Fusion Process Under Process Uncertainty

Abstract Laser powder bed fusion (LPBF) process is one of popular additive manufacturing techniques for building metal parts through the layer-by-layer melting and solidification process. To date, there are plenty of successful product prototypes manufactured by the LPBF process. However, the lack of confidence in its quality and long-term reliability could be one of the major reasons prevent the LPBF process from being widely adopted in industry. The existing LPBF process is an open loop control system with some in situ monitoring capability. Hence, manufacturing quality and long-term reliability of the part cannot be guaranteed if there is any disturbance during the process. Such limitation can be overcome if a feedback control system can be implemented. This article studies the control effectiveness of the proportional-integral-derivative (PID) control and the model predictive control (MPC) for the LPBF process based on a physics-based machine learning model. The control objective is to maintain the melt pool width and depth at required level under process uncertainties from the powder and laser. A sampling-based dynamic control window approach is further proposed for MPC as a practical approach to approximate the optimal control actions within limited time constraint. Control effectiveness, pros, and cons of the PID control and the MPC for the LPBF process are investigated and compared through various control scenarios. It is demonstrated that the MPC is more effective than the PID control under the same conditions, but the MPC demands a valid digit twin of the LPBF process.

The komatiite-mantle platinum-group element paradox

The platinum-group element (PGE) contents of komatiites have been used to estimate the PGE contents of their mantle sources and investigate temporal variations in the PGE systematics of the mantle throughout Earth history. However, the use of mantle melts to investigate source characteristics is critically dependent on understanding the fractionation of the elements in question between mantle sources and their derived magmas. We present new PGE and Re abundance data, together with Re-Os isotope data for the pristine 1.9 Ga Winnipegosis komatiites, Canada. Whole rock Re-Os isotope data define a 1865 ± 40 Ma isochron, consistent with previous age estimates, with initial γOs of +0.9 ± 1.4. The PGE and Re variations in these komatiites were controlled by fractionation of olivine, chromite, Os-Ir alloys, a Ru-Os rich phase (possibly laurite) from the komatiite melt. The calculated parental melt composition at 23.6 ± 1.6 wt% MgO has 1.1 ± 0.1 ppb Os, 0.91 ± 0.08 ppb Ir, 4.0 ± 0.5 ppb Ru, 7.0 ± 0.8 ppb Pt, 7.2 ± 0.7 ppb Pd, and 0.53 ± 0.06 ppb Re. The calculated PGE contents are low relative to many komatiites; using existing methods for calculating the PGE contents of mantle sources suggests the Winnipegosis source had PGE contents from 25 ± 19 wt% to 57 ± 7 wt% of primitive mantle values. This surprising finding substantiates a growing ‘PGE paradox’, where almost all komatiites appear to have formed from PGE-depleted mantle sources. We suggest the simplest resolution to this paradox is that current methods systematically underestimate mantle source PGE contents. We test the assumptions implicit in these methods by comparing detailed models of PGE behaviour during mantle melting to a large database of parental melt compositions of high degree melts. Ruthenium behaviour in high degree melts can be adequately modelled using our current understanding of Ru partitioning. However, the Ru contents of high degree mantle melts are strongly dependent on the degree of melting, as Ru-rich melts formed after sulphide exhaustion are increasingly mixed into early-formed Ru-poor melts. Platinum and Pd behaviour during mantle melting cannot be successfully modelled under the widespread assumption that they are strongly incompatible following sulphide exhaustion, suggesting that these elements cannot be used to estimate PGE contents of the mantle sources of high degree melts. Parental melt Pt and Pd in many high degree lavas are correlated with Al2O3/TiO2, suggesting a pressure control on their partitioning. We attribute the relatively low PGE contents of the Winnipegosis komatiites to their moderate degrees and depth of melting compared to other komatiites, rather than invoking a PGE-depleted mantle source. More broadly, the complex controls (T, P, fO2, S content, prior depletion) on the PGE contents of komatiites mean that most komatiites can be reconciled with being derived from sources with primitive mantle-like PGE contents, and few komatiites can be confidently asserted to come from PGE-depleted mantle sources. Pending a better understanding of PGE behaviour during mantle melting, we recommend caution when using komatiite PGE systematics to infer the highly siderophile element evolution and accretionary history of Earth’s mantle.

