Permittivity Measurements Research Articles

Interfacial polarization-driven relaxation in CuO epitaxial thin films

In this manuscript, we examine the electrical behavior of pulse laser deposition grown epitaxial (111) oriented CuO thin films using impedance spectroscopy to understand the microscopic origin of their relaxor-like characteristics. Temperature (T) dependent variation of the real part of dielectric permittivity (ε′) shows a relaxor ferroelectric-like anomaly with Vogel–Fulcher relation fitting well with the observed dielectric behavior, and thus, pointing toward a relaxor ferroelectric nature of the CuO thin film. However, the loss tangent and frequency-dependent dielectric spectroscopy measurements suggest the need to further explore the different mechanisms to understand the origin of observed relaxor behavior. Deconvolution of the impedance spectra reveals that interfacial contributions dominate in the dielectric response. Moreover, deconvoluted capacitances are temperature-independent within the specified temperature range, thereby excluding the possibility of a ferroelectric transition suggested by ε′ vs T data. The DC bias measurement of dielectric permittivity and I–V measurements reveal the MW (Maxwell–Wagner) nature of the observed dielectric anomaly. The measurements also suggest interface-limited Schottky conduction as the predominant conduction mechanism in the CuO thin films. This work demonstrates that the apparent relaxor behavior observed in the CuO thin film is related to extrinsic, i.e., interfacial polarization effect, instead of the intrinsic ferroelectric nature of the material.

Automated non-destructive 3D printing filament material properties monitoring based on electric permittivity, longitudinal encoding and diameter multi-axes real-time measurements

Rapid prototyping is an essential part of today’s research and development process. The ability to produce objects quickly, cost-effectively and on-site is critical to meeting this fundamental requirement. One of the factors that leads to inconsistencies and defects in the produced parts is the uncompensated change in material properties used in the material extrusion 3D printing manufacturing process. This creates the need for a real-time, low-cost filament quality monitor that can characterize the material properties of the filament along its length. This can be achieved by tracking the variation in measured capacitive tube capacitance and diameter of different sensor types over multiple selected axes and encoding the results to a specific fragment of filament used in material extrusion 3D printing. With such collected data it is possible to monitor factors such as material moisture, roundness, internal and external defects, component proportions, relative electrical permeability, Poisson’s ratio and material type. This work presents the first proof of concept of such a device and describes its operating principle in detail. As examples of applications, filament material type recognition is presented based on the characteristics of several types of filaments from different manufacturers, the process of moisture absorption over time for selected filaments is described, and the detection of defects of varying degrees is shown.

Trunk dielectric permittivity correlates with irrigation based on soil water content in fruit trees

Time-domain reflectometry (TDR) is an electromagnetic technique that measures the dielectric permittivity (K) which is a surrogate property influenced by water content. Advances in nanoelectronics have enabled the development of a TDR probe (TDR-305 N) to monitor changes in K, bulk electrical conductivity (ECbulk) and temperature (T) in a porous medium, such as a tree trunk. The main objective of this study was to assess the effectiveness of the TDR-305 N sensors for real-time monitoring changes in water content in the trunk of nectarine trees. Throughout the summer of 2022, irrigation was automatically managed with threshold values of soil water content (θv-soil) measured with capacitance probes. Different management allowed depletion (MAD) values were set to trigger irrigation: 50 % in July (moderate water deficit), 100 % in August (severe water deficit), and recovery to well-irrigated conditions in September. Discrete measurements of midday stem water potential (Ψs,md) and leaf gas exchange were made frequently. The results showed a progressive reduction of the measured physiological parameters, as well as of K and ECbulk and θv-soil decreased. Notably, Ψs,md reached a critically low value of -2.03 MPa, coinciding with pronounced and severe stomatal closure. Both K and Ψs,md, were able to explain the variations of θv-soil by more than 75 %. Daily, a positive relationship of K and ECbulk was observed, although ECbulk exhibited a stronger dependence on Ttrunk compared to K. Furthermore, K did not return to its initial values prior to the onset of water stress, possibly influenced by xylem cavitation and a reduction in leaf area during its senescence stage. The findings suggest that trunk permittivity measurements obtained using TDR-305 N sensors could be a reliable indicator for monitoring tree water status. However, further research is needed to determine the threshold values of trunk water content under non-limiting soil water conditions for accurate irrigation scheduling.

Dielectric Characterization of Ex-Vivo Breast Tissues: Differentiation of Tumor Types through Permittivity Measurements.

