Formation Mechanism Research Articles

The Formation Mechanism of Residual Oil and Methods of Enhanced Oil Recovery in a Fractured Low-Permeability Metamorphic Rock Reservoir in Bohai Bay

The oil reservoirs of the metamorphic rocks in Bohai Bay have geological characteristics such as low matrix porosity and permeability, developed natural microfractures, which result in the injection water rapidly advancing along fractures, a fast increase in the water content, and difficulties in extracting the remaining oil. In order to reveal water channeling and the residual oil formation mechanisms in fractured low-permeability reservoirs and solve the water channeling problem, we first analyzed the reservoir development status, then studied the formation mechanism of residual oil using a microfluidic chip device, and formed a method of hierarchical control to effectively control the water channeling problem of fractured reservoirs and maximize the displacement of residual oil. The results show that (1) Due to the low permeability of the reservoir matrix, a large amount of injected water flows along the fracture channel, which leads to the long-term high water cut of some oil wells and the retention of a large amount of crude oil in the matrix. (2) The results of microfluidic experiments show that the distribution of residual oil after water flooding mainly includes five types: blind end of the pore throat, columnar, cluster, flake and film, and residual oil. Among them, sheet-like and clustered residual oil are dominant, accounting for 75~85% and 10~13%, respectively. (3) Based on the characteristics of fracture development in buried-hill reservoirs, a hierarchical control technology of “gel particle + liquid crosslinked gel system” is established. The field application effect predicted that the input–output ratio was 1:3. This study provides a reference for the comprehensive treatment of water channeling in the same type of offshore fractured low-permeability metamorphic rock reservoirs.

Unveiling exotic multi-scale microstructure transformation and crack formation mechanisms in eutectic ceramic composite by laser powder bed fusion

Laser powder bed fusion (LPBF) represents an advanced and versatile technology. Exploiting its distinctive advantages for direct and rapid fabrication of complex-structured melt-grown oxide eutectic ceramic composite represents a pioneering yet challenging endeavor. In this work, LPBF is creatively employed to fabricate turbine blade-shaped, in-situ ternary eutectic ceramic composite. Through the integration of experimental procedures, Finite element method (FEM) simulations, and numerical analyses, an innovative design and manufacturing of oxide eutectic ceramic composites have been successfully established. Comprehensive FEM simulations, with detailed interface characteristic analysis, have revealed macro-scale cracks induced by intense maximum principal stress, and micro-cracks stemming from significant interfacial energy disparities among the three constituent phases. The applications of rapid solidification and nucleation theories have facilitated profound insights into the formation mechanisms of multi-scale exotic microstructures, including top-layer coarse dendrites, rosette-like spherical internally grown eutectic colony within layers, and columnar eutectic colonies with ultra-fine lamellar eutectic structures. Micro-mechanical property testing reveals enhanced performance in the inter-layer ultra-fine lamellar eutectic structure, which is attributed to a refined eutectic spacing of approximately 61 nm, coupled with distinct and robust bonding interfaces. These groundbreaking achievements, focusing on the processing-microstructure-property relationship in the fabrication of gas turbine blade-shaped solidified eutectic ceramic composite using LPBF, provide invaluable theoretical insights and data. This knowledge is crucial for the LPBF production of high-temperature structural materials, highlighting its significant potential applications in fields of aerospace and mechanical engineering.

Formation Mechanism and Biotransformation of Halogenated polycyclic aromatic hydrocarbons (HPAHs) from Ecological sources to Food chain sink

Halogenated polyaromatic hydrocarbons (HPAHs, H = F, Cl, Br) are a new class of PAHs derivatives that mainly originate from the incomplete combustion of halogen-laden materials and via metallurgical operations. These compounds circulate extensively in various environmental matrices. This survey provides a comprehensive review on governing synthesis routes of HPAHs, their environmental occurrence, and their health and ecological effects. The review comprehensively enlists and presents emission sources of these emerging organic pollutants into the air that serves as their main reservoir. The formation of HPAHs ensues through successive addition reactions of smally compounds accompanied by ring cyclization steps; in addition to direct unimolecular fragmentation of parents halogenated. Halogenation of parent PAHs rapidly occurs in saline ecosystems thus multiplying the availability of these notorious compounds in the environment. Certain HPAHs appear to be more carcinogenic than dioxins. Transmission routes of HPAHs from their emission sources to water bodies, soil, aquatic life, plants, terrestrial animals, and humans are well-documented. Later, the direct and indirect diffusion of HPAHs from air to the biotic (plants, animals, humans) and abiotic components (soil, water, sediments) are described in detail. The study concludes that HPAHs are permeable to the carbon matrices resulting in the alleviation of the source-to-to-sink interface. As a potential future perspective, understanding the transmission interfaces lays a foundation to intervene in the introduction of these toxicants into the food chain.