Laser ablation of lanthanum phosphate for pulsed laser deposition

AbstractA theoretical model has been used to simulate pulsed laser ablation of Lanthanum Phosphate (LaPO4) by nanosecond Nd:YAG laser irradiation. Material ablation rate per laser pulse was experimentally measured as a function of average incident laser fluence up to 12J/cm2. Calculations were performed by solving the heat conduction equation by an explicit finite‐difference technique to generate time evolution of temperature distribution, melt depth and ablation rate from the target during and after irradiation with a nanosecond laser pulse. Good agreement between our experimental and calculated ablation rates validates our theoretical model. The calculated maximum surface temperature of the LaPO4 target indicated that for laser fluence levels, up to 20J/cm2 material ejection from LaPO4 target is expected to occur via normal boiling and evaporation successfully avoiding explosive boiling. Our calculations confirm that operating with laser fluence at near ablation threshold levels for LaPO4 also restricts dissociation of the LaPO4 target to oxides with loss of gaseous products. Therefore, our study of pulsed laser ablation of LaPO4 target helps in making judicious selection of laser parameters for Pulsed Laser Deposition (PLD) of LaPO4 coatings and films of desired stoichiometric purity and homogeneity, while successfully ensuring phase stability of the target.

Platinum-group element geochemistry of the Paraná flood basalts – Modelling metallogenesis in rifting continental plume environments

The 135 Ma Paraná-Etendeka Large Igneous Province (PELIP) is one of the largest areas of continental flood basalt (CFB) volcanism in the world and is widely agreed to be a product of intracontinental melts related to thermal anomalies from the Tristan mantle plume. The province rifted during the break-up of Gondwana, as the plume transitioned into an oceanic geodynamic environment. This study reports analyses of plume-derived basalts from the Brazilian side of the PELIP (the Serra Geral Group) to investigate major, trace and platinum-group element (PGE) abundances in an evolving plume-rift metallogenic setting, with the aim of contextualising metallogenic controls alongside existing magmatic interpretations of the region. The chalcophile geochemistry of these basalts defines three distinct metallogenic groupings that fit with three modern multi-element magma classifications for Serra Geral lavas. In this scheme, Type 4 lavas have a distinctive PGE-poor signature, Type 1 (Central-Northern) lavas are enriched in Pd, Au and Cu, and Type 1 (Southern) lavas are enriched in Ru and Rh. Our trace element melt modelling indicates that the compositional variations result from changes in the melting regime between the garnet and spinel stability fields, in response to the thinning and ‘unlidding’ of the rifting continent above. This process imposes progressively shallower melting depths and higher degrees of partial melting. Accordingly, Type 4 magmas formed from small degree melts, reducing the likelihood of sulphide exhaustion/chalcophile acquisition at source. Type 1 (Central-Northern) magmas incorporated components of the sub-continental lithospheric mantle (SCLM) in higher-degree partial melts; the SCLM was heterogeneously enriched via metasomatism prior to plume melting, and this produced enrichment in volatile metals (Pd, Cu, and Au) in these magmas. In contrast, the Ru-Rh enrichment in Type 1 (Southern) lavas is attributed to increased spinel-group mineral and sulphide incorporation from the mantle into higher degree partial melts close to the continental rift zone. Our models confirm the importance of contributions from SCLM melts in precious metal mineral systems within CFB provinces, and reinforce the role of heterogeneous metasomatic enrichment underneath cratons in boosting intracontinental prospectivity with respect to ore deposits.

Differentiated Archean Dolerites: Igneous and Emplacement Processes that Enhance Prospectivity for Orogenic Gold

