Mean Concentrations Of Chromium Research Articles

Evaluating Heavy Metals in Human Breast Milk: a Cross-Sectional Study from Mining and Agricultural Areas in Northwestern Iran.

This study aimed to assess the levels of heavy metals in the breast milk of women residing in the mining and agricultural areas of East Azerbaijan province in Iran. This cross-sectional study analyzed 68 lactating mothers from mining (n = 28) and agricultural (n = 40) areas of East Azerbaijan province in Iran between June 2022 and March 2023. The study used an Inductively Coupled Plasma Optical Emission Spectroscopy (ICP-OES) to measure the concentrations of heavy metals, including arsenic (As), chromium (Cr), copper (Cu), and iron (Fe). A semi-quantitative food frequency questionnaire (SQ-FFQ) was used to collect data on the dietary and sociodemographic characteristics of the mothers. Although the concentration of arsenic (As) was below the limit of detection (LOD), the mean concentrations of chromium (Cr), copper (Cu), and iron (Fe) were 1.11, 0.87, and 13.25mg/L in agricultural areas and 0.83, 0.93, and 11.35mg/L in mining areas, respectively. The concentrations of Cr (p < 0.001) and Fe (p = 0.019) were significantly higher in the breast milk of women residing in agricultural areas. However, the concentration of Cu was significantly higher (p = 0.085) in the breast milk of women living in mining areas. Additionally, lactation age had a significant effect on Cu levels (p = 0.015), with a negative coefficient of -0.011. The study indicates that the levels of heavy metals in breast milk can be influenced by the exposure to pesticides, fertilizers, volcanic soil, and disparities in access to post-natal care and iron supplements.

Concentration and Ecological Risk Assessments of Potentially Toxic Elements in Soils around Lapite Dump Site, Akinyele Local Government Area, Ibadan, Nigeria

The contamination and ecological risk posed by Potentially Toxic Elements (PTEs) on soils around Lapite dumpsite and its environs were assessed using different analytical techniques after complete digestion of the soil using mixed acids. Results showed that the mean concentration of chromium (Cr), cadmium (Cd), and lead (Pb) (153.2mg/kg, 13.83mg/kg, 137.2mg/kg and respectively) have higher concentrations than their crustal abundance (CA). The enrichment factor analysis revealed that most of the soils collected have been enriched with Pb showing the most enrichment at the upper and middle slopes while Cd is the most enriched at the downslope. The contamination factor showed that Cr, Pb and Cd are also the elements showing significant contamination with Cr and Pb moderately contaminating soil (1.54 and 1.62 respectively) and Cd showing very high contamination in the soil (17.3). The ecological risk indices revealed that only Cd has high risk of polluting the soils (519) of the study area while the whole area is considered to be at a high risk of various degrees of pollution (534). Considering the health implications of these concerned elements (Cr, Pb and especially Cd) to the body, the habitants of the study area are advised to move away from these dumpsite and also relocate their farmlands to more environmental friendly sites.

Health Risk Assessment of Heavy Metals in Lettuce and Spring Onion on Human Health in Kumasi, Ghana.

The demand and consumption of vegetables are significantly increasing worldwide, which has resulted in urban farming on anthropogenic sites. This study assessed the concentrations of some selected heavy metals in lettuce and spring onion in line with the WHO/FAO required standard and its implications on human health. The study was carried out in Kumasi, within moist semi-deciduous forest vegetation, Ghana. The digested samples were analyzed for heavy metals (Cu, Cr, Fe, Mg, Ni, and Zn) using atomic absorption spectrophotometer (AAS Model AA 400p). Analysis of variance was used to test the level of significance at α = .05. The study found mean concentrations of chromium and iron in lettuce and spring onion to be below detection level (BDL) in all study sites based on WHO/FAO permissible level. Also, while copper in lettuce was BDL at all the sites, there were higher mean concentration of copper in spring onion at BSGS (131.5 ± 0.31 mg/kg) and BSG (120.8 ± 0.01 mg/kg). The mean concentration of nickel in lettuce (137.15 ± 0.0231) and spring onion (173.55 ± 0.02 mg/kg) at BSGS were higher than WHO/FAO permissible level. Mean concentration of zinc in both lettuce and spring onion were higher than WHO/FAO permissible level in all the study sites, except zinc in spring onion at KT. The ANOVA test statistics showed no significant difference among the concentrations of heavy metals in all sites, except zinc in lettuce and nickel in spring onion. The study found cancer risk factor for nickel, which exceeded the benchmark of 1 × 10-6 for both lettuce and spring onion, indicating that long-term consumption could increase the risk of cancer in consumers. The study's findings call for strict regulation and regular monitoring of heavy metals in vegetables cultivated at anthropogenic sites in urban areas to ensure food safety and consumer health.

