Mean Concentrations Of Metals Research Articles

Elemental and Ecological Health Risk Assessment of Wastewater and Soils Collected During the Wet Season at Selected Industrial Sites in Kano Nigeria

In this study, the elemental analysis of soils and effluents collected from selected manufacturing industries in Kano metropolis of Nigeria West Africa for the wet season of 2020 has been carried out using standard analytical methods, Analar grade reagents and approved calibrated equipment. All samples were analyzed in triplicates and the outcome values are presented as mean concentration in mg/kg. The mean concentration of heavy metals evaluated such as Co, Cd, Cr, Zn, Mn, Fe, Ni and Pb show mixed levels (excessive, moderate and normal levels) when compared to the recommended levels by NESREA. Contamination factor (CF) and contamination degree (Cd) was determined for investigated elements in all 58 samples. CF for Ni, Pb, Fe, Mn and Zn were all ˂ 1, implying no potential ecological risk contamination. Enrichment factor (EF) was calculated to determine anthropogenic input of metals in all the samples investigated. High enrichment factor for samples MW, MS, ADS, FS, PPS, MW, DW, PPW, MyW, DFS, DS, AS, LZS, 7upW, and DFW (67.2 % of the samples), The mean concentration of the metals is an indication of pollution was tested with a high implication outcome most likely, when samples are continuously emptied into the environment untreated. Safe to remind us that heavy metals are toxic with excessive human health risks.

Heavy metal status in cocoa (Theobroma cacao L.) soils and beans: the case of Abuakwa North Municipality of Eastern Region, Ghana.

In recent times, public concerns over the potential accumulation of heavy metals in agricultural soils and crops due to the excessive use of agrochemicals are increasing. This study was conducted in the Abuakwa North Municipality of Eastern Region, Ghana, to assess the status of heavy metals in cocoa soils and beans. Cocoa farms aged between 10 and 20years and have received agrochemicals for at least 5years were selected, and their adjacent forests were used as controls. Soil samples and cocoa pods were collected randomly and processed for laboratory analysis. The study discovered that across the sampling sites, heavy metal concentrations in soil were below permissible limits. However, contamination factor and geo-accumulation index results revealed that Tontro cocoa farms were considerably contaminated and moderately polluted respectively with Cu, probably due to long-term fungicide application. The concentrations of Fe (39.3-47.1mgkg-1) and Zn (54.8-70.0mgkg-1) in the cocoa beans across the communities were below the FAO/WHO's safe limit of 99.4mgkg-1 and 73.0mgkg-1 respectively. Lead (0.03-0.06mgkg-1) and Cd (0.12-0.20mgkg-1) concentrations were below the EU's maximum allowable level and Codex Alimentarius Commission's limit of 1.0mgkg-1 respectively. However, bean Cu content in the Tontro farm (51.5mgkg-1) was slightly above the EU's recommended maximum limit of 50.0mgkg-1, possibly due to the continuous application of copper-based fungicides. The study showed that, overall, agrochemicals used for cocoa farming in Abuakwa North Municipality of Ghana did not cause serious harm to the soils and beans, since the mean metal concentrations were not alarming and guarantee public health safety.

Physicochemical Parameters of Ground Water Quality in Crown Estate and Its Environs in Okada Town, Edo State, Nigeria

The evaluation of drinking water quality mainly by determination of some physicochemical parameters present is of paramount importance due to the impact on human health. The present study presents investigation on the physicochemical parameters of ground water samples collected from selected boreholes, in Crown Estate and environs, in Okada, Benin City, Nigeria. Samples were collected from selected boreholes and pH taken and immediately taken to the laboratory to investigate some selected physicochemical characteristics. The mean concentrations of metals in the water samples followed a decreasing order: Zn (0.5122mg/l) > Fe (0.4378mg/l) > Mn (0.0594mg/l) > Ni (0.0358mg/l) > Cr (0.0302mg/l) > Cu (0.3000mg/l), Pb and Cd were below detection limit. The laboratory results of all the selected physico-chemical parameters analyzed when compared with the world health organization (WHO), National Agency for Food and Drug Administration Control (NAFDAC) and Nigerian Standards for Drinking Water Quality (NSDWQ) standards for water showed that all the selected Physicochemical parameters with the exception of iron (for NAFDAC) were within national and international standards limits for drinking water.