A Carbon Capture and Utilization Process for the Production of Solid Carbon Materials from Atmospheric CO2 - Part 2: Carbon Characterization.

This article is the second part of a study reporting the results of a novel carbon capture and utilization (CCU) process, which converts atmospheric CO2 into solid carbon materials. The CCU process combines direct air capture (DAC) with catalytic methanation, which is then followed by methane pyrolysis in a reactor filled with liquid tin. While Part 1 discussed the performance of the overall process and individual process steps regarding conversions and yields, Part 2 characterizes the solid carbon products obtained under various synthesis conditions. The effects of the pyrolysis temperature and the composition of the gas mixture from the methanation step on the solid carbon product are analyzed. Carbon powder is synthesized from methane with either H2 or CO2 as most important impurity. Carbon samples are characterized using SEM, TEM, Raman spectroscopy, XPS and XRD analysis. Very thin, disordered carbon flakes, soot aggregates and large carbon onions are identified as the main solid products of the process. Their formation mechanisms in the liquid metal-filled pyrolysis reactor are discussed.

Oscillating Structural Transformations in the Electrochemical Synthesis of Graphene Oxide from Graphite.

Electrochemical synthesis of graphene oxide (GO) is known to occur with potential oscillations, but the structural changes underlying these oscillations have remained unclear. In situ time-resolved synchrotron radiation X-ray diffraction demonstrates that the electrochemical synthesis of GO in aqueous H2SO4 can be described as an oscillating reaction. The transformation from graphite to GO proceeds through periodic structural oscillations that correlate with potential cycles. Stage-1 graphite intercalation compound (GIC) is found only at the peak of the potential cycle, but not at the bottom of the cycle. Stage-1 GIC is formed in the first half-cycle from stage-2 GIC and then transforms into "pristine graphite oxide" (PGO) on the lower side of the potential cycle, after which the cycle restarts with the formation of a new portion of stage-1 GIC. Water-washing results in the transformation of PGO into water-swollen GO with d(001) ~11 Å. These periodic structural changes can be considered a new type of oscillating reaction. The presented results provide broad insights into the oscillating structural changes occurring during the anodic graphite oxidation in aqueous H2SO4 and allow to update of the mechanism of GO electrochemical formation.

Oscillating Structural Transformations in the Electrochemical Synthesis of Graphene Oxide from Graphite

AbstractElectrochemical synthesis of graphene oxide (GO) is known to occur with potential oscillations, but the structural changes underlying these oscillations have remained unclear. In situ time‐resolved synchrotron radiation X‐ray diffraction demonstrates that the electrochemical synthesis of GO in aqueous H2SO4 can be described as an oscillating reaction. The transformation from graphite to GO proceeds through periodic structural oscillations that correlate with potential cycles. Stage‐1 graphite intercalation compound (GIC) is found only at the peak of the potential cycle, but not at the bottom of the cycle. Stage‐1 GIC is formed in the first half‐cycle from stage‐2 GIC and then transforms into “pristine graphite oxide” (PGO) on the lower side of the potential cycle, after which the cycle restarts with the formation of a new portion of stage‐1 GIC. Water‐washing results in the transformation of PGO into water‐swollen GO with d(001) ~11 Å. These periodic structural changes can be considered a new type of oscillating reaction. The presented results provide broad insights into the oscillating structural changes occurring during the anodic graphite oxidation in aqueous H2SO4 and allow to update of the mechanism of GO electrochemical formation.

Research Progress on the Effect and Mechanism of Superchilling Preservation Technology on Meat Quality Control.