Elemental concentration of heavy metals in oyster mushrooms grown on mine polluted soils in Pretoria, South Africa

Issues of food security remains a major subject in ensuring sustainable global development and thus the hazardous effects of heavy metals on food substances call for concern due to the threat on human health and food security at large. Pleurotus ostreatus is an edible mushroom species with a promising nutritional and medicinal values. However, P. ostreatus is quite susceptible to heavy metal contamination from either polluted soil, mining or other anthropogenic activities. Aim at elucidating on the level of contamination and risk associated with the consumption of P. ostreatus from a polluted source, this study examined the amount of heavy metals in the caps and stalks of P. ostreatus grown in a soil sample collected from a mined site. Soil samples were obtained from three different mining areas and P. ostreatus spawns were grown in triplicates on these soils and on unpolluted soil. At maturity, the harvested parts (cap and stalks) were analyzed for heavy metals using Inductively Coupled Plasma Mass Spectrometry (ICP–MS). We found that mean concentration of chromium, manganese, cobalt, nickel, zinc, cadmium, mercury and lead were significantly different (p < 0.05) across the sites. Among the heavy metals investigated, Zn, Cd and Cr topped the permissible values allow for consumption. Though P. ostreatus stalk had higher concentrations of heavy metals than the caps, there was a positive correlation of the metal contents between the two components. The values obtained for the transfer factor pointed to the ability of P. ostreatus to accumulate cobalt, copper, zinc, arsenic, cadmium and lead. Based on hazard quotient (HQ) values obtained for both adults and children, we suggest that there are no possible human carcinogenic risks associated with the consumption of the Oyster mushroom. However, the continuous consumption may result into a serious health hazard owing to the levels of some heavy metals that were above the permissible limit considered safe for human consumption. It can be concluded from the study that P. ostreatus possess the potential to bio-accumulate toxic metals from polluted soils hence we recommend that caution must be taken not to harvest mushroom on polluted soils.

COMPARATIVE ANALYSIS OF SOME HEAVY METALS LEVELS IN LEAVES, PEELS AND TUBERS OF CASSAVA PLANTED ALONG EAST-WEST ROAD RIVERS STATE

Introduction: Pollution of the environment by heavy metals has caused serious environmental problems, which threatens the existence of various ecological system, agriculture and human health. This study assessed the comparative analysis of some heavy metals levels in leaves, peels and tubers of cassava planted along East-West Road Rivers State.&#x0D; Materials/Methods: Cassava leaves and tubers samples were collected from farmlands along East-West road (SX, SY and SZ communities, in Emohua, Tai, and Ahoada West LGA respectively), Rivers state, Nigeria. The samples were monitored for heavy metals levels to assess the impact of automobiles on cassava peels, leaves and tubers using Solar Thermo Elementary Atomic Absorption Spectrometer, ModelSG 71906. Metals studied were Lead (Pb), Nickel (Ni), Chromium (Cr), Cadmium (Cd), and Arsenic (As).&#x0D; Results: The mean concentration of Ni present in leaf was 2.81±0.104 mg/kg, tubers recorded 2.23±0.073 mg/kg and peels 3.20±0.06 mg/kg. The highest concentration (4.064±0.035 mg/kg) of Ni was observed in peels while the least concentration (1.80±1.023 mg/kg) was recorded in the tubers. The mean values of Pb in leaves, tubers and peels were 2.22±1.023 mg/kg, 1.80±1.023 mg/kg and 2.64±0.32, highest concentration was recorded in tubers. Arsenic values were 0.16±0.020 mg/kg &gt; 0.51±0.021 mg/kg &gt; 0.38±0.203 mg/kg in peels, tubers and leaves respectively. The values of As were above WHO safe limit of 0.1mg/kg. Also, the mean values of cadmium in leaves, tubers and peels were 0.054±0.570 mg/kg, 0.046±0.057 mg/kg and 0.16±0.609 mg/kg respectively. The highest concentration (0.138±0.109 mg/kg) was in the tubers. Finally, chromium was found to be present in all the cassava samples (leaves, peels and tubers). The mean concentration of chromium (Cr) was 3.58±0.023 mg/kg, 2.76±0.005 mg/kg and 3.83±0.203 mg/kg in leaves, tubers and peels respectively.&#x0D; Conclusion: From the findings, heavy metals were found in the samples and thus, crops should be cultivated far away from major roads.