Bioaccumulation and sources of metal(loid)s in fish species from a subtropical river in Bangladesh: a public health concern.

Toxic metals and freshwater fish's metalloid contamination are significant environmental concerns for overall public health. However, the bioaccumulation and sources of metal(loids) in freshwater fishes from Bangladesh still remain unknown. Thus, the As, Pb, Cd, and Cr concentrations in various freshwater fish species from the Rupsha River basin were measured, including Tenualosa ilisha, Gudusia chapra, Otolithoides pama, Setipinna phasa, Mystus vittatus, Glossogobius giuris, and Pseudeutropius atherinoides. An atomic absorption spectrophotometer was used to determine metal concentrations. The mean concentrations of metal(loids) in the fish muscle (mg/kg) were found to be As (1.53) > Pb (1.25) > Cr (0.51) > Cd (0.39) in summer and As (1.72) > Pb (1.51) > Cr (0.65) > Cd (0.49) in winter. The analyzed fish species had considerably different metal(loid) concentrations with seasonal variation, and the distribution of the metals (loids) was consistent with the normal distribution. The demersal species, M. vittatus, displayed the highest bio-accumulative value over the summer. However, in both seasons, none of the species were bio-accumulative. According to multivariate statistical findings, the research area's potential sources of metal(loid) were anthropogenic activities linked to geogenic processes. Estimated daily intake, target hazard quotient (THQ), and carcinogenic risk (CR) were used to assess the influence of the risk on human health. The consumers' THQs values were < 1, indicating that there were no non-carcinogenic concerns for local consumers. Both categories of customers had CRs that fell below the permissible range of 1E - 6 to 1E - 4, meaning they were not at any increased risk of developing cancer. The children's group was more vulnerable to both carcinogenic and non-carcinogenic hazards. Therefore, the entry of metal(loids) must be regulated, and appropriate laws must be used by policymakers.

Pollution and Ecological Risk Assessment of Metal Elements in Groundwater in the Ibinur Lake Basin of NW China

Groundwater pollution by metal elements is a serious issue due to its probable risks to the ecosystem and human health. In the present study, 75 groundwater samples were collected from the Ibinur Lake Basin (ILB) of NW China. The contents of As, Se, Pb, Cu, Cr(Ⅵ), Zn, Mn, and Cd were determined. The levels, pollution degrees, and potential ecological risks of metals in groundwater were systematically analyzed for the first time in this area. The potential sources of metals were also discussed. It was observed that the mean contents of metals in groundwater in the ILB were lower than the Class III thresholds of the Standard for Groundwater Quality of China (GB/T 14848–2017), whereas the maximum contents of As, Se, Pb, Cr(Ⅵ), and Mn exceeded the Class III thresholds values. The pollution index of each metal and the Nemerow comprehensive index (NPI) caused by the overall pollution by all these metals in groundwater showed the pollution-free level. The single and comprehensive potential ecological risk index of analyzed metals in groundwater showed a relatively low level of potential ecological risk. Additionally, spatial distribution patterns of contents, pollution levels, and ecological risks of metals in groundwater in the ILB were found to be substantially heterogeneous. Furthermore, As and Se in groundwater originated from anthropogenic sources such as agriculture and mining, whereas Mn mainly originated from natural factors, and Pb, Cu, Cr(Ⅵ), Zn, and Cd were correlated with both natural and anthropogenic sources. Overall, As was identified as the main pollution factor, while As and Se were identified as the main ecological risk factors in the groundwater in the ILB. These results can provide important information for groundwater management in the ILB and will guide authorities in taking the necessary measures to ensure the safety of groundwater supply in the northwestern arid regions of China.

United States Grown and Imported Rice on Sale in Las Vegas: Metal(loid)s Composition and Geographic Origin Discrimination.