Early analysis and diagnosis of breast tumors is essential for either quickly launching a treatment or for seeing the evolution of patients who, for instance, have already undergone chemotherapy treatment. Once tissues are excised, histological analysis is the most frequent tool used to characterize benign or malignant tumors. Dielectric microwave spectroscopy makes use of an open-ended coaxial probe in the 1-8 GHz frequency range to quickly identify the type of tumor (ductal carcinoma, lobular carcinoma, mucinous carcinoma and fibroadenoma). The experiment was undertaken with data from 70 patients who had already undergone chemotherapy treatment, which helped to electrically map the histological tissues with their electric permittivity. Thus, the variations in the permittivity of different types of tumors reveal distinctive patterns: benign tumors have permittivity values lower than 35, while malignant ones range between 40 and 60. For example, at a frequency of 2 GHz, the measured permittivity was 45.6 for ductal carcinoma, 33.1 for lobular carcinoma, 59.5 for mucinous carcinoma, and 27.6 for benign tumors. This differentiation remains consistent in a frequency range of 1 to 4.5 GHz. These results highlight the effectiveness of these measurements in the classification of breast tumors, providing a valuable tool for quick and accurate diagnosis and effective treatment.

Permittivity and Concentration Measurements Based on Coplanar Waveguide and Split Ring Resonator Sensor

Permittivity and Concentration Measurements Based on Coplanar Waveguide and Split Ring Resonator Sensor

Dielectric Behavior of Stretchable Silicone Rubber–Barium Titanate Composites

In this study, elastomer composites, including silicone rubber and barium titanate, were fabricated by mechanical mixing, a low-cost, fast, and easy technique to produce highly dielectric materials. The resulting composites were investigated in terms of their dielectric and mechanical properties in terms of filler percentage in the mixture. Dielectric permittivity measurements were taken using the microwave regime, and uniaxial tensile tests were carried out for the study of the materials’ mechanical properties, while combined experiments were also carried out to investigate potential correlations between them. The experimental results show that barium titanate inclusions in silicone matrix significantly improve the dielectric constant while reducing the mechanical properties of composites. In addition, combined experiments show that the composites exhibit a nearly stable dielectric profile under mechanical deformations. Consequently, mechanically mixed barium titanate–silicone elastomer composites could potentially become a cost-effective alternative in the extensive market for insulating materials and flexible electronics.

Solid Permittivity Measurement Sensor Based With IDE-ELC Substrate Integrated Waveguide Resonator

Solid Permittivity Measurement Sensor Based With IDE-ELC Substrate Integrated Waveguide Resonator

Measuring dielectric and electro-optic responses of thin films using plasmonic devices.

This paper introduces a simple method for the measurement of the relative permittivity and the Pockels coefficient of electro-optic (EO) materials in a waveguide up to sub-THz frequencies. By miniaturizing the device and making use of plasmonics, the complexities of traditional methods are mitigated. This work elaborates the fabrication tolerance and simplicity of the method, and highlights its applicability to various materials, substrates and configurations. The method is showcased using drop-casted perovskite barium titanate (BaTiO3, BTO) nano-particle thin-films and it has previously been used to measure epitaxial thin film BTO. In this work we show the effective relative permittivity of drop casted BTO to be εeff ∼ 30 at 200 MHz, dropping to ∼ 18 at 67 GHz and similarly, the effective Pockels coefficient was found to be reff ∼ 16 at 350 MHz and ∼ 8 at 70 GHz. These values are a factor > 50 below the values found for thin film BTO. Yet, the fact that the method can be applied to such different samples and Pockels strengths gives testimony to its versatility and sensitivity.

Microwave dielectric characterization studies of PVDF-TrFE-Nafion blended films

The solution-based casting method fabricates the free-standing pure PVDF-TrFE, PVDF-TrFE-Nafion blended films and tests them for structural, morphological, and microwave studies. The X-ray diffraction pattern and FTIR spectrum confirmed the formation of the ferroelectric β-phase of PVDF-TrFE. The surface morphology of blended films is studied by scanning electron microscope (SEM), and noticeable changes in the morphological features are observed in the blended films resulting from the differences in the nucleation process in these films. Then using the open-ended coaxial probe method, the complex permittivity measurements were carried out over a large frequency range, from 0.5 GHz to 50 GHz. These results were verified with the Transmission-Reflection method using a rectangular waveguide in the X-band and Ku-band frequency range. The microwave absorption properties of the blends are also studied in the same frequency range. The stability of the dielectric properties and low microwave absorption indicates that the blending of PVDF-TrFE with Nafion results in a new potential material for high frequency flexible capacitor applications.

High-Precision Complex Permittivity Measurement of High Loss Dielectric Materials Using a Geometrical Gap in Millimeter Wave Frequency

High-Precision Complex Permittivity Measurement of High Loss Dielectric Materials Using a Geometrical Gap in Millimeter Wave Frequency

Self-Calibration Technique and Permittivity Measurement Using a Slotted Rectangular Waveguide

Self-Calibration Technique and Permittivity Measurement Using a Slotted Rectangular Waveguide

Measurement of Complex Permittivity in 0.11–0.27 THz With a Novel Multichannel-Coupled Open Resonator

Measurement of Complex Permittivity in 0.11–0.27 THz With a Novel Multichannel-Coupled Open Resonator

In Vivo Measurements of Murine Melanoma's Complex Permittivity between 500 MHz – 8.5 GHz

<i>In Vivo</i> Measurements of Murine Melanoma's Complex Permittivity between 500 MHz – 8.5 GHz

Observation of ferroelectric behaviour in non-symmetrical cholesterol-based bent-shaped dimers.