Natural enrichment of chromium and nickel in the soil surrounds the karst watershed

BACKGROUND AND OBJECTIVES: As a public concern, monitoring and controlling toxic metals pollution is needed worldwide. Due to the ability of poisonous metals in biomagnification and bioaccumulation, they can cause several adverse impacts on ecological and human health. The study aims to assess chromium and nickel enrichment levels and estimate the soil''s ecological risk surrounds the Pangkajene watershed.METHODS: The total concentrations of chromium and nickel were determined using the Flame Atomic Absorption Spectrophotometer. This study used contamination factor, geo-accumulation index, and pollution load index to evaluate soil enrichment status. The ecological hazard index is used to estimate the potential hazard that may occur due to contamination. FINDINGS: The mean concentrations of chromium and nickel were 92.9 and 43.18 mg/kg, respectively. Chromium concentration exceeded the soil quality guideline for the protection of environment and human health, while Ni still below the standards. The geo-accumulation index value indicated no human-made-derived contamination in the soil. Weathering of carbonate rocks is the chromium and nickel major enrichment factor in the Pangkep regency. Contamination factor and pollution load index values showed low pollution in the studied soil. However, all study sites exceeded the ecological hazard index value (Ecological hazard index>1), which indicates a considerable ecological risk in the Pangkajene watershed area. CONCLUSION: These findings may provide baseline information related to chromium and nickel enrichment in the soil for Pangkep regency municipality. The Pangkep regency municipality must highlight the importance of strengthening environmental standards and monitoring mechanism as the priority to maintain a healthy environment.

Toxic heavy metals and nutrient concentration in the milk of goat herds in two Iranian industrial and non-industrial zones.

This work aimed to explore the concentration of nickel, manganese, iron, copper, chromium, and lead in the milk of goat herds in the industrial area of Asaluyeh (southern Iran) and the non-industrial area of Kaki. The milk of 16 goat herds (each herd had at least ten goats) was collected in several villages in each area, and at the same time, the drinking water and forage of goats were sampled. The concentration of elements in the samples was determined by ICP-OES. The mean concentrations of chromium, copper, iron, manganese, lead, and nickel in milk samples of the Asaluyeh area were 16.423 ± 0.349, 0.146 ± 0.118, 6.111 ± 0.501, 0.239 ± 0.016, 0.141 ± 0.030, and 1.447 ± 0.101 mg/kg, respectively. Concentrations of heavy metals (except for copper) in the milk of goats in the industrialized area of Asaluyeh were significantly higher than that of Kaki (P < 0.05). Also, the content of heavy metals was significantly correlated with lactose levels (P < 0.05). The hazard index for drinking the goat milk was computed to be 0.444 and 0.386 for the Asaluyeh and Kaki area, respectively, which shows a minimal effect of this exposure pathway.

ENVIRONMENTAL IMPACT ASSESSMENT OF HEAVY METALS EFFLUIENT (CHROMIUM &amp; NICKEL) RELEASED INTO ROMI RIVER, KADUNA STATE: A CASE STUDY

Industrial effluents discharged into the river poses a serious threat to our environment; the research examines the impact of some heavy metals of Kaduna refinery effluent into the Romi River. It asserts the nature of effluent released into the water body and also the impact of effluent on water quality. However the important water quality became relatively slowly as early human could only judge water quality through the physical senses of sight, taste and smell, now a days there is an increase of contamination of natural water bodies by industrial effluents in developing and densely populated countries like Nigeria, because rivers are major means of waste disposal and especially effluents from industries nearby. The data used in this research were generated from direct field measurement of pH, Conductivity, and Turbidity, heavy metal profiles (Chromium &amp; Nickel) from Kaduna Refinery Effluent. The mean concentrations of the metals; chromium, iron, nickel, and zinc with the standard deviation were found to be: &lt; 0.01 ± 0.1 mg/kg, and 0.06 ± 0.1 mg/kg. This study has shown that the mean concentration of chromium and Nickel found to be lower than the World Health Organization (WHO) acceptable limits while the concentration values of nickel 0.06 ± 0.1 mg/kg and iron 0.06 ± 0.1 mg/kg as found to be higher than the WHO, acceptable limits of the metals) obtained at the effluent points and this implicate the industry adjacent to the area as one of the sources of heavy metals in the river.