Concentrations of metal(loid)s, Ag, Al, As, Cd, Co, Cr, Cu, Fe, Mn, Ni, Se, Sr, V and Zn, were determined in rice on sale in Las Vegas. The rice samples were grown in five different countries, the USA, Thailand, India, Pakistan, and Bangladesh. The elemental concentrations in rice grain were determined using inductively coupled plasma mass spectrometry (ICP-MS) following hot block-assisted digestion. The accuracy of the laboratory procedure was verified by the analysis of rice flour standard reference material (NIST SRM 1568b). The mean metal(loid) contents in rice of various geographic origins were 3.18-5.91 mg kg-1 for Al, 0.05-0.12 mg kg-1 for As, 3.64-41 μg kg-1 for Cd, 5.11-12 μg kg-1 for Co, 0.12-0.14 mg kg-1 for Cr, 1.5-1.91 mg kg-1 for Cu, 3.04-4.98 mg kg-1 for Fe, 4.2-10.4 mg kg-1 for Mn, 0.21-0.41 mg kg-1 for Ni, 0.02-0.07 mg kg-1 for Se, 0.68-0.88 mg kg-1 for Sr, 3.64-5.26 μg kg-1 for V, and 16.6-19.9 mg kg-1 for Zn. respectively. The mean concentration of As in US rice was significantly higher than in Indian, Pakistani, and Bangladeshi rice. On the other hand, it was found a significantly low mean level of Cd in US-grown rice. It was also found that the concentrations of metal(loid)s in black and brown rice on sale in Las Vegas were statistically similar, except for Mn and Se. The geographic origin traceability of rice grain involved the use of ICP-MS analysis coupled with chemometrics that allowed their differentiation based on the rice metal(loid) profile, thus confirming their origins. Data were processed by linear discriminant analysis, and US and Thai rice samples were cross-validated with higher accuracy (100%). This authentication quickly discriminates US rice from the other regions and adds verifiable food safety measures for consumers.

Health risk assessment of heavy metals in PM2.5 and PM10 in Sarajevo air, Bosnia and Herzegovina

The concentrations of eight heavy metals (Cd, Cr, Cu, Fe, Mn, Ni, Pb and Zn) associated with PM2.5 and PM10 in Sarajevo air, Bosnia and Herzegovina (BiH) have been studied. A total of 136 PM2.5 and PM10 samples were simultaneously collected from 21 February to 11 November 2020. Metal contents were determined by atomic absorption spectrometry, flame (FAAS) and electrothermal (ETAAS) techniques. The mean concentrations of metals in PM10 are 2.93 ng/m3 (Cd), 7.21 ng/m3 (Cr), 12.02 ng/m3 (Cu), 126 ng/m3 (Fe), 20.74 ng/m3 (Mn), 6.98 ng/m3 (Ni), 8.74 ng/m3 (Pb) and 128 ng/m3 (Zn). In PM2.5 samples the mean concentrations of Cd, Cr, Cu, Fe, Mn, Ni and Zn are 0.39, 4.06, 2.26, 110, 0.63, 1.93 and 5.28 ng/m3, respectively. Pb was not detected in PM2.5 samples. Strong correlation was obtained for metal pairs Mn-Cu in PM10 and moderate for Ni-Fe in PM2.5. The health risk assessment shows that the adult population of Sarajevo is at increased lifetime risk of experiencing cancer because of exposure to Cd concentrations in PM10.