Abstract Magnetite-bearing granophyre and quartz dolerite are the evolved fractions of differentiated dolerite (diabase) sills and are an important host to Archean gold deposits because they are chemical traps for orogenic fluids. Despite their economic importance, there is a poor understanding of how melt composition, crystal fractionation, sill geometry, and depth of emplacement increase the volume of host rock that is most favorable for gold precipitation during orogenesis. We use drill core logging, whole-rock geochemistry, magnetic susceptibility, gold assay, and thermodynamic modeling data from 11 mineralized and unmineralized ca. 2.7 Ga differentiated dolerites in the Eastern Goldfields superterrane (Yilgarn craton, Western Australia) to better understand the influence of igneous and emplacement processes on gold prospectivity. Orogenic gold favors differentiated dolerites, derived from iron-rich parental magmas, that crystallize large volumes of magnetite-bearing quartz dolerite (&amp;gt;25% total thickness). Mineralized sills are commonly &amp;gt;150 m thick and hosted by thick and broadly coeval sedimentary sequences. Sill thickness is an important predictor for gold prospectivity, as it largely controls cooling rate and hence fractionation. The parental melts of gold-mineralized sills fractionated large amounts of clinopyroxene and plagioclase (possibly up to 50%) at depth before emplacement in the shallow crust. A second fractionation event at shallow levels (&amp;lt;3 km) operated both vertically and laterally, resulting in an antithetic relationship between quartz (magnetite) dolerite and cumulates (pyroxenites and peridotites). By comparison with younger mafic sills emplaced in synsedimentary basins, we argue that the geometry of these high-level sills was more irregular than the often-assumed tabular form. Any irregularities in the lower sill margin act as traps for early formed (dense) ferromagnesian minerals, now represented by pyroxene and peridotite cumulates. In contrast, irregularities in the upper sill margin trap the buoyant fractionated liquids when the sill is more crystalline, through magma flow on the scale of &amp;lt;1 km. Sills derived from iron-poor melts are rarely mineralized and, all else being equal, probably have to be thicker than Fe-rich sills to be similarly prospective for orogenic gold. Finally, we provide a list of quantifiable parameters that can be incorporated into an exploration program targeting differentiated dolerites that host orogenic gold.

Picrite-basalt complex in the Baoshan-Gongshan Block of northern Sibumasu: Onset of a mantle plume before breakup of Gondwana and opening of the Neo-Tethys Ocean

Abstract Mantle plumes are thought to play key roles in Earth's geodynamics, including mantle convection, continental formation, and plate tectonics. The connection between plume activity and continental dispersion, as exemplified by the breakup of Gondwana and the generation of the Neo-Tethys Ocean, is a key question for the geosciences. Here, we present detailed investigations for the picrite-basalt sequence in the Baoshan-Gongshan Block of the northern Sibumasu terrane, southwest China. Field relations and petrological and geochemical data reveal that these volcanic rocks are continental flood picrites and basalts, consistent with a mantle plume origin. The estimated mantle potential temperatures range from 1527 ± 86 °C to 1546 ± 98 °C, and melting depths vary from the spinel to garnet stability fields (1.1–5.3 GPa), similar to Cenozoic Hawaiian picrites. Zircon geochronological data show that the mantle plume activity started at ca. 335 Ma and lasted to 280 Ma; this range is earlier than the breakup of the Gondwana continent and opening of the Neo-Tethys Ocean (270–260 Ma). We conclude that the long-lived mantle plume impacted the continental lithosphere but it did not drive continental breakup and the opening of Neo-Tethys Ocean, which took place because of the subduction-induced stress generated by initial subduction of the Paleo-Tethys Ocean.

Influence of processing parameters on joint shear performance in laser direct joining of CFRTP and aluminum alloy

Laser direct joining of a carbon fiber reinforced thermoplastic (CFRTP) and an alloy is prone to thermal defects, thereby reducing the joint performance. This can be avoided by reasonably controlling the joining temperature. To this end, a process optimization method characterized by taking full control of the melting depth and local peak temperature is proposed for representative CFRTP/Al and CFRTP/polymer/Al stacks. For the first time, a temperature simulation model considering the heat transfer during the laser direct joining of heterogeneous CFRTP/alloy stacks is established; the average calculation error of the model is <10%. Based on the simulation results, regression models of the melting depth and local peak temperature are established. Subsequently, constraints are determined by defect distribution observation and joint fracture surface analysis; thus, the optimized ranges of the process parameters are obtained. Finally, through laser direct joining experiments, the improvement in the joint performance is demonstrated and analyzed. The results suggest an enhancement in the strength of the aforementioned stacks under the optimized process, thus proving the rationality of the proposed method by controlling the melting depth and local peak temperature, particularly for CFRTP/polymer/Al stacks with strength close to 30 MPa.