A study on the transfer of chromium from meadows to grazing livestock: an assessment of health risk.

The present investigation was performed in different district of Punjab to determine the chromium level in soil, forages, and blood plasma of the small ruminants (goat and sheep). The results showed that the mean concentrations of chromium in the soil of Sargodha, Mianwali, and Bhakkar districts were ranged from 1.8 to 2.3, 3.01 to 4.99, and 2.04 to 2.87 mg/kg, respectively. The chromium level was higher in Mianwali compared with Sargodha and Bhakkar. The mean concentrations of chromium in forages which were used for feeding purposes were found between 0.672 and 1.631, 1.493 and 2.612, and 0.7804 and 1.047 mg/kg for Sargodha, Mianwali, and Bhakkar, respectively. The mean concentrations of chromium in blood plasma of goat which consumed the contaminated forages were between 0.666 and 1.269 mg/L in Sargodha, 0.657 and 0.752 mg/L in Mianwali, and 1.39 and 2.37 mg/L in Bhakkar. In blood plasma of sheep, the residual levels of chromium in the districts Sargodha, Mianwali, and Bhakkar were ranged from 0.673 to 1.384, 0.83 to 1.086, and 1.496 to 3.611 mg/L, respectively. In the present research, there was a higher concentration of chromium in blood plasma of sheep from Bhakkar and the lowest was in Sargodha. The chromium level in blood samples was found to be higher than the tolerable level of 1.0 mg/L in all districts. In light of these results, it was concluded that chromium levels in the soil and forages of all sites were present within the safe limit while in blood samples of sheep and goats were found to be above the acceptable limit. Sheep and goats also consume water from river, streams, and ponds and other contaminated water sources. So it might be the reason of higher level of chromium in their blood plasma. Hence, the proper monitoring of study sites will be necessary to prevent the excessive accumulation of chromium in ruminants in the near future.

Retracted Human Health Risk of Chromium Intake From Consumption of Poultry Meat and Eggs in Dhaka, Bangladesh.

Background. Heavy metals contamination of food is a serious threat. Long term exposure may lead to human health risks. Poultry and eggs are a major source of protein, but if contaminated by heavy metals, have the potential to lead to detrimental effects on human health.Objectives.The objective of this study is to determine chromium concentrations in poultry meat (flesh and liver) and eggs collected from poultry farms in Dhaka, Bangladesh, to calculate the daily intake of chromium from the consumption of poultry meat and eggs for adults, and to evaluate their potential health risk by calculating the target hazard quotients (THQ).Methods.All samples of poultry feed, meat (flesh and liver) and eggs were analyzed by a graphite furnace atomic absorption spectrometer (AAS) (GFA- EX- 7i Shimadju, Japan).Results.Chromium concentrations were recorded in the range of not detected (ND) to 1.3926±0.0010 mg kg−1 and 0.0678±0.0001 mg kg−1 to 1.3764±0.0009 mg kg−1 in the liver of broiler and layer chickens, respectively. Chromium concentrations were determined in the range of 0.069±1.0004 mgkg−1 to 2.0746±0.0021 mg kg−1 and 0.0362±0.0002 mg kg−1 to 1.2752±0.0014 mg kg−1 in the flesh of broiler and layer chicken, respectively. The mean concentration of chromium in eggs was 0.2174−1.08 mg kg.−1 The highest concentration of chromium 2.4196±0.0019 mg kg−1 was found in egg yolk. Target hazard quotients values in all poultry flesh, liver and eggs samples were less than one, indicating no potential health risks to consumers.Conclusions.The estimated daily intake values of chromium were below the threshold limit. Thus, our results indicate that no adverse health effects are expected as a resultof ingestion of chicken fed with tannery waste.Ethics Approval:This study was approved by the Biosafety, Biosecurity & Ethical Committee of Jahangirnagar University.