Non-symmetrical cholesterol-based dimers have emerged as crucial materials in the field of liquid crystal research, owing to their remarkable ability to stabilize various exotic mesophases, including the blue phases (BPIII, BPII, BPI), cholesteric nematic (N*) phase, smectic blue phase (SmBP), twist grain boundary (TGB) phase, smectic A/smectic A* (SmA/SmA*) phase, and smectic C/smectic C* (SmC/SmC*) phase. These mesophases have garnered considerable attention due to their diverse applications in spatial light modulation, chiro-optical devices, optical switching, thermochromic materials, and more. In this study, we present the synthesis and comprehensive characterization of a series of non-symmetrical cholesterol-based bent-shaped dimers (1/12, 1/14, 1/16) in which the cholesterol unit is intricately linked to an aromatic mesogenic core through a flexible spacer. These novel materials exhibit the intriguing ability to stabilize a variety of mesophases, including the N*, TGBA, SmA, and SmC* phases. The chiro-optical properties of the helical SmC* phase have been meticulously investigated through temperature-dependent chiro-optical measurements, shedding light on their potential for advanced optoelectronic applications. Additionally, we have conducted a thorough examination of the physical characteristics of these cholesterol-based dimers, including static permittivity measurements, dielectric spectroscopy, and electro-optical performance analysis. Remarkably, two homologues (1/14, 1/16) exhibit negative dielectric anisotropy, a crucial parameter for liquid crystal devices. Furthermore, our investigation reveals that these materials exhibit ferroelectric behaviour in the SmC* phase, with compounds 1/14 and 1/16 demonstrating substantial spontaneous polarization (PS) values of approximately 132 nC cm-2 and 149 nC cm-2, respectively. These findings underscore the potential of non-symmetrical cholesterol-based dimers as versatile components for the development of innovative electro-optical devices.

In Situ Wide-Range Permittivity Measurement: Compact, Cost-Effective, and Highly Sensitive Sensor Using Reconfigurable Phase Shifter

In Situ Wide-Range Permittivity Measurement: Compact, Cost-Effective, and Highly Sensitive Sensor Using Reconfigurable Phase Shifter

Multiband Permittivity Measurement of Metallized-Bulk Substrate With Negative Group Delay-Based Ring Resonator

Multiband Permittivity Measurement of Metallized-Bulk Substrate With Negative Group Delay-Based Ring Resonator

Relative Permittivity Measurement of Sea and Land by Ground-Based Dual Circularly Polarized GNSS-Reflectometry

Relative Permittivity Measurement of Sea and Land by Ground-Based Dual Circularly Polarized GNSS-Reflectometry

Multiband Permittivity Measurement Using Directional Coupler Based on Groove–Ridge-Gap Waveguide

Multiband Permittivity Measurement Using Directional Coupler Based on Groove–Ridge-Gap Waveguide

Estimation of buried pipe depth in an artificial soil tank using ground-penetrating radar and moisture sensor

A method is required for accurate determination of the location (horizontal position and depth) of subsurface utilities with minimal digging. Ground-penetrating radars (GPRs) have been used at many sites as a nondestructive method for detecting underground structures. Previous studies have examined the accuracy and resolution of GPRs based on comparisons of exploration images and factors such as soil, pipe material, and environmental conditions. Although numerous studies have explored the influence of relative permittivity and water content on GPR surveys, only a limited number have conducted direct measurements of water content using a moisture sensor within a soil tank and applied this data to enhance the precision of depth estimation. In this study, the effects of pipe material, relative permittivity, and antenna frequency on the depth estimation accuracy were quantitatively investigated using an artificial soil tank made of silica sand with known physical properties. In addition to the GPR survey, relative permittivity measurements were conducted using time-domain reflectometry (TDR) sensors located at different water levels. The results show that the antenna frequency and pipe material affect the resolution but not the depth estimation accuracy. Furthermore, the GPR survey using the relative permittivity from the TDR sensors estimated the pipe depths with a relative error of <7.33% relative to the actual burial depth under the following conditions: a volumetric water content of 2.6–38.2%, the relative permittivity of 2.9–23.2, and buried pipes of 0.1 m in diameter and 1.5 m in depth. The study findings show that the selection of an appropriate frequency and the estimation of soil permittivity using a moisture sensor can improve the depth estimation accuracy of buried pipes by GPR survey.

Thermal Effect of Microwave Radiation on Dactylopius opuntiae in Morocco and Coaxial Probe for Permittivity Measurements

Thermal Effect of Microwave Radiation on <i>Dactylopius opuntiae</i> in Morocco and Coaxial Probe for Permittivity Measurements