ASSESSMENT OF HEAVY METAL POLLUTION AND CONTAMINATION IN WASTE DUMPSITES WITHIN GUSAU AREA, NORTHWEST NIGERIA

The aims of this research work are to determine the concentrations of metals present in waste dump soils, to evaluate the metal contamination of the soils using the pollution indices and to identify whether the sources of heavy metals were natural and/or anthropogenic. Analysis of the soil was carried out using EDXRF technique. Three points were assessed from each three wastes dumpsites (Hira Dekodi, Low Cost and Old Market), using portable XRF equipment for the in-situ data acquisition. The data obtained were subjected to statistical analysis and environmental pollution index models. The data showed mean concentrations of the heavy metals analyzed in the following order Fe &gt; Zn &gt; Mn &gt; Cr &gt; Pb &gt; Ni. The mean concentrations of these three metals (Pb, Zn and Cu) exceeded their average crustal abundance, which is an indication of possible contamination. Environmental pollution models applied to the geochemical dataset revealed Zn, Pb and Cu as considerable/moderately contaminated, which generally indicated severe potential contamination in the investigated area. Other metals such as Mn, Cr, Ni and Fe showed low contamination factors. However, from the results of geo-accumulation/ecological risk index of the heavy metals, the study areas were unpolluted and indicated low ecological risk factors with respect to the analyzed parameters. The chemical assay revealed positive and significant relationship between Cu, Pb, Mn and Fe while Cr showed positive and significant relationship with Mn, Fe and Cu. However, Zn shows significant level of relationship only to Mn. Virtually, all the heavy metals showed...

Cadmium, Nickel and Zinc Concentration in Some Common Fruits Samples Collected from Different Super Shops Located in Dhaka City and Probable Health Risk Assessment

Heavy metals concentration in fruits samples collected from different super shops were determined by using Atomic Absorption Spectrophotometry and potential health risk from the consumption of these fruits was estimated. Mean concentration of Cd, Ni and Zn in the studied fruits samples (Fuji Apple, Green Apple, Red Grape, Green Grape, Pear, Malta and Pomegranate) were within the range of 0.00 to 0.15, 0.17 to 10.78, 3.44 to 19.88 mg/kg for Agora; 0.00 to 0.20, 0.00 to 42.75, 3.20 to 13.40 mg/ kg for Meena Bazaar and 0.00 to 0.15, 0.60 to 18.65, 4.31 to 17.68 mg/kg of dry weight, for Swapno, respectively. Cadmium concentration was the highest in Fuji Apple and Red Grape (0.15 mg/kg) samples, which was higher than MAC value by FAO/ WHO, collected from Swapno. The highest Nickel concentration (42.75 mg/kg) was found in Green Grape, collected from Meena Bazaar, which was 53.44 times higher than MAC value according to FAO/WHO. Mean concentration of metals were found above the maximum allowable limit in most of the fruits though mean Average Daily Intake (ADI) values were below the PMTDI value for all fruits. The Hazard Quotient (HQ) and Hazard Index (HI) values for all metals were below 1.00 which signifies that these fruits were not carcenogenic but continuous consumption of some of high metals containing fruits sold in the market is imposing threat to food security

The use of marine sponge species as a bioindicator to monitor metal pollution in Red Sea, Saudi Arabia

The existing data on trace elements of benthic sea organisms is scarce. Yet, the pressing issue of environmental contamination has spurred a surge in the use of organisms as biomonitors. In this study, sediment cores were sampled with the sponges, and metal concentrations were determined in both samples using ICP-MS. The mean concentrations of metals in benthic sediments and sponge species analyzed in this study differed significantly (Sediment >Phorbas species > Negombata magnifica > Callyspongia species > Amphimedon chloros). This could be due to the varying capacity of each sponge species to accumulate a particular metal by different means. Negombata magnifica and Phorbas species appear to be indicators, accumulators, or hyper-accumulators of Cu and Mn, while Callyspongia species is an indicator, accumulator, or hyper-accumulator of Cu only due to bioconcentration factor > 1 for the aforementioned metals. Concentrations of Cu and As in sediment were below the Effects Range Median but above the Effects Range Low threshold, hence the need to give more attention to these metals. This research provides a baseline dataset for designing monitoring strategies on this ecosystem and using sponge species for biomonitoring.

