Rainwater harvesting is a promising tool for supplementing surface water and groundwater to overcome the imbalance between water supply and demand under changing climate conditions. Multi-Criteria Evaluation is one of the well-known methods of decision-making. In this study, the geographical information system (GIS)-based Multi-Criteria Evaluation is used to select the optimum rainwater harvesting sites in Maysan province, Iraq. Fuzzy membership is used for standardization of the criteria, and Fuzzy Gamma overlay for a combination of multi-layers using ArcGIS 10.5. Seven criteria layers, including slope, stream order, soil type, precipitation, evaporation, roads, and the Normalized Difference Vegetation Index (NDVI) are derived to identify rainwater-harvesting catchment. The results determined the optimum sites for water storage within the study area. The resultant potential rainwater harvesting catchment map can be used as a reference to enhance the effectiveness of water management, especially in drought-stricken areas that offer significant potential for sustainable agricultural production in the semi-arid region.