During storage and transportation, meat is susceptible to the effects of microorganisms, endogenous enzymes, and oxygen, leading to issues such as moisture loss, spoilage, and deterioration. Superchilling, as a preservation method that combines the benefits of refrigeration and freezing, can effectively slow the growth and reproduction of microorganisms, control protein and lipid oxidation, reduce water loss, and maintain the quality and sensory properties of meat. This paper reviews the current application status of superchilling technology in meat preservation, focusing on the mechanisms of ice crystal formation, water retention, tenderness preservation, protein and fat oxidation control, and microbial growth inhibition under superchilling conditions. Additionally, it summarizes the research progress on the combined application of superchilling with emerging technologies such as electric fields, magnetic fields, and electron beams in meat preservation and explores its potential and future prospects for improving meat quality. The aim is to provide scientific evidence and technical support for the application of superchilling technology in enhancing meat quality.

Domestic violence and depression among Chinese adolescents: The role of self-evaluation.

Depression of adolescents seriously affects their mental health as well as the formation and development of sound personality. According to Family Systems Theory, individuals' mental health is closely related with external (e.g. domestic violence) and internal factor (e.g. self-evaluation). The formation mechanism of depression needs deep investigation in order to provide better educational intervention for students and promote their healthy development. The study examined the relationship among domestic violence, depression, and self-evaluation. The data were collected from 1,011 Chinese adolescents (Mage = 12.04 ± 1.71) by the questionnaire of Family Violence Scale, Depression Questionnaire, and Rosenberg Self Esteem Scale. We found domestic violence and depression were significantly positively correlated (r = .25, p < .001); self-evaluation was significantly negatively correlated with domestic violence (r = -.26, p < .001) and depression (r = -.50, p < .001). Moreover, domestic violence could directly and positively predict depressed psychology, and could also indirectly predict depressed psychology through the mediating effect of self-evaluation. The level of depression of adolescents was closely related with domestic violence and self-evaluation. And self-evaluation played a mediating role between domestic violence and self-evaluation.

Ultralean Combustion Mechanism of Methane–Air Swirling Premixed Flame

ABSTRACT This study investigated a methane – air premixed flame in a partially tapered swirl burner. Experimentally, we succeeded in forming almost steady ultralean flames with an equivalence ratio as lean as 0.465. On the other hand, a numerical simulation of the flame with detailed chemistry revealed that the flame head existed in a large recirculation zone under ultralean conditions. In addition, high-value peaks of temperature, heat-release rate (HRR), and concentrations of OH, O, and H radicals were formed at the flame head, enabling ultralean combustion. Subsequently, to identify the formation mechanism of these peaks, adiabatic swirl burner flames were simulated with and without the effect of thermal-diffusive imbalance (a Lewis number effect). The results show that a Lewis number of less than unity caused a temperature increase in the flame located in the recirculation zone owing to the thermal-diffusive imbalance, which increased the peak heights of the HRR and the three radicals. The results also showed that even in a flame unaffected by thermal-diffusive imbalance, the backward convective transport could accumulate CO and OH at the flame head thus enhancing the chemical reactions at the head. (185 words)

Fluid Modernity and Virtual Communities: An Analysis of the Popularity of MBTI on Social Media

This paper, rooted in Zygmunt Baumans theory of modernity, examines the formation of virtual communities and the characteristics of liquid modernity as manifested in the widespread phenomenon of Myers-Briggs Type Indicator (MBTI) on social media. As a psychological assessment tool, MBTI has pervaded social media platforms, engendering virtual communities characterized by high fluidity and consumerist tendencies. Through participatory observation and online ethnography, this study delves into the MBTI virtual communities on the "Xiaohongshu" platform, exploring their consumerism-driven formation mechanisms and cultural attributes. In modern society, virtual communities exhibit dynamic stability and structural elasticity, with identity constantly being reshaped and redefined within these virtual spaces. The popularity of MBTI underscores the anxieties surrounding identity in contemporary society and reflects the liquid nature of modern identity formation. Under the influence of technology and consumerism, virtual communities have emerged as a significant social form in modern society.

Local Strain-Dependent Etching Patterns of Chemical Vapor Deposited Molybdenum Disulfide.