Microplastic pollution and heavy metal risk assessment in Perca fluviatilis from Anzali wetland: Implications for environmental health and human consumption

The worldwide increase of anthropogenic contaminants in aquatic ecosystems has raised concerns, particularly heavy metals and microplastics (MPs), posing potential health risks for aquatic organisms. Therefore, this study aimed to investigate the presence of heavy metals (Cu, Ni, Pb, Cd, Hg, Zn, Mn, As, V, Co, Cr, Fe, and Se) and MPs in the muscle, liver, and gills of Perca fluviatilis Linnaeus 1758 from Anzali Wetland during the autumn-winter 2021 and spring-summer 2022 periods. The mean concentration of metals in the muscle was lower than that in the liver and gills. The highest level of metal in the liver, gills, and muscle was related to Fe (4.049 ± 1.192, 3.605 ± 0.878, and 3.459 ± 0.895 μg/g, respectively), while the lowest concentration in the muscle was related to Co (0.011 ± 0.004 μg/g), and in the liver and gills was related to Se (0.013 ± 0.004 and 0.012 ± 0.003 μg/g, respectively) and As (0.013 ± 0.004 and 0.012 ± 0.004 μg/g, respectively). The concentration of metals in summer was higher than in other seasons. The Hazard Index (HI) and Target Hazard Quotient (THQ) values below 1 indicate that consuming this fish does not pose any risk to consumers in terms of metal contamination. Moreover, MPs were identified in the gills of all fish, while no MPs were found in the muscle and liver. The mean number of MPs in the gills was 3.5 ± 1.02 item/individual, and the number of MPs in spring (4.6 ± 0.84 item/individual) was higher than in autumn, winter and summer (4.2 ± 1.22, 3 ± 1.63, and 2.4 ± 0.51 item/individual, respectively). The MPs were dominated by fiber in shape, black in color, 300–1000 μm in size, and nylon in polymer. No significant correlation was found between metal concentrations and MPs, except for Co.

Potential health risk assessment of selected metal concentrations of Indian backwater oyster, (Crassostrea madrasensis) in Sri Lanka

The study was conducted to assess the health risks of selected metals in cultured and wild Crassostrea madrasensis in Sri Lanka over 13 months. Metal concentrations varied monthly, and Zn and Cu concentrations significantly varied between cultured and wild oysters. The mean metal concentrations (mg kg−1) were accumulated in order of Zn (1220.60) > Mg (496.97) > Fe (356.30) > Cu (114.95) > Pb (23.20) > Cd (6.15) > As (3.09) > Hg (0.12). The metal concentrations were well below the standard guidelines given by international standards except for Pb, Cd, As and Zn. The weekly intakes of Hg, Cu, Fe, and Zn from C.madrasensis were below the Provisional Tolerable Weekly Intake while Cd exceeded the established limit. The calculated non-carcinogenic and carcinogenic risk indices for Hg, As, Pb and Zn were within safe levels and the values for Cd exceeded the limit revealing carcinogenic results with long-term consumption. Hence, creating proper awareness and a suitable depuration system ensures human health and supports export-oriented markets.

Spatial and temporal distribution of geochemical elements and their processes in different size fractions–Miri River (NW Borneo)

The toxicity, persistence, and propensity for accumulation of metals in aquatic environments have raised significant concerns globally. Expansion of urbanization with the growth of industrial and agricultural sectors in Miri City results in a high concentration of pollutants that flow directly into the Miri River. Hence, this study provides a comprehensive analysis of the Miri River water quality, focusing on spatial and temporal variations. River water samples were collected in two different time periods and analysed for physico-chemical parameters includes major ions, nutrients, metals and isotopes. Particularly, the metals were analysed in different size fractions (particulate and colloid) of the suspended solids. Geochemical plots, pollution index, geochemical modelling and factor analysis were used for the data analysis. Interpretation of data reveals that the mean concentration of metals in river water were increased from downstream to the upstream of the river irrespective of the seasons. Major ions were mostly derived from the chemical weathering of source rocks, which was supported by the Gibbs plot. Piper plot indicates the seasonal shifting of water types from Ca–Mg to Na–Cl. Isotopic signatures reveal direct atmospheric precipitation and evaporation were the major origins of river water. Fe was the dominant metal concentration in river water irrespective of the seasons (mean concentration 1.05 mg/L). Fe and Zn were the dominant metal concentration observed in all the 3 size fractions of suspended solids. Industrial activities and seawater influx dominate in the downstream, whereas weathering and agricultural inputs are significant in the upstream of the river. Particulate and colloidal fractions are the major contributors for the metal transport in the midstream and downstream of the river. The outcome of this study offer a thorough understanding of the seasonal elemental distribution at different size fractions, geochemical behaviour and the pollution status of the Miri River. With this knowledge, sustainable management strategies can be developed for this crucial water resource to the benefit of Miri community.