Assessment of the level of chromium species in the discharged effluents of Haik and Debre Berhan tanneries in the Amhara Region using ICP-OES and UV-VIS spectrometry

The purpose of this study was to assess the level of chromium species in the discharged effluents of selected tanneries in the Amhara Region; Haik and Debre Berhan tanneries. The level of total chromium, and hexavalent chromium in the discharged effluent of the studied tanneries were determined using the ICP-OES, and UVVis spectrometry, respectively. The level of trivalent chromium species in the samples was then estimated by difference. Recovery results in the range 96.3 to 103.3% verified the applicability of the methods for the determination of the chromium species in the effluent samples. One way ANOVA statistical analysis was used to check whether the results between sampling months were statistically different or not. The mean concentration of Chromium (VI) before and after treatment in the effluent of Haik tannery was 0.618±0.076 and 0.123±0.064 ppm while in the effluent of Debre Berhan tannery, 0.070±0.009 and 0.039±0.005 ppm, respectively. Similarly, the average total chromium concentration before and after treatment in the discharged effluents of Haik and Debre Berhan tannery was 4,772.3±2.4 and 392.7±1.7 ppm, and 512.8±1.1 and 325.0±0.3 ppm, respectively. Although the average levels of chromium species over the sampling times looked not much higher than the permitted levels, some of the results indicated that the factories release effluent which is extremely loaded with chromium species including the most toxic form of chromium (hexavalent chromium). The assessment results in general showed the pollution of the river waters into which the studied tanneries are discharging their effluent.Key Words/Phrases: Debre Berhan tannery, Inductively coupled plasma-optical emission spectrometry, Diphenylcarbazide, Recovery study, Tannery effluent, UV-Visible spectrophotometry

Geochemical distribution of trace metal pollutants in water and sediments of downstream of an urban river

A study was conducted to investigate the trace metal pollution of water and sediments of downstream of Tsurumi River, Yokohama, Japan. Twenty samples of water and sediments were collected from the river starting from Tokyo bay side up to the junction point of the Yagami River. Results show that the mean concentrations of chromium, cupper and nickel in water greatly exceed (>100 times) the surface water standard. The concentration of molybdenum and lead was also higher than standard values while iron and manganese was lower than that of surface water standard. The mean concentration of zinc, cupper, cadmium, lead, chromium, vanadium, bromine and iodine was 381.1, 133.0, 1.0, 40.8, 102.9, 162.0, 71.5 and 10.6 µg/g sediments, respectively and was greatly exceed the average worldwide shale concentrations and average Japanese river sediment values. However, mean concentration of arsenic, nickel and strontium was 11.0, 36.6 and 164.6 µg/g sediments, respectively which was lower than the average shale value. Other analyzed trace metals, including barium, zirconium, rubidium, yttrium, tin, antimony, cesium, lanthanum, cerium, praseodymium and neodymium were detected in river sediments; the concentration of which was close to the Japan's river sediment average values. Pollution load index values of the sites of the studied area ranged from 1.24 to 7.65 which testify that the river sediments are polluted. The PLI value of the area was, however, high (6.53) as the concentration of trace metals like zinc, cupper, cadmium, lead and chromium were very high and were the major pollutants.

LIPID PEROXIDATION IN WORKERS EXPOSED TO HEXAVALENT CHROMIUM

The aim of this study was to investigate whether exposure to hexavalent chromium induces lipid peroxidation in human. This study involved 25 chrome-plating factory workers and a reference group of 28 control subjects. The whole-blood and urinary chromium concentrations were determined by graphite furnace atomic absorption spectrophotometry. Malondialdehyde (MDA), the product of lipid peroxidation, was determined by high-performance liquid chromatography, and the activities of protective enzymes were measured by ultraviolet-visible spectrophotometry. In the chrome-plating workers, the mean concentrations of chromium in blood and urine were 5.98 mug/L and 5.25 mug/ g creatinine, respectively; the mean concentrations of MDA in blood and urine were 1.7 mumol/L and 2.24 mumol/g creatinine. The concentrations of both chromium and MDA in blood and urine were significantly higher in the chromium-exposed workers. The activities of superoxide dismutase (SOD), glutathione peroxidase (GPX), and catalase (CAT) were not markedly different between control and exposed workers. Data suggest that MDA may be used as a biomarker for occupational chromium exposure. Antioxidant enzymic activities are not a suitable marker for chromium exposure.