This study reveals a local strain-dependent etching behavior that enables the formation of distinguished etching patterns in differently strained chemical vapor deposited (CVD) 2D molybdenum disulfide (MoS2) monolayers. It is demonstrated that when the local tensile strain of CVD 2D MoS2 is as uniformly low as ɛ ≈ 0.33% or less, the oxidative etching pattern possesses conventional triangular etching pits (TEPs), while when the local tensile strain is as uniformly high as ɛ ≈ 0.55% or larger, the oxidative etching pattern consist of uniformly oriented hexagonal etching channels (HECs). More interestingly, when the CVD 2D MoS2 monolayer has heterogenous strain distribution from ɛ ≈ 0.55% (center region) to ɛ ≈ 0.33% (perimeter region), the oxidative etching pattern comprise of non-uniformly hexagonal-mixed-parallel etching channels (HPECs). The further characterization and analysis reveal the formation mechanism of such strain-dependent etching patterns is built on the local strain-related fractures propagation under oxidative etching, as well as the anisotropy fractures-based oxidative etching kinetics. This study may enhance the understanding of the relationship between etching and growth features of 2D TMDs, and paves the way to etching-nanostructured (or defect) engineering of 2D TMDs and other 2D materials for potential applications in electrocatalysis and optoelectronics.

Mechanisms of Reservoir Space Preservation in Ultra-Deep Shales: Insights from the Ordovician–Silurian Wufeng–Longmaxi Formation, Eastern Sichuan Basin

This study aims to explore the reservoir characteristics and formation mechanisms of ultra-deep shale gas in the Ordovician–Silurian Wufeng–Longmaxi Formation in the Sichuan Basin in order to provide theoretical support and practical guidance for the exploration and development of ultra-deep shale gas. With recent breakthroughs in ultra-deep shale gas exploration, understanding its organic matter development, mineral composition, and reservoir space characteristics has become particularly important. The background of this research lies in the significant potential of ultra-deep shale gas, which remains inadequately understood, necessitating an in-depth analysis of its pore structure and reservoir quality. Through a systematic study of the ultra-deep shale in well FS1 of Sichuan Basin, that the following was found: (i) The ultra-deep shale in the Wufeng–Longmaxi Formation is mainly composed of quartz and clay minerals, exhibiting high total organic carbon (TOC) and high porosity characteristics, indicating it is in an overmature thermal evolution stage. (ii) Organic pores and microcracks in the ultra-deep shale are more developed compared to middle-shallow and deep shale, forming a complex pore structure that is conducive to gas storage. (iii) In the diagenesis process, the dissolution and recrystallization of the biogenic skeleton promote the cementation between autogenetic quartz particles, forming a rigid skeleton that effectively inhibits the impact of mechanical compaction. (iv) The overpressure environment created by the hydrocarbon generation process, along with gas production from hydrocarbon cracking, can effectively offset the mechanical compaction of overburden pressure on micropores, and this overpressure environment also promotes the further development of microfractures, which is beneficial for the development and preservation of ultra-deep shale pores. In summary, this study not only reveals the reservoir characteristics and formation mechanisms of ultra-deep shale but also provides essential references for the exploration and development of ultra-deep shale gas in the Sichuan Basin and similar regions, emphasizing the ongoing significance of research in this field.

Coal‐wall spalling prevention mechanism using advance‐grooving pressure relief in the large‐mining‐height working face of a shallow coal seam

AbstractIn mining, the roof structure of a working face with a large mining height in a shallow‐buried coal seam is prone to cutting instability in front of the support, which causes support crushing and coal‐wall spalling. This study analyzes 2201 working faces with large mining heights in the Haiwan No. 3 Mine by investigating the mechanical response law of coal walls under the transient excitation of roof structure instability. A mechanical model of coal walls under dynamic and static load coupling is established, revealing the formation mechanism of coal wall spalling and its main influencing factors. Prevention and control technologies of advanced grooving and pressure relief are proposed, and grooving parameters are determined. The results show that: During the mining process of large mining height working face in shallow buried coal seam, the step change of static response of coal wall is induced by the transient instability of roof structure, and the high abutment pressure is formed on the coal wall. At the same time, the strain energy and gravitational potential energy of roof cutting instability are released to form a dynamic load. Under the action of dynamic and static load, the plastic failure dissipation power of the coal wall is greater than the critical power, and the coal wall spalling occurs. The main influencing factors are mining load, mining height, and internal friction angle of the coal wall. The method of advanced grooving pressure relief can change the roof structure and coal force mechanism, by cutting off the connection between the coal wall and immediate roof, reducing the height of the coal wall force, effectively controlling the position of the roof cut off break line, reducing the static load effect of the roof on the coal, and transferring the position of the dynamic load response to the depth of the coal wall. When the grooving height‐depth ratio k is 0.75, the peak value of the abutment pressure moves 5.57 m to the front of the working face, and the pressure relief effect is the best. The above research results provide an effective active protection method for controlling coal wall spalling in fully mechanised working face with large mining height.