Distribution and toxicological risk assessment of metals in commercial fish species from a lentic ecosystem in Nigeria

Background of StudyThe increasing exposure of lentic water bodies to pollutants and the ability of aquatic organisms to bioaccumulate heavy metals in its edible body parts has raised concerns on the food safety of aquatic animals harvested from them. This study investigated the distribution of metals in the organs of C. gariepinus and T. zillii from Ikpoba reservoir and evaluated the potential human health risk associated with their consumption. MethodologyFish samples of Clarias gariepinus and Tilapia zillii were collected for a period of six months (January 2019 to June 2019) from Ikpoba reservoir using a drag net with the assistance of artisanal fishermen. Fish samples were properly identified and heavy metal content in the gills, liver and muscles were determined using atomic absorption spectrophotometer. FindingsThe results showed that C. gariepinus had higher mean concentration of metals and metalloids than T. zillii in all the organs examined. The order of accumulation of metals in the gills and muscles of C. gariepinus and T. zillii was Fe > Zn > Mg > Cu > Pb > Cd, while order in the liver for both fish species was Fe > Zn > Cu > Mg > Pb > Cd. Human health risk assessment for metals in C. gariepinus and T. zillii indicated no significant health risk to the adults (HI < 1), whereas children were predisposed to health risk of non-carcinogenic effect (HI > 1). Carcinogenic risk values for Pb and Cd in adults and children did not exceed the acceptable carcinogenic risk value for humans. The integrated carcinogenic risk (ICR) values classified the consumption of C. gariepinus and T. zillii as low – medium risk (Grade III). ConclusionThe study has shown that the consumption of the selected fish species is not safe for children. Also, the consumption of the gills of C. gariepinus along with the head portion of the fish should be discouraged to reduce exposure to heavy metal toxicity. The continuous monitoring of activities within the reservoir watershed to mitigate heavy metal pollution of the reservoir is recommended.

Determination of some heavy metal concentrations in water and sediment of River Gidin Dorowa, at Gidin Dorowa, Taraba, North Eastern Nigeria

This study examined some heavy metal concentrations in water and sediment of River Gidin Dorowa, Taraba, North Eastern, Nigeria. It was examined with atomic absorption spectrophometer (AAS) buck scientific model 210 VGP. Mean concentrations of metals in water and sediment showed significant (p&lt; 0.05) during the study period between September, 2022 to February, 2023. Samples were collected upstream and downstream at River Gidin Dorowa. Higher mean value (0.3087 mg/l) was reported for lead (Pb) in October compare to other metals with lower value (0.1647 mg/l) recorded in November. Zinc (Zn) recorded higher value (0.1334 mg/l) in September. Cadmium (Cd) recorded higher value (0.0170 mg/l) in September and lower value (0.0027 mg/l) in February. Heavy metals in sediment showed variation (p&lt;0.05) between metal during the study. Cadmium recorded higher value (0.0154 mg/kg) in December and lower value (0.0087 mg/kg) in January. Lead (Pb) value (0.6380 mg/kg) was higher in January while lower value (0.3707 mg/kg) were observed in October and November. Zinc (Zn) recorded a higher mean value (1.6667 mg/kg) in October. Copper value showed higher variation (0.4000 mg/kg) in October and lower value (0.2667 mg/kg) in February. Monthly variation between water and sediment during the study period showed higher variation (0.3910 mg/kg) for Lead (Pb) in the sediment and water value (0.2880 mg/l) in September. Copper (Cu) value (0.1000 mg/l) in water was lower than values in the sediment. Mean Cadmium value for water (0.0027 mg/l) and value (0.0100mg/kg) in sediment showed variations (p&lt;0.05) in February from other metals considered. The levels of Zn, Cu, and Cd in water and sediment at Gidin Dorowa for this study were generally low compared to safe limits recommended by WHO and USEPA except values of Lead (Pb) in water. Therefore, routine monitoring of the heavy metals’ concentrations in water and sediments of River Gidin Dorowa should be sustained.