Seismic Discontinuities Across the North American Caribbean Plate Boundary From S‐to‐P Receiver Functions

AbstractThe evolution of the Caribbean plate has resulted in the formation of volcanic arcs, the Caribbean Large Igneous Province (CLIP) and micro‐plates across the plate boundary zones. The northern plate boundary with the North American plate has been particularly segmented with the transition from oblique subduction to oblique collision moving from east to west. However, there are few constraints on the seismic structure of the upper mantle across the plate boundary. Here we use S‐to‐P receiver functions to map seismic velocity discontinuities across the plate boundary, placing constraints on crustal and lithospheric thicknesses, as well as the structures associated with subduction and collision. We image a velocity increase with depth, consistently seen at 28–34 ± 4 km along the plate boundary, which corresponds to the Moho. A second strong velocity increase with depth is observed at depths of 64–66 ± 5 km, which is related to the presence of subducting slabs and anisotropic effects. We image a velocity decrease with depth at 95–135 ± 7 km, which reflects a lithosphere‐asthenosphere boundary that varies in depth across the plate boundary. The deepest negative discontinuity spatially maps to the CLIP. We suggest that a deep melting depth at 135 km, associated with an elevated potential mantle temperature of 1585 ± 20°C during CLIP formation, caused a depleted and dehydrated root to the base of melting, thus thickening the lithosphere.

The Influence of Laser Defocusing in Selective Laser Melted IN 625.

Laser defocusing was investigated to assess the influence on the surface quality, melt pool shape, tensile properties, and densification of selective laser melted (SLMed) IN 625. Negative (−0.5 mm, −0.3 mm), positive (+0.3 mm, +0.5 mm), and 0 mm defocusing distances were used to produce specimens, while the other process parameters remained unchanged. The scanning electron microscopy (SEM) images of the melt pools generated by different defocusing amounts were used to assess the influence on the morphology and melt pool size. The mechanical properties were evaluated by tensile testing, and the bulk density of the parts was measured by Archimedes’ method. It was observed that the melt pool morphology and melting mode are directly related to the defocusing distances. The melting height increases while the melting depth decreases from positive to negative defocusing. The use of negative defocusing distances generates the conduction melting mode of the SLMed IN 625, and the alloy (as-built) has the maximum density and ultimate tensile strength. Conversely, the use of positive distances generates keyhole mode melting accompanied by a decrease of density and mechanical strength due to the increase in porosity and is therefore not suitable for the SLM process.

Pulsed laser melting of implant amorphized Si1-xGex thin films

Nanosecond pulsed laser annealing using a frequency doubled Nd:YAG laser (λ = 532 nm) was performed on undoped implant amorphized Si and 40 nm Si1-xGex epitaxial thin films ranging from x = 0.1 to 0.5. Ge+ implants were used to create ~ 15 nm thick surface amorphous layers. The microstructural evolution of the layers was investigated for laser powers that ranged from the sub-melt, partial amorphous layer melt, full amorphous layer melt, to full epi-layer melt regimes. Time resolved reflectometry and transmission electron microscopy was used to couple the impact of melt dynamics with resulting microstructures and to determine processing benchmarks as a function of Ge concentration. It was shown that for the right combination of power and amorphous layer thickness, defect free regrowth is possible. At melt depths ≥ 22 nm for the Si0.7Ge0.3 films, it was found that progressive liquid/solid interface roughening during solidification led to lateral germanium segregation coupled with the formation of dislocation half loops and dislocation loop clusters at the surface. These results are important for the exploration of pulsed laser melting of Si1-xGex for CMOS source/drain contact and channel strain engineering applications.

Spatially and Geochemically Anomalous Arc Magmatism: Insights From the Andean Arc

AbstractWhile most volcanic arcs show a distinctive spatial relationship to subducting plates, there are many examples where volcanoes occur in anomalous locations. These are commonly also geochemically anomalous relative to the composition of more typical subduction‐related rocks. Using Holocene volcanoes in South America as a case study, we document the spatial and geochemical patterns along the Andean volcanic belt. To determine whether spatial variations are also geochemically anomalous, we assess a series of geochemical indices that provide information on the depth and degree of melting, and the role of metasomatic subduction inputs in melt generation. We use these parameters to develop a scoring system, with the lowest and highest scores indicating “typical” and “anomalous” arc melting processes, respectively. Typical arc magmatism is defined as melts generated in the sub‐arc mantle wedge through slab‐derived fluid metasomatism, with or without contributions from subducted sediments. In contrast, we show that anomalous volcanism in South America appears to relate to geometric anomalies in the subducting Nazca plate (e.g., beneath Sumaco, Laguna Blanca and Payun Matru), or to areas affected by variations in mantle flow due to the proximity to the slab edge (Crater Basalt Volcanic Field). By establishing relationships between anomalous magmatism and slab structure, we propose that similar geochemical fingerprints could be used to explore the magmatic response to slab deformation and/or tearing in older arc systems, particularly in cases where the three‐dimensional slab structure is no longer detectable.