CY GNSS significant wave height inversion model based on multivariate machine learning

The Cyclone Global Navigation Satellite System (CYGNSS) provides high-quality Global Navigation Satellite System Reflectometry (GNSS-R) data, which can be reliably used for the inversion of Significant Wave Height (SWH). Due to the high dynamics of CYGNSS, the received signal is easily affected by environmental factors, and the complexity of the sea conditions makes it difficult for simple models to accurately invert SWH. In order to solve the above problems, this paper proposes a multivariate SWH inversion model based on machine learning. According to the formation mechanism of waves and the correlation analysis between CYGNSS parameters and SWH, relevant parameters are selected, and three training schemes of 5 parameters, 9 parameters and 17 parameters are designed. Subsequently, the inversion model was trained and validated using Random Forest (RF) and Convolutional Neural Network (CNN), and the SWH inversion results were compared with the reference values of the European Centre for Medium-range Weather Forecasts (ECMWF). The best inversion model was the 17-parameter CNN inversion model with an RMSE of = 0.1840 m.

Transcriptomic Analysis Reveals the Mechanism of Color Formation in the Peel of an Evergreen Pomegranate Cultivar 'Danruo No.1' During Fruit Development.

Pomegranate (Punica granatum L.) is an ancient fruit crop that has been cultivated worldwide and is known for its attractive appearance and functional metabolites. Fruit color is an important index of fruit quality, but the color formation pattern in the peel of evergreen pomegranate and the relevant molecular mechanism is still unknown. In this study, the contents of pigments including anthocyanins, carotenoids, and chlorophyll in the peel of 'Danruo No. 1' pomegranate fruit during three developmental stages were measured, and RNA-seq was conducted to screen key genes regulating fruit color formation. The results show that pomegranate fruit turned from green to red during development, with a dramatic increase in a* value, indicating redness and anthocyanins concentration, and a decrease of chlorophyll content. Moreover, carotenoids exhibited a decrease-increase accumulation pattern. Through RNA-seq, totals of 30, 18, and 17 structural genes related to anthocyanin biosynthesis, carotenoid biosynthesis and chlorophyll metabolism were identified from differentially expressed genes (DEGs), respectively. Transcription factors (TFs) such as MYB, bHLH, WRKY and AP2/ERF were identified as key candidates regulating pigment metabolism by K-means analysis and weighted gene co-expression network analysis (WGCNA). The results provide an insight into the theory of peel color formation in evergreen pomegranate fruit.

Mechanisms of memory-supporting neuronal dynamics in hippocampal area CA3.

Hippocampal CA3 is central to memory formation and retrieval. Although various network mechanisms have been proposed, direct evidence is lacking. Using intracellular Vm recordings and optogenetic manipulations in behaving mice, we found that CA3 place-field activity is produced by a symmetric form of behavioral timescale synaptic plasticity (BTSP) at recurrent synapses among CA3 pyramidal neurons but not at synapses from the dentate gyrus (DG). Additional manipulations revealed that excitatory input from the entorhinal cortex (EC) but not the DG was required to update place cell activity based on the animal's movement. These data were captured by a computational model that used BTSP and an external updating input to produce attractor dynamics under online learning conditions. Theoretical analyses further highlight the superior memory storage capacity of such networks, especially when dealing with correlated input patterns. This evidence elucidates the cellular and circuit mechanisms of learning and memory formation in the hippocampus.

Antisolvent controls the shape and size of anisotropic lead halide perovskite nanocrystals

Colloidal lead halide perovskite nanocrystals have potential for lighting applications due to their optical properties. Precise control of the nanocrystal dimensions and composition is a prerequisite for establishing practical applications. However, the rapid nature of their synthesis precludes a detailed understanding of the synthetic pathways, thereby limiting the optimisation. Here, we deduce the formation mechanisms of anisotropic lead halide perovskite nanocrystals, 1D nanorods and 2D nanoplatelets, by combining in situ X-ray scattering and photoluminescence spectroscopy. In both cases, emissive prolate nanoclusters form when the two precursor solutions are mixed. The ensuing antisolvent addition induces the divergent anisotropy: The intermediate nanoclusters are driven into a dense hexagonal mesophase, fusing to form nanorods. Contrastingly, nanoplatelets grow freely dispersed from dissolving nanoclusters, stacking subsequently in lamellar superstructures. Shape and size control of the nanocrystals are determined primarily by the antisolvent’s dipole moment and Hansen hydrogen bonding parameter. Exploiting the interplay of antisolvent and organic ligands could enable more complex nanocrystal geometries in the future.

