Bio alternative fuels is the most researched concept due to the exhausting fossils and aggregating pollutants. Fuels of liquid and gaseous types are much in demand due to the high expectations from liquid and gas dependent engines. This report is the first of its kind to establish the effectiveness of the synthesized synergistic composite material of micro and mesoporosity for the simultaneous production of biohydrogen and bioliquid organics from kitchen waste. Optimization of temperature, feed:catalyst ratio, and time of study were studied using AlMCM-41 catalyst. Significant yield of products was obtained at 400 0C, 0.5 g of catalyst and at 40 min period. Core -shell type of composites were synthesized using AlMCM-41 and ZSM-5 zeolite with mesopores and micropores as shell and core respectively. The synthesized materials were characterized using XRD, BET, N2 sorption studies, TPD, SEM and TEM techniques. Composite AlMCM-41/ZSM-5 yielded the highest of 70% GLF and maximum of 26.5% of H2. The synergism was well established and also the catalysts showed remarkable reproducibility.