A spatiotemporal study on contamination and bioaccumulation of heavy metals in sediment and cyprinid fish (Capoeta razii) from Telar River, Iran

The concentrations of heavy metals (Cr, Cd, Ni, and Pb) were investigated in sediment and cyprinid fish (Capoeta razii) from Telar River, Iran in spring, summer, and autumn. Mean concentration of metals in fish and sediment over the seasonal sampling was as follows: Cr > Ni > Pb > Cd. Metal deposition in sediment was higher than their bioaccumulation in fish tissue. Unlike sedimentary metals, the tissue-content of Pb and Cr varied seasonally. Enrichment Factor (EF) values of Cr and Ni showed partial enrichment, implicating the role of anthropogenic inputs, while Pb was derived from natural weathering. When considering Pollution Load Index (PLI), an uneven temporal and spatial distribution of contamination was observed in sediment with moderate contamination level in spring and summer and no pollution in autumn. Tissue-contents of Pb, Cr, and Cd were below permissible limits while a higher risk level of Ni was noted for human consumption.

Monitoring the spatial distribution patternaccording to urban land use and health risk assessment on potential toxic metal contamination via street dust in Ankara, Türkiye.

The urbanization processes with growing vehicle numbers cause heavy metal pollution in street dust, and high populations in metropolitan cities are exposed to pollutants. This paper aims to monitor the spatial distribution of heavy metals and evaluate the concentrations via health risk assessment of HMs (Cu, Ni, Cd, Co, Pb, and Zn) that expose the inhabitants to health hazards. According to the results of the current study, sixty street dust samples were applied to the acid digestion technique and quantification by inductively coupled plasma-mass spectrometry (ICP-MS). The spatial distribution of the selected heavy metals in the street dust was investigated using the spatial analysis tool in ArcGIS 10.0 according to population density and land use. In the present study, we used hazard index and cancer risk methods to estimate the public health risk of the pollutants exposed to street dust in Ankara. The concentrations range of the elements in street dust over the study area ranged from 3.34-4.50, 31.69-42.87, 16.09-21.54, 42.85-57.55, 0.00-3.51, and 23.03-30.79, respectively. The overall decreasing order of mean concentration of metals was observed as follows: Pb > Cu > Ni > Co > Cd > Zn. Vehicle traffic and industrial activities seem to be the most critical anthropogenic sources responsible for dust pollution in the study area. The risk assessment of Pb and Ni exposure was the highest, and the hazard index values were 2.42E + 00 and 2.28E + 00 mg/kg/day for children. However, the effect on adults was 2.62E-01 and 2.37E-02 mg/kg/day, followed by inhalation and dermal contact with street dust was almost negligible. The decreasing concentration is modeled spatially along the western development corridor of the city. The risk to public health is high in areas with high densities close to the city center and the main artery.

Evaluation of metal pollution related to human health risk in freshwater snail Viviparus contectus (Millet, 1813) as a potential bioindicator species in Lake Habitat (Turkey).

Freshwater mollusks are employed as bioindicators for the assessment of water quality in biomonitoring studies since the water quality of natural resources is crucial for humans. The freshwater snail species known as Viviparus contectus (Viviparidae: Gastropoda) is one that people eat. Here, the levels of heavy metals (Cd, Cr, Pb, As, Zn, and Cu) in water and V. contectus samples were determined. An Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES, Spectro Arcos, vertical plasma) was used for the analysing the heavy metal concentrations in water and freshwater snail samples. The results of the current investigation demonstrated that freshwater snails accumulated metals in their water and soft tissues in the following orders: Pb > Cr = Zn = Cu = Cd = As and Zn > Cu > Pb > Cd > As = Cr. Autumn was the time of year when higher amounts of heavy metals (As, Cr, Cu, Zn, and Hg) were found. Pb content in the freshwater snail samples was strongly impacted by seasonal fluctuations (P 0.05). For adults, the EDI (estimated daily intake) values were lower than the TDI (tolerable daily intake) values, and the HI (hazard index) values were below 1. Freshwater snail samples had Zn and Pb levels that were over the FAO/WHO, Turkish Food Codex, JECFA, and EC limit values. Except for Pb, the water study shows mean metal concentrations below the USEPA, Turkish Pollution Control Regulation, and World Health Organisation maximum allowed levels. Aquatic ecosystems were negatively impacted by anthropogenic activities overall, and this study can provide a helpful data set for investigations on metallic contamination in water bodies and biomonitoring in freshwater ecosystems.