Fully charmed tetraquarks from LHC to FCC: natural stability from fragmentation

We investigate the inclusive production of fully charmed tetraquarks, T4c(0++)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$T_{4c}(0^{++})$$\\end{document} or T4c(2++)\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$T_{4c}(2^{++})$$\\end{document} radial excitations, in high-energy proton collisions. We build our study upon the collinear fragmentation of a single parton in a variable-flavor number scheme, suited to describe the tetraquark formation mechanism from moderate to large transverse-momentum regimes. To this extent, we derive a novel set of DGLAP-evolving collinear fragmentation functions, named TQ4Q1.0 determinations. They encode initial-scale inputs corresponding to both gluon and heavy-quark fragmentation channels, defined within the context of quark-potential and spin-physics inspired models, respectively. We work within the NLL/NLO+\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$\\hbox {NLO}^+$$\\end{document} hybrid factorization and make use of the JETHAD numeric interface along with the symJETHAD symbolic calculation plugin. With these tools, we provide predictions for high-energy observables sensitive to T4c\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$T_{4c}$$\\end{document} plus jet emissions at center-of-mass energies ranging from 14 TeV at the LHC to the 100 TeV nominal energy of the FCC.

Formation mechanism and oil-bearing properties of gravity flow sand body of Chang 63 sub-member of Yanchang Formation in Huaqing area, Ordos Basin

Abstract Gravity flow sand body is an important reservoir for deep water deposition. The in-depth study of its formation mechanism and oil enrichment law can provide important guidance for oil and gas exploration in deep water areas. In this article, taking the deep-water gravity flow sand body of the Triassic Chang 63 sub-member in the Huaqing area as an example, the identification characteristics, formation mechanism, and oil-bearing characteristics of the gravity flow sand body are systematically discussed. The results show that sandy debris flow, turbidite flow, and mixed event flow present different superposition combination modes on vertical gravity flow deposition. The lithofacies of the gravity flow sandstone complex are mainly affected by lake level fluctuation, provenance supply, and hydrodynamic conditions. According to the formation conditions, sedimentary types. and distribution characteristics of deep water gravity flow sand bodies, a three-dimensional sedimentary mode of deep water gravity flow sand bodies is established. It is found that the physical and oil-bearing properties of the sandy debris flow sand body are better than those of the turbidity flow sand body. The reason is that the proportion of debris in the sand body of sandy debris flow is high, and the content of debris particles is generally greater than 70% according to the statistics of thin sections, which is conducive to the formation of pores. Second, sandy debris flow belongs to block transport, and the mixing of lithology is not sufficient in the process of block flow transport, so some pores will be preserved. Finally, gravity flows, which are dense at the beginning, become less dense later as detrital sediments unload, allowing them to be transported to distant regions. Therefore, the monolayer thickness of the sandy debris flow sand body is large (generally greater than 0.5 m), and the particle size of the debris ranges from 0.03 to 0.3 mm. Finally, the physical and oil-bearing properties of the sandy clastic flow sand body are better than those of the turbidity flow sand body.

Complexion-induced Cu2+ coordinated phase separation PBI membrane for lithium metal batteries

The uncontrolled dendritic lithium production issues and the highly reactive behavior of lithium with electrolytes has limited use of lithium metal batteries. Herein, we utilized a straightforward method of the Complexion-Induced Phase Separation (CIPS) to fabricate a Cu2+ coordinated polybenzimidazole (PBI) membrane for a lithium metal battery. CIPS offer improved control over the structure and composition of the membrane, potentially leading to improved selectivity in ion transport, enhancing the safety and longevity of the battery. The formation mechanism and influencing elements of PBI-Cu are analyzed through experimental analysis and density functional theory calculations (DFT). The PBI-Cu membrane is effective in facilitating reversible lithium stripping and plating processes, suppressing dendrite formation, and promoting stable long-term cycling. Notably, the PBI-Cu cell demonstrated stable cycling conditions for over 200 h at a very high current density of 4 mA cm−2. The impressive rate performance was also confirmed during Li//LiFePO4 full cell operation, where it maintained a stable capacity of 120 mAh g−1 for more than 300 cycles. This research provides an in-depth insight into membrane design and paves the way for its application in various other energy-related technologies.