Effects of Defocus Distance on Three-Beam Laser Internal Coaxial Wire Cladding

Three-beam laser internal coaxial wire feeding cladding is regarded as a promising additive manufacturing technique because it is highly efficient and controllable. In this study, the effects of the defocus distance on cladding using a three-beam laser with internal wire feeding are experimentally and numerically studied. A process map indicating the surface characteristics at different defocus distances with various parameter combinations was developed. The transmission characteristics including laser intensity, beam size, and laser spot distance of the three-beam laser at different defocus distances were analyzed using TracePro software. Based on the TracePro results as heat source, a three-dimensional transient finite element (FE) thermal model was formulated to predict the thermal field, temperature history and molten pool shape at different defocus distances. A molten pool with a flat bottom and low melting depth is generated when the defocus distance is − 2.5 mm, whereas when this distance is − 1.5 mm, a pool with a valley-shaped bond and high melting depth is formed. The simulated results of the temperature cycle and clad geometry are both validated and found to well agree with experimental measurements. The influence of the defocus distance on the microstructure and microhardness are discussed based on the temperature history and cooling rate. With the increase in the absolute defocus distance, the height and dilution of the clad decreased, whereas the width increased. In addition, the effects of defocus distance with various parameter combinations on clad geometry were explored using the formulated FE model.

Process Optimization and Microstructure Analysis to Understand Laser Powder Bed Fusion of 316L Stainless Steel

The microstructural development of 316L stainless steel (SS) was investigated over a wide range of systematically varied laser powder bed fusion (LPBF) parameters, such as laser power, scan speed, hatch spacing and volumetric energy density. Relative density, melt pool width and depth, and the size of sub-grain cellular structure were quantified and related to the temperature field estimated by Rosenthal solution. Use of volumetric energy density between 46 and 127 J/mm3 produced nearly fully dense (≥99.8%) samples, and this included the best parameter set: power = 200 W; scan speed = 800 mm/s; hatch spacing = 0.12 mm; slice thickness = 0.03; energy density = 69 J/mm3). Cooling rate of 105 to 107 K/s was estimated base on the size of cellular structure within melt pools. Using the optimized LPBF parameters, the as-built 316L SS had, on average, yield strength of 563 MPa, Young’s modulus of 179 GPa, tensile strength of 710 MPa, and 48% strain at failure.

New evidence for Late Cretaceous plume-related seamounts in the Middle East sector of the Neo-Tethys: Constraints from geochemistry, petrology, and mineral chemistry of the magmatic rocks from the western Durkan Complex (Makran Accretionary Prism, SE Iran)

The Durkan Complex in the Makran Accretionary Prism (SE Iran) has been interpreted either as a continental margin succession or a Late Cretaceous tectonically disrupted seamount chain. New whole rock and clinopyroxene chemical data for basaltic and metabasaltic rocks of the Durkan Complex allow us to distinguish two main rock groups: a) rocks showing transitional chemical affinity (Group 1) and compositions resembling those of plume-type mid-oceanic ridge basalts; b) rocks with within-plate oceanic island basalt (OIB) compositions showing a clear alkaline affinity (Group 2). Based on whole rock REE contents and clinopyroxene chemistry, alkaline rocks can be further subdivided in two sub-groups, namely, the Group 2a and 2b. Compared to Group 2a, Group 2b rocks show a more pronounced alkaline nature marked by higher whole rock La/Yb and Sm/Dy ratios and higher TiO2 and Na2O contents in clinopyroxenes. Trace element and REE petrogenetic models show that the Durkan basaltic rocks were generated from the partial melting of depleted sub-oceanic mantle source that was metasomatized by OIB-type chemical components in a within-plate oceanic setting. The chemical differences in the three rock groups are related to different combinations of partial melting degree, depths of melting, and various extent of enrichment of the mantle sources by OIB-type chemical components, which are related, in turn, to a Late Cretaceous mantle plume activity in the northern Neo-Tethys realm. We suggest that the Durkan Complex formed in a seamount setting and that its different volcano-sedimentary successions record different stages of seamount formation.