Urbanization-driven soil degradation; ecological risks and human health implications.

Urban soils contaminated with heavy metals and pesticide residues are of great concern because of their adverse impact on human health. A total of 66 agricultural topsoil samples (15cm) were collected to represent the study area and determine how anthropogenic activities adversely affect soil quality and human health. Sampling was conducted in the summer, when it was dry and hot, and in the winter, after atmospheric deposition. Seventeen potentially hazardous metals/metalloids (Ag, As, Al, B, Ba, Cd, Cr, Cu, Fe, Hg, Mn, Ni, Mo, Pb, Se, Zn, and V) were measured in the soils. The mean concentrations of metals ranged between 0.05 and 8080mg/kg, and their distribution was site-specific, with high pollution at the sampling sites owing to proximity to human activities. In agricultural areas, the greatest arsenic concentration was recorded at 48mg/kg. The potential ecological risk index (PERI) and health hazard index (HI) were calculated, as well as metal contamination indices including contamination factor (Cf), geo-accumulation index (Igeo), and pollution load index (PLI). The mean PLI was calculated to be 4.89, indicating that the area is highly polluted. The potential ecological risk index showed remarkably high risks for As, Cd, and Hg, and moderate risks for Ni and Pb. The arsenic hazard index (HI) was greater than one (2.41) in children, indicating a risk of exposure through ingestion. Pesticide residue analyses were performed in areas where the metal intensity was high. Banned or restricted organochlorine pesticide (OCPs) residues, including, dieldrin, endrin ketone, endosulfan I, II, heptachlor, heptachlor epoxide, lindane (γ-HCH), PP-DDD, and methoxychlor, were detected between 0.002 and 1.45mg/kg in the soil samples.

Investigating the phytoavailability of metals in roots of Croton macrostachyus and Phytolacca dodecandra: induced rhizosphere processes.

Medicinal plants are key component of complementary and alternative medicine, and constitute the first therapeutic strategy for majority of the global population, particularly in developing nations. Croton macrostachyus and Phytolacca dodecandra are among such plants, widely used to treat various diseases. The present study aimed at investigating the elemental composition of both plant root samples collected from four districts in the Central Gondar Zone, Northwest Ethiopia. An optimized wet-digestion procedure was applied with 0.5g of root sample using HNO3: HCl: H2O2 (v/v) in the ratio of 8:2:1 at 240°C for 3:00h (for P. dodecandra), and 5:2:2 at 300°C for 3:00h (for C. macrostachyus). Then, concentrations of metals in the digested samples were determined using a flame atomic absorption spectrophotometer; and the validity of the optimized procedure was evaluated by spiking experiments. Results showed good accuracy and repeatability of the methods with percent of recoveries ranging from 85 to 103%. The mean concentrations of metals in C. macrostachyus root samples were higher than their P. dodecandra counterparts, and the distribution of metals showed the following decreasing order: Mg > Ca ≈ Fe > Mn > Zn > Cu > Cr. One-way ANOVA revealed no significant differences (p > 0.05) between the mean concentrations of the same metals in both plant root samples, except for Mg and Cr. Correlation matrix, principal component and cluster analyses suggested that accumulation of metals in the root samples originated from both natural and anthropogenic sources. In conclusion, the roots of both medicinal plants contained substantial amounts of metals, thereby serving as valuable sources of essential elements.